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AU2018204773B2 - Carpet tile - Google Patents
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AU2018204773B2 - Carpet tile - Google Patents

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Publication number
AU2018204773B2
AU2018204773B2 AU2018204773A AU2018204773A AU2018204773B2 AU 2018204773 B2 AU2018204773 B2 AU 2018204773B2 AU 2018204773 A AU2018204773 A AU 2018204773A AU 2018204773 A AU2018204773 A AU 2018204773A AU 2018204773 B2 AU2018204773 B2 AU 2018204773B2
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Australia
Prior art keywords
adhesive
carpet tile
carpet
manufacturing
base material
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AU2018204773A
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AU2018204773A1 (en
Inventor
Nobuki Miyauchi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Carpet Co Ltd
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JAPAN CARPET CO Ltd
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Publication date
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Priority to AU2018204773A priority Critical patent/AU2018204773B2/en
Publication of AU2018204773A1 publication Critical patent/AU2018204773A1/en
Application granted granted Critical
Publication of AU2018204773B2 publication Critical patent/AU2018204773B2/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G27/00Floor fabrics; Fastenings therefor
    • A47G27/04Carpet fasteners; Carpet-expanding devices ; Laying carpeting; Tools therefor
    • A47G27/0475Laying carpet tiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/08Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers using foamed adhesives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38Pressure-sensitive adhesives [PSA]
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
    • D06N3/144Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer with polyurethane and polymerisation products, e.g. acrylics, PVC
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0063Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0063Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
    • D06N7/0071Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0063Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
    • D06N7/0071Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing
    • D06N7/0076Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing the back coating or pre-coat being a thermoplastic material applied by, e.g. extrusion coating, powder coating or laminating a thermoplastic film
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0092Non-continuous polymer coating on the fibrous substrate, e.g. plastic dots on fabrics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/033 layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0253Polyolefin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0261Polyamide fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2471/00Floor coverings
    • B32B2471/02Carpets
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/314Applications of adhesives in processes or use of adhesives in the form of films or foils for carpets
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/24Presence of a foam
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00Presence of (meth)acrylic polymer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00Presence of polyurethane
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00Condition, form or state of the materials
    • D06N2205/04Foam
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/10Properties of the materials having mechanical properties
    • D06N2209/106Roughness, anti-slip, abrasiveness

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Carpets (AREA)
  • Floor Finish (AREA)

Abstract

] Mass production of carpet tiles can be enabled by a method for manufacturing a carpet tile by plying an adhesive layer to a carpet tile base material containing pile, the method including: a first ocess of mixing 15 to 25 wt.% of urethane resin glue to an acrylic foamed resin to produce 100 wt.% of a mixture, thereby obtaining an adhesive; a second process of subjecting the adhesive to viscosity adjustment adjust viscosity thereof to 3000 to 6000 cps; and a third process of applying the adhesive to the carpet tile .se material by using a screen mesh having a mesh thickness of 20 pm or more and less than 100 pm and L opening area ratio of 40% to 60%. 13

Description

[TITLE OF INVENTION] CARPET TILE [TECHNICAL FIELD]
[0001]
The present invention relates to a carpet tile, and in particular, the present invention
relates to an adhesive for a carpet tile exhibiting optimal adhesion by being used in a carpet
tile.
[BACKGROUND ART]
[0002]
The discussion of the background to the invention herein is intended to facilitate
an understanding of the invention. However, it should be appreciated that the discussion is not
an acknowledgement or admission that any aspect of the discussion was part of the common
general knowledge as at the priority date of the application.
[0003]
Unless the context requires otherwise, where the terms "comprise", "comprises" or
''comprising" are used in this specification (including the claims) they are to be interpreted as
specifying the presence of the stated features, integers, steps or components, but not
precluding the presence of one or more other features, integers, steps or components, or group
thereof.
[0004]
Carpet tiles are rectangular carpets. The greatest feature of carpet tiles is being
capable of carpeting only a necessary area with carpet tiles, and in recent years, carpet tiles
have been widely used mainly in offices. A normal carpet is required to have a size that fits in the size of a place to be carpeted, and a business model of build-to-order manufacturing is heavily used. However, in the case of the carpet tile, sites to be carpeted in various sizes can be carpeted with some carpet tiles that have the same size and are mass-produced, and this has an advantage in cost. Moreover, when a carpet tile is fouled, only this carpet tile can be replaced or washed. This point is also advantageous compared with conventional carpets.
