AU2004244668B2

AU2004244668B2 - Magnetic nanoparticles

Info

Publication number: AU2004244668B2
Application number: AU2004244668A
Authority: AU
Inventors: Abdul Cadir Hussein; David Mainwaring; Pandiyan Murugaraj; Colin Rix
Original assignee: MNT Innovations Pty Ltd
Current assignee: Mems ID Pty Ltd
Priority date: 2003-06-04
Filing date: 2004-06-03
Publication date: 2007-07-05
Anticipated expiration: 2024-06-03
Also published as: AU2004244668A1

Description

WO 2004/108330 PCT/AU2004/000728 Magnetic Nanoparticles This invention relates to a method of synthesizing magnetic alloy nanoparticles from non aqueous solutions.

Background to the invention Cobalt platinum (CoPt) alloys are known for their unique magnetic properties arising from high magnetocrystalline anisotropy. CoPt alloys close to equiatomic composition have been extensively studied in the past as possible candidates for permenant magnets.

According to the phase diagrams reported in the literature, bulk CoPt alloy, similar to CuAu, exists as ordered face centered tetragonal (fct) up to temperatures of 8250C, above which it become disordered face centered cubic (fcc). While the former is a strongly ferromagnetic, the later is a weak ferromagnet. CoPt has first degree atomic ordering and has an fcc structure in a disordered state and structure in its ordered state. The L10 structure has four atoms per unit cell, the coordinates of the atoms are 2Co at (000, 0) and 2Pt at 1 0 0 2 2 The tetragonal form has a large uniaxial anisotropy K 7 x 108 erg/cm 3 This phase possesses excellent magnetic properties with remanence magnetization Mr of 510kAm-', Coercivity He of 400kAm 1 and magnetic energy of Umax= 76kJm 3 This equiatomic CoPt system is also known to exhibit magneto optic kerr effect.

CoPt alloy prepared in the form of thin films are ideally suited for magnetic data storage.

Continuous efforts have been made in the magnetic data recording industry to increase the areal storage density with low noise level. Data storage capabilities of 40-100 Gbit/square inch, with CoPt magnetic particle sizes of 12 nm has been so far reported The high magnetocrystalline anisotropy observed in the fct phase of equiatomic CoPt alloy is responsible for the high Hc values obtained in these materials and it also compensates for the destabilization of the magnetization of the recorded bits due to thermal fluctuations and demagnetizing fields. To achieve this, magnetic thin films with very fine (10nm) and well-isolated particles with high coercivity is essential.

USA patent 4902583 discloses a method of depositing a cobalt platinum magnetic film by sputtering.

WO 2004/108330 PCTiAU2004/000728 2 One of the limitations of this process is that the deposited CoPt alloy film always have disordered fcc phase and require heat treatment above 600°C for more than 24 hours for conversion to the required fct phase. Heat treatment for that duration can increase the particle size to more than 10 nm and reduce the inter-particle separation resulting in poor magnetic properties and lower signal to noise ratio in the recorded information.

Many attempts have been made to form nano sized magnetic particles.

European patent 412222 discloses a data storage medium formed by the epitaxial growth of a magnetic thin film.

USA patent 4983230 discloses a melt processing method of increasing the coercivity of cobalt platinum alloys.

USA patent 5456986 discloses a method of forming a magnetic nanoparticle with a carbon coating by electric arc discharge of packed graphite rods.

USA patent 5766306 discloses a method of sonicating a metal carbonyl to produce magnetic nano particles USA patent 5108636 discloses a method of using a crosslinked organosiloxane matrix to form a magnetisable composite.

WO 01/39217 and European patent application 1217616 disclose a method of forming magnetic nanoparticles in a protein matrix. Example 5 of WO 01/39217 prepares a CoPt alloy in a ferritin shell. This has an advantage of forming nanoparticles of a uniform size.

