AU2007245731B2

AU2007245731B2 - Gasification system and its use

Info

Publication number: AU2007245731B2
Application number: AU2007245731A
Authority: AU
Inventors: Robert Erwin Van Den Berg; Hendrik Jan Van Der Ploeg; Franciscus Gerardus Van Dongen; Thomas Paul Von Kossak-Glowczewski; Pieter Lammert Zuideveld
Original assignee: Air Products and Chemicals Inc
Current assignee: Air Products and Chemicals Inc
Priority date: 2006-05-01
Filing date: 2007-04-27
Publication date: 2010-08-12
Anticipated expiration: 2027-04-27
Also published as: AU2007245731A1; CN101432401A; RU2441900C2; KR20090012255A; JP2009543890A; WO2007125046A1; CN101432401B; CA2650604A1; CN101432400A; RU2008147138A; CN101432400B; CA2650604C; EP2013317A1; KR101367691B1; JP5559532B2; BRPI0710627A2; UA93551C2

Description

WO 2007/125046 PCT/EP2007/053869 GASIFICATION SYSTEM AND ITS USE Field of the Invention The present invention relates to an improved gasification system for preparing mixture comprising of carbon monoxide and hydrogen from a carbonaceous stream using an oxygen containing stream. The gasification system 5 comprises a gasification reactor and a synthesis gas cooling vessel. The invention is also directed to a process to prepare a mixture comprising of carbon monoxide and hydrogen in a system according to the invention. Background of the invention 10 Methods for producing synthesis gas are well known from practice. An example of a method for producing synthesis gas is described in EP-A-400740. Generally, a carbonaceous stream such as coal, brown coal, peat, wood, coke, soot, or other gaseous, liquid or solid fuel or 15 mixture thereof, is partially combusted in a gasification reactor using an oxygen containing gas such as substantially pure oxygen or (optionally oxygen enriched) air or the like, thereby obtaining a.o. synthesis gas (CO and H 2 ), CO 2 and a slag. The slag formed during the partial 20 combustion drops down and is drained through an outlet located at or near the reactor bottom. The hot product gas in the reactor of EP-A-400740 flows upwardly. This hot product gas, i.e. raw synthesis gas, usually contains sticky particles that lose their 25 stickiness upon cooling. These sticky particles in the raw synthesis gas may cause problems downstream of the gasification reactor where the raw synthesis gas is further processed. This because undesirable deposits of the sticky particles on, for example, heat exchange surfaces, walls, 30 valves or outlets may adversely affect the process. Moreover such deposits are hard to remove.

