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AU599958B2 - Pile protection wrapping sheet - Google Patents
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AU599958B2 - Pile protection wrapping sheet - Google Patents

Pile protection wrapping sheet Download PDF

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Publication number
AU599958B2
AU599958B2 AU69498/87A AU6949887A AU599958B2 AU 599958 B2 AU599958 B2 AU 599958B2 AU 69498/87 A AU69498/87 A AU 69498/87A AU 6949887 A AU6949887 A AU 6949887A AU 599958 B2 AU599958 B2 AU 599958B2
Authority
AU
Australia
Prior art keywords
wrapping
pile
sheet
around
sealant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU69498/87A
Other versions
AU6949887A (en
Inventor
Anthony Edward John Strange
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NICC Ltd
Original Assignee
NICC Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NICC Ltd filed Critical NICC Ltd
Publication of AU6949887A publication Critical patent/AU6949887A/en
Application granted granted Critical
Publication of AU599958B2 publication Critical patent/AU599958B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02DFOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D5/00Bulkheads, piles, or other structural elements specially adapted to foundation engineering
    • E02D5/22Piles
    • E02D5/60Piles with protecting cases

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  • Engineering & Computer Science (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Paleontology (AREA)
  • Civil Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Bulkheads Adapted To Foundation Construction (AREA)
  • Piles And Underground Anchors (AREA)