[0005]
For example, if a sufficient friction force is not generated between a carpet and a floor
face at the time when someone walks on the carpet, carpet slips on the floor face, and thus, a
risk where the person falls down is generated. The size of the carpet tile is one severalth of
to several tenths of the size of a conventional carpet, and a friction force is thus difficult to be
generated, and such risk is thus easily generated. The most reliable technique for preventing
this risk can be said to be integrating the carpet tile and the floor face. Specifically, the floor
face may be carpeted with carpet tiles by applying glue to the floor face and thereafter
carpeting the floor face with carpet tiles.
[0006]
As carpet tiles become widely available, buildings mainly for use as offices based on
using carpet tiles come into use. Specifically, for example, there is a floor having a two-layer
structure (generally called as a double floor or a free-access floor) that easily achieves Internet
access by wiring in a space provided between the floors. The surface of this floor is uniform,
and a sufficient friction force thus can be generated between carpet tiles and the floor by using
an adhesive having a low adhesive force without bonding with glue, and anti-slip property can
be exhibited on the carpet tile.
[0007]
Glue is not used on the floor, and any special technique nor chemical agent is not
required to remove glue, and carpet tiles can be easily removed. Thus, an advantageous effect of being capable of readily replacing only a carpet tile that is fouled can be maximally exhibited.
[0008]
In recent years, a commercial product of a carpet tile that is sold in the state where an
adhesive has been applied to the back of the carpet tile in advance has been distributed. In
the case of using this type of carpet tile, the process of applying the adhesive to the base to be
carpeted is abbreviated, and the base to be carpeted is merely carpeted with the carpet tile.
Thus, an advance knowledge and skills are not required in carpeting. Therefore, the carpet
tile comes into use as a household carpet tile with which a flooring and a corridor are easily
carpeted.
[0009]
However, general adhesives cannot exhibit sufficient anti-slip property on all of the
floorings. For example, carpet tiles do not adhere to a base to be carpeted in the environment
containing dust and sand. Thus, a large friction force is not generated.
[0010]
In order to exhibit sufficient anti-slip property in such an environment, an adhesive
that generates a larger friction force may be used. However, when an adhesive force is
merely increased, the back of the carpet tile adheres to a floor face, and the condition is the
same as the case using glue.
[0011]
Generally, 16 to 20 carpet tiles are packed in a box and are shipped and sold. When
an adhesive force is increased, carpet tiles conglutinate with each other, and it is assumed to be
difficult to release carpet tiles at the time of taking carpet tiles out from the box and in
carpeting.
[0012]
It is thus required not to generate much adhesive force in the direction perpendicular
to the floor face and generate a strong adhesive force in the direction parallel with the floor
face. In order to solve this problem, technologies have been developed, and as shown in PTL
1, as an adhesive that exhibits sufficient anti-slip property on various floor faces, a technology
in which an adhesive is obtained by mixing a urethan resin glue with an acrylic foamed resin,
and the proportion of the urethane resin to be added is 10 to 30 wt.% was developed.
[CITATION LIST] [PATENT LITERATURE]
[0013]
Japanese Patent Application Publication No. 2014-158663
[SUMMARY OF THE INVENTION]
[0014]
In the composition described in PTL 1, the adhesion in the direction parallel with the
floor face and the adhesion in the direction perpendicular direction to the floor face are
sufficiently achieved. However, automation of a process of applying, required for
commercialization, i.e., large-scale production cannot be achieved. Furthermore, at about the
upper limit and about the lower limit of the proportion of the urethane resin to be added, some
floor faces could not exhibit sufficient performance.
[0015]
As a method for applying an adhesive to the back of a carpet tile, there is a method in
which a screen mesh in a shape of a pattern for applying an adhesive is caused to be close to
the back of a carpet tile, the adhesive is then applied from the top of the screen mesh to apply the adhesive from openings of the screen mesh. However, when the adhesive having the composition described in PLT 1 is used in this process, the adhesive is partially solidified, many lumps are generated, and the adhesive cannot smoothly pass through the screen mesh in many cases.