WO 2007/125046 PCT/EP2007/053869 -2 Therefore, the raw synthesis gas is quenched in a quench section. In such a quench section a quench gas is injected into the upwardly moving raw synthesis gas in order to cool it. 5 WO-A-2004/005438 describes a gasification system comprising a gasification reactor and a synthesis gas cooling vessel. This publication describes a gasification combustion chamber and a tubular part fluidly connected to an open upper end of said combustion chamber. Both 10 combustion chamber and tubular part are located in a pressure shell defining an annular space between said pressure shell and the combustion chamber and tubular part respectively. In the tubular part a quench gas is injected into the hot synthesis gas. This publication 15 also describes a separate cooling vessel provided with three banks of heat exchange heating surfaces located one above the other. US-A-5803937 describes a gasification reactor and a syngas cooler within one pressure vessel. In this reactor 20 a tubular part is fluidly connected to an open upper end of a combustion chamber. At the upper end of the tubular part the gas is deflected 1800 to flow downwardly through the annular space between tubular part and the wall of the pressure shell. In said annular space heat exchanging 25 surfaces are present to cool the hot gas. US-A-4836146 describes a gasification system for a solid particulate comprising a gasification reactor and a synthesis gas cooling vessel as in WO-A-2004/005438. In this publication a method and apparatus is described for 30 controlling rapping of the heat exchange surfaces as present in the separate cooling vessel. Rapping is required to avoid deposits to accumulate on the surfaces of the heat exchangers. The afore discussed gasification reactors have in 35 common that the synthesis gas as produced flows 3 substantially upwards and the slag flows substantially downwards relative to the gasification burners as present in said reactors. Thus, all these reactors have an outlet for slag, which is separate from the outlet for synthesis gas. This in contrast to a class of gasification reactors as for example described in EP-A-926441 where both slag and 5 synthesis gas flow downwardly and wherein both the outlet for slag and synthesis gas are located at the lower end of the reactor. A problem with the syngas cooler of WO-A-2004/005438 and US-A-4836146 and also with the apparatus of US-A-5803937 is that the heat exchanging surfaces introduce a large complexity to the design of said apparatuses. Furthermore extensive to measures like rapping are required to avoid deposits to accumulate on the heat exchanger surfaces. Another problem is that the heat exchanging surfaces are even more vulnerable to fouling from feedstocks with for instance a high alkaline content. There is thus a desire to process high alkaline feedstocks as well as a desire to provide more simple gasification systems. I5 Object of the Invention It is the object of the present invention to substantially overcome or ameliorate one or more of the disadvantages of the prior art. 20 Summary of the Invention The present invention, at least in a preferred embodiment, is directed to an improved reactor of the type where slag flows downwardly and is discharged at the bottom end of the reactor and wherein synthesis gas flows upwardly and is discharged at the upper end of said reactor. 25 One aspect of the present invention provides a gasification system comprising a gasification reactor and a synthesis gas cooling vessel, wherein the gasification reactor comprises: - a pressure shell for maintaining a pressure higher than atmospheric pressure; - a slag bath located in a lower part of the pressure shell; 30 - a gasifier wall arranged inside the pressure shell defining a gasification chamber wherein during operation the synthesis gas comprising CO, C02 and H2 can be formed, a lower open part of the gasifier wall which is in fluid communication with the slag bath and an open upper end of the gasifier wall which is in fluid communication with the synthesis gas cooling vessel via a connecting conduit; 4 wherein injecting means are present in the connecting conduit for injecting a liquid or gaseous cooling medium into the synthesis gas; wherein the synthesis gas cooling vessel has the inlet for receiving hot synthesis gas at its upper end and the outlet for cooled synthesis gas at its lower end such that, in 5 use, a substantially downwardly directed flow path of synthesis gas will result and wherein in the flow path downwardly directed injecting means are present, said injecting means suited to inject a mist of water; and wherein the synthesis gas cooling vessel comprises a water bath in the flow path of the synthesis gas. 10 Applicants found that by using the reactor as disclosed above the use of complicated heat exchange surfaces could be avoided. Additionally, high alkaline feedstocks can be more easily processed. Other advantages and preferred embodiments will be discussed hereafter. The invention is also directed to a process to prepare a mixture comprising of is carbon monoxide and hydrogen by partial oxidation of a solid carbonaceous feed in the gasification system according to the invention. In the gasification chamber the solid carbonaceous feed is partially oxidized with an oxygen comprising gas to form an upwardly moving gas mixture having a temperature of between 1200 and 1800'C, preferably between 1400 and 1800*C, and a pressure of between 20 and 100 bar, cooling 20 said gas mixture in the connecting conduit to a temperature of between 500 and 900*C by injecting a liquid cooling medium and subsequently further cooling the gas in the synthesis gas cooling vessel to below 500*C by contacting with water, wherein said cooling in the connecting tube and/or in the synthesis gas cooling vessel is performed by injecting a mist of water droplets into the gas flow. 25 It has been found that the raw synthesis gas is cooled very efficiently, as a result of which the risk of deposits of sticky particles downstream of the gasification reactor is reduced. Brief Description of the Drawings 30 Preferred embodiments of the invention will be described hereinafter, by way of examples only, with reference to the accompanying drawings. Figure 1 schematically shows a process scheme for a system for preparing a purified mixture comprising carbon monoxide and hydrogen; and Figure 2 schematically shows a longitudinal cross-section of a preferred 35 gasification system consisting of a reactor vessel and a cooling vessel.