Description

ra AU-AI-694 9 8 8 7 paCT WORLD INTELLECTl PR2 RT RO \TON i" INEN I A~l '1 TY \rIO INTERNATIONAL APPLICATION PUBLISHED UN R THE PATEN O iATION TREATY (PCT) (51) International Patent Classification 4 (11) International Publication Number: WO 87/ 05066 E02D 5/60 Al (43) International Publication Date: 27 August 1987 (27.08.87) I (21) International Application Number: PCT/GB87/00127 (22) International Filing Date: 20 February 1987 (20.02.87) (31) Priority Application Number: 8604285 (32) Priority Date: (33) Priority Country: 20 February 1986 (20.02.86) (71) Applicant (for all designated States except US): N.I.C.C.
LIMITED [GB/GB]; The Pound, Ampney Crucis, Cirencester, Gloucestershire GL7 5SA (GB).
(72) Inventor; and Inventor/Applicant (for US only) STRANGE, Anthony, Edward, John [GB/GB]; Lydiard House, 1 Tetbury Lane, Chariton, Nr. Malmesbury, Wiltshire (GB).
(74) Agents: WYNNE-JONES, John, Vaughan et al.; Wynne-Jones Laine James, 22 Rodney Road, Cheltenham, Gloucestershire GL50 1JJ (GB).
amendsints a ds r ec (81) Designated States: AU, BE (European patent), BR, CF (OAPI patent), CG (OAPI patent), CM (OAPI patent), DE (European patent), DK, FI, FR (European patent), GA (OAPI patent), GB (European patent), IT (European patent), JP, KP, KR, LK, MC, MG, ML (OAPI patent), MR (OAPI patent), MW, NL (European patent), NO, SE (European patent), SN (OAPI patent), SU, TD (OAPI patent), TG (OAPI patent), US.
Published With international search report.
A.O.Jp, 8 OCT 1987
AUSTRAUAN
-9 SEP 1987 TEt CE PATh~ ENT GICE (54) Title: IMPROVEME~N ATnT'TE9 O--TPH 4CTION OF PILES (57) Abstract A pile wrapper is in the form of a flexible sheet 2) which, when encircling a pile (11) has two contiguous edges.
These have abutments which are urged together by a power tool and fastened, conveniently by nuts (19) and bolts (18).
The hoop tension induced in the wrapper resists wave suction forces. The wrapper can have an inner layer containing a water resistant sealant which is forced into intimate contact with the pile as the tension is applied. The wrapper may also be given anti-fouling and cathodic protection properties.
k i- n- L I i WO 87/05066 PCT/G B87/00 127 -1- "Improvements relating to the Protection of Piles" This invention relates to the protection of piles or risers, such as those of oil rigs, piers or jetties. For convenience, the specification will simply refer to piles.
These are usually massive steel tubing, or concrete or wooden members. Although they may initially be painted or otherwise coated, they inevitably become subject to corrosion or bacterial attack in the hostile environment of sea water. This is particularly so over the splash zone, where the pile is alternately wetted and dried.
It is comparatively easy to apply a protective sheathing to such a structural member before it is placed in the sea, for the job can be done in comfortable and dry conditions. However, it is not always desirable to put such sheathing on beforehand, as it may easily be damaged in transit to the site. Also, of course, there are thousands of existing piles already in place, corroding away and needing attention.
S There have been various proposals for sheathing
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i Ai i i 2 such piles in situ. The difficulties are formidable, starting with the need in most cases to clean the pile of virtually every trace of marine growth and corrosion.
The favoured approach then has been to construct a jacket around the pile leaving an annular space, sealed around the bottom so that it can be emptied of water. Then a filler material is poured in; for example concrete is suggested in GB-A-1,352,226. Other proposals have been for an inert bonding material as in GB-A-1,546,710 and GB-A2,108,566. Such a jacket has to be tailor-made for the particular size of pile, and it also has to be in two parts at least so that it can be Sassembled around the pile. There also have to be spacers
S.
to keep the jacket uniformly distanced around the pile, "5 adding to the complexity and cost.
Another drawback is that once such sheathing has been fitted it is permanent unless completely destroyed. There can be no absolute guarantee that corrosion will be kept at bay by any of these systems, 20 and it is desirable from time to time to make a visual inspection. Existing sheathing systems of this sort make this extremely difficult and expensive, and there is the temptation to assume all is well underneath.
In GB-A-1,503,464 (Liddell) there is a flexible 25 sheet which wraps around a pile. The same technique is also described in GB 1,557,077, also of Liddell. The edges SL/MP 2 7- 77 I.
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0O S 3 which meet are provided with "pole pieces" of semi-circular cross section whose flat sides are put together and then rolled by a tool applied at one end. While this can draw the wrapping tight, it cannot do so over the entire surface area of the pile. There is inevitably a gap where one edge portion of the wrapping leaves the pile to wind around the combined pole pieces. That gap must, of course, then be closed at the ends. It follows that, the pole pieces cannot extend over the whole length of the wrapping, but must leave end portions to be closed tightly, against the pile when the roll has been completed. Part of Liddell's answer to this is the extra step of wrapping the pile with accurately spaced sealing bands at the top and bottom of the main sheet.
i5 Another drawback with Liddell is that by rotating from one end, long slim pole pieces are bound zo twist, and there will be uneven tension in the wrapping. It will tend ct be tighter at the top than at the bottom.
Nevertheless, a flexible wrapping drawn tight around 20 the pile is a simpler system and one that should give many advantages once the problems of Liddell are resolved, which the present invention aims to do. Furthermore it should allow fairly easy replacement, or even re-use after removal for inspection. It would also be advantageous to have a 25 wrapping that could sustain minor damage and keep its sealing properties for a reasonable length of time there- 3 3 i 4 Al^ 0 S S* 0 *5 -4 ct. 4 after, without deterioration. Any protective system should also advantageously be resistant to marine growth and, particularly for steel piles, protect against electrolytic action.