[0016]
When the screen mesh is released from the carpet tile after the completion of applying
the adhesive, the amount of the adhesive leaked from the screen mesh side toward to carpet
tile side is required not to be higher than expected. However, when a property of allowing
the adhesive to pass through the screen mesh is bad, the adhesive adheres to the screen mesh
surface side, the adhesive remains in an unintended line on the carpet tile, and a print pattern is
fouled in many cases.
[0017]
A plurality of carpet tiles are packed in a box such as cardboard and are shipped. At
that time, the carpet tiles are packed in a box in the state where backs of the respective carpet
tiles are faced to each other in many cases. This is employed to completely eliminate a risk
where the adhesive on the back, which may be generated in the case where the back of a carpet
tile and the surface of a carpet tiles are directly in contact with each other conglutinates with
pile on the surface.
[0018]
However, it is required to appropriately select a lattice pattern as a pattern for
applying an adhesive to have alternating relationship when the backs of carpet tiles are faced
to each other so that adhesives do not conglutinate with each other, and it is also required to
have production facilities for flipping carpet tiles over and facing backs of the respective
carpet tiles to each other when packing the carpet tiles in a box. It costs a lot.
[SOLUTION TO PROBLEM]
[0019]
According to one form of the present invention there is provided a method for
manufacturing a carpet tile by applying an adhesive layer to a carpet tile base material
containing pile, wherein the carpet tile base material includes a base material integrated with a
base fabric and a pile driven into the base fabric, and the method comprises a first process of
mixing 15 to 25 wt.% of urethane resin glue to an acrylic foamed resin to produce 100 wt.% of
a mixture, thereby obtaining an adhesive; a second process of adding a viscosity reducer to the
adhesive at a ratio of 10 to 20 wt.% of the viscosity reducer to 100 wt.% of the mixture,
thereby subjecting the adhesive to viscosity adjustment to adjust viscosity thereof to 3000 to
6000 cps; and a third process of applying the adhesive as an outermost surface layer of the
carpet tile, to a surface of the base material facing away from a surface of the base fabric into
which the pile is driven, by using a screen mesh having a mesh thickness of 20 Pm or more
and less than 100 pm and an opening area ratio of 40 to 60%.
[ADVANTAGEOUS EFFECTS OF INVENTION]
[0020]
With the use of the adhesive of the present invention, the kind of the base to be
carpeted that is limited when conventional adhesives are used is not limited because of the
strong adhesive force, and sufficient anti-slip property can be obtained regardless of the kind
of the floor face base to be used. Furthermore, by optimizing the process of drying, the
productivity of the process of applying is largely increased, and the yield in large-scale
production can be drastically improved (generation of errors in applying can be largely
decreased).
[0021]
Moreover, a strong adhesive force is generated in the direction parallel with the base,
and an adhesive force is barely generated in the direction perpendicular to the base. Thus,
even when pile on the surface of the carpet tile and the adhesive applied to the back are
directly in contact with each other, a risk where the adhesive conglutinates with the pile on the
surface is not generated. Thus, in a method for packing carpet tiles, carpet tiles can be
packed, the back of the pile on all of carpet tiles facing downward and the surface of the pile
on all of carpet tiles facing upward, and cost in packing can be reduced.
[0022]
It is also not required to select an appropriate pattern for applying the adhesive so that
adhesives are not directly in contact with each other when the backs are in contact with each
other. Thus, the pattern for applying the adhesive can be freely selected, and flexibility of
selecting an application design is drastically increased.
[0023]
Furthermore, coating characteristics of the adhesive in product shipping are largely
changed from those of the adhesive in applying by introducing a strictly controlled process of
drying after the process of applying the adhesive, and an adhesive that can sufficiently exhibit
anti-slip property on various floor faces at the time of product shipping and thus have really
specific and excellent coating characteristics was developed.
[BRIEF DESCRIPTION OF THE DRAWINGS]
[0024]
[FIG.1]
FIG. 1 is a drawing showing a carpet tile of the present invention.
