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AU577382B2 - Preparing aldehydes from olefins - Google Patents
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AU577382B2 - Preparing aldehydes from olefins - Google Patents

Preparing aldehydes from olefins

Info

Publication number
AU577382B2
AU577382B2 AU43218/85A AU4321885A AU577382B2 AU 577382 B2 AU577382 B2 AU 577382B2 AU 43218/85 A AU43218/85 A AU 43218/85A AU 4321885 A AU4321885 A AU 4321885A AU 577382 B2 AU577382 B2 AU 577382B2
Authority
AU
Australia
Prior art keywords
carbon atoms
water
olefins
preparing aldehydes
soluble
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU43218/85A
Other versions
AU4321885A (en
Inventor
Helmut Dr. Bahrmann
Boy Dr. Cornils
Werner Dr. Konkol
Wolfgang Dr. Lipps
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ruhrchemie AG
Original Assignee
Ruhrchemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ruhrchemie AG filed Critical Ruhrchemie AG
Publication of AU4321885A publication Critical patent/AU4321885A/en
Application granted granted Critical
Publication of AU577382B2 publication Critical patent/AU577382B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00Compounds having —CHO groups
    • C07C47/02Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

1. A process for preparing aldehydes by the reaction of olefins having 6 to 20 carbon atoms with carbon monoxide and hydrogen in liquid phase in the presence of water, rhodium in metallic form or as a compound and a water-soluble arylphosphine at temperatures of 20 to 150 degrees C and pressures of 1 to 200 bar (100 to 2 X 10**4 kPa), characterised in that the water-soluble phosphine has the general formula : see diagramm : EP0163234,P6,F2 where Ar denotes an aryl group and X a sulfonic acid group, x**1 , x**2 and x**3 are 0 or 1 subject to the condition that at least one number x**1 , x**2 or x**3 is 1, A stands for an alkyl or, aralkyl radical having 7 to 18 carbon atoms and B, C and D are straight-chain or branched alkyl radicals having 1 to 4 carbon atoms and n is an integer between 1 and 3.
AU43218/85A 1984-06-01 1985-05-31 Preparing aldehydes from olefins Ceased AU577382B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19843420491 DE3420491A1 (en) 1984-06-01 1984-06-01 METHOD FOR PRODUCING ALDEHYDES
DE3420491 1984-06-01

Publications (2)

Publication Number Publication Date
AU4321885A AU4321885A (en) 1985-12-05
AU577382B2 true AU577382B2 (en) 1988-09-22

Family

ID=6237409

Family Applications (1)

Application Number Title Priority Date Filing Date
AU43218/85A Ceased AU577382B2 (en) 1984-06-01 1985-05-31 Preparing aldehydes from olefins

Country Status (13)

Country Link
EP (1) EP0163234B1 (en)
JP (1) JPS611633A (en)
KR (1) KR880001353B1 (en)
AT (1) ATE50556T1 (en)
AU (1) AU577382B2 (en)
BR (1) BR8502451A (en)
CA (1) CA1244053A (en)
DE (2) DE3420491A1 (en)
HU (1) HU204249B (en)
PL (1) PL253588A1 (en)
RO (1) RO91880B (en)
SU (1) SU1537134A3 (en)
ZA (1) ZA853971B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU597652B2 (en) * 1986-05-13 1990-06-07 Ruhrchemie Aktiengesellschaft Process for the preparation of aldehydes using preformed rhodium complex catalysts
AU605773B2 (en) * 1986-07-10 1991-01-24 Union Carbide Corporation Hudroformylation using low volarile/organic soluble phosphine ligands

