AU2012203881B2 - Synthetic resin bottle and process for molding the same - Google Patents

Abstract

SYNTHETIC RESIN BOTTLE AND PROCESS FOR MOLDING THE A synthetic resin bottle which is a biaxially drawn, blow molded bottle having a mouth opening portion disposed on a body, wherein the mouth opening portion has a bore diameter of 10 mm or less and that the maximum diameter of the body is 2.5 times or more, or even 3.0 times or more, as much as the bore diameter of the mouth opening portion wherein a maximum diameter portion of the body has a minimum wall thickness of 0.45 mm or more.

Description

S&F Ref: 933670D1 AUSTRALIA PATENTS ACT 1990 COMPLETE SPECIFICATION FOR A STANDARD PATENT Name and Address Yoshino Kogyosho Co., Ltd., of 2-6, Ojima 3-chome, of Applicant: Koto-ku, Tokyo, 1368531, Japan Actual Inventor(s): Katsuyoshi Inagawa Yusuke lshii Takashi Otsuka Takao lizuka Address for Service: Spruson & Ferguson St Martins Tower Level 35 31 Market Street Sydney NSW 2000 (CCN 3710000177) Invention Title: Synthetic resin bottle and process for molding the same The following statement is a full description of this invention, including the best method of performing it known to me/us: 5845c(6441596_1) 1 SYNTHETIC RESIN BOTTLE AND PROCESS FOR MOLDING THE SAME Field [0001] This invention relates to a synthetic resin bottle and especially a biaxially drawn, blow molded bottle of a small-sized and narrow-mouthed type, which is used as a makeup container for mascara and eyeliner, and to a process for molding the same. Background [0002] Patent Document 1 describes and invention concerning a biaxially drawn and blown molded bottle made of a propylene resin and a process for molding the same [Patent Document 1] JP-1997-52278 [0003] In recent years, many biaxially drawn, blow molded bottle have been in use in the field of small-sized, narrow-mouthed bottles to be filled with makeup liquids, such as mascaras and eyeliners. The mouth opening portion of narrow-mouthed bottles of this type has a bore diameter of about 10mm or less. Meanwhile, injection-molded performs to be biaxially drawn and blow molded into bottles have a shape of a test tube. The mouth opening portion is disposed in an upper portion, and is in the same shape as that of the bottles molded from these preforms. Due to the restriction on the structure of the injection mold, the perform body has a peripheral outer surface of an almost right circular cylinder. The outer diameter of the perform body is limited to a length somewhat larger than that of the mouth opening portion. Because cooling water is passed through the injection core mold, there is a limitation in decreasing the bore diameter of the perform body and increasing the thickness of the body. [0004] Because of the above-described limitations on the perform shape, the perform body wall thickness has to be set in a limited range. Especially in a case where the bottle has a substantially expanded body over the entire height range of the body or in a part of the height range, the expanded portion cannot have sufficient thickness. In that case, if the body is squeezed with fingers in the vicinity of the expanded portion, the body wall would easily get dented, and the contents may instantly burst outside. The bottle does not only give damage to its functions, but also it fails to feel well to the touch and fails to give the image of high 2 quality, thus affecting merchantability of the product. Accordingly, previous bottles have a number of disadvantages. Object of the Invention [0005] It is the object of the present invention to overcome or substantially ameliorate at least one of the above disadvantages. Summary of Invention [0006] There is disclosed herein a synthetic resin bottle which is a biaxially drawn, blow molded bottle having a body and a mouth opening portion, wherein the mouth opening portion has a bore diameter not greater than 10mm, the body having a body portion with a maximum diameter at least 2.5 times the bore diameter, said body portion having a minimum wall thickness of at least 0.45 mm. [0007] Preferably, said body maximum diameter is at least 3.0 times the bore diameter. [0008] Preferably, the bottle further includes a neck portion joining the mouth opening portion and the body, and wherein the neck portion is of a right circular cylinder configuration, and the mouth opening portion has an outer diameter and the neck portion has a minimum outer diameter ranging from the outer diameter of the mouth opening portion to no more than 2.0 times the bore diameter of the mouth opening portion. [0009] Preferably, the bottle is utilized as a container for accommodating a make-up liquid such as mascara or eyeliner. [00010] Preferably, a resin of the polypropylene series is used as the synthetic resin material for the bottle. [00011] Preferably, a resin selected from the polyethylene naphthalate and polyacrylonitrile series is used as the synthetic resin material for the bottle.