USA patent 5147841 discloses a method of using an inverse micelle solution to reduce a metal salt to colloidal particles of the elemental metal or alloy.

USA patent 6262129 discloses a method of making nano particles including CoPt magnetic nano particles in a surfactant solution under an inert atmosphere. The nano particles are protected with a phosphine and an organic molecule stabilizer.

It is an object of this invention to provide a non melt processing technique for forming magnetic nano particles that is relatively quick and inexpensive.

Brief description of the invention To this end the present invention provides a method of forming magnetic ;Znanoparticles which includes the steps of a) forming a concentrated aqueous solution of transition metal salts preferably selected from salts of cobalt, nickel, iron and chromium with platinum salts 00 b) dispersing the metal salt solution in a non aqueous solution of a surfactant IDc) adding a reducing agent to reduce the metal salts to metallic alloy nanoparticles in the absence of oxygen Separating the metallic alloy nanoparticles e) heating the metallic alloy nanoparticles under controlled time and temperature conditions sufficient to form particles of a desired size and magnetic characteristics.

In this invention nanoparticle sized metal or alloy is synthesized through a reverse micelle system. Reverse micellar systems are made of aqueous droplets suspended in non-aqueous medium stabilized by surfactants. The precipitated metal or alloy nanoparticle has an average size of 3nm and is superparamagnetic.

The ratio of the transition metal to platinum in the alloy is x :1 -x where x is from 0.4 to 0.6. Equiatomic alloys are preferred. In the reaction the platinum salt PtCI 4 is used at a concentration of 0.002M to 0.005M and the transition metal salts such as CoCI 2 .6H 2 0, FeCI 2 .6H 2 0, NiCI 2 .6H 2 0 at 0.002M to 0.0045M.

This invention is partly predicated on the discovery that Cobalt platinum alloys formed in this way can be converted to a face centered tetragonal (FCT) partially ordered structure (L10 structure) through annealing treatment at 600 0 C for minutes to 12 hours depending on the desired magnetic and particle characteristics required.

As synthesised the nanoparticle formed by the process of this invention is an alloy with face centered cubic (FCC) structure exhibiting weak ferromagnetism. With post synthesis annealing treatment, FCC structure changes to partially ordered face centered tetragonal (FCT) structure with enhanced magnetic coercivity.

The invention of this low temperature route using solution chemistry is ideally suited for synthesis of variety of magnetic alloy nanoparticles in transition metalplatinum systems. The metal alloy is synthesized by reduction of metal salts in a WO 2004/108330 PCT/AU2004/000728 4 non-aqueous medium. The metallic alloy nanaoparticles are preferably separated from the reaction mixture using washing and centrifuge processes. The particle size can be precisely controlled through controlled nucleation and crystal growth.

The resulting product is highly homogeneous, with narrow particle size distribution.

The low temperature synthesis route of this invention yields alloy nanoparticles with a disordered face centred cubic lattice possible due to the high concentration of point defects in the as synthesized nanoparticles. High temperature annealing treatment enables reduction of these defects resulting in the stabilization of the partially or5dered face centred tetragonal phase(fct or L1, phase) which is the room temperature stable phase resulting from the alloy melt that has been reported in the literature. This is also the phase responsible for high magnetic coercivity. A minimum annealing temperature of 6000C is required for stabilizing the fct phase. In another aspect, this invention provides a method of lowering this fct phase formation temperature by using additives such as Ag, Sb, Bi and Pb. The temperature for fct phase formation can be lowered by 1000C. The additive concentration may be from 5 to 15 at% calculated with respect to Cobalt in an equimetric CoPt alloy.

The magnetic alloy nanoparticles of this invention have potential use in advanced applications such as magnetic bio-beads, thin film microactuators, nanocomposite membranes for the microfluidic pumps and ultrahigh density magnetic data storage media. For instance, the nanoparticles exhibiting superparamagnetism are suitable for magnetic bio-bead applications. Weakly ferromagnetic magnetic alloy nanoparticles are suitable for actuator applications. The strongly ferromagnetic magnetic alloy nanoparticles exhibiting high coercivity can be potential candidate for magnetic data storage applications. Data storage capabilities of >100Gbit/square inch, with CoPt magnetic alloy particles sizes of 10nm are possible with this invention.