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3420493A1 (en) * 1984-06-01 1985-12-05 Ruhrchemie Ag, 4200 Oberhausen QUARTERS OF AMMONIUM SALTS OF SULPHONED TRIARYLPHOSPHINS
DE3534314A1 (en) * 1985-09-26 1987-04-02 Ruhrchemie Ag METHOD FOR PRODUCING ALDEHYDES
DE3546123A1 (en) * 1985-12-24 1987-06-25 Ruhrchemie Ag METHOD FOR PRODUCING ALDEHYDES
US4825003A (en) * 1986-09-17 1989-04-25 Mitsui Toatsu Chemicals, Incorporated Production process of 2-chloropropionaldehyde
US4731486A (en) * 1986-11-18 1988-03-15 Union Carbide Corporation Hydroformylation using low volatile phosphine ligands
US5113022A (en) * 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
DE3942954A1 (en) * 1989-12-23 1991-06-27 Hoechst Ag PROCESS FOR THE PREPARATION OF ALDEHYDE
FR2671078A1 (en) * 1990-12-31 1992-07-03 Rhone Poulenc Chimie REAGENT AND METHOD FOR THREE - PHASE HYDROCARBONYLATION.
US5215667A (en) * 1991-08-20 1993-06-01 Exxon Chemical Patents Inc. Method for separating water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
US5288818A (en) * 1991-08-20 1994-02-22 Exxon Chemical Patents Inc. Method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
DE4242725A1 (en) * 1992-12-17 1994-06-23 Hoechst Ag Process for the production of higher, predominantly unbranched, primary alcohols
DE4440552A1 (en) * 1994-11-12 1996-05-15 Hoechst Ag Process for the preparation of formyl carboxylic acid esters
US6756411B2 (en) 1995-06-29 2004-06-29 Sasol Technology (Proprietary) Limited Process for producing oxygenated products
KR100451631B1 (en) * 2002-05-17 2004-10-08 주식회사 바름인 Preparation of fermented soybean product enriched γ-aminobutylic acid and phytoestrogens using Bifidobacterium breve K-110 of korean-type lactic acid bacteria
KR100460697B1 (en) * 2002-06-01 2004-12-09 고을빛 생식마을 (주) Manufacturing Method for Soaking and Germinated Soybean Containing High Isoflavone
DE102008044783B4 (en) 2008-08-28 2012-05-16 Oxea Gmbh Process for the recovery of aliphatic C3 to C10 aldehydes from high boilers by thermal treatment
DE102009004655B4 (en) 2009-01-15 2013-02-14 Oxea Gmbh Process for the preparation of aldehydes
DE102009016651B4 (en) 2009-04-07 2011-11-17 Oxea Gmbh Process for the preparation of aldehydes

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU541966B2 (en) * 1979-03-28 1985-01-31 Union Carbide Corporation Hydroformylation catalyst reactivation
AU557579B2 (en) * 1982-09-18 1986-12-24 Ruhrchemie Aktiengesellschaft Perparation of aldehydes
AU572641B2 (en) * 1984-04-10 1988-05-12 Ruhrchemie Aktiengesellschaft Aldehydes from olefins by hydroformylation

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3928232A (en) * 1972-10-24 1975-12-23 Chevron Res Aryl sulfonate stabilized cobalt carbonyl complex compounds
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
FR2314910A1 (en) * 1975-06-20 1977-01-14 Rhone Poulenc Ind Aldehyde prepn. by olefine hydroformylation in liquid phase - using catalyst system contg. sulphonated aryl phosphine and rhodium (NL 22.12.76)
FR2473504A1 (en) * 1979-10-31 1981-07-17 Rhone Poulenc Ind Aldehyde prepn. from hydrogen, carbon mon:oxide - and olefin, in presence of cobalt cpd. and water soluble phosphine
GB2085874B (en) * 1980-09-04 1984-08-08 Johnson Matthey Plc Hydroformylation of olefins

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU541966B2 (en) * 1979-03-28 1985-01-31 Union Carbide Corporation Hydroformylation catalyst reactivation
AU557579B2 (en) * 1982-09-18 1986-12-24 Ruhrchemie Aktiengesellschaft Perparation of aldehydes
AU572641B2 (en) * 1984-04-10 1988-05-12 Ruhrchemie Aktiengesellschaft Aldehydes from olefins by hydroformylation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU597652B2 (en) * 1986-05-13 1990-06-07 Ruhrchemie Aktiengesellschaft Process for the preparation of aldehydes using preformed rhodium complex catalysts
AU605773B2 (en) * 1986-07-10 1991-01-24 Union Carbide Corporation Hudroformylation using low volarile/organic soluble phosphine ligands

Also Published As

Publication number Publication date
ZA853971B (en) 1986-01-29
EP0163234A2 (en) 1985-12-04
RO91880B (en) 1987-07-31
SU1537134A3 (en) 1990-01-15
JPH0140019B2 (en) 1989-08-24
PL253588A1 (en) 1986-02-11
ATE50556T1 (en) 1990-03-15
HUT39703A (en) 1986-10-29
EP0163234A3 (en) 1987-05-27
JPS611633A (en) 1986-01-07
RO91880A (en) 1987-07-30
KR860000237A (en) 1986-01-27
CA1244053A (en) 1988-11-01
AU4321885A (en) 1985-12-05
DE3576150D1 (en) 1990-04-05
EP0163234B1 (en) 1990-02-28
KR880001353B1 (en) 1988-07-28
BR8502451A (en) 1986-01-28
HU204249B (en) 1991-12-30
DE3420491A1 (en) 1985-12-05

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