[DETAILED DESCRIPTION OF EMBODIMENTS]
[0025]
The following describes an embodiment of the present invention with reference to an
attached drawing.
[0026]
FIG. 1 is a drawing showing a carpet tile of the present invention. The carpet tile of
the present invention is mainly composed of pile la, a base fabric lb, a base material Ic, and
an adhesive layer Id, and is manufactured by integrating the base fabric lb with the pile la
and a base material l cand thereafter applying an adhesive le to a face of the base material lc
on which the pile is not present to configure an adhesive layer ld. The carpet tile of the
present invention, however is the same as known carpet tile other than the configuration of the
adhesive layer ld.
[0027]
The present invention is described below using polypropylene as the pile la, any
nonwoven fabric or woven fabric as the base fabric, and polyvinyl chloride as the base
materials. Another material, for example, spun dyed nylon maybe used as the pile la.
[0028]
Furthermore, the configuration can be changed by, for example, arranging glass
nonwoven fabric inside the base material le and further arranging a felt layer and a polyvinyl
chloride layer between the base material le and the adhesive layer ld. All of the materials
that can be used in known carpet tiles can be employed, and the features of the present
invention lie in the material and amount of the adhesive, and the mass-production method for
manufacturing carpet tiles with the use of the adhesive.
[0029]
The adhesive le used in the adhesive layer ld of the present invention can be used in carpet tiles in all sizes. However, the amount of the adhesive le to be used changes according to the sizes. Therefore, the present invention is described assuming that the carpet tile has a size of 500 mm x 500 mm square, unless otherwise noted.
[0030]
As the adhesive le, a mixture obtained by mixing 80 wt.% of the acrylic foamed resin
2 and 20 wt.% of the urethane resin glue 3 was employed. As the acrylic foamed resin 2, an
acrylic copolymer aqueous emulsion obtained by dispersing fine particles of acrylic resin in
water is preferable. The foaming ratio of the acrylic foamed resin 2 is preferably in the range
of 1.5 times or more and less than 2.0 times. As the urethane resin glue 3, a mixture obtained
by mixing a surfactant or N-methyl-2-pyrrolidone in aliphatic polyester urethane and water is
preferable.
[0031]
At the above-mentioned ratio between the acrylic foamed resin 2 and the urethane
resin glue 3, the balance between anti-slip property and peeling property is the highest.
However, it has been turned out that the performance degradation is minimum when the
variation is about 5 wt.%. That is, the amount of the acrylic foamed resin 2 is allowed to be
from 75 wt.% to 85 wt.%, and the amount of the urethane resin glue 3 is allowed to be from 25
wt.% to 15 wt.%. The expression means that the amount of the urethane resin glue 3 is 25
wt.%, when the amount of the acrylic foamed resin 2 is 75 wt.%, and the amount of the
urethane resin glue 3 is 15 wt.% when the amount of the acrylic foamed resin 2 is 85 wt.%.
[0032]
It has also been turned out that when the amount of the acrylic foamed resin 2 and the
amount of the urethane resin glue 3 exceed these values, for example, the amount of the
acrylic foamed resin 2 is 70 wt.%, and the amount of the urethane resin glue 3 is 30 wt.%,
sufficient anti-slip property can be exhibited on most of bases, and however, variations in drying conditions and the like lead to dirt on the pile surface. That is, when the amount of the acrylic foamed resin 2 is 69 wt.% or less, and the amount of the urethane resin glue 3 exceeds 31 wt.%, properties of the adhesive change from adhesive-like properties to glue-like properties, a carpet tile strongly adheres to a base in carpeting, and the ease of replacement of the carpet tile, which is a feature of the carpet tile is affected. This is thus unfavorable.
[0033]
A viscosity reducer (catalyst) 4 is added in addition to the acrylic foamed resin 2 and
the urethane resin glue 3. The viscosity reducer (catalyst) 4 is preferably an inorganic
salt-based catalyst aqueous solution and preferably contains about 10% to about 20% of
ammonium nitrate. The viscosity of the adhesive layer ld after being shipped as a carpet tile
1 can be adjusted to be optimal when the viscosity reducer (catalyst) 4 is added, and spreading
out the adhesive le on the entire screen mesh and certainly applying the appropriate amount of
the adhesive le can be easily performed when the viscosity of the entire adhesive le in
manufacturing is reduced.
