AU614822B2 - Hair-dyeing composition - Google Patents
Hair-dyeing composition Download PDFInfo
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- AU614822B2 AU614822B2 AU31738/89A AU3173889A AU614822B2 AU 614822 B2 AU614822 B2 AU 614822B2 AU 31738/89 A AU31738/89 A AU 31738/89A AU 3173889 A AU3173889 A AU 3173889A AU 614822 B2 AU614822 B2 AU 614822B2
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- AU
- Australia
- Prior art keywords
- hair
- solution
- dyeing composition
- composition
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 60
- 238000004043 dyeing Methods 0.000 title claims description 33
- 239000000243 solution Substances 0.000 claims description 48
- 239000001648 tannin Substances 0.000 claims description 30
- 229920001864 tannin Polymers 0.000 claims description 30
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 20
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 14
- 229910052725 zinc Inorganic materials 0.000 claims description 14
- 239000011701 zinc Substances 0.000 claims description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 13
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 13
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 12
- 239000010949 copper Substances 0.000 claims description 12
- 239000011777 magnesium Substances 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- 239000011135 tin Substances 0.000 claims description 11
- 229910052718 tin Inorganic materials 0.000 claims description 11
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 10
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 8
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 8
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical class SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 229960003280 cupric chloride Drugs 0.000 claims description 5
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 4
- 239000004201 L-cysteine Substances 0.000 claims description 3
- 235000013878 L-cysteine Nutrition 0.000 claims description 3
- 229920005989 resin Chemical class 0.000 claims description 3
- 239000011347 resin Chemical class 0.000 claims description 3
- FWWXYLGCHHIKNY-UHFFFAOYSA-N 2-ethoxyethyl prop-2-enoate Chemical compound CCOCCOC(=O)C=C FWWXYLGCHHIKNY-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 229940091250 magnesium supplement Drugs 0.000 claims 2
- PWKSKIMOESPYIA-UHFFFAOYSA-N 2-acetamido-3-sulfanylpropanoic acid Chemical class CC(=O)NC(CS)C(O)=O PWKSKIMOESPYIA-UHFFFAOYSA-N 0.000 claims 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims 1
- 235000008853 Zanthoxylum piperitum Nutrition 0.000 claims 1
- 244000131415 Zanthoxylum piperitum Species 0.000 claims 1
- RRXGIIMOBNNXDK-UHFFFAOYSA-N [Mg].[Sn] Chemical compound [Mg].[Sn] RRXGIIMOBNNXDK-UHFFFAOYSA-N 0.000 claims 1
- 229940022663 acetate Drugs 0.000 claims 1
- 229940063656 aluminum chloride Drugs 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims 1
- 229940045803 cuprous chloride Drugs 0.000 claims 1
- 229960002337 magnesium chloride Drugs 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 34
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 16
- 235000018553 tannin Nutrition 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 229920002125 Sokalan® Polymers 0.000 description 10
- 229910000027 potassium carbonate Inorganic materials 0.000 description 8
- 239000000975 dye Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 239000003086 colorant Substances 0.000 description 6
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000001119 stannous chloride Substances 0.000 description 3
- 235000011150 stannous chloride Nutrition 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 241000365112 Monsonia angustifolia Species 0.000 description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 2
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 2
- 235000019646 color tone Nutrition 0.000 description 2
- 150000001879 copper Chemical class 0.000 description 2
- 229960002433 cysteine Drugs 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 210000004185 liver Anatomy 0.000 description 2
- 159000000003 magnesium salts Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 210000004877 mucosa Anatomy 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 2
- 229940001482 sodium sulfite Drugs 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 239000004246 zinc acetate Substances 0.000 description 2
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- XJKSTNDFUHDPQJ-UHFFFAOYSA-N 1,4-diphenylbenzene Chemical compound C1=CC=CC=C1C1=CC=C(C=2C=CC=CC=2)C=C1 XJKSTNDFUHDPQJ-UHFFFAOYSA-N 0.000 description 1
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 206010013911 Dysgeusia Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- 235000010676 Ocimum basilicum Nutrition 0.000 description 1
- 240000007926 Ocimum gratissimum Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- VLSOAXRVHARBEQ-UHFFFAOYSA-N [4-fluoro-2-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=C(F)C=C1CO VLSOAXRVHARBEQ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000001142 anti-diarrhea Effects 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- -1 aromatic amino compound Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229940018564 m-phenylenediamine Drugs 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 229960001755 resorcinol Drugs 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 239000010930 yellow gold Substances 0.000 description 1
- 229910001097 yellow gold Inorganic materials 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
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- Devices For Executing Special Programs (AREA)
- Cosmetics (AREA)
Description
I,
COMMONWEALTH OF AUSTRALIA PATENTS ACT 1952 Form COMPLETE SPECIFICATION FOR OFFICE USE Short Title: Int. Cl: 614822 Application Number: Lodged: Complete Specification-Lodged: Accepted: Lapsed: Published: Priority: Related Art: TO BE COMPLETED BY APPLICANT Name of Applicant: Address of Applicant: Actual Inventor: Address for Service: SHO SEIYAKU CO., LTD. and TERUAKI
HAYASHI
26-7 Oike 2-chome, Onojo-shi, Fukuoka-ken, JAPAN and 189-11 Aza-Futoinokakiuchi, Higashitada, Kawanishi-shi, Hyogo-ken, JAPAN, respectively Masahiro Motono GRIFFITH HACK CO.