The magnetic properties as well as the particle size can be precisely controlled through control of post synthesis annealing parameters so that the resulting product is suitable for specific applications.

WO 2004/108330 PCTAU2004/000728 Detailed description of the invention A preferred embodiment of the invention will be described with reference to the drawings in which: Figure 1 is an X-ray diffractograms of CoPt particles formed by the method of this invention: la) 60°C dried sample; Ib) 550 0 C annealed sample and 1c) 600°C annealed sample; Figure 2 shows the HRTEM of the CoPt magnetic alloy nanoparticle a) as prepared and b) 600°C annealed; Figure 3 shows the magnetic hysterisis characteristics for the CoPt samples a) annealed at 3500C; b) annealed at 550°C and c) annealed at 600°C; Figure 4 shows the variation of He for the CoPt alloy nanoparticle samples and the corresponding co/ao ratio calculated from their crystal lattice parameters; Figure 5 illustrates XRD patterns of an antimony modified nanoparticle alloy; Figure 6 shows the B-H loop characteristics of an antimony modified nanoparticle alloy annealed at 6000C Figure 7 shows the B-H loop characteristics of an antimony modified nanoparticle alloy annealed at 500oC; Figure 8 shows the B-H loop characteristics of an antimony modified nanoparticle alloy annealed at 6000C for 4hours.

Example 1 Synthesis of CoPt magnetic alloy nanoparticles: Sodium tetrachloroplatinate tetrahydrate Na 2 PtCI 4 .4H 2 0 sodium borohydride NaBH 4 sodium bis(2-ethylhexyl) sulfosuccinate commonly known as ACT and cobalt chloride hexahydrate, n-heptane and ethanol were the ingradients used for the above mentioned synthesis.

The first step is to prepare reverse micellar solutions of cobalt and platinum ions of the desired concentration and water content w. A concentrated aqueous solution of cobalt chloride and sodium tetrachloroplatinate was solubilized in the solution of NaAOT in Heptane previously prepared, to the desired concentration of the ionic salts. The proportions of cobalt and platinum salts are based on the final alloy composition sought. For example, to prepare a micellar solution of Co:Pt with a 1:1 WO 2004/108330 PCT/AU2004/000728 6 proportionality, the starting concentration of Co 2 and of Pt 2 should be 0.002M in a 100mL flask with w 8. Cobalt chloride hexahydrate (47.6 mg) together with sodium tetrachloroplatinate (153 mg) in the form of powder were weighed into a flask. Doubly distilled water (3.6mL) was then added to form very small but concentrated solution of Co 2 and Pt 2 ions in water. Then the previously prepared solution of NaAOT in heptane was added to this concentrated aqueous solution to fill to the mark.

Reverse micellar solution of sodium borohydride with the same water content, w 8 (3.6mL) was prepared in a separate 100mL volumetric flask in the same manner.

This solution is then added into a vigorously mixing of reverse micellar solutions of the metal ions. The colour of the mixture turned from golden brown to black, indicating the formation of metallic nanoparticles. The stirring is maintained for min to insure complete reduction of the metal ions.

After the reduction was complete, the alloy nanoparticles were extracted and washed with water-ethanol mixtures for effective removal of all the unwanted constituents such as the surfactant and the other byproducts of the reaction such as sodium chloride and the other borate species. The washed CoPt nanoparticles which are black in colour are then extracted by centrifugation. The as prepared CoPt nanoparticles are highly reactive and susceptible to oxidation and hence had to be dried under inert atmosphere Ar). The drying temperature can be 60 0

C

for 5 hours.