[0034]
The amount of the viscosity reducer (catalyst) 4 to be added is preferably 10 wt.%.
The total weight of the acrylic foamed resin 2 and the urethane resin glue 3 is defined to be
100 wt.% (generally referred to as PHR), and based on this, the percentage by weight of the
additive is calculated. Thus, the total amount of the acrylic foamed resin 2, the urethane resin
glue 3, and the additive exceeds 100 wt.%.
[0035]
To finely adjust the viscosity of the adhesive le, 0.1 wt.% of the thickener 5 is added.
The thickener 5 is preferably a mixture of a nonionic surfactant, water and the like. The
viscosity is adjusted to be in the range from 3000 to 6000 cps, and an ideal viscosity is 4500
cps. It is more preferred that the viscosity is adjusted to be close to the ideal viscosity.
[0036]
Necessary components of the adhesive le are an acrylic foamed resin 2 and a
urethane resin glue 3. However, when the viscosity of the adhesive le is adjusted to be in the
range from 3000 to 6000 cps by the combination of the viscosity reducer (catalyst) 4 and the
thickener 5, and, in particular, when the viscosity is adjusted to the vicinity of an ideal value
- 4500 cps, the composition of the adhesive le may not be the same as described above.
That is, when the viscosity is in this range without the thickener 5, the thickener 5 may not be
used.
[0037]
The adhesive le added as mentioned above is applied to a carpet tile using a screen
mesh. Various patterns (for example, Japanese Patent Application Laid-open No.
2013-118913, Japanese Examined Patent Publication No. H06-68205) have conventionally
been developed for applying an adhesive. Any pattern can be employed as a pattern for
applying the adhesive le of the present invention.
[0038]
Carpet tiles are shipped in the state where a plurality of carpet tiles are put in a box.
At that time, generally, backs face to each other to reduce a risk of adhesion of the adhesive to
the pile. When adhesives are directly in contact with each other in this state, adhesives
conglutinate with each other and are difficult to be released from each other in sites to be
carpeted in some cases. In order to prevent this, there is a method for inserting release paper,
for example. However, a larger amount of release paper waste is generated in the sites to be
carpeted.
[0039]
In order to solve this problem, a lattice pattern (checkered pattern) is used as the
pattern for applying an adhesive so that adhesives are not directly in contact with each other when backs of the respective carpet tiles face to each other. That is, a pattern of alternating relationship is employed.
[0040]
The adhesive le of the present invention has a feature of having really favorable
anti-slip performance in the parallel direction and barely exhibiting adhesion in the
perpendicular direction. Thus, the adhesive le does not at all adhere to the pile la when
carpet tiles are put in one direction, and the adhesive layer ld and the pile la are directly in
contact with each other.
[0041]
Thus, in shipping of carpet tiles, involving a cost, it is not required to employ a
technique of facing backs to each other, carpet tiles are put in a box in sequence, with the
surface of the carpet tile 1 on the pile la side facing downward and the back of the carpet tile 1
on the adhesive le side facing upward, and a sheet of release paper is put on the adhesive layer
1d of the last carpet tile (the carpet tile packed on the top), to eliminate the possibility of
conglutinating the pressure-sensitive adhesive layer Id and the box. As the release paper,
single-sided cardboard (or one side cardboard) is optimal.
[0042]
When carpet tiles are packed using this technique, the adhesive le and the pile la do
not conglutinate with each other even in the case where the weight is loaded on the carpet tiles
by, for example, stacking, after shipping, boxes in which the carpet tiles are packed. Thus,
there is no ban on stacking.
[0043]
In contrast, when backs face to each other, and adhesives le are directly in contact
with each other, the adhesives le conglutinate with each other without selecting appropriate
pattern for applying the adhesives le. This is not preferable. The adhesive le of the present invention exhibits really strong adhesive force. Thus, when an adhesive le of a carpet tile and a base material le of another carpet tile are directly in contact with each other, the adhesive le may conglutinate with the base material Ic. Also from this viewpoint, carpet tiles are desired to be packed not by a conventional method for packing carpet tiles using the technique of causing backs to be in contact with each other, but by the above-mentioned method.