3 [00012] There is further disclosed herein a process for molding a synthetic resin bottle, the process comprising the steps of: (1) injection molding a preform in a shape of a tube taller than the bottle, wherein the preform has a cylindrical mouth opening portion disposed in an upper part of the preform, and wherein the mouth opening portion of the preform serves also as a mouth opening portion of the bottle product; (2) thermally shrinking the performs to provide a thermally shrunk perform, from an initial height so that portions other than the mouth opening portion of the preform are reduced in light; and (3) setting the thermally shrunk preform in a blow mold and biaxially drawing and blow molding the thermally shrunk perform into the bottle. [00013] Preferably, a bore diameter of 10 mm or less is set for the mouth opening portion of the preform and wherein a draw ratio of 2.0 times or more in the lateral direction is set for a maximum diameter portion of a body of the bottle. [00014] Preferably, the portions other than the mouth opening portion of the preform has a rate of thermal shrinkage in a range of 10 to 50%. [00015] Preferably, thermal shrinkage of the preform and preliminary heating for biaxially drawing and blow molding the preform are conducted simultaneously. [00016] Preferably, a synthetic resin is selected from a group comprising a resin of a polypropylene series, a resin of a polyethylene naphthalate series, or a resin of a polyacrylonitrile series. Brief Description of the Drawings [0017] A preferred form of the present invention will now be described by way of example with reference to the accompanying drawings wherein: Fig. 1 is an explanatory diagram showing an embodiment of the molding process of this invention.

4 Fig. 2 is a front view of the bottle of this invention molded by the molding process shown in Fig. 1, with a right half portion shown in a vertical section. Fig. 3 is a plan view of the bottle shown in Fig. 2. Fig. 4 is a front view, with the right half in a vertical section, of an example of the make up container for mascara, in which the bottle of Fig. 1 is utilized as the container. Description of References [00018] 1. Preform 2. Mouth opening portion of preform 3. Body 4S. Bottom (obtained after thermal shrinkage) 11. Bottle 12. Mouth opening portion of bottle 13. Body 13f. Maximum diameter portion 14. Bottom 15. Neck portion 16. Flat ring portion 17. Overhang 21. Cap 22. Application unit 22a. Shaft 22b. Brush 23. Built-in cylinder 23a. Squeezer HI, H2, H3. Height Dla. Bore diameter (of the mouth opening portion of the perform or the bottle) DIb. Outer diameter (of the mouth opening portion of the perform or the bottle) D2b. Outer diameter (of the bottle neck portion) D3bx. Maximum outer diameter (of the bottle body) 5 Preferred Embodiments [00019] This invention is further described with respect to preferred embodiments, now referring to the drawings. Fig. I is an explanatory diagram showing an embodiment of the molding process of this invention combined with the biaxial drawing and blow molding step. For the convenience of showing dimensional relationships, the injection molded preform I (partly shown in the vertical section) is superimposed with the bottle 11 (a front view drawn by a chain double dashed line), while respective mouth opening portions 2 and 12 are positionally aligned. Fig. 2 is a front view, with the right half in the vertical section, and Fig. 3, a plan view, respectively showing the embodiment of a synthetic resin bottle molded by the molding process shown in Fig. 1. Fig. 4 is a front view, with the right half in the vertical section, showing an example of a makeup container for mascara, in which this bottle is utilized. [00020] The perform 1 made of a polypropylene resin has the following dimensions: * Total height: 69.8 mm * Height HI excluding the mouth opening portion 2: 62.1 mm e Bore diameter Di a of the mouth opening portion 2: 8.3 mm * Outer diameter DIb of the mouth opening portion 2: 9.9 mm e Average outer diameter of the body 3: 11.6 mm * Wall thickness of the body 3: 3.05 mm * Weight: 4.4 g [00021] The bottle 1I shown in Fig. 2 is obtained by biaxially drawing and blow molding the above perform 1. The bottle 11 has a cylindrical neck portion 15, which has been blow molded to have a somewhat larger diameter than that of the mouth opening portion 12. Under the neck portion, and by way of a flatly disposed ring portion 16, the bottle has a body 13 blow molded in a substantially expanded shape. The bottle 11 has the following dimensions: e Bore diameter DIa of the mouth opening portion 12: 8.3 mm o Outer diameter DIb of the mouth opening portion 12: 9.9 mm " Total bottle height: 65.0 mm " Height H3 excluding that of the mouth opening portion 12: 57.3 mm * Outer diameter D2b of the neck portion 15: 14.0 mm (The neck portion in this embodiment has the shape of a right circular cylinder and the outer diameter D2b is equal to the minimum outer diameter).