This product is then subjected to various annealing treatments to improve its magnetic characteristics, Physical and magnetic characteristics of the as synthesized CoPt nanoparticles: The as synthesized product, dried at 60°C, is a very fine powder which exhibits broad diffraction peaks in the X-ray diffractrogram revealing that the low temperature synthesis did produce crystalline grains whose average size is about 4 nm as calculated from Scherrer's XRD line width expression. Figure 1 a gives the XRD pattern for the CoPt alloy nanoparticles as prepared and dried at 600C.

The observed absorption peaks in the XRD pattern could be indexed to face centered cubic pattern with lattice constant 3.8567+ 0.0003 A.

WO 2004/108330 PCT/AU2004/000728 7 High Resolution Transmission electron Microscope (HRTEM) studies also confirmed that the as-synthesized CoPt alloy nanoparticles are well-formed nanocrystallites. Most of the particles sizes were in the range of 3-5 nm (see Figure The bright field HRTEM image of the as-synthesized CoPt alloy nanoparticles shown in figure 4 reveals the crystalline nature of the nanoparticles.

These samples exhibit a superparamagnetic behavior (Figure 3a) and remain so upto the annealing temperature 3500C. This is due to two factors namely small particle size and weak ferromagnetism. Firstly, particles exhibit superparamagnetism when the particle sizes are comparable to the magnetic domain wall width. Secondly, these samples particles possess a disordered cubic lattice structure which has low magnetic anisotropy constant resulting in weak ferromagnetic character (He values >20 Oe).

Annealing treatment induced changes in the physical and magnetic properties of CoPt magnetic nanoallovs: The CoPt magnetic alloy nanoparticles were then annealed at different temperatures between 350°C and 600°C for pre-selected time duration. Upon heat treatment, noise level reduced considerably in the XRD pattern accompanied by the peak sharpening, which is indicative of the growth in particle size. The basic structure remained face centered cubic (fcc) during high annealing temperatures up to 550°C with no appreciable change in the lattice constant (see Figure 1b).

Using Scherrer's formula, the particle size was calculated. The particle size increased from 3nm at 60°C to -6nm at 5500C Table 1 shows the structural and magnetic characteristics of the CoPt magnetic alloy nanoparticles processed at different temperatures and different annealing durations.

WO 2004/108330 PCT/AU2004/000728 8 TABLE 1 S. No Annealing Annealing Particle size Temperature OC Time (hrs.) (nm) c (kOe) Cod/a 1 350 1 3.304 0 1.00000 2 400 1 0.2 1.00000 3 450 1 3.582 1.00000 4 500 1 5.943 0.4 1.00000 550 1 5.390 1.00000 6 600 0.5 8.587 2.0 1.348814 7 600 2 9.216 3.5 1.362446 8 600 4 10.922 4.0 1.375861 9 600 6 14.424 4.6 1.379495 600 10 17.237 12.0 1.400158 Upon heating to 6000C for 30 mins, an irreversible phase transformation occurred and new peaks were observed in the XRD pattern (Figure Ic). All the peaks could be indexed to a face centered tetragonal (fct) lattice whose lattice constants ao and co are 2.6767 A and 3.7303 A respectively. Maintaining the annealing temperature constant at 6000C the annealing duration of varied from 30 min to a maximum of hours. The Co/ao ratio (1.3488 for CoPt alloy obtained after half an hour heat treatment at 600°C) gradually increased with duration of annealing. It reached 1.4001 for CoPt magnetic alloy nanoparticles annealed for 10 hours (Figure 4).

During this process, the average particle size also increased from ~8nm (for samples for half an hour) to about 17 nm (when heated to for 10 hours).

The magnetic coercivity (Ho) values increased considerably. The sample heat treated for half an hour showed He value of 2kOe (see Figure 3b) while the 10 hour heated sample exhibited 12kOe (Figure 3c). This is the highest value obtained for the free powder of CoPt magnetic alloy reported to date.