[0044]
In the method for packing carpet tiles of the present invention, backs do not face to
each other. It is thus not required to select appropriate pattern for applying so that adhesives
le are not directly in contact with each other. Thus, any pattern for applying the adhesive can
be freely selected among various designs, and it is also not required to differently use a
plurality of patterns so that carpet tiles face complementary, and it is only required to control
the amount of the adhesive le to be applied using only one pattern.
[0045]
In the method for applying the adhesive, in the state where a screen mesh weaved
using polyester yarns that has a thickness from 20 to 100 pm is pressed against the carpet tile 1,
the adhesive is spread on the screen mesh using a squeegee rubber. By employing this
thickness, an excessively large mass of the adhesive le is not generated, and a risk where the
adhesive le is not sufficiently applied to carpet tiles because an excessively small mass of the
adhesive le lacks weigh to cause the adhesive le to stick to the screen mesh is eliminated.
[0046]
The design (pattern for applying) of the screen mesh may be any design. It is
however preferred that the number of meshes (the number of warp yarns and weft yams in one
square inch) is about 25 to about 60 meshes, and the opening are ratio (the proportion of the
openings in the screen mesh) is 40% to 60%.
[0047]
The rubber hardness of the squeegee rubber is preferably 50 to 80. The squeegee
angle that is an angle at which the squeegee rubber is caused to be in contact with the screen
mesh is preferably 450 to 600.
[0048]
By pressing the adhesive le from the top of the screen mesh using the squeegee
rubber, the adhesive le is applied to the back of the carpet tile 1 via openings of the screen
mesh. The larger the amount of the adhesive le to be applied is, the higher the anti-slip
performance is. However, the cost of the adhesive le is increased. Thus, the amount is
preferably less than 40 to 80 g/m2 per 1 m2 of the carpet tile. With the amount of the
adhesive to be applied of less than 40 to 60 g/m 2 , sufficient anti-slip performance can be
obtained except for the concretes that highly require anti-slip performance.
[0049]
Thereafter, drying is performed, and it has been turned out that the physical properties
of the adhesive change according to the method of this drying. In the method of the drying
by which an optimal viscosity can be obtained, obtained as results of earnest studies by the
inventors of the present inventions, the drying temperature is from 120°C to 150°C, and the
drying time is from 4 to 6 minutes. By employing this method of drying, a risk where a coat
is formed in the state where the surface of the adhesive le is dried quickly, and the process of
the drying is finished in the state where moisture inside the adhesive protected with the coat is
not sufficiently volatilized (a kind of half dry state) is eliminated, and the performance of the
adhesive layer l d can be stabilized.
[0050]
After finishing the process of the drying, the carpet tile may be packed for shipping
by the above-mentioned method.
[0051]
In the carpet tile of the present invention, manufactured by the method as described
above, the acrylic foamed resin 2 is formed as the material of the adhesive le. Thus, the
adhesive layer Id itself has cushioning properties. Therefore, shock absorption properties of
the entire carpet tile can be increased.
[0052]
The adhesion (the extent of stickiness) obtained by mixing urethane resin glue to an
acrylic resin is optimal, and a change in adhesion not only in first use but also in repeated use
is really small. The adhesion in the parallel direction (tensile strength) is strong, and however,
the adhesion in the perpendicular direction (release strength) is weak as compared with the
adhesion in the parallel direction. Thus, when the carpet tiles are stored, backs of the
respective carpet tiles are not required to be adhered to each other. Even when the pile is
caused to be in contact with the adhesive layer, a risk where the adhesive conglutinates with
the pile is eliminated.
[0053]
With the really strong adhesion in the parallel direction, a carpet tile that exhibits
anti-slip performance that is practically sufficient in an environment of much dust and sand in
which conventional carpet tiles are inapplicable is achieved. Even when the adhesive layer
1d is washed with water, the adhesive layer ld is hardly deteriorated, and even when the
adhesive layer Id is used in a carpet tile that is made washable, the washable properties can be
maintained.