5 Figure 3 schematically shows a possible further embodiment for the cooling vessel. Detailed Description of the Invention The gasification reactor according to the present invention is suitably used to 5 prepare a mixture comprising of carbon monoxide and hydrogen by partial oxidation of a solid carbonaceous feed in a gasification reactor according to the present invention or in a system according to the present invention. In such a process a solid carbonaceous feed is partially oxidized in the gasification chamber with an oxygen comprising gas to form an upwardly moving gas mixture having a temperature of between 1200 and 1800*C to preferably between 1400 and 1800*C. This mixture is preferably cooled, in a first cooling step. In the separate cooling vessel the gas is further cooled to preferably below 500*C. The solid carbonaceous feed is partially oxidised with an oxygen comprising gas. Preferred carbonaceous feeds are solid, high carbon containing feedstocks, more preferably it is substantially (i.e. > 90 wt.%) comprised of naturally occurring coal or is synthetic (petroleum) cokes, most preferably coal. Suitable coals include lignite, bituminous coal, sub-bituminous coal, anthracite coal, and brown coal. In general, this so-called gasification is carried out by partially combusting the carbonaceous feed with a WO 2007/125046 PCT/EP2007/053869 -6 limited volume of oxygen at the elevated temperature in the absence of a catalyst. In order to achieve a more rapid and complete gasification, initial pulverisation of the coal is preferred to fine coal particulates. The term 5 fine particulates is intended to include at least pulverized particulates having a particle size distribution so that at least about 90% by weight of the material is less than 90 pm and moisture content is typically between 2 and 8% by weight, and preferably less 10 than about 5% by weight. The gasification is preferably carried out in the presence of oxygen and optionally some steam, the purity of the oxygen preferably being at least 90% by volume, nitrogen, carbon dioxide and argon being permissible as 15 impurities. Substantially pure oxygen is preferred, such as prepared by an air separation unit (ASU). Oxygen may contain some steam. Steam acts as moderator gas in the gasification reaction. The ratio between oxygen and steam is preferably from 0 to 0.3 parts by volume of steam per 20 part by volume of oxygen. The oxygen used is preferably heated before being contacted with the coal, preferably to a temperature of from about 200 to 500 'C. If the water content of the carbonaceous feed, as can be the case when coal is used, is too high, the feed is 25 preferably dried before use. The partial oxidation reaction is preferably performed by combustion of a dry mixture of fine particulates of the carbonaceous feed and a carrier gas with oxygen in a suitable burner as present in the 30 gasification chamber of the reactor according to the invention. Examples of suitable burners are described in US-A-48887962, US-A-4523529 and US-A-4510874. The gasification chamber is preferably provided with one or more pairs of partial oxidation burners, wherein said 35 burners are provided with supply means for a solid WO 2007/125046 PCT/EP2007/053869 -7 carbonaceous feed and supply means for an oxygen. With a pair of burners is here meant two burners, which are directed horizontal and diametric into the gasification chamber. This results in a pair of two burners in a 5 substantially opposite direction at the same horizontal position. The reactor may be provided with 1 to 5 of such pairs of burners. The upper limit of the number of pairs will depend on the size of the reactor. The firing direction of the burners may be slightly tangential as 10 for example described in EP-A-400740. Examples of suitable carrier gasses to transport the dry and solid feed to the burners are steam, nitrogen, synthesis gas and carbon dioxide. Preferably nitrogen is used when the synthesis gas is used for especially power 15 generation and as feedstock to make ammonia. Carbon dioxide is preferably used when the synthesis gas is subjected to downstream shift reactions. The shifted synthesis gas may for example be used to prepare hydrogen methanol and/or dimethyl ether or as feed gas of a 20 Fischer-Tropsch synthesis. The synthesis gas discharged from the gasification reactor comprises at least H 2 , CO. and CO 2 . The suitability of the synthesis gas composition for especially the methanol forming reaction is expressed as 25 the stoichiometric number SN of the synthesis gas, whereby expressed in the molar contents [H 2 ], [CO], and

