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NZ766525B2 - Fluid catalytic cracking process and apparatus for maximizing light olefin yield and other applications - Google Patents
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NZ766525B2 - Fluid catalytic cracking process and apparatus for maximizing light olefin yield and other applications - Google Patents

Fluid catalytic cracking process and apparatus for maximizing light olefin yield and other applications

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Publication number
NZ766525B2
NZ766525B2 NZ766525A NZ76652517A NZ766525B2 NZ 766525 B2 NZ766525 B2 NZ 766525B2 NZ 766525 A NZ766525 A NZ 766525A NZ 76652517 A NZ76652517 A NZ 76652517A NZ 766525 B2 NZ766525 B2 NZ 766525B2
Authority
NZ
New Zealand
Prior art keywords
particles
reactor
catalyst
feeding
stream
Prior art date
Application number
NZ766525A
Other versions
NZ766525A (en
Inventor
Justin Breckenridge
Liang Chen
Michael Dorsey
Jon A Hood
Peter Loezos
Rama Rao Marri
Hardik Singh
Bryan Tomsula
Original Assignee
Lummus Technology Llc
Filing date
Publication date
Application filed by Lummus Technology Llc filed Critical Lummus Technology Llc
Priority to NZ792307A priority Critical patent/NZ792307B2/en
Publication of NZ766525A publication Critical patent/NZ766525A/en
Publication of NZ766525B2 publication Critical patent/NZ766525B2/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D45/00Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
    • B01D45/04Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by utilising inertia
    • B01D45/06Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by utilising inertia by reversal of direction of flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D45/00Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
    • B01D45/04Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by utilising inertia
    • B01D45/08Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by utilising inertia by impingement against baffle separators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00327Controlling the temperature by direct heat exchange
    • B01J2208/00336Controlling the temperature by direct heat exchange adding a temperature modifying medium to the reactants
    • B01J2208/00353Non-cryogenic fluids
    • B01J2208/00362Liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00327Controlling the temperature by direct heat exchange
    • B01J2208/00336Controlling the temperature by direct heat exchange adding a temperature modifying medium to the reactants
    • B01J2208/0038Solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743Feeding or discharging of solids
    • B01J2208/00752Feeding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743Feeding or discharging of solids
    • B01J2208/00761Discharging
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00991Disengagement zone in fluidised-bed reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
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    • B01J8/005Separating solid material from the gas/liquid stream
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    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
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    • B01J8/0055Separating solid material from the gas/liquid stream using cyclones
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    • B01J8/0065Separating solid material from the gas/liquid stream by impingement against stationary members
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    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
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    • B01J8/1845Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised
    • B01J8/1863Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised followed by a downward movement outside the reactor and subsequently re-entering it
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    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
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    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/26Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
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    • C07ORGANIC CHEMISTRY
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
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    • C07C4/06Catalytic processes
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    • C10G11/14Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G55/00Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process
    • C10G55/02Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only
    • C10G55/06Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one catalytic cracking step

Abstract

Apparatus and processes herein provide for converting hydrocarbon feeds to light olefins and other hydrocarbons. The processes and apparatus include, in some embodiments, feeding a hydrocarbon, a first catalyst and a second catalyst to a reactor, wherein the first catalyst has a smaller average particle size and is less dense than the second catalyst. A first portion of the second catalyst may be recovered as a bottoms product from the reactor, and a cracked hydrocarbon effluent, a second portion of the second catalyst, and the first catalyst may be recovered as an overhead product from the reactor. The second portion of the second catalyst may be separated from the overhead product, providing a first stream comprising the first catalyst and the hydrocarbon effluent and a second stream comprising the separated second catalyst, allowing return of the separated second catalyst in the second stream to the reactor.

Claims (4)

1. A process for the conversion of hydrocarbons, comprising: feeding first particles and second particles to a reactor, wherein the first particles have a smaller average particle size and/or are less dense than the second particles, and wherein the first particles and second particles may independently be catalytic or non-catalytic particles; feeding a hydrocarbon feedstock to the reactor; recovering an overhead product from the reactor comprising a converted hydrocarbon effluent, the second particles, and the first particles; separating the second particles from the overhead product to provide a first stream comprising the first particles and the converted hydrocarbon effluent and a second stream comprising the separated second particles ; returning the separated second particles in the second stream to the reactor; feeding a second hydrocarbon feedstock and a mixture of first particles and second particles to a second reactor; contacting the mixture of first and second particles with the second hydrocarbon feedstock to crack the second hydrocarbon feedstock and form a second reactor effluent comprising lighter hydrocarbons and a mixture of first and second particles; feeding the first stream and the second reactor effluent to a separator to separate the first and second particles from the lighter hydrocarbons and the converted hydrocarbon effluent; and recovering a hydrocarbon product from the separator.
2. The process of claim 1, further comprising recovering a bottoms product from the reactor comprising the second particles.
3. The process of claim 1, wherein the second reactor is a riser reactor.
4. The process of claim 2, further comprising: stripping additional hydrocarbons from the second particles in the reactor and feeding the stripped particles to a regenerator; and feeding the separated first and second particles recovered from the separator to the regenerator.
NZ766525A 2017-09-14 Fluid catalytic cracking process and apparatus for maximizing light olefin yield and other applications NZ766525B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
NZ792307A NZ792307B2 (en) 2017-09-14 Fluid catalytic cracking process and apparatus for maximizing light olefin yield and other applications

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662395707P 2016-09-16 2016-09-16
NZ751807A NZ751807B2 (en) 2016-09-16 2017-09-14 Fluid catalytic cracking process and apparatus for maximizing light olefin yield and other applications

Publications (2)

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NZ766525A NZ766525A (en) 2025-05-30
NZ766525B2 true NZ766525B2 (en) 2025-09-02

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