SU797540A3 - Insecticide composition - Google Patents

Description

Continuation of the Table All compounds s of Table 1 correspond to the following formula. i About "in JC-O-CH with - e C / X / v- 8 V Typical, example insecticides. Most of the active products (of which more than one compound are included) are: Product 1: a mixture of 1 compound 1 with 4 parts of a compound 2 Product 2: I am 1 part of compounds 1 with a part of a compound 2. Product 3t coupling 2. Product 4: compound 1 Product 5: a mixture of 19 parts of compound 31 from 1 h, compounds 32. Product 6: a mixture of .19 hours, compounds 31 from 1 part of dinonea 32, 19 h, compounds 33 and IV of compound 34. Product 7: mixture IIch, compound 3 with 14 parts of compound 4. Product 8: mixture of compounds .15 (no composition installed). Product 9: mixture 1 4i of compound 39 with 1 hour of dininea 41. Prod. yk 10: a mixture of 19 h of compound 43, 1 h, a compound of 44, 19 h of compound 45, and 1 part of compound 46. Product 11: a mixture of 19 h, connections 43 with 1 h of compound 44. Product 12: a mixture of 19 h. Connected with 1H39 with 1 h of compound 40. Product 13: a mixture of 1 h of compound 19, 9 parts of compound 20, 1 part of compound 21 and 9 parts of a compound 22. Product 14: mixture of 1 part of compounds 23 9 part of compound 24 , 1 part of compound 25 and 9 parts of compound 26. Product 15: a mixture of 1 hour, compound 47 with 1 part of a compound 48. Product 16: compound 47. Product 17: a mixture of 1 part of compound 49 with 1 part of a compound 50 Product 18: a mixture of 1 part of Compound 1 with 2 parts of a compound 2. Product 19: a mixture of 3 parts of Compound 5 tim 2 hours. The compounds used. Product 20: mixture of 3 parts of compound 7 from 2h. Compounds 8. Product 21: a mixture of 9 parts of Compound 35, 1 h. Compound 36, 6 parts of Compound 37 and 4 parts of Compound 38. Product 22: a mixture of 9 hours, Compound 51 with 1 part of Compound 52. Product 23: Compound 53. Product 241 a mixture of 7 parts of Compound 9 with 13 parts of a compound 10. Product 25: a mixture of 7 parts of compound 11 from 13 hours, a compound of 12. Product 26: a mixture of unknown composition, consisting of compounds 27-30. Product 27: a mixture of 10 parts of compound 54, 1 part of compound 55, 10 parts of compound 56 and 1 part of compound 57. Product 28J a mixture of 10 parts of compound 58, 1 part of compound 5, 10 parts of compound 63 and 1 hour compounds 61. Product 29: mixture of 2 parts of compound 13 from 3h. soy; Er1neny 14. Example. Product 6 The composition of the active substance of which is () -B-cyano-3-phenoxybenzyl (±) - "is-trans-3- (2-chloro-3,3,3-trifluoro-2-trfluoromeTylprop-1-E- 1-yl) -2,2-dimethylcyclepropanecarboxylate (containing 60% cis-ismer) and also product 1, the active substance of which is 1 ×) is (±) -H-cyano-3-phenoxy-benzyl or (±) -cis (trans-3, 3,3, 3-trifluoro-2-trifluoroalkyl-prop-1-en-1-yl) -2,2-dimethylcycloPropanecarboxylate (containing 20% cis-isomer 20% c1), treated insect-harm, KOTOjMjBt placed on medium typically representing a host plant or semi-producer insects feed, or treated medium;. or insect NOTES "and drugs. Mortality rates are assessed within 1-3 days after treatment. The results of such experiments are grafted in Tables 2 and 3. The evaluation is expressed in whole chi. villages in the range from O to 3. O indicates mortality of less than 30%; 1 - 3049%; 2 - 50-90%; 3 - more than 90%; (-) - the test was not conducted. The contact test indicates that both the insect and the medium are treated, and the residual test indicates that the medium is treated before the filling. The results obtained for product 1 are presented in table 2, and for product 6 in table 3.

table 2

Beans

Ticks adults ordinary individuals

mosquito specimens

Home Fly Milk Sugar Contact Test

Mole cabbage, larva contact test

Mustard beetle residual test.

