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AU599125B2 - Plastic coated foil sheets, plates, boards, wall panels or moulded parts - Google Patents
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AU599125B2 - Plastic coated foil sheets, plates, boards, wall panels or moulded parts - Google Patents

Plastic coated foil sheets, plates, boards, wall panels or moulded parts Download PDF

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Publication number
AU599125B2
AU599125B2 AU76664/87A AU7666487A AU599125B2 AU 599125 B2 AU599125 B2 AU 599125B2 AU 76664/87 A AU76664/87 A AU 76664/87A AU 7666487 A AU7666487 A AU 7666487A AU 599125 B2 AU599125 B2 AU 599125B2
Authority
AU
Australia
Prior art keywords
foil sheet
plastic
ethylene
fabric
accordance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU76664/87A
Other versions
AU7666487A (en
Inventor
Heinz Altmann
Heinrich Dr. Heitz
Wolfgand Hilf
Helmut Loos
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alkor GmbH Kunstoffverkauf
Original Assignee
Alkor GmbH Kunstoffverkauf
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alkor GmbH Kunstoffverkauf filed Critical Alkor GmbH Kunstoffverkauf
Publication of AU7666487A publication Critical patent/AU7666487A/en
Application granted granted Critical
Publication of AU599125B2 publication Critical patent/AU599125B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers

Landscapes

  • Laminated Bodies (AREA)
  • Panels For Use In Building Construction (AREA)
  • Finishing Walls (AREA)
  • Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The invention relates to laminar or plastic-coated films, sheets, boards, wall panels or moulded objects in which at least one layer or coating has a certain melt flow index and consists of a copolymer, terpolymer, block copolymer or a blend of ethylene and acrylic acid and/or methacrylic acid and/or maleic acid or maleic anhydride and/or vinyl acetate, including ethylene/acrylic acid/acrylate, ethylene/methacrylic acid/acrylate or ethylene/methacrylic acid/methacrylate, and has a quite specific acid or acetate content. At least one printed layer, preferably a colour printed layer, is arranged on top, over part of or the entire surface, and a transparent or translucent sealing layer or lacquer layer is arranged over the entire surface of the plastic film, sheet, board or plastic layer printed over the entire surface or part of the surface with a printed layer, preferably a colour layer, covering over the printed layer and any unprinted areas of the plastic film, sheet, board or plastic layer.

