AU604764B2 - A method of manufacturing steel in a converter from a cold charge - Google Patents

Description

COMMONWEALTH OF AUSTRALIA 764 PATENTS ACT 1952 Formh SUBSTITUTE COMPLETE $,PECIFICATON FOR OFFICE USE Short Title: Int. Cl: Application Number: Lodged: Complete Specification-Lodged, Accepted: Lapsed: Published; Priority: Related Art: This documenit containsth amlenldiin t.S =mdC Under Section 49 adc is correct for printing.

TO BE COMPLETED BY APPLICANT Name of Applicant: Address of Applicant: Actual Inventor: Address for Service: NAUCHNO-PROIZVODSTVENNOE OBIEDINENIE

"TULACHERMET"

Ulitsa Frunze 10 kv. 124, TULA, U.S.S.R.

Gennady Sergeevich Kolganov; Stanislav Sergeevich Volkov; Jury Andreevich Rudnev; 'Vladimir Grigorievich Mizin and Evgeny Nektarievich Ivashina GRIFFITH HASSEL FRAZER 71 YORK STREET SYDNEY NSW 2000

AUSTRALIA

4 44 A Complete Specification for the invention entitled,- IINIE-T+KA-OF MELIGSE- ~3-E A Mdlo of __e/GN4,YE RTE R" mau-(oc4\'Knq .ee ea converteor r(roi't ao(a~ c/vrqe" The following statement is a full description of this invention, including the best method of performing it known to me/us:- 7915A/bm la The invention relates to metallurgy, and more particularly to a method of manufacturing steel in a converter from a cold charge.

The invention may be used for production of steel in an oxygen converter from solid metal iron-bearing materials. Such solid metal iron-bearing materials (metal charge) might be, for example, scrap, crop ends, metal waste from steel plants, as well as metallized pellets, sponge iron, etc.

Known in the art is a method of steel production in an oxygen converter with usage of a solid metal charge (DE,C,2719981, DE,C,2729982, DE, C,2729985).

S*t To produce steel by such a method, the oxygen converter is equipped with bottom and side tuyeres of "pipe- -in-pipe" type. Oxygen is injected through the central S, passage of these tuyeres and liquid or gaseous hydrocarbon fuel is supplied through exterior passages.

The converter is loaded with a solid metal charge which is first heated due to burning hydrocarbon fuel (gaseous or liquid) in an oxygen-containing gas which is injected through said tuyeres into the converter from bottom, and side (blowing). Being heated the soli,d metal charge is melted. Vhen the charge is melced (the metal bath is formed) at the zones of the tuyeres, milled pulverised) carbon-containing materials, such as coke, coal, graphite or their mixtures are loaded into the converter as an additional power carrier. The feed of the carbon-containing fuel is gradually reduced to a degree, which provides for the protection of the tuyeres from dest- -2ruction, i.e. to 8-12% (by volume) of oxygen consumption.

When the solid metal charge is completely melted the metal bath is refined by any known in the art method similar to the process of blowing iron. Heating the bath is obtained mainly with heat released by the reaction of oxidation of carbon dissolving in iron. At the same period milled lime is also loaded into the bath together with oxygen for forming slag. When the metal has the required temperature it is tapped from the converter.

The above technique of steel production permits to use available carbon-containing materials, such as coke, coal, graphite and their mixtures. However, for their preparation and transportation to a converter it is necessary to install additional equipment, what results in increasing capital investments.

In the process of melting oxygen moving through the liquid metal in the zones of the tuyeres is partly consumed for oxidation of iron what results in increasing slag quantity and ferrous oxide (FeO) content in it. Ferrous oxide forms lightly fusing eutectics with materials of the refractory lining, which being fused increase lining wear.

It is also known in the art "Method of production of steel in an oxygen converter" (International application SU 85/00025, 17.0L4.84).

This method is carried out in an oxygen converter, which is equipped with bottom and side tuyeres of "pipe- -in-pipe" type. Oxygen is injected through a central pasi~ ts_- sage of the tuyeres and liquid and gaseous hydrocarbons are injected through the exterior holes. It is a'lo provided the possibility for oxygen injection through an upper water-cooled lance.

