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NZ774425B2 - Decorative laminate - Google Patents
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NZ774425B2 - Decorative laminate - Google Patents

Decorative laminate

Info

Publication number
NZ774425B2
NZ774425B2 NZ774425A NZ77442519A NZ774425B2 NZ 774425 B2 NZ774425 B2 NZ 774425B2 NZ 774425 A NZ774425 A NZ 774425A NZ 77442519 A NZ77442519 A NZ 77442519A NZ 774425 B2 NZ774425 B2 NZ 774425B2
Authority
NZ
New Zealand
Prior art keywords
particle diameter
filler
decorative laminate
laminate according
decorative
Prior art date
Application number
NZ774425A
Other versions
NZ774425A (en
Inventor
Kazuya Shido
Original Assignee
Aica Kogyo Co Ltd
Filing date
Publication date
Application filed by Aica Kogyo Co Ltd filed Critical Aica Kogyo Co Ltd
Priority claimed from PCT/JP2019/003019 external-priority patent/WO2020054093A1/en
Publication of NZ774425A publication Critical patent/NZ774425A/en
Publication of NZ774425B2 publication Critical patent/NZ774425B2/en

Links

Classifications

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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Abstract

decorative laminate of the present disclosure includes a decorative layer and a core layer. The decorative layer includes a decorative paper and a thermosetting resin. The core layer includes: a fibrous base material; an organic resin component; and an inorganic filler including endothermic metal hydroxide and/or an inorganic substance other than the endothermic metal hydroxide. The inorganic filler includes: a small particle diameter filler having a first average particle diameter; a medium particle diameter filler having a second average particle diameter larger than the first average particle diameter; and a large particle diameter filler having a third average particle diameter larger than the second average particle diameter.

Claims (19)

1. Claim 1. A tive laminate formed by pressing a decorative layer and a core layer together under heat, the decorative layer sing: a decorative paper; and a thermosetting resin, the core layer comprising a prepreg, the prepreg comprising: a fibrous base material; and a slurry comprising: an c resin component; and an inorganic filler comprising: endothermic metal hydroxide; and/or an nic substance other than the endothermic metal hydroxide, the slurry being impregnated into the fibrous base material, an average particle diameter of the inorganic filler being 0.04 µm or more and less than 50 µm, the inorganic filler comprising: a small particle diameter filler having a first e particle diameter; a medium particle diameter filler having a second average particle er larger than the first average particle diameter; and a large particle diameter filler having a third average particle diameter larger than the second average particle diameter, and the first average le diameter of the small particle diameter filler being 0.04 µm or more and less than 4 µm, the second average particle diameter of the medium particle diameter filler being 4 µm or more and less than 12 µm, and the third average particle diameter of the large particle diameter filler being 12 µm or more and less than 50 µm, and n the second average particle diameter of the medium particle er filler and the third average particle er of the large particle diameter filler are arithmetic averages diameters calculated based on particle size distribution, determined as volume distribution and detected by a laser diffraction/scattering method, and wherein the first average particle diameter of the small le diameter filler is obtained by measuring le diameters of 100 particles of the inorganic filler with an electron microscope and averaging out the measured particle diameters.
2. Claim 2. The decorative laminate according to claim 1, wherein a blending ratio of the c resin component to the inorganic filler in the core layer by solid weight is .
3. Claim 3. The decorative laminate according to claim 1 or 2, wherein, as measured ing to JIS B 0601:2013, an arithmetic average ss Wa in a waviness curve in a longitudinal direction is 0.02 to 0.11 µm, and an arithmetic average waviness Wa in a waviness curve in a transverse direction is 0.03 to 0.12 µm.
4. Claim 4. The decorative laminate according to claim 1 or 3, wherein, as measured according to JIS B 0601:2013, a maximum nal height Wt in the waviness curve in the longitudinal direction is 0.1 to 0.8 µm, and a maximum sectional height Wt in the waviness curve in the transverse direction is 0.1 to 1.0 µm.
5. Claim 5. The decorative laminate according to claim 1, wherein a blending mass ratio of the small particle diameter filler to the medium particle diameter filler to the large particle diameter filler in the core layer is 1:0.1-20:0.1-20.
6. Claim 6. The decorative laminate according to claim 1 or 5, wherein the small particle diameter filler is calcium carbonate.
7. Claim 7. The tive laminate according to claim 1, wherein the inorganic substance other than the endothermic metal hydroxide is calcium carbonate or talc.
8. Claim 8. The decorative laminate according to claim 1, wherein the endothermic metal hydroxide is aluminum hydroxide.
9. Claim 9. The decorative laminate according to claim 1 or 2, n a mass per unit area of the inorganic filler contained in the core layer is 441.4 to 5296.9 g/m2.
10. Claim 10. The decorative laminate according to any one of claims 1, 5, and 6, wherein a percentage of the small le diameter filler in the inorganic filler contained in the core layer is 5 to 60% by weight.
11. Claim 11. The decorative laminate ing to claim 1 or 2, wherein a mass per unit area of the organic resin component contained in the core layer is 38.6 to 473.3 g/m2.
12. Claim 12. The decorative te according to any one of claims 1, 2, and 11, wherein the organic resin component ses a thermosetting resin.
13. Claim 13. The decorative laminate according to claim 12, wherein the thermosetting resin comprises a condensation-type thermosetting resin.
14. Claim 14. The decorative laminate according to claim 13, wherein the condensation-type thermosetting resin is at least one selected from among amino-aldehyde resins and phenol-aldehyde resins.
15. Claim 15. The decorative laminate according to any one of claims 1 to 14, the decorative laminate being a non-combustible decorative laminate.
16. Claim 16. The decorative laminate according to claim 1, wherein the fibrous base al comprises an inorganic fiber base material.
17. Claim 17. The decorative laminate according to claim 1 or 16, wherein, as measured by a laser diffraction/scattering-type le size distribution measurement method, volume cumulative particle diameters Dv(10) and Dv(90) of the inorganic filler are 0.2 µm or more and 45.0 µm or less.
18. Claim 18. The decorative laminate according to any one of claims 1, 16, and 17, wherein, as measured by a laser diffraction/scattering-type particle size bution measurement method, a specific surface area of the inorganic filler is 800 to 4000 m2/kg.
19. Claim 19. The decorative laminate according to any one of claims 1 to 18, wherein the fibrous base material is a en fabric which comprises a thermoplastic resin emulsion as a binder component. [
NZ774425A 2019-01-29 Decorative laminate NZ774425B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2018170501 2018-09-12
PCT/JP2019/003019 WO2020054093A1 (en) 2018-09-12 2019-01-29 Decorative laminate

Publications (2)

Publication Number Publication Date
NZ774425A NZ774425A (en) 2024-04-26
NZ774425B2 true NZ774425B2 (en) 2024-07-30

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