[CO

2 ], SN = ([H 2

]-[CO

2 ])/([CO]+[C0 2 ]). It has been found that the stoichiometric number of the synthesis gas produced by gasification of the carbonaceous feed is 30 lower than the desired ratio of about 2.05 for forming methanol in the methanol forming reaction. By performing a water shift reaction and separating part of the carbon dioxide the SN number can be improved. Preferably hydrogen separated from methanol synthesis offgas can be 35 added to the synthesis gas to increase the SN.

WO 2007/125046 PCT/EP2007/053869 -8 In one embodiment of the present invention the hot synthesis gas is first cooled in a first cooling step to a temperature of between 500 and 900 0 C before it enters the separate cooling vessel. This first cooling step is 5 preferred to achieve a gas temperature below the solidification temperature of the non-gaseous components present in the hot synthesis gas. The solidification temperature of the non-gaseous components in the hot synthesis gas will depend on the carbonaceous feed and is 10 usually between 600 and 1200'C and more especially between 500 and 1000 0 C, for coal type feedstocks. The first cooling step is preferably performed in the connecting conduit that fluidly connects the gasification chamber and the cooling vessel. Cooling may be performed 15 by injecting a quench gas. Cooling with a gas quench is well known and described in for example EP-A-416242, EP-A-662506 and WO-A-2004/005438. Examples of suitable quench gases are recycle synthesis gas and steam. More preferably this first cooling and/or the cooling 20 performed in the cooling vessel is performed by injecting a mist of liquid droplets into the gas flow as will be described in more detail below. The use of the liquid mist as compared to a gas quench is advantageous because of the larger cooling capacity of the mist. 25 The liquid may be any liquid having a suitable viscosity in order to be atomized. Non-limiting examples of the liquid to be injected are a hydrocarbon liquid, a waste stream etc. Preferably the liquid comprises at least 50% water. Most preferably the liquid is 30 substantially comprised of water (i.e. > 95 vol%). In a preferred embodiment the wastewater, also referred to as black water, as obtained in a possible downstream synthesis gas scrubber is used as the liquid. Even more preferably the process condensate of an optional 35 downstream water shift reactor is used as the liquid.

WO 2007/125046 PCT/EP2007/053869 -9 With the term hot synthesis gas is meant the gas mixture as directly obtained in the gasification chamber. With the term 'mist' is meant that the liquid is injected in the form of small droplets. If water is to be 5 used as the liquid, then preferably more than 80%, more preferably more than 90%, of the water is in the liquid state. Preferably the injected mist has a temperature of at most 50 0 C below the bubble point at the prevailing 10 pressure conditions at the point of injection, particularly at most 15 0 C, even more preferably at most 10 0 C below the bubble point. To this end, if the injected liquid is water, it usually has a temperature of above 90 0 C, preferably above 150 0 C, more preferably 15 from 200 0 C to 230 0 C. The temperature will obviously depend on the operating pressure of the gasification reactor, i.e. the pressure of the raw synthesis as specified further below. Hereby a rapid vaporization of the injected mist is obtained, while cold spots are 20 avoided. As a result the risk of ammonium chloride deposits and local attraction of ashes in the gasification reactor is reduced. Further it is preferred that the mist comprises droplets having a diameter of from 50 to 200 jLm, 25 preferably from 100 to 150 tim. Preferably, at least 80 vol.% of the injected liquid is in the form of droplets having the indicated sizes. To enhance quenching of the hot synthesis gas, the mist is preferably injected with a velocity of 30-90 m/s, 30 preferably 40-60 m/s. Also it is preferred that the mist is injected with an injection pressure of at least 10 bar above the pressure of the raw synthesis gas as present in the gasification reactor, preferably from 20 to 60 bar, more 35 preferably about 40 bar, above the pressure of the raw WO 2007/125046 PCT/EP2007/053869 - 10 synthesis gas. If the mist is injected with an injection pressure of below 10 bar above the pressure of the raw synthesis gas, the droplets of the mist may become too large. The latter may be at least partially offset by 5 using an atomisation gas, which may e.g. be N 2 , C0 2 , steam or synthesis gas, more preferably steam or synthesis gas. Using atomisation gas has the additional advantage that the difference between injection pressure and the pressure of the raw synthesis gas may be reduced 10 to a pressure difference of between 5 and 20 bar. Further it has been found especially suitable when the mist is injected in a direction away from the gasification reactor, or said otherwise when the mist is injected in the flow direction of the raw synthesis gas, 15 more preferably under an angle. Hereby no or less dead spaces occur which might result in local deposits on the wall of the connecting conduit. Preferably the mist is injected from the wall of the connecting conduit or from the wall of the cooling vessel in the direction of the 20 flow of hot synthesis gas and under an angle of between 30-60', more preferably about 450, with respect to a plane perpendicular to the longitudinal axis of the connecting conduit or cooling vessel. Alternatively the injection of the mist in the cooling vessel may be 25 performed by injecting the mist in the same, suitably downwardly, direction as the flow path of the synthesis gas. According to a further preferred embodiment, the injected mist is at least partially surrounded by a 30 shielding fluid. Herewith the risk of forming local deposits is reduced. The shielding fluid may be any suitable fluid, but is preferably selected from the group consisting of an inert gas such as N 2 and CO 2 , synthesis gas, steam and a combination thereof.