The XRD data (Figure 1) also reveals that the product obtained has a high degree of phase purity as evidenced from the absence of diffraction peaks due to elemental platinum and elemental cobalt or any other impurities, even though their presence in trace amounts beyond the limit of XRD sensitivity cannot be ruled out.

The proposed room temperature synthesis route yields CoPt alloy with disordered face centered cubic lattice, possibly be due to the high concentration of point defects in the as synthesized nanoparticles. The high temperature annealing WO 2004/108330 PCT/AU2004/000728 9 treatment enables reduction of these defects resulting in the stabilization of the partially ordered face centered tetragonal phase, which is the room temperature stable phase resulting from the alloy melt that is reported in the literature.

Example 2 Synthesis of FePt magnetic alloy nanoparticles Sodium tetrachloroplatinate tetrahydrate Na 2 PtCI4.4H 2 0 sodium borohydride NaBH 4 sodium bis(2-ethylhexyl) sulfosuccinate commonly known as AOT and Iron chloride hexahydrate FeCI 2 .6H 2 0, n-heptane (99%) and ethanol were the ingredients used for the synthesis.

A reverse micellar solution containing Fe 3 and Pt 2 with overall concentrations, for each metal ion of 0.002 M in 100ml and a water content of W=8 was prepared as follows: Iron chloride hexahydrate (54.05mg) together with Sodium tetrachloroplatinate in powder form were weighed into a 100ml flask. Doubly distilled water (2.88ml) was added to form a small concentrated solution of Fe 3 and Pt 2 ions in water. Then a previously prepared solution of AOT in heptane was added to the concentrated solution of Fe 3 and Pt 2 ions to fill to the mark. This suspension was homogenized by ultrasonication to form a clear golden brown solution. The Fe 3 and Pt 2 ions in solution were reduced into the metallic state with a reverse micellar solution of sodium borohydride. This reverse micellar solution of sodium borohydride was prepared in a separate 100ml flask; doubly distilled water (2.88ml) was added and filled to the mark. This solution was homogenized by ultrasonication. The reduction, extraction and purification of the alloy nanoparticles is similar to that in example 1. The average particle size is Example 3 Synthesis of NiPt magnetic alloy nanoparticles Sodium tetrachloroplatinate tetrahydrate Na 2 PtCI 4 .4H 2 0 sodium borohydride NaBH 4 sodium bis(2-ethylhexyl) sulfosuccinate commonly known as AOT and Nickel chloride hexahydrate NiCI 2 .6H 2 0, n-heptane and ethanol were the ingredients used for the synthesis.

WO 2004/108330 PCT/AU2004/000728 Nickel chloride hexahydrate (54.05mg) together with Sodium tetrachloroplatinate in powder form were weighed into a 100ml flask. Doubly distilled water (2.88mi) was added to form a small concentrated solution of Ni 2 and Pt 2 ions in water. Then a previously prepared solution of AOT in heptane was added to the concentrated solution of Ni 2 and Pt 2 ions to fill to the mark. This suspension was homogenized by ultrasonication to form a clear golden brown solution. The Ni 2 and Pt 2 ions in solution were reduced into the metallic state with a reverse micellar solution of an equivalent amount of sodium borohydride. This reverse micellar solution of sodium borohydride was prepared in a separate 100ml flask; Sodium borohydride (45.4mg) powder was added to the flask; doubly distilled water (2.88ml) was added and filled to the mark. This solution was homogenized by ultrasonication. The reduction, extraction and purification of the alloy nanoparticles is similar to that in example 1. The average particle size is 3-4nm.

Example 4 Synthesis of CoPt magnetic alloy nanoparticles with Chromium substitution Cr is commonly used as a substitute component in the transistion metal sitein parent compounds of CoPt, NiPt and FePt to obtain improved magnetic characteristics.

The amount of Cr used in CoPt, NiPt and FePt varies between 5 at% and 10 at% depending on the other components in the system. In this example Cr 3 concentration of 10 at% is used.