[0054]
In the laboratory, the above-mentioned performance could have been exhibited.
However, the completed present invention makes it possible to stably manufacture the carpet
tiles in large-scale production lines and to provide an adhesive le that can stably exhibit anti-slip property on various bases and a carpet tile using the adhesive l e in the market.
[0055]
Example
The following describes the present invention in further detail with reference to an
example.
[0056]
As an acrylic foamed resin, 80 weight (g) of Crosslen CLF-1 manufactured by Aica
Kogyo Co., Ltd. was used, and as a urethane resin, 20 weight (g) of Sunplex PUE-160D
manufactured by Murayama Chemical Laboratory Co., Ltd. was used. In addition, as an
additive, 10 weight (g) of a catalyst #3000 manufactured by Matsui Shikiso Chemical Co.,
Ltd., which is a viscosity reducer was used, and 0.1 weight (g) of Nopal 700N manufactured
by San Nopco Limited, which is a thickener was used. PUE-160D has a foaming ratio of 1.5
to 2.0 times. In this case, the viscosity was 4500 cps.
[0057]
When the composition of these materials is calculated to be 100 % as a whole (in the
case where the percentage by weight is used, the PHR unit in which the total weight of the
acrylic foamed resin and the urethane resin that are main agents is 100), the percentage of
Crosslen CLF-1 is 72.6612%, the percentage of Sunplex PUE-160D is 18.1653%, the
percentage of catalyst #3000 is 9.08265%, and the percentage of Nopal 700N is 0.09083%.
[0058]
The adhesive le obtained by mixing these materials was applied to a carpet tile by
causing a squeegee rubber having a rubber hardness of 60 to be in contact with a screen mesh
having a mesh thickness of 50 pm, the number of meshes of 25, and an opening area ratio of
40% at an angle from 45 to 55°. The amount of the adhesive le to be applied is 12 to 16
g/m2 per one carpet tile. After applying the adhesive le, the carpet tile was dried at a drying temperature of 140°C for 6 minutes.
[0059]
Anti-slip performance was exhibited without any displacement even when the carpet
tile thus obtained was arranged under the environment of much dust and sand, and a force was
applied in the parallel direction in the state where feet of an 82.5-kg male are pressed to the
carpet tile. Furthermore, the carpet tile could be really easily released.
[0060]
The embodiment of the present invention is described above. A part or whole of the
embodiment of the present invention can be described as the following Supplementary Notes.
Supplementary Note 1
A method for manufacturing a carpet tile by applying an adhesive layer to a carpet tile
base material containing pile,
the method including:
a first process of mixing 15 to 25 wt.% of urethane resin glue to an acrylic foamed
resin to produce 100 wt.% of a mixture, thereby obtaining an adhesive;
a second process of subjecting the adhesive to viscosity adjustment to adjust viscosity
thereof to 3000 to 6000 cps; and
a third process of applying the adhesive to the carpet tile base material by using a
screen mesh having a mesh thickness of 20 pm or more and less than 100 pm and an opening
area ratio of 40% to 60%.
Supplementary Note 2
The method for manufacturing a carpet tile according to Supplementary Note 1,
wherein
in the third process, a squeegee rubber having a rubber hardness of 50 or more and
less than 80 is caused to be in contact with the screen mesh at an angle of 45 to 55° thereby applying the adhesive to the carpet tile base material.
Supplementary Note 3
The method for manufacturing a carpet tile according to Supplementary Note 1 or 2,
further comprising:
a fourth process of drying, after the third process, the carpet tile base material at a
drying temperature of 120°C or more and less than 150°C for 4 minutes or more and less than
8 minutes thereby drying the adhesive applied to the carpet tile.
Supplementary Note 4
The method for manufacturing a carpet tile according to Supplementary Note 3,
further comprising:
a fifth process of packing, after the fourth process, a predetermined number of carpet
tiles in a state, where the pile faces downward and the adhesive faces upward, into a box and
putting a sheet of release paper on the last carpet tile after packing the last carpet tile in the
box.