Description

599-125
AUSTRALIA
Patents Act COMPLETE SPECIFICATION
(ORIGINAL)
Class Int. Class Application Number: Lodged: Complete Specification Lodged: Accepted: Published: Priority LThis document contains the amendmnents made uncr I Section 49 and is correct for printing.__
II
t t Related Art: APPLICANT'S REFERENCE: Sei/Gei AL 86/6 Name(s) of Applicant(s); ALKOR GrnbH Kunststoffe Address(es) of Ap,'licant(s): Morgensternstrasse 9, D-8000, Munchen 71, FEDEP7-' REPUBLIC OF GERMANY.
Address for Service is; PHILLIPS ORMONDE" FA FITZPATRICK Patent and Trade Mark Attorlieys 367 Collins Street Melbourne 3000 AUSTRAI Complete Specification for the invention entitled: PLASTIC COATED FOIL SHEETS, PLATES, BOARDS, WALL PANELS OR M'OULDED PARTS Our Ref 60808 POF Code: 28113/71564 The following statement is a ,uJl description of this inve~tion, inclading the best method of perfoikming it known to applicant(s)i ~1 /2 6003g/l 1-
N
r ii"-:~t I L11~- lili~ lll~PPL~L~^ -2- Plastic coated foil sheets, plates, boards, wall panels or moulded parts.
This invention refers to plastic coated foil sheets composed from at least one plastic foil sheet, which has one or se'eral layers, of which at least one layer or coating, preferiably the entire plastic foil sheet is based on a copolymer, terpolymer, blockpolymer or on a composition to be selected from .chylene and acrylic acid, ethylene and methacrylic acid, ethylene and maleic acid, ethylene and maleic acid anhydride or vinyl acetate, including ethylene-acrylic acid-acrylic acid ester, ethylene-methacrylic acid-acrylic acid ester or ethylene-methacrylic acid-mthacrylic acid ester, with an acrylic acid or methacrylic acid content or maleic acid or maleic acid anhydride content of 2 to 20% by mass, preferably 3 to 15% by mass, or vinyl acetate content of to 5% by mass, preferably 35 to 15% by mass, while the melt flow index of the plastic foil sheet (2.16kg, 190°C, 10 min) is 0.2 to 300 preferably to and the thickness of the single or multiple layered plastic foil sheet is um to 600 um, preferably um to 350 um.
Plastic coated foil sheet when used in the description and in the claims means plastic coated foil sheet, plate, board, wall panel or moulded part.
Plastic foil sheet when used in the description and in the claims means plastic foil sheet, plate, board, plastic film or plastic coating.
Fleeces are already known, which have a similar plastic coating. The water absorbing capacity of these fleeces in the dry state is, however, above 150 g/A2, mainly 200 to *44* 4.
*i 44 4 4 0e
S
S
Sia 4s*t
S
re, i -3- 650 g/m 2 Such fleeces have, in this respect, a very high absorbing capacity and are used as drip protection. This property is, howeve-, disturbing for several applications as the high water absorption of the fleece results in swelling, thus impairing and damaging the appearance of the fleece.
In the case of colour printing there is the risk of the print or the colour dissolving and the water absorption resulting in colouring or staining. Furthermore, there is the danger that microorganisms such as mould could develop due to the high water absorption.
Consequently, the airm and the task of this invention was to find plastic coated foil sheets, composed from at least one plastic foil sheet, which has one or several layers, of which at least one layer or coating, preferably the entire plastic foil sheet is based on a copolymer, terpolymer, blockpolymer or on a composition to be selected from ethylene and acrylic acid, ethylene and methacrylic acid ethylene and maleic acid, ethylene and maleic acid anhydridge or vinyl acetate, including ethylene-acylic acid -acrylic acid ester, ethylene-methacrylic acid-acrylic acid ester or ethylene-methacrylic acid-methacrylic acid ester, with an acrylic acid or methacrylic acid content or maleic e* acid or maleic acid anhydride content of 2 to 20% by mass, preferably 3 to 15% by mass, or vinyl acetate of 45 to 5% by mass, preferably 35 to 15% by mass, which have a decorative appearance and do not suffer considerable colour damages and decolourisation and the like, even when influenced by humidity or moisture.
The plastic foil sheet should firmly adhere, inter S. alia, to metal, plastic, timber and timber frame, preferably S" without the use of an adhesive layer, and in combination with the plastic coated foil sheet, should result in 9",9 improved properties for the wall panel or the moulded part.
It has been established according to this invention, that these aims are achieved and the tasks are fulfilled by plastic coated foil sheets which are composed from at least -one plastic foil sheet which has one of several layers, of "y which at least one layer or coating, preferably the entire
AB
Li -4plastic foil sheet is based on a copolymer, terpolymer, blockpolymer or on a composition to be selected from ethylene and acrylic acid, ethylene and methacrylic acid, ethylene and maleic acid, ethylene ard maleic acid anhydride or vinyl acetate, including ethylene-acrylic acid-acrylic acid ester, ethylene-methacrylic acid-acrylic acid ester or ethylene-methacrylic acid-methacrylic acid ester, with an acrylic acid or methacrylic acid content or maleic acid or maleic acid anhydride content of 2 to 20% by mass, preferably 3 to 15% by mass, or vinyl acetate content of to 5% by mass, preferably to 15% by mass, while the melt flow index of the plastic foil sheet (2.16kg, 190 0 C, 10 min) is 0.2 to 300 preferably to and the thickness of the single or multiple layered plastic foil sheet is 10 um to 600 um, preferably 20 um to 350 um.