71 YORK STREET SYDNEY NSW 2000
AUSTRALIA
Complete Specificati'n for the invention entitled: HAIR-D i EING COMPOSITION The following statement is a full description of this invention, including the best method of performing it known to me/us:- 9087A:rk I I, HAIR-DYEING COMPOSITION BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to a hair-dyeing composition comprising one or more tannins and one or more metal salts. The composition is safe and does not damage the skin or hair. Using the composition, hair can be dyed in various colors.
Prior Art In general, a so-called gray-hair-dyeing composition for dyeing gray hair of the aged is widely used. On the other hand, a so-called "dressing hairdyeing", which dyes hair into colors other than black, such as brown, ight brown, yellow or gold, for the decorative -purpose of modifying the personal appearance (looks) and matching with make-up and wear, has become popular these days.
Hitherto, conventional dressing hair-dyeing compositions comprises a main agent of an aromatic amino compound, such as p-toluenediamine, p-aminophenol, 2- 5-amino-2-hydroxytoluene, ophenylenediamine or o-aminophenol and a retouching agent of m-phenylenediamine, pyrogallol or resorcinol. The composition is oxidized and colored in the presence of an oxidizing agent such as hydrogen peroxide so as to
IA-
Position: GRIFFITH HACK CO MELBOURNE OFFICE G.P.O. BOX 1285K MELBOURNE. VIC. 3004 SYDNEY OFFICE G.P.O. BOX 4164 SYDNEY. N.S.W. 2001 I I I -I 2
OS
0 *0 0 00 a
S
.00.
0000S 0 0* 0 *5
S
50 color a hair into the desired color of light reddish brown, yellowish gold, reddish yellow or orange.
In the prior art, oxidizing dyes are essentially used in the dressing hair-dyeing compositions for dyeing hair into various colors other than black. However, the oxidizing agents to be used in hair-dyeing with this composition would often damage the hair and skin.
SUMMARY OF THE INVENTION One or more embodiments of the present invention are directed towards providing a non-oxidizing type 15 hair-dyeing composition which may dye hair in any desired color without damaging the hair and skin.
The present inventor studied the coloration by combination of tannins and metal salts and has found that 20 reaction of tannins and metal salts of zinc, copper, tin, magnesium or aluminuim forms various colors of dark or light or dense or sparse brown, yellow or green. The present invention has thus been completed on the basiL of such finding.
The present invention provides a hair-dyeing composition comprising geraniintannin or catechin-tannin and one or more compounds selected from water-soluble zinc, copper, tin, magnesium and aluminum salts; a 30 hair-dyeing composition additionally containing one or more compounds selected from L-cysteine and salts thereof, sodium sulfite, sodium hydrogen sulfite and vitamin E, in addition to the said tannin(s) and water-soluble salt(s); a one-solution-type hair-dyeing composition 'A 8/ ,h 877S/ST/26.O6.92.
4 'r o
I
c Li comprising one or more tannins and one or more compounds selected from water-soluble zinc, copper, tin, magnesium and aluminum as a mixture; and a two-solution-type hairdyeing composition composed of a tannin-containing solution and an aqueous solution of one or more compounds selected from water-soluble zinc, copper, tin, magnesium and aluminum salts.
