AU2005263118B2 - Stopper rod for delivering gas into a molten metal - Google Patents
Stopper rod for delivering gas into a molten metal Download PDFInfo
- Publication number
- AU2005263118B2 AU2005263118B2 AU2005263118A AU2005263118A AU2005263118B2 AU 2005263118 B2 AU2005263118 B2 AU 2005263118B2 AU 2005263118 A AU2005263118 A AU 2005263118A AU 2005263118 A AU2005263118 A AU 2005263118A AU 2005263118 B2 AU2005263118 B2 AU 2005263118B2
- Authority
- AU
- Australia
- Prior art keywords
- layer
- stopper
- stopper rod
- rod according
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 229910052751 metal Inorganic materials 0.000 title claims description 19
- 239000002184 metal Substances 0.000 title claims description 19
- 239000000463 material Substances 0.000 claims description 20
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 11
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- -1 boron carbides Chemical class 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/14—Closures
- B22D41/16—Closures stopper-rod type, i.e. a stopper-rod being positioned downwardly through the vessel and the metal therein, for selective registry with the pouring opening
- B22D41/18—Stopper-rods therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/14—Closures
- B22D41/16—Closures stopper-rod type, i.e. a stopper-rod being positioned downwardly through the vessel and the metal therein, for selective registry with the pouring opening
- B22D41/18—Stopper-rods therefor
- B22D41/186—Stopper-rods therefor with means for injecting a fluid into the melt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/14—Closures
- B22D41/16—Closures stopper-rod type, i.e. a stopper-rod being positioned downwardly through the vessel and the metal therein, for selective registry with the pouring opening
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
- Continuous Casting (AREA)
- Furnace Charging Or Discharging (AREA)
- Furnace Details (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Description
WO 2006/007672 PCT/BE2005/000116 Stopper rod for delivering gas into a molten metal.
Description.
[0001] This invention relates to a mono-block stopper rod used to control the flow of molten metal from a discharge nozzle in a holding vessel during metal teeming.
[0002] In continuous casting processes, the use of gases injected down the stopper has been shown to have significant benefits on the quality of metal being cast. For example, inert gases such as argon or nitrogen can be injected to reduce the problems due to alumina build-up and clogging or to assist in removing solidification products from the vicinity of the discharge nozzle.
Reactive gases may also be employed when the melt composition needs modifying.
Conventionally, the stopper generally made from an alumina carbon refractory composition is provided with an internal chamber connected to gas supply means on the one end and to a gas discharge port at the other end.
[0003] Various systems have been developed to ensure an accurately measured flow of gas is supplied to the stopper. Problems have been encountered with sealing such systems and ensuring that the gas follows its intended path and is not wasted. Stoppers which have proved to be successful in meeting many of these requirements are disclosed in EP-A2-358,535, WO-A1-00/30785 and WO-A1-00/30786 and more recently in WO-A1-02/100579.
[0004] Pursuing its development work in this field, the applicant has now realized that the gas injected into the molten metal through the stopper could be contaminated when passing through the stopper.
[0005] In particular, it is suspected that the carbon present in the composition constituting the stopper body could reduce some of the metal oxides also present in the composition; this reduction is accompanied by the generation of carbon monoxide. The carbon monoxide injected into the molten metal will in turn oxidize the aluminum which has been added to calm the steel producing thereby important quantities of alumina contributing thus to the alumina build-up and clogging.
[0006] It would therefore be advantageous to provide a stopper rod which would not contaminate the gas passing therethrough.
[00071 According to the invention, this problem is solved for a stopper rod adapted to deliver gas during pouring of molten metal comprising a stopper body having an internal chamber and a gas discharge port, a bore connecting the internal chamber to the gas discharge port, the internal chamber and the bore defining a gas passageway. According to the invention, the walls of the gas passageway are provided with a layer of a material which will not produce carbon monoxide at the temperature of use.
[0008] It must be noted that it is, to the applicant's knowledge, the first time that it is proposed to provide a refractory article with such a layer on a portion of said article that will never contact the molten metal. On the contrary, in the prior art as exemplified for example by the document US-A1 -5,691,061 or US-Al -5,681,499, such a layer is only provided on portions that are always CONFIRMATION COPY WO 2006/007672 PCT/BE2005/000116 2 in contact with the metal.
[0009] The layer can be formed as a coating applied on the walls of the gas passageway after the manufacture of the stopper rod. Such a coating can be applied by spraying a liquid, wet or semi-wet composition or simply by filling the inner chamber with the appropriate composition.
Once the coating is dried, the stopper rod can then be cured. Alternatively, the curing of the stopper can take place before the coating step. Advantageously, the layer is a liner pressed simultaneously with the stopper rod body. In this case, it is indeed possible to reduce the number of manufacturing steps. According to another variant, the layer extends through essentially the who!e thickness of the walls of the gas passageway.