A reverse micellar solution containing Co 2 Pt2+ and Cr 3 with overall concentrations, Co2+, Pt 2 is 0.002 M in 100ml and the concentration of Cr 3 is 0.0002M(10at%) and a water content of W=8 was prepared as follows: Cobalt chloride hexahydrate (47.6mg) together with Sodium tetrachloroplatinate (76.6 mg) and chromium chloride hexahydrate (5.3mg) in powder form were weighed into a 100ml flask. Doubly distilled water (2.88ml) was added to form a small concentrated solution of Co 2 Pt 2 and Cr 3 ions in water. Then a previously prepared solution of AOT in heptane was added to the concentrated solution of Co 2 Pt 2 and Cr 3 ions to fill to the mark. The Co 2 Pt 2 and Cr 3 ions in solution were reduced into the metallic state with a reverse micellar solution of an amount of sodium borohydride equivalent to one and a half times the stoichometric amount WO 2004/108330 PCT/AU2004/000728 11 of ions in solution. This reverse micellar solution of sodium borohydride was prepared in a separate 100ml flask; Sodium borohydride (48.8mg) powder was added to the flask; doubly distilled water (2.88ml) was added and filled to the mark.

This solution was homogenized by ultrasonication. The reduction, extraction and purification of the alloy nanoparticles is similar to that in example 1.

Example Synthesis of CoPt magnetic alloy nanoparticles in the presence of Antimony (Sb) The concentration range of Sb is 5 to 15at% based on equiatomic CoPt alloy.

During this synthesis PTSb is also formed so that a compensating addition of Pt is made to minimize the formation of free Co which is susceptible to oxidation which deteriorates the hard magnetic properties of the nanoparticles.

A reverse micellar solution containing Co 2 Pt 2 and Sb 3 in an atomic percent of 39.5at5 Co, %1.5at% of Pt, ad 9at% Sb with overall concentrations, Co 2 Pt 2 and Sb 3 of 0.01 M in 100ml and a water content of W=8 was prepared as follows: Cobalt chloride hexahydrate (94mg) together with Sodium tetrachloroplatinate (197.2 mg) and antimony potassium tartrate (29.2mg) in powder form were weighed into a 100ml flask. Doubly distilled water (2.88ml) was added to form a small concentrated solution of Co 24 Pt 2 and Sb 3 ions in water. Then a previously prepared solution of AOT in heptane was added to the concentrated solution of Co2+, Pt 2 and Sb 3 +ions to fill to the mark. The Co 2 Pt 2 and Sb 3 ions in solution were reduced into the metallic state with a reverse micellar solution of an equivalent amount of sodium borohydride. This reverse micellar solution of sodium borohydride was prepared in a separate 100ml flask; Sodium borohydride (48.8mg) powder was added to the flask; doubly distilled water (2.88ml) was added and filled to the mark. All solutions were homogenized by ultrasonication. The reduction, extraction and purification of the alloy nanoparticles is similar to that in example 1. The average particle size was 3-4nm.

Figure 5 illustrates XRD patterns for this alloy after annealing at 4000C (curve a), 4500C (curve 50000 (curve c) and 5500C (curve d).

As shown at curve a the annealing at 400 °C took place for 1 hour and a single phase of CoPt is formed indicating dissolution of the Sb in the Co Pt lattice. The WO 2004/108330 PCT/AU2004/000728 12 lattice parameter Co/ao calculated for this phase is 1. The magnetic parameters are Mr 74.8 emu/cc and He 7000e.

The sample treated at 450 °C for 1 hour (curve b) shows a single phase indicating that the CoPt with dissolved Sb is stable at this annealing temperature. The lattice parameter co/ao calculated for this phase is 1. The magnetic parameters are Mr 11.1 emulcc and Hc The sample treated at 500 OC for 1 hour (curve c) shows SbPt separating out and simultaneously the CoPt exhibits fct structure. The lattice parameter C o /ao calculated for this phase is 0.996. The magnetic parameters are Mr 67.2 emu/cc and H, 2.7kOe.