According to one aspect of the present invention there is provided a pile wrapping comprising a flexible sheet with substantially rigid members along substantially the entire length of the opposed edges which are adjacent when the wrapping is positioned .around a pile, the members affording means by which the wrapping can be tightened around the pile, characterised in that said members are in the form of outwardly extending flanges to provide :counter-abutments for the application of a tool by which DO the members can be closed together to impose hoop stresses on the wrapping, and.in that said flanges have apertures at intervals along their length to accept fastening elements securable while the hoops stresses are maintained.
The sheet will have a certain elasticity, but the hoop stresses applied can be made sufficient to prevent the sheet being sucked clean off the pile by wave action. They can also be evenly spread over the length of the wrapping.
The sheet preferably comprises an outer skin of water impermeable flexible material, such as reinforced plastics 0. sheet, and an inner layer of liquid permeable material such as felted or porous plastics material bonded to the Z skin and impregnated with a water resistant sealant. The 4 -4i II couter skin may have a thickness of the order of 3 mm, and a suitable material is that used for the skirts cf hovercraft. The thickness of the inner layer may be of the order of 6 mm, or at least sufficient to accommodate to variations in surface profile of that order of magnitude.
The wrapping is intended to go once around the pile, which is normally cylindrical. To help complete the seal at the contiguous edges the inner layer may have an extension beyond one of the opposed edges to tuck under the opposite one.
The sealant impregnated in the inner layer may have other properties beyond just being water resistant.
It may incorporate corrosion inhibiting and anti-fouling 15 components. Preferably, it will be in the form of a thixotropic gel and not form a permanent bond to a pile surface. Also the fastening means will generally be releasable, so that the wrapping can be easily removed for inspection, and later re-used.
20 The inner layer and sealant will generally be covered by a removable backing sheet on manufacture, which will be discarded before positioning around the pile.
The wrapping sheet may also be adapted to form an element of a cathodic protection system, being a carrier 25 for sacrificial anode material, or providing a jacket with a high dielectric constant, for example. It could SL/MP z fI
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also carry anti-fouling material externally.
To 4ssist in fitting this wrapping, the sheet may be outwardly provided with handles so that divers can manoeuvre it into position. Also, it will be advantageous to have temporary strap fasteners for holding the wrapping around a pile during an initial phase while at least some of the fastening elements are secured.
Conveniently, there will also be gauge marks on the outside of the sheet to provide an indication of the hoop stresses imposed. The fastening elements will usually be bolts.
According to another aspect of the present invention there is provided a method of protecting a pile comprising wrapping a sheet as outlined above around the pile, drawing said opposed edges together by at least one said tool to createhoop tensions that are resistant to wave suction forces, securing said fastening elements while the hoop stresses are maintained, and removing said tool or tools.
With the sealant version, this tensioning causes the sealant to exude into any surface irregularities. The pile will normally be cleaned first, but it need not be done so with the meticulousness of some previous systems. Any vestigial marine growths or other imperfections will be firmly encapsulated and rendered impotent due to lack of oxygen and/or reaction to corrosion or anti-fouling inhibitors.
For a fastening operation, tools may be engaged through some of the apertures to draw 0 5000 *C S ii
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1 i WO 87/05066 PCT/GB87/00127 7 the opposite edges together. Bolts are then engaged through others of said apertures in a first securing operation, the tools are removed, and replaced by bolts in a second securing operation.
The wrapping will usually be positioned at least partially under water and during the initial stages it will conveniently be supported by buoyancy bags as it is positioned by divers around the pile.
It is not practical to sheath a complete pile with a single such sheet. Where this is desired, a series of sheets will be wrapped around the pile-, butted together and sealing means applied around the butt joints.
For a better understanding of the invention, one embodiment will now be described, by way of example, with reference to the accompanying drawing, in which: Figure 1 is a perspective view of a wrapping sheet in preparation for installing around a pile, Figure 2 is a perspective view of the sheet in a first stage of installation, Figure 3 is a cross-section of the pile with the sheet secured around it, Figure 4 is a diagrammatic elevation of the co-operating edges of the wrapping sheet, and
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WO 87/05066 PCT/GB87/00127 -8 Figure 5 is a diagram of hydraulic closure apparatus.
The sheet is of composite construction having an outer skin 1 of material such as nylon reinforced Neoprene, 3mm thick, similar to hovercraft skirt material. Bonded to the rear side of this is an inner layer 2 of polypropylene felt, 6mm thick and impregnated with a polymeric thixotropic water-displacing gel sealant, formulated to act as a host for corrosion inhibitors and/or anti-foulants. It will be effective over a wide temperature range, say -40 C to 150 C.
On manufacture this felt is protected by a peel-off backing sheet 3, which remains during transport and handling and is only removed by the divers as they fit the wrapping around the pile. Handles 4 to assist that fitting operation are bonded or otherwise attached to the outer face of the skin 1, as are straps 5 and fasteners 6 for temporary use as described below. The skin 1 also has permanent datum marks 7 for checking the stability of the wrapping.
Sealing members 8 .i the form of substantially rigid flanges extend along the edges of the sheet that are to'meet when it has been wrapped around a S:pile. They will project radially outwardly and each has a series of apertures 9 which register when the SL/HGL *_7 .saaaa a WO 87/0;066 PCT/GB87/00127 -9wrapping is in place. The inner layer 2 is extended beyond one of the flanges 8 to form a flap 10 which will tuck under the opposite inner edge portion of the layer 2 and form an overlap, thus ensuring a good seal. If it is known that the wrapping will be used singly, the flanges 8 may extend the full length of their respective edges, but if several are to be used in series along a pile, the flanges 8 will be short of each end, by or thereabouts, for reasons explained below. Figures 1 and 2 show a hybrid, with the flanges 8 short at the top end only.