6 * Maximum outer diameter D3bx of the body 13: 27.0 mm " Minimum wall thickness (n=6) for the maximum diameter portion of 13f of the body 13: 0.55 - 0.61 mm [00022] The above dimensions indicate that the maximum outer diameter of the body 13 is 3.3 times as much as the bore diameter DIa of the mouth opening portion 12 and that the (minimum) outer diameter Db2 of the neck portion 15 is larger than the outer diameter DIb of the mouth opening portion 12 and is 1.7 times as much as the bore diameter DIa of the mouth opening portion 12. [00023] Because cooling water is passed rough the injection core mold, there is a limitation in decreasing the diameter of the core mold. The bore diameter of the body 3 of the preform 1 is thus determined by the diameter of this core mold. In the case of the above bottle I1 having a slim, cylindrical neck portion 15, attention has to be paid to the dragging that occurs in the vicinity of the split blow mold cavity where this neck portion 15 is formed (because dragging tends to occur more frequently if the bottle 11 has a flat ring portion 16 as in this embodiment), and also to the lateral draw ratio in the biaxial drawing and blow molding to form the neck portion 15. If these points are taken into consideration, the outer diameter of the body 3 of the preform 1 is larger by only about 2 mm than the outer diameter DIb of the mouth opening portion 2 at the longest. In the case of the preform in this embodiment, the mouth opening portion 2 has a bore diameter DIa of 10 mm or less, and the thickness of the body 3 of the preform I inevitably has an upper limit of about 3 mm. [00024] The process for molding the preform 1 into the bottle 11 comprises the following steps of (1), (2), and (3): (1) heating the body 3 and the bottom 4 of the preform 1 except for the mouth opening portion 2 to a temperature of 120 to 130'C to make the portions other than the mouth opening portion 2 shrink from a height H 1; (This heating step doubles as preliminary heating for the biaxial drawing and blow molding. Standard preliminary heating is usually conducted at a temperature of about 1 00*C, but in this case, a higher temperature of 120 to 130*C is used so as to proceed with the thermal shrinkage to a large extent. Due to this thermal shrinkage, the bottom 4 goes up to the height position 4S as shown in Fig. 1 by a chain double-dashed line. The body 3 except for the mouth opening portion 7 12 would shrink to a height H2 of about 46 mm. The rate of shrinkage, calculated by a formula of ((HI - H2)/H1) x 100, accounts for about 26 percent). (2) taking out from the heating furnace to perform 1 that has been thermally shrunk in the step of (1), and setting the shrunk perform in the split blow mold; and (3) molding the bottle 11 in the biaxially drawing and blow molding step. [00025] As described above, the preform 1 has a height H2 of 46 mm after the thermal shrinkage step (1). This height is considerably smaller than the height H3 of the bottle 11, and thus, the preform 1 can be set smoothly in the split blow mold. The vertical draw ratio in the biaxial drawing and blow molding, as calculated by H3 1 H2, is about 1.25 times. The lateral draw ratio for the maximum diameter portion 13f of the body 13 of the bottle 11 is about 2.3 times. At this ratio, the minimum thickness of the peripheral wall in this portion is in a range of 0.55 to 0.61 mm. In this range, the wall would be sufficiently rigid with no dent in the wall of the body 3 in ordinary handling of bottles. [00026] If the preform was injection molded to give the height HI of 46 mm, assuming a vertical draw ratio of 1.25 times but without thermal shrinkage as has been so in prior art, then the weight limit is about 3.4 g, and the minimum thickness of the peripheral wall in the maximum diameter portion would be in a range of 0.4 to 0.45 mm. Thus, it has been confirmed that according to the above embodiment associated with the molding process of this invention, the minimum wall thickness in the maximum diameter portion 13f of the body 13 of the bottle 1 can be increased by about 1.4 times. [00027] An example of how the bottle 11 of this embodiment is used will be described below. Fig. 4 is a front view, with the right half in the vertical section, of an example of the make-up container for mascara, in which the bottle 11 of Fig. 2 is utilized as the container. The container comprises the bottle 11 and the roofed cylindrical cap 21 which is screwed on the mouth opening portion 12 of the bottle 1. The cap 21 is fitted around the neck portion 15, and softly covers the neck portion 15 to the lower end. From the roof ceiling hangs the application unit 22 comprising a shaft 22a and a brush 22b fitted at the front end of the shaft 22a. [00028] A built-in cylinder 23 made of an elastomer resin is fitted firmly inside the mouth opening portion 12 in an area ranging from the upper end of the mouth opening portion 12 to the upper end of the neck portion 15. This built-in cylinder 23 is provided with a funnel-shaped 8 squeezer 23a which performs a function of squeezing an extra amount of the make-up liquid from the brush 22b. [00029] When the bottle 11 is molded, an overhang 17 is formed on the inner peripheral surface of the bottle 11 on the border between the mouth opening portion 12 and the neck portion 15. A locking mechanism is formed by using this overhang 17 to prevent the built-in cylinder 23 from slipping out of the mouth opening portion 12. [00030] This invention has been described with respect to a preferred embodiment, but this invention should not be construed as limitative to the above embodiment. In addition to the PP resin, there are other synthetic resins, such as PEN and PAN resins, which have been used conventionally in the biaxial drawing and blow molding. All these resins have high rates of thermal shrinkage enough to adjust the height of the injection molded preform adequately in this invention. The above embodiment associated with the molding process comprises that the thermal shrinkage of the preform 1 doubles as the preliminary heating, but this step of thermal shrinkage may be separated from the preliminary heating step. The bottle of this invention does not necessarily have a limited use as a make-up container for mascaras and eyeliners described above in the embodiment. [000311 The preferred molding process of this invention comprises three steps of: (1) injection molding a perform in the shape of a test tube taller than the bottle wherein the perform has a cylindrical mouth opening portion disposed in an upper part of the perform, and wherein the mouth opening portion of the perform serves also as a mouth opening portion of the bottle product; (2) thermally shrinking the preform from an initial height so that portions other than the mouth opening portion of the preform would have a height that is smaller than that of the bottle; and (3) setting this thermally shrunk preform in a blow mold and biaxially 30 drawing and blow molding the preform into the bottle. [00032] How much thickness the body of a biaxially drawn, blow molded bottle can have would depend on how much weigh the portions other than the mouth opening portion of the preform can have. The above-described molding process is intended to increase this weight by injection molding the perform preliminarily to a height larger than that of the bottle.