SThe method includes the following technique processes: loading a solid metal charge, for example, metal scrap, with its subsequent heating and melting through burning hydrocarbon and solid carbon-containing fuels, charged successively during the process, in an oxygen-containing gas injected into the converter from bottom, top and side through said tuyeres. Then the carbonized iron melt is refined.

i The hot combustion products moving from bottom to I top heat the solid metal charge loaded in the converter.

i In the process of heating the solid metal charge an air enriched with oxygen is injected through said bottom tuyeres to burn the fuel. At the same time a pure oxygen is injected through a top lance and side tuyeres. Later in the process of melting and refining the carbonized iron melt the oxygen consumption in the oxygen-containing gas injected through the bottom tuyeres is increased to 100%.

This method based on varying an oxygen quantity in the oxygen-containing gas provides uniform heating of the solid metal charge and its subsequent thorough melting.

However, blowing the melt with an oxygen-containing gas during heating the solid metal charge and its melting results in forming a significant part of the slag of higher ferrous oxide (FeO) content. This is caused by oxidation L~ 4 of iron and coming iron oxides as rust into the bath together with iron-bearing materials. Ferrous oxide forms fusible eutectics with refractory lining materials, which are fused and thereby cause lining wear.

Besides, refining the carbonized iron melt under the slag of a higher ferrous oxide (FeO) content can cause metal and slag slopping from the converter, what tells negatively on the duration of the process.

It is an aim of the present invention to provide a method of melting steel in an oxygen converter from solid metal iron-bearing materials, which would permit to reduce the duration of the melting process and decrease converter lining wear.

Therefore, the present invention provides a method of manufacturing steel in a converter from a cold charge, ucomprising the steps of loading the charge in the converter, heating the charge in the converter to form a melt by burning successively charged hydrocarbon and solid carbon containing fuels in an oxygen containing gas injected into the converter from below, above and to the side of the charge, removing and oxidising slag from the surface of the melt when the melt is at a temperature of between 1525 0 C 1580 0 C and subsequently, loading solid carbon containing iron into the melt in an amount of 2-5% of the initial quantity of the cold charge.

Implementation of the present invention permits to control temperature and slag conditions of the melting.

It creates possibility to decrease the duration of the melting process, i.e. to heat the bath quicker. This is due to higher degree of the post-combustion of carbon monoxide. The degree of the post-combustion of carbon monoxide in the exhausted gases of the converter, in the case if there is no liquid iron in the metal charge, increases with increasing ferrous oxide content in the slag. Increasing ferrous oxide content in the slag in the process of melting the charge and at the initial stage of heating the bath when its temperature is in the range of 1525-1580°C promotes to increasing the degree of post-combustion of carbon monoxide. Carbon monoxide burns out above the metal bath and significantly hastens melting the charge and heating the melt, thereby reducing the duration of the melting process.

However, with increasing the temperature of the melt over 15800C the higher degree of oxidation of the slag adversely affects the lining resistance because at a temperature over 1580C ferrous oxide forms lightly fusing eutectics with refractory lining materials, which being fused cause quick wear of the converter refractory lining.

For this reason it is necessary to remove the oxidizing slag from the surface of the melt at a temperature not higher than 1580°0. To remove the slag from the surface of the melt is possible at a temperature not lower than 1525C because to this end it is necessary to melt completely the charge, which has the melting point approximately 15250C.

At a temperature lower than 1525°C to remove the oxidizing _Ij -6slag from the melt surface is impossible. In practical conditions for thorough melting the charge it is necessary to overheat it in relation to its melting point.

After removal of the oxidizing slag from the surface of the melt a small quantity of this slag is still in the bath. To deoxidize the slag remained in the melt it is necessary to feed therein deoxidizing materials.

As a deoxidizing material in the present invention it is used a solid iron in an amount of 2-5 per cent by mass of the metal charge.

The necessity to use solid iron is stipulated by the fact that carbon therefrom directly goes into the melt and reacting with the slag permits to reduce the ferrous oxide content remained therein, what decreases the converter refractory lining wear at further increasing the temperature. Said effect takes place due to highly developed interaction surface of the reacting phases, i.e. a metal and a slag.

Besides, carbon from solid iron goes directly into the melt and acts as an additional power carrier, what results in decreasing the duration of the melting process.

Usage of any other carbon-containing material (for example coal) instead of iron is less effective in this respect, because reaction of the slag bath with the solid material due to its low diffusion speed occurs with greatly lower speed, and, besides is ,tllowed with slag foaming.

For said above reasons to minimize oxidation of the slag it is necessary to add iron.