WO 2007/125046 PCT/EP2007/053869 - 11 According to an especially preferred embodiment, the amount of injected mist is selected such that the raw synthesis gas leaving the cooling vessel comprises at least 40 vol.% H 2 0, preferably from 40 to 60 vol.% H 2 0, 5 more preferably from 45 to 55 vol.% H 2 0. In another preferred embodiment the amount of water added relative to the raw synthesis gas is even higher than the preferred ranges above if one chooses to perform a so-called overquench. In an overquench type process the 10 amount of water added, preferably the amount added in the cooling vessel, is such that not all liquid water will evaporate and some liquid water will remain in the cooled raw synthesis gas. Such a process is advantageous because a downstream dry solid removal system can be omitted. In 15 such a process the raw synthesis gas leaving the cooling vessel is saturated with water. The weight ratio of the raw synthesis gas and water injection can be 1:1 to 1:4. Overquench type process conditions may be achieved by injecting a large amount of water into the flow path of 20 the synthesis gas, by passing the flow of synthesis gas through a water bath positioned at the lower end of the cooling vessel or combinations of these measures. It has been found that herewith the capital costs can be substantially lowered, as no further or significantly 25 less addition of steam in an optional downstream water shift conversion step is necessary. With capital costs is here meant the capital costs for steam boilers. In a preferred method of the present invention, the synthesis gas or a part thereof, and especially the 30 synthesis gas as saturated with water, leaving the quenching section is preferably shift converted whereby at least a part of the water is reacted with CO to produce CO 2 and H 2 thereby obtaining a shift converted synthesis gas stream. As the person skilled in the art 35 will readily understand what is meant with a shift WO 2007/125046 PCT/EP2007/053869 - 12 converter, this is not further discussed. Preferably, before shift converting the raw synthesis gas, the raw synthesis gas is heated in a heat exchanger against the shift converted synthesis gas stream. Herewith the energy 5 consumption of the method is further reduced. In this respect it is also preferred that the liquid is heated before using the liquid injecting it as a mist in the process of the present invention. Preferably heating of this liquid is performed by indirect heat exchange 10 against the shift converted synthesis gas stream. Any desired molar ratio of H 2 /CO may be obtained by subjecting one part of the synthesis gas to a water shift reaction obtaining a CO depleted stream and by-passing the water shift unit with another part of the synthesis 15 gas and combining the CO depleted stream and the by-pass stream. By choosing the ratio of by-pass and shift feed one may achieve most desired ratios for the preferred downstream processes. Detailed description of the drawings 20 The invention will now be described by way of example in more detail with reference to the accompanying non limiting drawings. Same reference numbers as used below refer to similar structural elements. Reference is made to Figure 1. Figure 1 schematically 25 shows a system (1) for producing synthesis gas. In a gasification reactor (2) a carbonaceous stream and an oxygen-containing stream may be fed via lines (3), (4), respectively to a gasification chamber (2). In gasification chamber (2) a raw synthesis gas and a slag 30 is obtained. To this end usually several burners (not shown) are present in the gasification chamber (2). Usually, the partial oxidation in the gasification chamber (2) is carried out at a temperature in the range from 1200 to 1800 0 C, preferably between 1400 and 1800 'C 35 and at a pressure in the range from 1 to 200 bar, WO 2007/125046 PCT/EP2007/053869 - 13 preferably between 20 and 100 bar, more preferably between 40 and 70 bar. The produced raw synthesis gas is fed via a connecting conduit (5) to a cooling vessel (9); To 5 connecting conduit (5) water (17) in the form of a mist is injected, wherein the synthesis gas is cooled to below 500 0 C, for example to about 400 0 C. The ash components as are present in most of the preferred feeds will form a so-called liquid slag in 10 gasification chamber (2) at these temperatures. The slag will preferably form a layer on the inner side of the wall of gasification chamber (2), thereby creating an isolation layer. The temperature conditions are so chosen that the slag will create one the one hand such a 15 protective layer and on the other hand is still able to flow to a lower positioned slag outlet (7) for optional further processing. As shown in the embodiment of Figure 1, the partly cooled synthesis gas (8) enters a cooling vessel(9). In 20 cooling vessel (9) the synthesis gas (8) is contacted with an amount of water (6) in an overquench process mode to obtain a with water saturated synthesis gas (10). Water saturated synthesis gas (10) is directly fed to a wet gas scrubber (11) and subsequently via line (12) to 25 a shift converter (13) to react at least a part of the water with CO to produce CO 2 and H 2 , thereby obtaining a shift converted gas stream in line (14). Part of the scrubbed gas (21) may by-pass the shift converter (13). This gas and stream (20) may be combined, optionally 30 after both streams have been subjected to a further gas treating (not shown). As the wet gas scrubber (11) and shift converter (13) are already known per se, they are not further discussed here in detail. Waste water from gas scrubber (11) is removed via line (22) and optionally 35 partly recycled to the gas scrubber (11) via line (23).