9 [00033] Then, the tall perform is thermally shrunk so that the portions other than the mouth opening portion of the perform would have a height smaller than that of the portions other than the mouth opening portion of the bottle. [00034] Biaxial drawing and blow molding can be performed by setting the shrunk preform in a split mold used for that purpose. Since the initial preform has a greater height than the bottle, naturally the preform has a larger weight. Even in the case of a narrow-mouthed bottle having a relatively large expanded portion, the bottle would have a sufficient wall thickness. [00035] The larger the extent to which the preform is thermally shrunk, the higher the vertical draw ratio would be in the biaxial drawing and blow molding. When a high rate of thermal shrinkage is combined with the effect of drawing in the lateral direction, the resultant bottle would have higher rigidity than normal [00036] Another molding process in invention comprises in addition to the principal molding process described above, a bore diameter of 10 mm or less is set for the mouth opening portion of the preform and that a draw ratio of 2.0 times or more in the lateral direction is set for a maximum diameter portion of the bottle body. [00037] The preform body diameter is roughly determined by the diameters of the mouth opening portion of the bottle product. The minimum body wall thickness is determined by this preform body diameter and by the draw ratio in the lateral direction to be set for the maximum diameter portion of the bottle body. The molding process ensures a large action-and-effect to be performed in the biaxial drawing and blow molding of a bottle that is narrow-mouthed and yet has a substantially expanded portion in a part or in an almost entire height range of the body. Such a bottle is obtained under conditions that the mouth opening portion of the preform has a bore diameter of 10 mm or less and that the maximum diameter portion of the bottle body has a draw ratio of 2.0 times or more in the lateral direction [00038] Still another molding process comprises that the portions other than the mouth opening portion of the preform has a rate of thermal shrinkage in a range of 10 to 50%. [00039] It is preferred that the preform has a rate of thermal shrinkage in the range of 10 to 50%. At a rate less than 10%, no effective weight increase can be expected. At a rate exceeding 50%, 10 the preform could not help but shrink in a distorted shape because at such a rate, uniform drawing would become difficult in the biaxial drawing and blow molding operation [00040] Still another molding process comprises that thermal shrinkage of the preform and preliminary heating for biaxially drawing and blow molding the preform are conducted simultaneously. [00041] The molding steps can be simplified by simultaneously conducting the thermal shrinkage of the preform and the preliminary heating for the biaxial drawing and blow molding step. Naturally it is preferred to conduct these two steps separately if there is a large difference between the temperature best suited to the thermal shrinkage and the temperature suited to the biaxial drawing and blow molding step. [00042] Still another molding step comprises that the synthetic resin used is selected from a group comprising the resins of polypropylene series, polyethylene naphthalate series, and polyacrylonitrile series. [00043] The rate of perform shrinkage in the height direction caused by heating is determined mainly by the type of synthetic resins and the heating temperature. Among the synthetic resins used in the biaxial drawing and blow molding, the resins of the polypropylene (PP) series, the polyethylene naphthalate (PEN) series, and the polyacrylonitrile (PAN) series show relatively high rates of thermal shrinkage. [00044] The preferred synthetic resin bottle is a biaxially drawn, blow molded bottle having the mouth opening portion disposed on the body. The mouth opening portion has a bore diameter of 10 mm or less and that the maximum diameter of the body is 2.5 times or more, or even 3.0 times or more, as much as the bore diameter of the mouth opening portion. [00045] The narrow-mouthed bottle having a mouth bore diameter of 10 mm or less has limitations in the attempt to thicken the body wall of the preform in the shape of a test tube, which is used as a precursor in the above-described biaxial drawing and blow molding. The restricted upper limit to the preform body thickness can be supplemented to a satisfactory level by the above-described process for molding the synthetic resin bottle, i.e., by the process for thermally shrinking the perform having a greater height than that of the bottle product. The body wall thickness can be kept at a satisfactory level even if the body is expanded to a maximum 11 diameter 2.5 times or more as much as the bore diameter of the mouth opening portion, or even 3.0 times or more, depending on the bore diameter of the mouth opening portion and the type of the resin to be used. Thus, it becomes possible to provide a unique, synthetic resin bottle having a narrow mouth and yet having a substantially expanded body, made by the biaxially drawing and blow molding process. [00046] Another construction of the synthetic resin bottle is that, in addition to other features, the maximum diameter portion of the body has a minimum thickness of 0.45 mm or more. [00047] At a minimum thickness of 0.45 mm or more for the maximum diameter portion of the body, the body wall would not get dented easily by squeezing the areas nearby the expanded body portion with fingers. [00048] Still another construction of the synthetic resin bottle comprises that the mouth opening portion is disposed on the body by way of a neck portion in a shape of a right circular cylinder and that the neck portion has a minimum outer diameter ranging from the outer diameter of the mouth opening portion to 2.0 times or less as much as the bore diameter of the mouth opening portion. [00049] The above construction adds a new shape element to the bottle. This neck portion connected to the mouth opening portion is formed by biaxially drawing and blow molding the preform body in the same way as the bottle body is formed. The length and diameter of this neck portion, along with a cap fitted around this neck portion, give the bottle highly characteristic appearance. For use as a container for make-up liquids, such as mascaras or eyeliners, the bottle can be provided with a funnel-shaped squeezer, which can be fitted by utilizing an overhang formed on an inner peripheral wall at a lower end of the mouth opening portion at the time when the neck portion is formed. [00050] If the minimum outer diameter of the neck portion is set at a level considerably smaller than the maximum diameter of the body, e.g., 2.0 times or less as much as the mouth bore diameter, then attention has to be paid to the drawing in the lateral direction in the biaxial drawing and blow molding at the upper end of the preform body to be molded into this neck portion and to the ways to circumvent troubles, such as dragging caused by the split blow mold.