For installation, the sheet is folded concertina fashion as shown in Figure 1. It may be loosely held thus by ropes or straps. It is then supported by variable buoyancy bags and floated to the pile to be wrapped. Divers release and unfold it, wrapping it around the pile, which will have been locally cleaned as mentioned above. Once roughly in place, it can be loosely secured by the straps 5 and fasteners 6 as shown in Figure 2, and usually one at the top, one at the bottom and one at the middle will suffice. The wrapping can then be adjusted longitudinally of the pile 11.
Once precisely in position, porwer means are -9 applied to the members 8 to draw the wrapping tight.
In the preferred system, hydraulic rams 12 as shown
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1 T WO 87/05066 PCT/GB87/00127 in Figure 5 are used, attached to a diver operated handpump 13 via flexible hoses 14. These have swivel connections 15 at their ends to the rams 12 and to the T-pieces 16 or manifolds at the pump 13. Although only two rams are shown, for wrappings of any length it will be preferred to use three, applied to the top, bottom and middle of the members 8 adjacent the straps The ram rods 17 are inserted through the registering bolt apertures 9 and quick-lock nuts are fitted to their ends. The rams are then briefly actuated to apply a light tension to the wrapping.
Further rams operable by a second pump are then applied to other registering bolt apertures 9, preferably alternate ones, leaving half the apertures free. The temporary straps 5 can then be loosened or removed. One of the divers operates the first hand hydraulic pump to contract the rams at top and bottom and middle, and the second pump is operated to obtain even closure of the seal. Once the wrapping has been checked that it is free from wrinkles and correctly fSi? aligned, non-metallic bolts 18 are inserted into the vacant apertures, and nuts 19 are fitted and done up finger tight. The hydraulic pumps are then operated again to achieve full face to face closure of the sealing members 8. The nuts are tightened and the I;i l I"'1 i. SL/HGL
I
4 T i
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c~ WO 87/05066 PCT/GB87/00127 11 rams are removed.
This exposes the other half set of alternate apertures, into which bolts 18 are then fitted and secured by nuts 19. Tightening of these is completed, preferably using an air-operated "nut spinner", and then nylon locking rings are installed on each bolt.
During these tightening operations, the impregnated sealant will be exuded into any surface irregularities and between the members 8 to complete the encasement and protection of the wrapped zone.
Finally, the datum marks 7 are used to measure and note the extension achieved, and this will be compared against a table, and recorded for-future reference and checks.
Where a greater length of pile is to be wrapped, two or more such sheets are applied and butt jointed together, usingones where the members 8 do not extend right to the ends. There might be an overlap of the inner layers in the manner of the flap Over this joint there will be placed a band or "cumierbund", which is simply a foreshortened version of the wrapping described with similar flanges by which it is stretched tight and secured in the manner of the main wrappings. It may not need such a substantial inner layer and its flanges will preferably be offset
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~jll WO 87/05066 PCT/GB87/00127 2 circumferentially from those of the main wrappings to ensure a good seal. Generally, the flanges 8 of the main wrappings will be arranged to be downstream in relation to the most powerful tidal stream or current expected and the offset of any cummerbund will preferably be 10° 300 Such a wrapping can be removed by reversing this procedure. Unless ,ts removal is occasioned by damage it will normally be possible to replace it.
Minor punctures of the outer skin 1 will self seal as radial hoop stresses in the material will cause the permanently soft sealant impregnated in the inner layer to exude and fill a punctured cavity.
However, even major cuts and tears will remain stable, the tension placed on the material during installation being less than that which causes tears to propagate.
But, even though it will not be totally immune to damage, such a wrapping will provide additional impact resistance being, in effect, a cushion around the pile.
In general, a particular material for the outer skin 1 has not yet been settled and different ones may be suitable for different applications. Polyester reinforced polychloroprene is one further example beirg Sconsidered. Likewise there may be suitable materials for the inner layer 2 otTer than the polypropylene ii SL/HGL
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6 WO 87/05066 :4 PCT/GB87/00127 13 referred to above, and rather than felt the material may be homogeneous but porous.
It is envisaged that future applications for or modifications of the system will include the loading of polychloroprene rubber (forming the outer or only skin) with conductive particles of the type used in the construction of sacrificial anodes. An alternative approach is to make the wrapping, as a single or multi-skin jacket, of materials that will give it a very high dielectric constant; this alone should be an efficacious cathodic protection device.
Both forms will provide a flexible anode assembly or a shield by which cathodic protection effects could be directed into suspected vulnerable areas of subsea structures.
A further application is to use the system as a carrier for anti-foulant materials, preventing marine growth build up and consequent increase in current drag forces on subsea platform legs, risers and caissons. This could be achieved by providing an additional outer skin, conveniently a foamed polymer matrix for the ant-i-foulant material, such as copper particles. If used solely for this purpose the inner sealant layer could be dispensed with. It will be understood however, that a single wrapping could combine any of these functions.
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Claims (11)