[0010] The material constituting the a layer which will not produce carbon monoxide at the temperature of use can be selected from three different categories of materials: a) materials which do not contain carbon; b) materials essentially constituted of non reducible refractory oxides; or c) materials comprising elements which will react with the generated carbon monoxide.
Preferably, the selected material will present two or three of the above properties.
[0011] Examples of suitable material of the first category are silica (for example vitreous silica), alumina, mullite or magnesia based material (spinel). In certain cases, these materials can however be somehow difficult to apply as a liner or coating (the lack of carbon in the layer can cause some thermal shock problems) and do not constitute the preferred embodiment of the invention.
[0012] Suitable materials of the second category are for example pure alumina carbon compositions. In particular, these compositions should contain very low amount of silica or of conventional impurities which are usually found in silica (sodium or potassium oxide). In particular, the silica and its conventional impurities should be kept under 2 wt. preferably under 1 wt. [0013] Suitable materials of the third category comprises for example free metal able to combine with carbon monoxide to form a metal oxide and free carbon. Silicon and aluminum are suitable for this application. These materials can also or alternatively comprise carbides or nitrides able to react with carbon monoxide (for example silicon or boron carbides).
[0014] Preferably the selected material will belong to the second or third categories, even preferably, it will belong to the second and third category.
[0015] A suitable material constituting the layer which will not produce carbon monoxide at the temperature of use can comprise 60 to 88 wt. of alumina, 10to 20 wt. graphite and 2 to wt. of silicon carbide. Such a material is essentially constituted of non-oxides species or nonreducible oxides and comprises silicon carbide which can react with the carbon monoxide if some is generated in working condition.
[0016] The invention will now be described with reference to the attached drawing in which Fig.
1 shows a cross-section of a stopper rod according to the invention. Reference 1 depicts respectively the internal chamber and a gas discharge port of the stopper rod. A bore 3 WO 2006/007672 PCT/BE2005/000116 3 connects the internal chamber 1 to the gas discharge port 2. The bore 3 and the internal chamber 1 define a passageway for the gas. Fig. 1 represents an embodiment wherein the layer 4 has been copressed as a liner with the stopper body. Very conveniently, the liner 4 can be constituted of several pre-formed tubular portions (41, 42, 43) which are all copressed with the stopper body. A portion of the metal rod 5 connecting the stopper rod to the rigging device (not shown) is depicted in working position. Preferably, the metal rod 5 extends beyond the highest point of the layer 4. Even more preferably, a sealing gasket 6 is inserted around the lower end of the metal rod
Claims (9)
1. Stopper rod adapted to deliver gas during pouring of molten metal comprising a stopper body having an internal chamber and a gas discharge port a bore connecting the internal chamber to the gas discharge port the internal chamber and the bore defining a gas passageway, characterized in that the walls of the gas passageway are provided with a layer which will not produce carbon monoxide at the temperature of use.
Stopper rod according to claim 1, characterized In that the layer is a liner copressed with the body.
3. Stopper rod according to claim 1, characterized in that the layer is a coating applied on the walls of the gas passageway.
4. Stopper rod according to claim 1, characterized in that the layer extends through essentially the whole thickness of the walls of the gas passageway.
5. Stopper rod according to any one of claims 1 to 4, characterized in that the layer (4) extends upwardly beyond the lowest point reached by a metal rod used to attach the stopper to a rigging device.
6. Stopper rod according to any one of claims 1 to 5, characterized in that the material constituting the layer is a selected from the groups of a) materials which do not contain carbon; b) materials essentially constituted of non reducible refractory oxides; and/or c) materials comprising elements which will react with the generated carbon monoxide, or mixtures thereof.
7. Stopper rod according to any one of the preceding claims, characterized in that the layer comprises 60 to 88 wt. of alumina, 10 to 20 wt. graphite and 2 to 10 wt. of silicon carbide.