According to this invention, at least one printed coating, preferably coloured printed coating, is applied S partially or to the entire surface of the plastic foil sheet and onto the partially or fully covered with printed coating, preferably coloured printed coating, plastic foil sheet a transparent or translucent sealing coating or lacquer coating is applied, which covers the printed coating and, if applicable, the not printed parts of the plastic S foil sheet,, The printed coating or coloured printed coating is especially highly adhesive to the plastic foil sheet so .that good printability ald adhesion are present.
According to this invention, the plastic foil sheet is applied to a carriBr material selected from a foil sheet, toSf plate, board, wall pa',el, moulded part, or film composed substantially of metal, plastic or timber or a timber frame, S preferably without the intermediate use of an adhesive layer.
SAB
.r ~slil.
According to another preferred embodiment, an additional lattice-structured fabric or an inlay from or based on cotton, flaked bast, linen, jute, synthetic wool, polyester or glass fibre is arranged on top of the transparent or translucent sealing coating or lacquer coating. Improved optical and decorative effects are achieved by this arrangement.
According to another embodiment, the sealing coating consists of thermoplastics, having a sealing range of minimum 20 0 C, preferably minimum 300C below the melting point or below the lower temperature limit of the melting range of the fabric or inlay, which is arranged on top of it.
The sealing range is the range of temperature in which the plastic material becomes partially free-flowing thermoplastic so that bonding, adhesion or a partial penetration of the plastic material (in the case of fleeces of fabrics) onto or into the carrier material will become possible.
According to a further embodiment, a fleece, fabric, metallic foil or metallic coating is arranged between the plastic foil sheet based on a copolymer, terpolymer, So blockpolymer or on a composition selected from ethylene and o acrylic acid, ethylene and methacrylic acid, ethylene and maleic acid, ethylene and maleic acid anhydride or vinyl S acetate, including ethylene-acrylic acid-acrylic acid ester, .ethylene-methacrylic acid-acrylic acid ester or ethylene-methacrylic acid-methacrylic acid ester, with an acrylic acid or methacrylic acid content or maleic acid or maleic acid anhydride content of 2 to 20% by mass, S* preferably 3 to 15% by mass, or vinyl acetate 45 to 5% by mass, preferably 35 to 15% by mass, and the printing coating.
The weight per unit surface area of the plastic foil Sr sheet, said weight measured relative to untreated or raw i fleece or fabric without printing colour or surface treatment or surface coating agent, is 40 to 500 g/m 2 2 preferably 60 to 200 g/m and above 75% per weight, Spreferably above 90% per weight of the fleece or fabric ;H consists of one or more of the group of polyester, -6polyolefin, polyamide, fluorpolymer or glass fibres, or the fabric is a cotton fabric, flaked bast fabric, cotton-linen fabric, jute fabric, synthetic wool fabric or glass fibre fabric.
According to this embodiment the fleece or the fabric has a preference for surface structuring.
Furthermore, according to a preferred embodiment of the invention, the fleece or fabric after the application of the printing and sealing coating has a water absorption 2 2 capacity below 15 g/m 2 mainly below 8 g/m 2 The fleece is a pressed, preferably pre-strengthened and pressed fleece or is pressed during the process.
The plastic coated foil sheets are used, inter alia, as prefabricated building components and wall panels for the ship, vehicle, aircraft, building industries, as well as for industrial and domestic buildings, mainly for internal wall panels, internal wall decorating plates and internal building components in ships.
Figures 1 and 2 depict schematically forms s /me embodiments of the invention, wherein a double-layered foil "L *sheet, plate or board consisting of a plastic film S, on the basis of a copolymer, terpolymer, blockpolymer or a composition of ethylene and acrylic aeid or ethylene and methacrylic acid or vinyl acetate, arranged on a polyethylene layer The foil sheet, plate or table receives a printed coating on its top surface, either fully or partially covering the surface which in turn is covered by a transparent sealing layer. In figure 2, the number 5 represents a layer from metal, plastic or timber.
1*«o Summary The invention refers to layered or plastic coated foil sheets, plates, boards, wall panels or moulded parts, in which at least one layer or coat, with certain melt flow index, consists of a copolmer, terpolymer, blockpolymer or o*L« of a composition to be selected from ethylene and acrylic acid, ethylene and tethacrylic acid, ethylene and maleic acid or ethylene and Mtaleic acid anhydride
/#AB
i f| i; j i, -iFii ri~,, -7or vinyl acetate, including ethylene-acrylic acid-acrylic acid ester, ethylene-methacrylic acid-acrylic acid ester or ethylene-methacrylic acid-methacrylic acid ester and with a well defined acid or acetate content.
At least one printed coating, preferably coloured printed coating, is applied partially or to the entire surface of the plastic foil sheet, plate, board or plastic film, and onto the partially or fully covered with printed coating, preferably coloured printed coating, plastic foil sheet, plate, board or plastic film a transparent or translucent sealing( coating or lacquer coating is applied, which covers the printed coating and, if applicable, the not printed parts of the plastic foil sheet, 2late, board or plastic film.
SSW$
0 A4 Noa 4 4 e 0 0006
SOY
6 6 0 0 #at 4 04 4044 i
C
j