WO 2007/125046 PCT/EP2007/053869 - 14 Part of the wastewater, black water, from gas scrubber (11) may be preferably used as liquid water as injected via line (17) or (6). In a non-overquench mode the synthesis gas (10) is suitably fed to a dry-solids 5 removal unit to at least partially remove dry ash. Preferred solids removal units are cyclones or filter units as for example described in EP-A-551951 and EP-A-1499418. Further improvements are achieved when the raw 10 synthesis gas in line (12) is heated in a heat exchanger (15) against the shift converted synthesis gas in line (14) that is leaving the shift converter (13). Further it is preferred according to the present invention that energy contained in the stream of line 15 (16) leaving heat exchanger (15) is used to warming up the water in line (17) prior to be used in a first or second cooling step. To this end, the stream in line (16) may be fed to an indirect heat exchanger (19), for indirect heat exchange with the stream in line (17). 20 As shown in the embodiment in Figure 1, the stream in line (14) is first fed to the heat exchanger (15) before entering the indirect heat exchanger (19) via line (16). However, the person skilled in the art will readily understand that the heat exchanger (15) may be dispensed 25 with, if desired, or that the stream in line (14) is first fed to the indirect heat exchanger (19) before heat exchanging in heat exchanger (15). The CO depleted synthesis gas leaving the indirect heat exchanger (19) in line (20) may be further 30 processed, if desired, for further heat recovery and gas treatment. If desired the heated stream in line (17) may also be partly used as a feed (line (24)) to the gas scrubber (11).