1. A pile wrapping comprising a flexible sheet with substantially rigid members along substantially the entire length of the opposed edges which are adjacent when the wrapping is positioned around a pile,the members affording means by which the wrapping can Le tightened around the pile characterised in that said members are in the form of outwardly extending flanges to provide counter-abutments for the application of a tool by which the members can be closed together to impose hoop stresses on the wrapping, and in that said flanges have apertures at intervals along their length to accept fastening elements securable while the hoop stresses are maintained.
2. A wrapping as claimed in Claim 1, characterised in that the sheet comprises an outer skin of water impermeable S0I. flexible material, such as reinforced plastics sheet, and an o inner layer of liquid permeable material such as felted or :porous plastics material bonded to the skin and impregnated with a water resistant sealant.
3. A wrapping as claimed in Claim 2, characterised in 66oe that the inner layer has an extension beyond one said :opposed edge to tuck under the other opposed edge portion J I. whe .ie e when the wrapping is positioned around a pile.
4. A wrapping as claimed in Claim 2 or 3, characterised in that the impregnated sealant has corrosion inhibiting and/or anti-foulant properties, and is a thixotropic gel. l 1 I 1 A wrapping as claimed in Claim 2, 3 or 4, characterised in that the impregnated sealant does not form a permanent bond to a pile surface, and wherein the fastening means are releasable.
6. A wrapping as claimed in any one of Claims 2 to characterised in that the inner layer and sealant are covered by a removable backing sheet discarded before positioning around a pile.
7. A wrapping as claimed in any preceding claim, characterised in that the sheet is adapted to form an element of a cathodic protection system, being a carrier for sacrificial anode material or providing a jacket with a high dielectric constant.
8. A wrapping as claimed in any preceding claim, j characterised in that the sheet is outwardly provided with handles for assisting manoeuvring the wrapping into e position, and with temporary strap fastening means for holding the wrapping loosely in position around a pile while at least some of the fastening elements are secured.
9. A wrapping as claimed in any preceding claim, characterised in that the sheet is outwardly provided with gauge marks to provide an indication of the hoop stresses t imposed. 2 10. A wrapping as claimed in any preceding claim, characterised in that the fastening elements are bolti-.
11. A method of protecting a pile comprising wrapping a sheet according to any preceding claim around the pile, 1 1 *y 1 A• :K ii 1 7 1 1 1 16 drawing said opposed edges together by at least one said tool to create hoop tensions that are resistant to wave suction forces, securing said fastening elements while the hoop stresses are maintained, and removing said tool or tools.
12. A method as claimed in Claim 11, characterised I in that said tools are engaged through some of said apertures to draw the opposite edges together, whereafter bolts are engaged through others of said apertures in a first securing operation, and wherein the tools are removed and replaced by bolts in a second securing operation.
13. A pile wrapping substantially as hereinbefore described and with reference to and as shown in the accompanying drawings. DATED THIS 22ND DAY OF MAY, 1990 N.I.C.C. LIMITED By Its Patent Attorneys: GRIFFITH HACK CO., bel, Fellows Institute of Patent Attorneys of Australia *9 S *I 'a f 1 S 0 G
AU69498/87A 1986-02-20 1987-02-20 Pile protection wrapping sheet Ceased AU599958B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB868604285A GB8604285D0 (en) 1986-02-20 1986-02-20 Protection of piles
GB8604285 1986-02-20