DETAILED DESCRIPTION OF THE INVENTION In general, tannins are polyoxyphenols existing in plant components and it is said that they have an astringent action to the skin and mucosa. Because of .0 this action, in the past tannins have widely been utilized as a tanning agent, an antidiarrheal and an antiinflammatory agent.
Tannins are roughly grouped into pyrogalloltannins and catechol-tannins, any of which can be used in the present invention. In particular, geraniintannin and tanniic acid in the group of pyrogallol-tannins and catechin-tannin in the group of catechol-tannins are 0* Spreferably used.
Geraniintannin is especially preferred as it has a high dyability.
Geraniintannin is known as the main component in a herb cranesbill (Geramium nepalense var. thunbergii).
It does not taste bitter and hardly stimulates the skin and mucosa, although it has a strong binding capacity with proteins.
.1 -3- Geraniintannin is derived from a herb cranesbill.
A powdered form of the herb is extracted with a mixed solvent of ether/water and the ether layer is harvested. This is concentrated under reduced pressure and ethanol is added thereto. The resulting mixture is discolored, filtered and further concentrated undur reduced pressure. The concentrated liquid is dried to obtain a powder. The powder thus obtained contains geraniintannin in an amount of about 90 The water-soluble zinc, copper, tin, magnesium and aluminum salts for use in the present invention may be in the form of a water-soluble salt, such as chloride, acetate, sulfate or phosphate, of the respective metal.
In particular, stannous chloride, 'zinc acetate, cupric chloride, magnesium chloride, aluminum chloride and zinc phosphate are preferred.
The hair-dyeing composition of the present invention comprises one or more of the above-mentioned tannins and one or more composition selected from the above-mentioned water-soluble zinc, copper, tin, magnesium and aluminum salts. The composition may be in any form of one-solution-type and two-solution-type compositions, which may properly be selected in accordance with the use of the composition.
When catechin-tannin or catechol-tannin is used, the tin salt forms an yellowish brown color, the zinc salt a reddish brown color, the copper salt a yellowish green color, the magnesium salt a liver brown color and 4 i I .he aluminum salt a reddish brown color; when geraniintannin or pyrogallol-tannin is used, the zinc salt forms an yellow color, the copper salt a green color, the tin salt an yellow color, the magnesium salt a pale yellow color and the aluminum salt a gold color; and when tannic acid is used, the copper salt forms a green color, and the tin salt and zinc salt form a white color.
On the basis of the said color tones, plural tannins may be combined so as to control the density and deepness of the color tone to be formed on the hair dyed 0 with the composition.
When two or more kinds of the said water-soluble zinc, copper, tin, magnesium and aluminum salts are 0 combined, the intermediate colors may be obtained.
When the hair-dyeing composition of the present invention is a one-solution-type composition, it is in the form of an aqueous solution containing one or more 0. tannins in an amount of from 0.1 to 10.0 by weight, preferably from 1.0 to 5.0 by weight, and one or more water-solbule zinc, copper, tin, magnesium and/or aluminum salts in an amount of from 0.01 to 5.0 by weight, preferably from 1.0 to 3.0 by weight. A polyhydric alcohol such as prop'.ene glycol or glycerin or ethanol is added to the said aqueous solution to form a liquid, emulsion or cream, which may directly be applied to hair to dye the same in a desired color.
c_ Alternatively, it may be incorporated into shampoo or rinse.
When the composition of the present invention is a two-solution-type hair-dyeing composition, a polyhydric alcohol such as propylene glycol or glycerin or ethanol is added to an aqueous solution containing one or more tannins in an amount of from 0.1 to 1.0 by weight, preferably from 1.0 to 5.0 by weight, to form a first e* solution.
On the other hand, ethanol is added to an aqueous
C.
*ee S solution containing one or more water-soluble zinc, copper, tin, magnesium and/or aluminum salts in an amount of from 0.1 to 10.0 by weight, preferably from 2.0 to 5.0 by weight, to form a second solution.
Addition of one or more selected from sodium sulfite, sodium hydrogen sulfite, L-cysteine and Lcysteine hydrochloride and resins for hair such as ethoxyethyl acrylate/hydroxyethyl acrylate copolymer or
SC
cationated celluose to the hair dyeing composition of the present invention is advantageous, since the hair as dyed with the resulting composition may have an elevated color fastness even after repeated hair-shampooing.