Supplementary Note 5
The method according for manufacturing a carpet tile to any one of Supplementary
Notes 1 to 4, wherein
a foaming ratio of the acrylic foamed resin is 1.5 times or more and less than 2.0
times.
Supplementary Note 6
The method for manufacturing a carpet tile according to any one of Supplementary
Notes I to 5, wherein
an amount of the adhesive to be applied in the third process is 40 to 80 g/m2 per 1 m2
of the carpet tile.
Supplementary Note 7
A carpet tile comprising an adhesive applied thereon, the adhesive having a viscosity
of 3000 cps or more to 6000 cps or less, and produced by mixing 15 to 25 wt.% of urethane
resin glue with an acrylic foamed resin to produce 100 wt.% of a mixture.
[REFERENCE SIGNS LIST]
[0061]
1 Carpet tile of the present invention
la Pile
lb Base fabric
1c Base material
1d Adhesive layer
le Adhesive of the present invention
2 Acrylic foamed resin
3 Urethane resin glue
4 Viscosity reducer(catalyst)
Thickener

Claims (7)

The claims defining the invention are as follows:
1. A method for manufacturing a carpet tile by applying an adhesive layer to a carpet tile
base material containing pile,
wherein the carpet tile base material includes a base material integrated with a base
fabric and a pile driven into the base fabric, and the method comprises:
a first process of mixing 15 to 25 wt.% of urethane resin glue to an acrylic foamed
resin to produce 100 wt.% of a mixture, thereby obtaining an adhesive;
a second process of adding a viscosity reducer to the adhesive at a ratio of 10 to 20
wt.% of the viscosity reducer to 100 wt.% of the mixture, thereby subjecting the adhesive to
viscosity adjustment to adjust viscosity thereof to 3000 to 6000 cps; and
a third process of applying the adhesive as an outermost surface layer of the carpet
tile, to a surface of the base material facing away from a surface of the base fabric into which
the pile is driven, by using a screen mesh having a mesh thickness of 20 Pm or more and less
than 100 pm and an opening area ratio of 40 to 60%.
2. The method for manufacturing a carpet tile according to claim 1, wherein
in the third process, a squeegee rubber having a rubber hardness of 50 or more and less than 80
is caused to be in contact with said screen mesh at an angle of 45 to 550 thereby applying the
adhesive to the carpet tile base material.
3. The method for manufacturing a carpet tile according to claim 1 or 2, further
comprising:
a fourth process of drying, after the third process, the carpet tile base material at a
drying temperature of 120°C or more and less than 150°C for 4 minutes or more and less than
8 minutes thereby drying the adhesive applied to the carpet tile.
4. The method for manufacturing a carpet tile according to claim 3, further comprising:
a fifth process of packing, after the fourth process, a predetermined number of carpet
tiles in a state, where the pile faces downward and the adhesive layer faces upward, into a box
and putting a sheet of release paper on the last carpet tile after packing the last carpet tile in the
box.
5. The method for manufacturing a carpet tile according to any one of claims 1 to 4,
wherein
a foaming ratio of the acrylic foamed resin is 1.5 times or more and less than 2.0 times.
6. The method for manufacturing a carpet tile according to any one of claims 1 to 5,
wherein
an amount of the adhesive to be applied in the third process is 40 to 80 g/m2 per 1 m 2 of the
carpet tile.
7. The method for manufacturing a carpet tile according to any one of claims 1 to 6,
wherein the second process further comprises adding a thickener to the adhesive at a ratio of
0.1 wt.% of the thickener to 100 wt.% of the mixture.
Fig. 1 1/1
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140158276A1 (en) * 2012-12-10 2014-06-12 Higgins Research & Development, LLC Floor coverings with universal backing and methods of making, installing, and recycling
US20150159324A1 (en) * 2013-01-22 2015-06-11 Japan Carpet Co. Ltd. Tile carpet

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140158276A1 (en) * 2012-12-10 2014-06-12 Higgins Research & Development, LLC Floor coverings with universal backing and methods of making, installing, and recycling
US20150159324A1 (en) * 2013-01-22 2015-06-11 Japan Carpet Co. Ltd. Tile carpet

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