Publications (2)

Publication Number Publication Date
AU6949887A AU6949887A (en) 1987-09-09
AU599958B2 true AU599958B2 (en) 1990-08-02

Family

ID=10593424

Family Applications (1)

Application Number Title Priority Date Filing Date
AU69498/87A Ceased AU599958B2 (en) 1986-02-20 1987-02-20 Pile protection wrapping sheet

Country Status (7)

Country Link
EP (1) EP0295254B1 (en)
JP (1) JPH01501641A (en)
AU (1) AU599958B2 (en)
BR (1) BR8707601A (en)
GB (1) GB8604285D0 (en)
OA (1) OA08904A (en)
WO (1) WO1987005066A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5476576A (en) * 1991-08-15 1995-12-19 Winn And Coales International Limited Impressed current cathodic protection system

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5102265A (en) * 1990-08-31 1992-04-07 T C Manufacturing Co., Inc. Adjustable width split sleeve and method of forming ends thereto
GB9207624D0 (en) * 1992-04-08 1992-05-27 Strange Anthony E J Improvements relating to the protection of corrosion-susceptible members

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU422555B2 (en) * 1966-09-09 1972-03-22 Divework Limited Improved method of and means for protecting underwater woodwork against attack by marine organisms
AU495705B2 (en) * 1976-06-28 1978-01-05 E. Liddell Orval Apparatus for protecting metallic structural elements against corrosion

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE411382A (en) *
US3939665A (en) * 1974-01-08 1976-02-24 Bethlehem Steel Corporation Method for protecting metal H-piling in underwater environments and protected H-piling
FR2337792A1 (en) * 1976-01-07 1977-08-05 Liddell Orval Metal building component corrosion protection equipment - comprises flexible plastic sheet with vertical bars held wrapped round component

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU422555B2 (en) * 1966-09-09 1972-03-22 Divework Limited Improved method of and means for protecting underwater woodwork against attack by marine organisms
AU495705B2 (en) * 1976-06-28 1978-01-05 E. Liddell Orval Apparatus for protecting metallic structural elements against corrosion

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5476576A (en) * 1991-08-15 1995-12-19 Winn And Coales International Limited Impressed current cathodic protection system

Also Published As

Publication number Publication date
EP0295254A1 (en) 1988-12-21
GB8604285D0 (en) 1986-03-26
OA08904A (en) 1989-10-31
EP0295254B1 (en) 1991-11-06
WO1987005066A1 (en) 1987-08-27
JPH01501641A (en) 1989-06-08
BR8707601A (en) 1989-03-14
AU6949887A (en) 1987-09-09

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