8. Assembly of a stopper rod according to any one of the preceding claims with a metal rod used to attach the stopper to a rigging device wherein the metal rod of extends beyond the highest point of the layer
9. Assembly according to claim 8, wherein a sealing gasket is inserted around the lower end of the metal rod
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04447179 | 2004-07-20 | ||
| EP04447179.5 | 2004-07-20 | ||
| PCT/BE2005/000116 WO2006007672A2 (en) | 2004-07-20 | 2005-07-15 | Stopper rod for delivering gas into a molten metal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2005263118A1 AU2005263118A1 (en) | 2006-01-26 |
| AU2005263118B2 true AU2005263118B2 (en) | 2009-02-19 |
Family
ID=34933070
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2005263118A Ceased AU2005263118B2 (en) | 2004-07-20 | 2005-07-15 | Stopper rod for delivering gas into a molten metal |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US20070210494A1 (en) |
| EP (1) | EP1789220B1 (en) |
| JP (1) | JP4933430B2 (en) |
| KR (1) | KR101128610B1 (en) |
| CN (1) | CN1988972A (en) |
| AR (1) | AR050257A1 (en) |
| AT (1) | ATE381402T1 (en) |
| AU (1) | AU2005263118B2 (en) |
| BR (1) | BRPI0513258B1 (en) |
| CA (1) | CA2572497C (en) |
| DE (1) | DE602005003968T2 (en) |
| ES (1) | ES2299056T3 (en) |
| MX (1) | MX2007000764A (en) |
| MY (1) | MY141417A (en) |
| PL (1) | PL1789220T3 (en) |
| RU (1) | RU2375150C2 (en) |
| TW (1) | TWI357837B (en) |
| UA (1) | UA89642C2 (en) |
| WO (1) | WO2006007672A2 (en) |
| ZA (1) | ZA200700750B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007004958B4 (en) * | 2007-01-26 | 2010-04-29 | Innotec Ltd. | Plugs for use in metallurgical installations |
| ATE485909T1 (en) * | 2008-11-19 | 2010-11-15 | Refractory Intellectual Prop | PLUG ROD |
| PL2209056T3 (en) * | 2009-01-16 | 2012-05-31 | Refractory Intellectual Property Gmbh & Co Kg | Flow control device in a continuous casting steel-making process |
| CN101513670B (en) * | 2009-03-18 | 2010-12-01 | 山东中齐耐火材料集团有限公司 | Integral stopper screw rod connecting device and a manufacturing method thereof |
| ES2428314T3 (en) * | 2011-09-23 | 2013-11-07 | Refractory Intellectual Property Gmbh & Co. Kg | Ceramic refractory casting plug |
| EP2653248B1 (en) | 2012-04-16 | 2014-04-02 | Refractory Intellectual Property GmbH & Co. KG | Ceramic refractory stopper |
| CN104368804B (en) * | 2014-09-25 | 2016-08-24 | 武汉重工铸锻有限责任公司 | Chock plug and the integral processing method of nozzle connection |
| PL3705204T3 (en) * | 2019-03-08 | 2022-10-17 | Refractory Intellectual Property Gmbh & Co. Kg | A stopper rod and a method for providing a uniform gas curtain around a stopper rod |
| JP7022095B2 (en) * | 2019-03-28 | 2022-02-17 | 日本製鋼所Ｍ＆Ｅ株式会社 | Stopper |
| JP2022552257A (en) | 2019-10-10 | 2022-12-15 | リフラクトリー インテレクチュアル プロパティ ゲーエムベーハー ウント コ カーゲー | Isostatic press product and method of manufacture for use in processing molten metal |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3200457A (en) * | 1964-03-09 | 1965-08-17 | United States Steel Corp | Method of regulating the discharge of molten metal from ladles |
| US3565412A (en) * | 1968-12-03 | 1971-02-23 | Dresser Ind | Device for stirring molten metal |
| IT1156736B (en) * | 1978-05-12 | 1987-02-04 | Centro Speriment Metallurg | METHOD FOR THE INTRODUCTION OF BONES-DESULPHANTS SUBSTANCES UNDER FLOATING METALS WITHOUT USING GASEOUS VEHICLES |
| US4682718A (en) * | 1983-08-16 | 1987-07-28 | Toshiba Ceramics Co., Ltd. | Nozzle for continuous casting of molten steel |
| JPS6246167A (en) * | 1985-08-22 | 1987-02-28 | 株式会社東芝 | Defrost device |
| US4870037A (en) * | 1987-09-23 | 1989-09-26 | Vesuvius Crucible Company | Prevention of Al2 O3 formation in pouring nozzles and the like |
| US5185300A (en) * | 1991-03-11 | 1993-02-09 | Vesuvius Crucible Company | Erosion, thermal shock and oxidation resistant refractory compositions |
| GB2263427A (en) * | 1992-01-09 | 1993-07-28 | Thor Ceramics Ltd | Refractory stopper rod with a lined channel |