WO 2007/125046 PCT/EP2007/053869 - 15 Figure 2 shows a longitudinal cross-section of a gasification system, which may be part of the system 1 of Figure 1. Figure 2 shows the gasification reactor (43) of Figure 1 of WO-A-2004/005438 in combination with a 5 downstream cooling vessel or quench vessel (44) fluidly connected by a connecting conduit, i.e. transfer duct (45). Shown in Figure 2 is the gasification chamber (47), which is connected to a tubular part (51), which connects, by means of a connecting conduit, gasification 10 chamber (47) via an upper wall part (52) to the interior of cooling vessel (44). At the lower end of the tubular part (51) injecting means (48) are present for injecting a liquid or gaseous cooling medium. Cooling vessel (44) is further provided with an outlet (49) for cooled 15 synthesis gas. The system of Figure 2 differs from the system disclosed in Figure 1 of WO-A-2004/005438 in that the cooling vessel 3 of said Figure 1 is omitted and replaced by a simple vessel comprising means (46) to add liquid 20 water. A further difference is that injecting means (48) may be suited for injecting a mist of liquid water. Preferably the wall of the gasification chamber (43) and/or the wall of the connecting conduit (51) are provided with cooling means. Preferably the cooling means 25 are an arrangement of water-cooled tubes, more preferably in the form of a membrane wall. Figure 2 also shows a burner (50). The burner configuration may suitably be as described in EP-A 0400740, which reference is hereby incorporated by 30 reference. The various other details of the gasification reactor (43) and the transfer duct (45) as well as the upper design of the cooling vessel (44) are preferably as disclosed for the apparatus of Figure 1 of WO-A-2004/005438.

WO 2007/125046 PCT/EP2007/053869 - 16 The embodiment of Figure 2 is preferred when retrofitting existing gasification reactors by replacing the syngas cooler of the prior art publications with a cooling vessel (44) or when one wishes to adopt the 5 process of the present invention while maintaining the actual gasification reactor of the prior art. The invention is thus preferably directed to a system, wherein the inlet for receiving hot synthesis gas of the cooling vessel is at its upper end and the outlet 10 for cooled synthesis gas is at its lower end, such that in use, a substantially downwardly directed flow path of synthesis gas will result and wherein in the flow path downwardly directed injecting means are present, said injecting means suited to inject a mist of water. 15 Figure 3 shows the upper end of gasification reactor (43) and the upper end of gasification chamber (47). This upper end is fluidly connected by means of connecting conduit (51) to separate cooling vessel (53). Injecting means (48) are present to inject a gaseous or liquid 20 quenching medium in accordance with the process of the present invention. In cooling vessel (53) a dip tube (54) is present to create a downwardly directed flow path for synthesis gas. At the upper end of the dip-tube (54) injecting means 25 (46) are present to inject a mist of liquid water into the synthesis gas. The dip-tube is partly submerged in a water bath (55). In use the synthesis gas will flow through water bath (55) to an annular space (56) as present between dip-tube (54) and the wall of the cooling 30 vessel (53). From said annular space (56) the water saturated synthesis gas is discharged from said cooling vessel via conduit (57). Figure 3 also shows a pump (58) to recirculate water (59), providing a bleed stream (60) and a supply 35 stream (61) for fresh water.

WO 2007/125046 PCT/EP2007/053869 - 17 The invention is thus also directed to a system, wherein the synthesis gas cooling vessel has an opening for receiving hot synthesis gas at its upper end and an outlet for cooled synthesis gas defining a flow path for 5 synthesis gas there between, and wherein a water bath is present in the flow path of the synthesis gas. More preferably the invention is directed to a system, wherein in the connecting conduit injecting means are present for injecting a liquid or gaseous cooling 10 medium into the synthesis gas. Even more preferably wherein the injecting means are injecting means for injecting a liquid cooling medium in the form of a mist of water droplets. The person skilled in the art will readily understand 15 that the present invention may be modified in various ways without departing from the scope as defined in the claims.