The sample treated at 550 °C for 1 hour (curve d) shows a stable phase separated SbPt and simultaneously the ordering of the CoPt lattice improves as indicated by the increase in intensity of the superstructure peaks which exhibit fct structure. The lattice parameter co/ao calculated for this phase is 0.996. The magnetic parameters are Mr 44.9 emu/cc and He 7kOe.

Figure 6 shows the B-H loop characteristics for the alloy of example 5 when annealed at 600 °C for 1 hour.

Figure 7 shows the the B-H loop characteristics for the alloy of example 5 when annealed at 500 °C for 1 hour.

Figure 8 shows the B-H loop characteristics for the alloy of example 5 when annealed at 600 °C for 4 hours.

The nanoparticles prepared according to this invention can be used in a range of applications.

Magnetic biobeads can be prepared by annealing at 300 OC for 1 hour to produce beads of particle size 2-4nm with superparamagnetic characteristics.

Microactuator applications require alloy nanoparticles with lower magnetic hardness and annealing at 400-500 °C for 1-5 hours will produce suitable particles with a particle size of 6-8nm.

High density magnetic storage media require nanoparticles of 8nm exhibiting strong ferromagnetism (magnetic coercivity 5-8 kOe) and these can be produced by annealing at 500-600 OC for 1 hour.

WO 2004/108330 PCT/AU2004/000728 13 Micromagnets for MEMS applications require nanoparticles of a size from 5-15 nm with strong.ferromagnetism (magnetic coercivity 10 kOe and above) and these can be produced by annealing at 600 OC for up to 10 hours.

From the above it can be seen that the present invention provides a cost effective process for producing a range of nanoparticle sizes. Those skilled in the art will realize that the invention may be varied without departing from the essential teaching of the invention.

Claims

2. A method as claimed in claim 1 in which the transition metals are selected from salts of cobalt, nickel, iron and chromium.
3. A method as claimed in claim 2 in which Chromium is used as a substitution metal for part of the Nickel, Cobalt or Iron in the alloy.
4. A method as claimed in claim 2 in which a metal selected from Silver, Antimony Bismuth or Lead is added to the transition metal solution to lowering the fct phase formation temperature during the annealing process. Nano particles of transition metals and platinum prepared by the process defined in claim 1 wherein the ratio of the transition metal to platinum in the alloy is x :l-x where x is from 0.4 to 0.6.
6. Nano particles of transition metals and platinum prepared by the process defined in claim 3 wherein the chromium content is between 5 and 10 at%.
7. Nano particles of transition metals and platinum prepared by the process defined in claim 4 wherein the additive metal content is between 5 and 15 at%.
08. Magnetic storage medium formed from equi-atomic nano particles of cobalt Sand platinum prepared by the process defined in claim 1 in which the alloy is annealed at a temperature of 500-600 °C and has a particle size of 8 to 12nm. 00 9. Magnetic bio beads formed from nano particles prepared by the process D defined in claim 1 in which the alloy is annealed at a temperature of 300 °C and has a particle size of 2 to 4nm. (N 0 10 10. A micro actuator formed from magnetic nanoparticles produced by the process defined in claim 1 in which the particles have been annealed at 400 to 500 °C for 1to 5 hours to form nanoparticles of 6 to 8nm.
11. Annealed Nano particles of platinum and a transition metal selected from Nickel, Cobalt and Iron produced by the process defined in claim 1 in which a metal selected from Silver, Antimony, Bismuth or Lead is added to the alloy to lower the fct phase formation temperature during the annealing process.
12. Micro magnets formed from nanoparticles produced by the process defined in claim 1 in which the particles have been annealed at 600 °C for up to hours to form nanoparticles of 5 to 15nm with magnetic coercivity from