12 [00051] If these points are taken into consideration, limitations would become stronger in the ways to increase the outer diameter of the preform body. Therefore, in combination with the bore diameter of the mouth opening portion as small as about 10 mm or less, the upper limit to the preform body wall thickness would have to be restricted more and more. The molding process can make up for the restricted upper limit to the preform body wall thickness, thus making it possible to provide the bottle having above construction. By the way, this neck portion may also have the shapes of a right elliptical cylinder, a right oval cylinder, or a right square cylinder, in addition to the shape of a right circular cylinder. If the neck portion has a shape other than the right circular cylinder, the diameter would change in the peripheral direction. But since the minimum outer diameter limits any increase in the outer diameter of the preform body, the above construction specifies a constructive requirement that "the neck portion has a minimum outer diameter ranging from the outer diameter of the mouth opening portion to 2.0 times or less as much as the bore diameter of the mouth opening portion. [00052] Still another construction of the synthetic resin bottle comprises that a screw thread is notched on the outer peripheral surface of the mouth opening portion and that a cap in a roofed cylindrical shape is screwed on the mouth opening portion so as to cover the neck portion softly. [00053] Under the above construction, the container has a characteristic external appearance, which can be achieved by combining the shape of the neck portion, an expanded shape of the body, and the cap. [00054] Still another construction of the synthetic resin bottle comprises that the bottle is utilized as a container for accommodating a makeup liquid such as mascara or eyeliner. [00055] The preferred bottle is narrow-mouthed and yet has a substantially expanded body. The bottle may be provided with a slim neck portion. When combined with a cap and an application unit, the bottle can be utilized as a container for makeup liquid, such as mascara or eyeliner. Furthermore, the bottle can be differentiated from other makeup containers. [00056] Still another construction of the synthetic resin bottle comprises that a resin of the polypropylene series (hereinafter referred to as a PP resin) is used as the synthetic resin material for the bottle.