| JP2627473B2 (en) * | 1992-07-15 | 1997-07-09 | 新日本製鐵株式会社 | Long stopper for continuous casting |
| FR2695848B1 (en) * | 1992-09-21 | 1994-12-09 | Lorraine Laminage | Metal casting nozzle and methods of manufacturing this nozzle. |
| US5370370A (en) * | 1993-02-19 | 1994-12-06 | Vesuvius Crucible Company | Liner for submerged entry nozzle |
| US5681499A (en) * | 1994-06-15 | 1997-10-28 | Vesuvius Crucible Company | Method and compositions for making refractory shapes having dense, carbon free surfaces and shapes made therefrom |
| IN191421B (en) * | 1994-06-15 | 2003-11-29 | Vesuvius Frnance Sa | |
| JP2796524B2 (en) * | 1996-04-11 | 1998-09-10 | 品川白煉瓦株式会社 | Composite immersion nozzle |
| KR100585977B1 (en) * | 1998-11-20 | 2006-06-07 | 비수비우스 크루서블 컴패니 | Stopper rod |
| WO2000078484A1 (en) * | 1999-06-22 | 2000-12-28 | Foseco International Limited | Article formed from carbon-bonded refractory material |
| JP3426177B2 (en) * | 1999-12-28 | 2003-07-14 | 明智セラミックス株式会社 | Casting stopper |
| KR20020054132A (en) * | 2000-12-27 | 2002-07-06 | 이구택 | Gas channel typed stopper and continuous casting method using it |
| US6475426B1 (en) * | 2001-03-27 | 2002-11-05 | Vesuvius Crucible Company | Resin-bonded liner |
-
2005
- 2005-07-15 CA CA2572497A patent/CA2572497C/en not_active Expired - Fee Related
- 2005-07-15 JP JP2007521753A patent/JP4933430B2/en not_active Expired - Fee Related
- 2005-07-15 CN CNA2005800244202A patent/CN1988972A/en active Pending
- 2005-07-15 RU RU2007100205/02A patent/RU2375150C2/en not_active IP Right Cessation
- 2005-07-15 DE DE602005003968T patent/DE602005003968T2/en not_active Expired - Lifetime
- 2005-07-15 US US11/630,633 patent/US20070210494A1/en not_active Abandoned
- 2005-07-15 AU AU2005263118A patent/AU2005263118B2/en not_active Ceased
- 2005-07-15 KR KR1020077001592A patent/KR101128610B1/en not_active Expired - Fee Related
- 2005-07-15 AT AT05763960T patent/ATE381402T1/en active
- 2005-07-15 WO PCT/BE2005/000116 patent/WO2006007672A2/en not_active Ceased
- 2005-07-15 ES ES05763960T patent/ES2299056T3/en not_active Expired - Lifetime
- 2005-07-15 PL PL05763960T patent/PL1789220T3/en unknown
- 2005-07-15 MX MX2007000764A patent/MX2007000764A/en active IP Right Grant
- 2005-07-15 ZA ZA200700750A patent/ZA200700750B/en unknown
- 2005-07-15 UA UAA200701790A patent/UA89642C2/en unknown
- 2005-07-15 EP EP05763960A patent/EP1789220B1/en not_active Expired - Lifetime
- 2005-07-15 BR BRPI0513258A patent/BRPI0513258B1/en not_active IP Right Cessation
- 2005-07-19 AR ARP050102974A patent/AR050257A1/en not_active Application Discontinuation
- 2005-07-19 MY MYPI20053295A patent/MY141417A/en unknown
- 2005-07-19 TW TW094124292A patent/TWI357837B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE602005003968T2 (en) | 2008-12-04 |
| AR050257A1 (en) | 2006-10-11 |
| RU2375150C2 (en) | 2009-12-10 |
| AU2005263118A1 (en) | 2006-01-26 |
| MY141417A (en) | 2010-04-30 |
| EP1789220A2 (en) | 2007-05-30 |
| WO2006007672A3 (en) | 2006-03-02 |
| CN1988972A (en) | 2007-06-27 |
| CA2572497C (en) | 2012-05-01 |
| WO2006007672A2 (en) | 2006-01-26 |
| ATE381402T1 (en) | 2008-01-15 |
| MX2007000764A (en) | 2007-03-28 |
| DE602005003968D1 (en) | 2008-01-31 |
| JP2008506536A (en) | 2008-03-06 |
| KR101128610B1 (en) | 2012-03-26 |
| BRPI0513258B1 (en) | 2016-09-27 |
| RU2007100205A (en) | 2008-08-27 |
| TWI357837B (en) | 2012-02-11 |
| CA2572497A1 (en) | 2006-01-26 |
| US20070210494A1 (en) | 2007-09-13 |
| ES2299056T3 (en) | 2008-05-16 |
| JP4933430B2 (en) | 2012-05-16 |
| BRPI0513258A (en) | 2008-04-29 |
| UA89642C2 (en) | 2010-02-25 |
| ZA200700750B (en) | 2008-08-27 |
| PL1789220T3 (en) | 2008-07-31 |
| TW200615062A (en) | 2006-05-16 |
| EP1789220B1 (en) | 2007-12-19 |
| KR20070030913A (en) | 2007-03-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FGA | Letters patent sealed or granted (standard patent) | ||
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |