AU538535B2 - Production of urethanes - Google Patents
Production of urethanesInfo
- Publication number
- AU538535B2 AU538535B2 AU63713/80A AU6371380A AU538535B2 AU 538535 B2 AU538535 B2 AU 538535B2 AU 63713/80 A AU63713/80 A AU 63713/80A AU 6371380 A AU6371380 A AU 6371380A AU 538535 B2 AU538535 B2 AU 538535B2
- Authority
- AU
- Australia
- Prior art keywords
- production
- lead
- salts
- catalysts
- tin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 150000003673 urethanes Chemical class 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 230000032050 esterification Effects 0.000 abstract 2
- 238000005886 esterification reaction Methods 0.000 abstract 2
- 239000011133 lead Substances 0.000 abstract 2
- 239000002841 Lewis acid Substances 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 abstract 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 abstract 1
- 150000001242 acetic acid derivatives Chemical class 0.000 abstract 1
- 125000005595 acetylacetonate group Chemical group 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- PBIBSLUOIOVPLU-UHFFFAOYSA-N bis(2-ethylhexyl)-oxotin Chemical compound CCCCC(CC)C[Sn](=O)CC(CC)CCCC PBIBSLUOIOVPLU-UHFFFAOYSA-N 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 150000003841 chloride salts Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000012975 dibutyltin dilaurate Substances 0.000 abstract 1
- LQRUPWUPINJLMU-UHFFFAOYSA-N dioctyl(oxo)tin Chemical compound CCCCCCCC[Sn](=O)CCCCCCCC LQRUPWUPINJLMU-UHFFFAOYSA-N 0.000 abstract 1
- 150000007529 inorganic bases Chemical class 0.000 abstract 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000005474 octanoate group Chemical group 0.000 abstract 1
- 150000007530 organic bases Chemical class 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 150000003141 primary amines Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/75—Amino or imino radicals, acylated by carboxylic or carbonic acids, or by sulfur or nitrogen analogues thereof, e.g. carbamates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
- C07D295/20—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carbonic acid, or sulfur or nitrogen analogues thereof
- C07D295/205—Radicals derived from carbonic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/91—Dibenzofurans; Hydrogenated dibenzofurans
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/46—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings substituted on the ring sulfur atom
- C07D333/48—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings substituted on the ring sulfur atom by oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Furan Compounds (AREA)
- Heterocyclic Compounds Containing Sulfur Atoms (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Pyridine Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Peptides Or Proteins (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Circuits Of Receivers In General (AREA)
- External Artificial Organs (AREA)
Abstract
1. A process for the production of urethanes by reacting a) urea or polyurets with b) primary amines and c) alcohols in the presence of catalysts at temperatures in the range from 120 to 350 degrees C, characterised in that the reaction is carried out in the presence of any esterification catalysts for carboxylic acids with the proviso that, in the production of di- and/or polyurethanes, the esterification catalysts are selected from the group comprising (i) inorganic or organic bases which are inert under the reaction conditions, (ii) Lewis acids, (iii) salts or complex compounds of transition metals, except for alcoholates of titanium, and (iv) lead naphthenate, acetyl acetonates of lead, aluminium or magnesium, dibutyl tin dilaurate, dibutyl tin diacetate, di-(2-ethylhexyl)-tin oxide, dioctyl tin oxide, tin salts of C1 -C20 -carboxylic acids and also acetates, chlorides, sulfates or octoates of divalent lead.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE29434819 | 1979-10-27 | ||
| DE19792943481 DE2943481A1 (en) | 1979-10-27 | 1979-10-27 | METHOD FOR PRODUCING URETHANES AND THE USE THEREOF FOR PRODUCING ISOCYANATES |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU6371380A AU6371380A (en) | 1981-04-30 |