Claims

1. Gasification system comprising a gasification reactor and a synthesis gas cooling vessel, wherein the gasification reactor comprises: 5 - a pressure shell for maintaining a pressure higher than atmospheric pressure; - a slag bath located in a lower part of the pressure shell; - a gasifier wall arranged inside the pressure shell defining a gasification chamber wherein during operation the synthesis gas comprising CO, C02 and H2 can be formed, a lower open part of the gasifier wall which is in fluid communication with the 1o slag bath and an open upper end of the gasifier wall which is in fluid communication with the synthesis gas cooling vessel via a connecting conduit; wherein injecting means are present in the connecting conduit for injecting a liquid or gaseous cooling medium into the synthesis gas; wherein the synthesis gas cooling vessel has the inlet for receiving hot synthesis is gas at its upper end and the outlet for cooled synthesis gas at its lower end such that, in use, a substantially downwardly directed flow path of synthesis gas will result and wherein in the flow path downwardly directed injecting means are present, said injecting means suited to inject a mist of water; and wherein the synthesis gas cooling vessel comprises a water bath in the flow 20 path of the synthesis gas.

2. System according to claim 1, wherein the wall of the combustion chamber and the wall of the connecting conduit are provided with cooling means.

3. System according to claim 2, wherein the cooling means is an arrangement of water-cooled tubes. 25

4. System according to claim 3, wherein the arrangement of water-cooled tubes forms a membrane wall.

5. System according to any one of claims 1-4, wherein the gasification chamber is provided with one or more pairs of partial oxidation burners, wherein said burners are provided with supply means for a solid carbonaceous feed and supply means 30 for an oxygen containing gas.

6. System according to any one of claims 1-5, wherein the outlet for cooled synthesis gas is fluidly connected to an inlet of a wet gas scrubber.

7. System according to claim 6, wherein the gas outlet of the wet gas scrubber is fluidly connected to an inlet of a water shift converter. 19

8. Process to prepare a mixture comprising carbon monoxide and hydrogen by partial oxidation of a solid carbonaceous feed in a gasification system according to any one of claims 1-7, wherein in the gasification chamber the solid carbonaceous feed is partially oxidized with an oxygen comprising gas to form an 5 upwardly moving gas mixture having a temperature of between 1200 and 1800 'C and a pressure of between 20 and 100 bar, cooling said gas mixture in the connecting conduit to a temperature of between 500 and 900 *C by injecting a liquid cooling medium and subsequently further cooling the gas in the synthesis gas cooling vessel to below 500 *C by contacting with water, wherein said cooling in the connecting tube and/or in the 10 synthesis gas cooling vessel is performed by injecting a mist of water droplets into the gas flow.

9. Process according to claim 8, wherein the injected water mist has a temperature of at most 50 'C below the bubble point of water at the pressure of the hot synthesis gas. 15

10. Process according to claim 8 or 9, wherein the mist comprises droplets having a diameter of from 50 to 200 pm and wherein the mist is injected with a velocity of between 30-100 m/s.

11. Process according to claim 10, wherein the mist is injected with a velocity of between 40-60 m/s. 20

12. Process according to any one of claims 8-1 1, wherein the mist is injected with an injection pressure of at least 10 bar above the pressure of the raw synthesis gas as present in the gasification reactor.

13. Process according to claim 12, wherein the mist is injected with an injection pressure of from 20-60 bar above the pressure of the raw synthesis gas as 25 present in the gasification reactor.

14. Process according to any one of claims 8-11, wherein the mist is injected using an atomising gas with an injection pressure between 5-20 bar above the pressure of the raw synthesis gas.

15. Gasification system comprising a gasification reactor and a synthesis 30 gas cooling vessel substantially as hereinbefore described with reference to any one of the embodiments as that embodiment is shown in the accompanying drawings. Dated 23 June 2010 Shell Internationale Research Maatschappij B.V. Patent Attorneys for the Applicant/Nominated Person 35 SPRUSON & FERGUSON