_i When a solid metal charge is used, an addition of solid iron in an amount of 5% of the total quantity of the metal charge permits to decrease the total content of ferrous oxide (FeO) in the slag to 15-20%, what is enough to provide the slag with the satisfactory refining ability and prevent from its foaming during the subsequent charging coal or any other carbon-containing material into the converter. Taking in mind the said above influence of solid iron additives to oxidation of the slag, its addition in an amount of more than 5% is not desirable. This is because with addition of more amount of iron the carbon content in the metal will significantly increase, what is not advisable as results in increasing the duration of the melting process. Addition of solid iron in an amount of less than 2% will not permit to reduce the ferrous oxide content to 20%, that is why the lower limit of quantity of solid iron additives is 2% of its initial quantity of the metal charge.

It is desirable after charging solid iron into the melt to add a solid carbon-containing fuel therein in an amount of 1-5% of the original quantity of solid metal iron-bearing materials.

Such additive permits to accelerate the process of bath hoating due to burning carbon out of the carbon-containing fuel on the bath surface, what results in further decreasing the duration of the melting process.

Besides, this fuel acts as a deoxidizer for the oxidizing slag still remained in the bath because carbon therein reduces iron from ferrous oxides, what results in decreasing the wear of the converter refractory lining.

Consumption of the solid carbon-containing fuel, for example, coal, additionally loaded in the converter, according to the present invention is determined by values from I to The exact value of the additive depends on temperature of the melt after removal of the oxidizing slag, as well as on the required temperature at the end of the melting process, i.e. it depends on the required temperature increase. %ith the temperature increase from 1580 to 1600-1610 0 C 1% of coal is necessary, from 1580 to 1640-1650°C 2% of coal, from 1580 to 1680-1700C of coal.

For a better understanding of the present invention the following specific examples are given below.

The method is implemented in an oxygen converter equipped with bottom and side tuyeres of the "pipe-in-pipe" type. Oxygen is injected through a central passage of these tuyeres and a hydrocarbon fuel is supplied through their exterior passages. The converter is also provided with facilities for injection of oxygen through an upper water-cooled lance.

The method of production of steel from solid metal iron-bearing materials, for example metal scrap, com.prises the following.

As solid metal iron-bearing materials for steel making by this method the next materials can be used: scrap, crop ends, metal waste from steel plants, metallized -9pellets, sponge iron, etc.

As a fuel it is preferable to use gaseous hydrocarbons, such as natural gas, methane, propane, butane, as well as liquid hydrocarbons, such as residual oil, petroleum, diesel fuel. Also, as a fuel, it can be used a solid carbon-containing fuel, such as coke, coal, lignite, etc.

The process of making steel from solid carbon-containing materials in an oxygen converter comprises the periods of loading a charge into the converter, heating the charge, its melting, removal of the slag from the bath and subsequent oxidizing refining.

Heating the solia charge and its tielting is done with heat released by burning the hydrocarbon fuel supplied through bottom and side tuyeres in an oxygen-containing gas injected through the same tuyeres, as well as through a top water-cooled lance.

During the periods of heating and melting the solid iron-bearing materials to maintained burning the solid carbon-containing fuel is periodically loaded onto the metal charge. When the period of heating the charge goes into the period of its melting the oxygen rate in the oxygen-containing gas injected through the bottom tuyeres is increased from 20-70% up to approximately 100%. At the periods of charge melting and heating through the side tuyeres and the top water-cooled lance pure oxygen is injected.

When the charge is melted and its temperature is 1525- -1580°C the oxidizing slag containing 30-70% of ferrous L i r *i' -1L~C-UI oxide, FeO, is removed from the bath surface.

After the oxidizing slag is removed from the surface of the bath, a solid iron and an additional coal is successively supplied therein in an amount of 2-5% and of the total metal scrap mass respectively, and then the melt is refined.

Refining the carbonaceous iron melt is carried out by any known in the art methods,i.e. during the refining process a ratio of amounts of oxygen and hydrocarbons fed through the bottom tuyeres is controlled in such a way that hydrocarbons do not act as a fuel but as a protective medium for the oxygen lances. Steel is refined up to the required chemical composition and temperature.