Claims (19)

1. A plastic coated foil sheet composed from at least one plastic foil sheet, which has one or several layers, of which at least one layer or coating, preferably the entire plastic foil sheet is based on a copolymer, terpolymer, blockpolymer or on a composition to be selected from ethylene and acrylic acid, ethylene and methacrylic acid, ethylene and maleic acid, ethylene and maleic acid anhydride or vinyl acetate, including ethylene-acrylic acid-acrylic acid ester, ethylene-methacrylic acid-acrylic acid ester or ethylene-methacrylic acid-methacrylic acid ester, with an acrylic acid, methacrylic acid, maleic acid or maleic acid anhydride content of 2 to 20% by mass, or vinyl acetate content of to 5% by mass while the melt flow index of the plastic foil sheet (2.16kg, 190 0 C, 10 min) is 0.2 to 300 and the thickness of the plastic foil sheet is 1 0 um to 600 um wherein at least one printed coating, preferably coloured printed coating, is applied partially or to the entire surface of the plastic foil sheet and onto the partially or fully covered with printed coating, preferably coloured printed coating, plastic foil sheet a transparent or translucent sealing coating or lacquer coating is applied, which covers the printed coating, and if applicable, the not i 1 printed parts of the plastic foil sheet. .j
2. A plastic coated foil sheet in accordance with claim 1, wherein the acrylic acid, methacrylic acid, nimalaic acid Sor maleic acid anhydride content is 3 to 15% by mass
3. A plastic coated foil sheet in accordance with claim 1 or claim 2 wherein the vinyl acetate content is 35 to 15% by mass S
4. A plastic coated foil sheet in accordance with any one r.
I3 I- -I i I rr :;url l r,*rrrr;ru;,rs IIIL.liil I-YCY__ Iti (-_-ilill* i^ll l i i..lii:.i i _i i. ii. i. -9- of claims 1 to 3, wherein the melt flow index of the plastic foil sheet (2.16kg, 190 0 C, l0min) is to A plastic coated foil sheet according to any one of claims; 1 to 4, wherein the thickness of the plastic foil sheet is 20um to 350um.
6. A plastic coated foil sheet in accordance with any one of claims 1 to 5, wherein the plastic foil sheet is applied to a carrier material selected from a foil sheet, plate, board, wall panel, moulded part or a film composed substantially of metal, plastic or timber or a timber frame.
7. A plastic coated foil sheet in accordance with claim 6, wherein the plastic foil sheet is applied to the carrier material without the intermediate use of an adhesive layer.
8. A plastic coated foil sheet in accordance with any one of claims 1 to 7, wherein an additional lattice-structured fabric or an inlay, is arranged on top of the transparent or translucent sealing coating or lacquer coating.
9. A plastic coated foil sheet in accordance with claim 8, wherein the additional lattice-structured fabric or inlay is an open fabric or inlay consisting substantially of cotton, flaked bast, lined, jute, synthetic wool, polyester or glass fiber.
10. A plastic coated foil sheet in accordance with claim 8 or claim 9, wherein the sealing coating consists of thermoplastics, having a sealing range of minimum 20 0 C below the melting point or below the lower temperature limit of the melting range of the fabric or inlay, which is arranged on top of it.
11. A plastic coated foil shoet in accordance with claim 10, wherein the sealing range is minimum 30 0 C below the melting point or below the lower temperature limit of the melting range of the fabric or inlay.
12. A plastic coated foil sheet in accordance with any one of claims 1 to 4, wherein a fleece, fabric, metallic foil or metallic coating is arranged between the plastic foil sheet based on a copolymer, terpolymer, blockpolymer or on a composition to be selected from ethylene and acrylic acid, AB 4, 44r 4 4 tt 4* 4 *444 1 4* *i 4 4444 II 4 $1.4 4- *0*4 *44e, 4 /xi .444 4UU 4 i :;f o! 4ni ta f i i i; ethylene and methacrylic acid, ethylene and maleic acid, ethylene and maleic acid anhydride or vinyl acetate, including ethylene-acrylic acid-acrylic acid ester, ethylene-methacrylic acid-acrylic acid ester or ethylene-methacrylic acid-methacrylic acid ester, with an acrylic acid or methacrylic acid content or maleic acid or maleic acid anhydride content of 2 to 20% by mass or vinyl acetate content of to 5% by mass and the printing coating.
13. A plastic coated foil sheet in accordance with claim 12, wherein the acrylic acid, methacrylic acid, maleic acid or maleic acid anhydride content is 3 to 15% by mass.
14. A plastic coated foil sheet in accordance with claim 12 or claim 13 wherein the vinyl acetate content is 35 to by mass. A plastic coated foil sheet in accordance with any one of claims 12 to 14, wherein the weight per unit surface area is 40 to 500 g/m 2 o said weight measured relative to an untreated or raw fleece or fabric without printing colour of surface treatment or surface coatinq agent, and wherein 9 sQ above 75% per weight of the fleece or fabric consists of one or more of the group of polyester, polyolefin, polyamide, fluorpolymer or glass fibres, or ileece or the fabric is a cotton fabric, flaked bast fabric, cotton-linen fabric, jute fabric, synthetic wool fabric or glass fibre fabric.
S
16. A plastic coated foil sheet in accordance with claim wherein the weight per unit surface area is 60 200 g/m'
17. A plastic coated foil sheet in accordance with claim or claim 16 wherein above 90% per weight of the fleece of fabric consists of one or more of the group of polyester, A olyolefin, polyamide, fluorpolyrer or glass fibres. i AB
18. A plastic coated foil sheet according to claim 1, substantially as herein before described with reference to any one of the~ accompanying drawings. DATED:
19 A PRIL, 1990 PHILLIPS ORMON'DE FITZPATRICK Attorneys For: ALKOR GmnbH KUIJSTOFFE AB
AU76664/87A 1986-08-12 1987-08-07 Plastic coated foil sheets, plates, boards, wall panels or moulded parts Ceased AU599125B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE8621594U DE8621594U1 (en) 1986-08-12 1986-08-12 Plastic coated plate
DE8621594 1986-08-12