| AU538535B2 true AU538535B2 (en) | 1984-08-16 |
Family
ID=6084534
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU63713/80A Ceased AU538535B2 (en) | 1979-10-27 | 1980-10-27 | Production of urethanes |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0027940B2 (en) |
| JP (1) | JPS57114561A (en) |
| AT (1) | ATE4640T1 (en) |
| AU (1) | AU538535B2 (en) |
| BR (1) | BR8006849A (en) |
| CA (1) | CA1144562A (en) |
| DE (2) | DE2943481A1 (en) |
| ES (1) | ES8106883A1 (en) |
| ZA (1) | ZA806546B (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3110573A1 (en) * | 1981-03-18 | 1982-10-21 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING N- AND O-SUBSTITUTED DI- AND / OR POLYURETHANES |
| DE3523692A1 (en) * | 1985-07-03 | 1987-01-08 | Basf Ag | METHOD FOR PRODUCING (OMEGA) -ISOCYANATOALKYL (METH) ACRYLATES |
| US4925971A (en) * | 1987-12-08 | 1990-05-15 | Asahi Kasei Kogyo Kabushiki Kaisha | Method for producing aliphatic o-arylurethanes |
| DE4342426A1 (en) * | 1993-12-13 | 1995-06-14 | Bayer Ag | Process for the preparation of diurethanes and their use in the preparation of diisocyanates |
| DE4441176A1 (en) | 1994-11-18 | 1996-05-23 | Bayer Ag | Polyisocyanates containing allophanate groups |
| DE19523386A1 (en) * | 1995-06-23 | 1997-01-09 | Bayer Ag | Process for removing by-products from diurethanes |
| DE19541384A1 (en) * | 1995-11-07 | 1997-05-15 | Basf Ag | Process for the preparation of organic diurethanes and / or polyurethanes and their use for the preparation of di- and / or polyisocyanates |
| WO2001047870A2 (en) * | 1999-12-27 | 2001-07-05 | Huntsman International Llc | Process for the production of aromatic polycarbamates |
| US9150502B2 (en) * | 2009-03-26 | 2015-10-06 | Mitsui Chemicals, Inc. | Urethane compound and method for producing the same, and isocyanate and method for producing the same |
| JP5499023B2 (en) * | 2009-04-09 | 2014-05-21 | 三井化学株式会社 | Method for producing urethane compound and method for producing isocyanate |
| JP5643517B2 (en) * | 2010-02-04 | 2014-12-17 | 三井化学株式会社 | Catalyst treatment method |
| JP5518605B2 (en) * | 2010-07-07 | 2014-06-11 | 三井化学株式会社 | Toluene dicarbamate production method, toluene diisocyanate production method, and toluene dicarbamate |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2409712A (en) * | 1944-02-03 | 1946-10-22 | Du Pont | Chemical process and products |
| US2806051A (en) * | 1955-11-01 | 1957-09-10 | Goodrich Co B F | Method for preparing urethanes by reacting urea, amines and an alcohol |
| DE2917493A1 (en) * | 1979-04-30 | 1980-11-13 | Basf Ag | METHOD FOR PRODUCING ALIPHATIC AND CYCLOALIPHATIC DI- AND POLYURETHANES |
| DE2917569A1 (en) * | 1979-04-30 | 1980-11-13 | Basf Ag | METHOD FOR PRODUCING AROMATIC DI- AND POLYURETHANES |
-
1979
- 1979-10-27 DE DE19792943481 patent/DE2943481A1/en not_active Withdrawn
-
1980
- 1980-10-11 AT AT80106196T patent/ATE4640T1/en not_active IP Right Cessation
- 1980-10-11 DE DE8080106196T patent/DE3064837D1/en not_active Expired
- 1980-10-11 EP EP80106196A patent/EP0027940B2/en not_active Expired
- 1980-10-20 CA CA000362772A patent/CA1144562A/en not_active Expired
- 1980-10-24 ES ES496232A patent/ES8106883A1/en not_active Expired
- 1980-10-24 BR BR8006849A patent/BR8006849A/en unknown
- 1980-10-24 ZA ZA00806546A patent/ZA806546B/en unknown
- 1980-10-25 JP JP55148903A patent/JPS57114561A/en active Granted
- 1980-10-27 AU AU63713/80A patent/AU538535B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CA1144562A (en) | 1983-04-12 |
| DE3064837D1 (en) | 1983-10-20 |
| EP0027940B1 (en) | 1983-09-14 |
| EP0027940B2 (en) | 1986-12-30 |
| JPH0314819B2 (en) | 1991-02-27 |
| ES496232A0 (en) | 1981-09-16 |
| ATE4640T1 (en) | 1983-09-15 |
| EP0027940A1 (en) | 1981-05-06 |
| ES8106883A1 (en) | 1981-09-16 |
| DE2943481A1 (en) | 1981-05-07 |
| ZA806546B (en) | 1981-11-25 |
| JPS57114561A (en) | 1982-07-16 |
| BR8006849A (en) | 1981-04-28 |
| AU6371380A (en) | 1981-04-30 |
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