House fly

residual

test

Cereal beetle

residual

test

Varieties

Wednesday as insect test objects

Common Beans

Horse bob horse bob plywood

Milk sugar

33333

33333

33333

Table 3

Indicator of insecticidal activity, concentration score, parts per million

50

25

12.5

2.25

3 3 3

3 3 3 3 2 2

Mole of cabbage, larvae contact test

Mustard Beetle

residual

test

House fly

residual

test

Example 2. Products 1-29 at a concentration of 25.50, 100.250 parts of a million are treated with insect varieties selected in a test object according to the method described in Example 1.

Tetranychus.

Red yauti telar {us Klytsik adult individuals

Tetranychus Red spiderweb (us nye, Aphis fabul chern's eggs

Hegoura

Green tl

vi cea (edes aegypti mosquitoes

1001008070

100100100100

100100100100

100100100100

100100100100

100100100 I 60

10010010090

100100IQQ50

79754010

Continued table. 3

33333

33333

33220

F musca

five

Domshin fly - con-domest ica tact of activity 6 Musca Same.

domestica H Plutelia

Residual

xylostella

activity / 3 days

0 I Plutelia

Residual

xyiostella

Activity / 10 days J Phaedon

Mustard

cochlearial

bug K Calahdra

SepHOBbdt beetle

granaria L TriboHum

Khrutsak flour

big

castaneuro M Spodoptera

Scoop of cotton

Utrarahs

amvricans1

0

The test results presented tab. four.

: Us

Table 4 By} "1mo specified mortality is all susceptible and should be tested. Example 3. For comparison with the reference, the product 1 was tested in insect insects of the species He It th is viriscens, Heliothls zea, Spodoptera littoraHs and the range of active substance termination was determined In parts C 50 million. Compound A: phenoxybenzyl ester 2,2- dimethyl-3-1,1-di orvi |; 1yl cyclopropanecarboxylic acid ,. chosen as etgshona. The test results are presented in Table 5. T a b l and c a

625-316

78-3.9

250-125

15.6-7.8

Continued table. four

.

where one of R and K is CFj.CHFCFaC. The CPD, or CFaCFg, and the other of R and I are F, C1, Br, CH9.CF, CHf.lIL. R hydrogen or -CM, -C "C in the amount of

0.0001 to 85 wt.%. More Ngyucaems and to a considerable extent their Deaths if you increase the time of the Forex according to the invention, the Insecticide Composition containing acting starting on the basis of the derivatives of cyclopropicarboxylic acid and the additive selected from the group | W: carrier, diluent, filler, which is different in order , it contains a compound o as a derivative of cyclopropanecarboxylic acid (formula 15 formula sources taken into account in examination 1. Japanese patent 41-4196, class 16 Е 311, published.02.02.71. 79754014 2. Melnikov NN Chemistry, and pesticide technologists. M. Khimi, 1974, p. 679. 3, Patent of the USSR 649295, class A 01 N 9/24, 28.05.75 (prototype),

Claims (1)

Claim An insecticidal composition containing an active principle based on cyclopropanecarboxylic acid derivatives and an additive selected from the group: carrier, diluent, excipient, characterized in that, in order to enhance the insecticidal effect, it contains a compound of the general formula as a cyclopropanecarboxylic acid derivative 1a 60 where one of R and R are CF ₃ , CHF _ft , CF ^ CI, CF * ^ 1 · or CF ^ CF ₃ , and the other of R and R ¹ are F, Cl, 8r, CH ₃ , CF. , CHF _a or CF _a Cl, R® ~ hydrogen or -CN, -C = C in an amount of 6 $ 0.0001 to 85% by weight.