Publications (2)

Publication Number Publication Date
AU7666487A AU7666487A (en) 1988-02-18
AU599125B2 true AU599125B2 (en) 1990-07-12

Family

ID=6797342

Family Applications (1)

Application Number Title Priority Date Filing Date
AU76664/87A Ceased AU599125B2 (en) 1986-08-12 1987-08-07 Plastic coated foil sheets, plates, boards, wall panels or moulded parts

Country Status (7)

Country Link
EP (1) EP0256275B1 (en)
KR (1) KR880002661A (en)
AT (1) ATE60259T1 (en)
AU (1) AU599125B2 (en)
BR (1) BR8704149A (en)
DE (2) DE8621594U1 (en)
ES (1) ES2019907B3 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU620153B2 (en) * 1989-09-29 1992-02-13 Sekisui Kagaku Kogyo Kabushiki Kaisha A thermosetting covering sheet and a method of forming hard coating on the surface of substrates using the same

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4208991A1 (en) * 1992-03-20 1993-09-23 Alkor Gmbh PLASTIC EDGEBAND, METHOD FOR THE PRODUCTION AND USE THEREOF
EP0595550A1 (en) * 1992-10-26 1994-05-04 Rohm And Haas Company Polyolefin substrates with improved adhesion properties

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1456899A (en) * 1973-04-04 1976-12-01 Kaiser E Prefabricated wall units
GB1511241A (en) * 1974-02-01 1978-05-17 Charlotte Investments Corp Laminate

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1456899A (en) * 1973-04-04 1976-12-01 Kaiser E Prefabricated wall units
GB1511241A (en) * 1974-02-01 1978-05-17 Charlotte Investments Corp Laminate

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU620153B2 (en) * 1989-09-29 1992-02-13 Sekisui Kagaku Kogyo Kabushiki Kaisha A thermosetting covering sheet and a method of forming hard coating on the surface of substrates using the same

Also Published As

Publication number Publication date
AU7666487A (en) 1988-02-18
ES2019907B3 (en) 1991-07-16
EP0256275A3 (en) 1988-08-17
DE8621594U1 (en) 1987-04-23
KR880002661A (en) 1988-05-10
EP0256275A2 (en) 1988-02-24
EP0256275B1 (en) 1991-01-23
BR8704149A (en) 1988-04-12
ATE60259T1 (en) 1991-02-15
DE3767602D1 (en) 1991-02-28

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