The present invention is based on temperature and slag conditions control. Blowing the melt while the slag is highly oxidized (Fe0=50-7uo) in the period of melting the charge and at the initial stage of heating the melt when temperature of the bath is not higher than 1525-1580 0

C

promotes to increasing the degree of the post-combustion of carbon monoxide. In the converter carbon monoxide burns above the metal bath and significantly promotes to hastening the process of melting the metal charge and heating the bath, what permits to decrease the duration of melting. At this period the oxidizing slag acts positively-the more quantity of the slag there is in the converter and higher its ferrous oxide content, the more intensive is the process of the carbon monoxide post-combustion. Besides, with increasing the temperature of the melt i ;i I 1 i, _i -11it is necessary to lower the degree of slag oxidation, i.e.

to decrease the duration of interaction between ferrous oxides presenting in the oxidizing slag and the converter refractory lining, and thereby to reduce converter lining wear. The problem of lowering the degree of slag oxidation is solved by removing the slag from the surface of the bath and by subsequent deoxidizing the metal bath with addition of solid iron and a supplemental quantity of the solid carbon-containing fuel.

The implementation of the present invention permits to shorten the duration of the melting process approximately by 10% and decrease converter lining wear approximately by 30-35%.

Example 1 A 10-t converter equipped witih bottom and side fuel oxygen tujores as well as with a top water-cooled oxygen lance was loaded with t of lime and 10 t of metal scrap. The scrap was heated by enriched air containing of oxygen and 5-8 m 3 /min of natural gas injected through the bottom tuyeres. Through the side tuyeres oxygen in an amount of 5-10 m /min was injected. Consumption of ox gen injected through the top lance was changed in the range of 10-15 m 3 /min.

Melting the charge was done in the same way as its heating i.e. consumption of gas components supplied into the converter in the process of melting was the same as for heating. Besides, instead of enriched air through the bottom tuyeres oxygen was injected in an amount of 10-15 m 3 /min. During heating and melting 400 kg _I -12of coal was loaded into the converter in parts of 100U kg By the moment when the charge was melted the slag contained 30% of ferrous oxide and 4% of magnesium oxide. The solid charge got melted in 30.5 minutes. Temperature was 1525°C. The oxidized slag in the amount of 0.5 t was removed (pumped out) from the converter. After blowing was restarted again (through the bottom tuyeres it was injected mi /min of oxygen and 2.5-3.0 m /min of natural gas, through the side tuyeres it was injected 5m 3 /min of oxygen and 2 m /mrin of natural gas, through the upper lance it was injected lu-15 /min of oxygen) 200 kg of solid iron and 500O kg of small size coal were charged successively into the converter. Blowing was cor,tinned 7 minutes more. Total net time of blowing was 37.5 minubes. When the blowing was over the temperature of the metal was 16350°C. Metal composition was: 0,071o 0; 0.02 Mn; 0.008 P; 0.0355 S, iron was the balance.

Ferrous oxide content in the final slag was 16.8%, magnozium oxide content was 5.9%, Example 2. A 10-t converter was loaded with 0.5 t of lime and 9.9 t of metal scrap. Blowing conditions were the same as in Example 1. During heating and melting te scrap 450 kg of coal dust was loaded into tb oonverte'r.

By the moment of the charge is melted (32 min total ferrous oxide content in the slag was Magensium oxide content was Temperature of the bath was 550 kg of the slag was pumped out from the oon- 350 kg of solid iron was charged thereinto. Du.

~-L-II 1. .LI 13 further blowing (6 min) 100 kg of coal dust was loaded into the converter. Before steel tapping its composition was: 0.04% C, 0.03% Mn; 0.010% P, 0.027% S, iron being the rest. Ferrous oxide content in the final slag was 18.3%, magnesium oxide content was Metal temperature was 16500C.

Example 3 A converter was loaded with 0.5 t of lime and 9.6 t of metal scrap. During heating and melting 300 kg of coal dust was loaded into the converter. By the moment of charge melting (31 min) total ferrous oxide content in the slag was 36.7%, magnesium oxide content was Temperature of the bath was 15500C. 500 kg of the slag was pumped out from the converter, and 300 kg of solid iron was charged thereinto. During a subsequent blowing min) 300 kg of coal dust was loaded into the converter. Before tapping steel composition was: 0.05% 0; 0.02% Mn; 0.008%1 P and 0.033% S. Perr... oxide content in the final slag was 15.1%; magnesium oxide content was Metal temperature was 16500C.