13 [00057] The PP resins are crystalline materials. These resins have the drawing properties largely dependent on temperatures in the biaxial drawing and blow molding, and tend to have considerably uneven body wall thickness. Thus, it has so far been difficult to biaxially draw and blow mold the preforms into the narrow-mouthed bottles having a substantially expanded body. On the other hand, the PP resins are the materials capable of having the rate of thermal shrinkage increased in the direction of preform height. The molding process can make up for the restricted upper limit to the preform body thickness to a satisfactory level. In other words, the process enables the preform to have a sufficiently high average wall thickness so as to be able to supplement uneven wall thickness. Therefore, it has become possible to provide a new, narrow mouthed PP resin bottle having a substantially expanded body. [00058] Still another construction of the synthetic resin bottle comprises that synthetic resin to be used is selected from a group comprising a polyethylene naphthalate (PEN) resin and a polyacrylonitrile (PAN) resin. [00059] The polyethylene naphthalate (PEN) resins and the polyacrylonitrile (PAN) resins are amorphous materials, but have relatively high glass transition temperatures. These resins, too, have the drawing properties largely dependent on temperatures in the biaxial drawing and blow molding, and tend to have considerably uneven body wall thickness. And like the PP resins, the PEN and PAN resins are capable of having the rate of thermal shrinkage increased in the direction of preform height, thus making it possible to provide a narrow-mouthed bottle having a substantially expanded body. [00060] The above molding process and the synthetic resin bottle having the above construction has the effects described below. In the first place, the molding process ensures that the preform has a larger weight now that the initially formed preform has been taller than the bottle formed therefrom. Thus, the process allows the bottle to have a sufficient body wall thickness, even though the bottle has a narrow mouth and a substantially expanded body. [00061] The larger the extent to which the preform is thermally shrunk, the higher the vertical draw ratio would be in the biaxial drawing and blow molding. When a high rate of thermal shrinkage is combined with the effect of drawing in the lateral direction, the resultant bottle would have higher rigidity.