Data on examples 1,2,3 and other examples specifying the present invention within the applied parameters as well as beyond the applied parameters (examples 4-6) are shown in the table attached. Data specifcying the process of steel production from a solid metal charge in a 10-t converter with using a known in the prior art method are also shown for comparison.

-14- Table Main technological parameters of the process of melting steel from solid metal charge in a converter with the use of the present method and the method known in the art Nos Prior art technique 2 3 I Weight of a metal charwe to be melted, t 9.7 2 Amount of lime, used, t 3 Amount of coal used in the process of heating and melting a solid metal charge, t 0.70 4 Duration of the period of heating and melting a solid metal charge, ::.in-sec 52-30 Tem)erature of the metal at the end of the period of heating and melting, °C 1530 o Ferrous oxide (FeO) total content in the the slag removed, 24.2 7 MgO content in the slag removed, 8.1 8 Amount of slag removed, t 9 Mass of MgO in the slag removed, t Amount of solid iron added after the slag removal: weight, t 11 of the scrap weight 12 Amount of coal (pulverized) added: weight, t 13 of the scrap weight 14 Duration of blowing after slag removal, min -sec _-00 Weight of the final slag, t 1.75 16 Ferrous oxide (FeO) content before tapping, 27.4 17 MgO content before tapping, 6.6 18 Mass of MgO in the final slag, kg 115.5 19 Sulphur content in metal before tapping, 0.057 Temperature of meual, OC before tapping 1620 21 Net time of blowing, min -sec 41-30 22 Total quantity of MgO transferred to the slag, kg 115.5 I~ Table (cont.) Nos Example of melting 1 2 3 4 5 6 1 4 5 6 7 8 9 2 3 4 6 7 8 9 12 14 16 17V 18 19 21 22 10.0 0.5 0.40 1525 30.0 4.0 0.50 2U.0 0.20 0.50 5.0 /-00 5.9 52.6 0.05 1630 5:7-50> 72.6 0.5 0.45 52-00 1 583 49.2 4.3 0.55 23.6 0.5 3.5 0.1 1.0 b-'00 11 L O 1843 4,2 58 8 0.027 l b50 38-00 82.4 0.5 0.50 31-00 "1550 36. V 4.5 0.50 22.5 0.50 3-1 0.50 5.1 6-3u 15.1 4. 5 58.> 0,033 1Ib50 37-30 81.0 9.9 9.6 9.8 0.5 0.30 29-35u 1555 7u-0 14. 7 0.61 28.2 0.50 5.0 J.2 2.1 ~50 1r 9 7; 4. 7 61-1 0.028 37-00 839.3 9.5 0.5 0.30 50,-30 1590 75. 6 50.0 0.10 1.1 0. 50 5.5 5.2 71.2 0. Olj.,+ 4j-00 '100.2 9.7 0.45 51-40 1593 48.9 0.55 2,7.0 0.53 0. 0.51 I 31 21.2 o5: .0 40-30 9. i_ i The comparison shows that the present invention pormits to reduce the duration of heating and melting a soljd metal charge and to dimuinish the overall time of blowin6 3pproxinately by 4 min. Refratory lininpj wear is reduced by Thus, the use of the present method permits to reduce the du'ration of meting and decrease the refractory lining wear-thvough. slag-forming control and the of deoxidizing materials.

Claims (3)

1. A method of manufacturing steel in a converter from a cold charge, comprising the steps of loading the charge in the converter, heating the charge in the converter to form a melt by burning successively charged hydrocarbon and solid carbon containing fuels in an oxygen containing gas injected into the converter from below, above and to the side of the charge, removing and oxidising slag from the surface of the melt when the melt is at a temperature of between 1525°C 1580°C and subsequently, loading solid carbon containing iron into the melt in an amount of 2-5% of the initial quantity of the cold charge.

2. A method as claimed in claim 1, wherein after the introduction of the solid iron into the melt, an additional quantity of solid carbon containing fuel is loaded therein in an amount of 1-5% of the initial quantity of the cold charge.

3. A method of manufacturing steel in a converter from a cold charge substantially as herein described with reference to any one of examples 1 to 3. DATED this 18th day of December, 1989 NAUCHNO-PROIZVQDSTVENNOE OBIEDINENIE "TULACHERMET" SBy their Patent Attorneys GRIFFITH HACK CO. 422S/KLH U~1LY'~ Ttc