14 [00062] The molding process ensures a large action-and-effect to be performed in the case of the preform having a bore diameter of 10 mm or less and the maximum diameter portion of the bottle body having a draw ratio of 2.0 times or more in the lateral direction. [00063] In the case where the portions other than the mouth opening portion of the preform have a rate of thermal shrinkage in the range of 10 to 50%, effective weight increase can be expected for the perform. [00064] The molding steps can be simplified by simultaneously conducting the thermal shrinkage of the preform and the preliminary heating for the biaxial drawing and blow molding step. [00065] If the synthetic resin to be used is selected from the group comprising a 20 polypropylene resin, a polyethylene naphthalate resin, and a polyacrylonitrile resin, then a relatively high rate of thermal shrinkage is obtained, and as a result, an effective increase in preform weight can be easily achieved. [00066] The construction of the synthetic resin bottle can be 25 achieved by the molding process combined with the biaxial drawing and blow molding step. The narrow-mouthed synthetic resin bottle made in the biaxially drawing and blow molding step has the following unique construction: (1) The bottle mouth opening portion has a bore diameter of 10 mm or less and that the maximum diameter of the body is 2.5 times or more, or even 3.0 times or more, as much as the bore diameter of the mouth opening portion. Thus, there is provided a bottle having a narrow mouth and yet having a substantially expanded body. (2) Sufficient body wall strength can be achieved by setting a minimum wall thickness of 0.45 mm or more for the maximum diameter portion of the body. (3) A new shape element found in the neck portion is added to the bottle to give the bottle unique appearance. This neck portion, combined with a cap, gives an additional change to the bottle appearance. As a container for makeup liquids, such as mascaras or eyeliners, the bottle can be provided with a funnel-shaped squeezer, which can be fitted by utilizing an overhang formed at a lower end of an inner peripheral wall of the mouth opening portion during the time when the neck portion is formed.

15 (4) Although relatively uniform drawing is difficult for the PP resin, a narrow mouthed PP resin bottle having a substantially expanded body can be provided by the molding process. [00067] The above-described synthetic resin bottle has a narrow mouth and yet has a substantially expanded body. The bottle can also be provided with a slim neck portion. When used as a container for make-up 5 liquids such as mascaras or eyeliners, the bottle should be differentiated from other products because of the new and unique shape. Industrial Applicability [00068] As described above in detail, the molding process of this invention can fully make up for the restricted upper limit to the perform body wall thickness. The bottle of this invention has a narrow mouth and yet has a substantially expanded body, and can be provided additionally with a slim neck portion. Because of its unique shape, the bottle is expected to have wide use in the field of narrow-mouthed bottles to be used as the containers for mascaras and eyeliners.

Claims (8)

1. A synthetic resin bottle which is a biaxially drawn, blow molded bottle having a body and a mouth opening portion, wherein the mouth opening portion has a bore diameter not greater than 10mm, the body having a body portion with a maximum diameter at least 2.5 times the bore diameter, said body portion having a minimum wall thickness of at least 0.45 mm.

2. The synthetic resin bottle according to claim 1, wherein said body maximum diameter is at least 3.0 times the bore diameter.

3. The synthetic resin bottle according to claim 1 or 2, further including a neck portion joining the mouth opening portion and the body, and wherein the neck portion is of a right circular cylinder configuration, and the mouth opening portion has an outer diameter and the neck portion has a minimum outer diameter ranging from the outer diameter of the mouth opening portion to no more than 2.0 times the bore diameter of the mouth opening portion.

4. The synthetic resin bottle according to claim 3, wherein the mouth opening portion has an outer peripheral surface with a screw thread, and the bottle further includes a cap of cylindrical shape having an end transverse wall, the cap being threaded to engage the mouth opening portion so that the cap softly covers the neck portion.

5. The synthetic resin bottle according to any one of claims 1 to 4, wherein the bottle is utilized as a container for accommodating a make-up liquid such as mascara or eyeliner.

6. The synthetic resin bottle according to any one of claims Ito 5, wherein a resin of the polypropylene series is used as the synthetic resin material for the bottle.

7. The synthetic resin bottle according to any one of claims 1 to 6, wherein a resin selected from the polyethylene naphthalate and polyacrylonitrile series is used as the synthetic resin material for the bottle. 17

8. A synthetic resin bottle, substantially as herein before described with reference to the accompanying drawings. Dated 2 July 2012 Yoshino Kogyosho Co., Ltd. Patent Attorneys for the Applicant/Nominated Person SPRUSON & FERGUSON