The amount of the said additives to be added to the composition of the invention is from 0.1 to 5.0 by weight, preferably from 0.5 to 3.0 by weight. They may be added to the mixture of the two components for the one-solution-type composition, or may be added to -6- 1M the tannin-containing aqueous solution for the twosolution-type composition.
When the one-solution-type hair-dyeing composition of the present invention is actually used for hairdyeing, the mixture comprising both tannin(s) and metal salt(s) may be directly applied to the hair to be dyed.
When the two-solution type hair-dyeing composition of the invention is actually used for hair-dyeing, the first solution is first applied to the hair to be dyed S" and kept as it is until the solution becomes dried, or 'the hair is dried with a drier, and the second solution is then applied to the hair.
Next, the following examples illustrate some embodiments of the hair-dyeing composition of the present invention and the hair-dyeing method using the composition, which, however, do not whatsoever restrict *O the scope of the present invention.
EXAMPLE 1 Two-solution-type Composition: 1.0 geraniintannin, 5.0 propylene glycol, ethanol (95 1.2 carboxyvinyl polymer, 0.5 1cysteine hydrochloride and 87.3 pure water were blended to form a first solution.
stannous chloride, 40.0 ethanol and 55.0 pure.water were blended to form a second solution. (The "percentage" is all by weight.) -7ii i" EXAMPLE 2 One-solution-type Composition: geraniintannin, 5.0 propylene glycol, 30.0 r ethanol, 1.0 cupric chloride, 0.5 L-cysteine hydrochloride and 62.5 pure water were blended to form a hair-dyeing composition. (The "percentage" is all by weight.) EXPERIMENTAL EXAMPLE Hair-dyeing Test Using Various Tannins and Various Zinc, Copper, Tin, Magnesium and Aluminum Salts: S Samples: First Solution: Pure water was added to a composition consisting of 5.0 ethanol, 5.0 propylene glycol, 0.8 *0 carboxyvinyl polymer and 2.0 catechin-tannin, and the resulting solution was gelled with potassium carbonate.
Second Solution: 3.
Aqueous 5 zinc acetate solution.
*0 First Solution: Pure water was added to a composition consisting of 5.0 ethanol, 5.0 propylene glycol, 0.8 carboxyvinyl polymer and 2.0 geraniintannin, and the resulting solution was gelled with potassium Scarbonate.
Second Solution: Aqueous 5 stannous chloride solution.
8 First Solution: Pure water was added to a composition consisting of 5.0 ethanol, 5.0 propylene glycol, 0.8 carboxyvinyl polymer, 1.0 catechin-tannin and geraniintannin, and the resulting solution was gelled with potassium carbonate.
First Solution: Pure water was added to a composition consisting of 5.0 ethanol, 5.0 propylene glycol, 0.8 carboxyvinyl polymer and 2.0 catechin-tannin, and the resulting solution was gelled with potassium carbonate.
o Second Solution: too Aqueous 5 cupric chloride solution.
e S* First Solution: Pure water was added to a composition consisting e of 5.0 ethanol, 5.0 propylene glycol, 0.8 carboxyvinyl polymer and 2.0 geraniintannin, and the resulting solution was gelled with potassium carbonate.
Second Solution: Aqueous 5 cupric chloride solution.
First Solution: Pure water was added to a composition consisting .of 5.0 ethanol, 5.0 propylene glycol, 0.8 carboxyvinyl polymer and 2.0 catechin-tannin, and the resulting solution was gelled with potassium carbonate.
-9k c *0 4 *9
S
9 596 4.
0 .9 Second Solution: Aqueous 5% magnesium chloride solution.
First Solution: Pure water was added to a composition consisting of 5.0 ethanol, '5.0 propylene glycol, 0.8 carboxyvinyl polymer and 2.0 geraniintannin, and the resulting solution was gelled with potassium carbonate.
Second Solution: Aqueous 5 magnesium chloride solution.
First Solution: Pure water was added to a composition consisting of 5.0 ethanol, 5.0 propylene glycol, 0.8 carboxyvinyl polymer and 2.0 catechin-tannin, and the resulting solution was gelled with potassium carbonate.
Second Solution: Aqueous 5 aluminum chloride solution.
First Solution: Pure water was added to a composition consisting of 5.0 ethanol, 5.0 propylene glycol, 0.8 carboxyvinyl polymer and 2.0 geraniintannin, and the resulting solution was gelled with potassium carbonate.
.Second Solution: Aqueous 5 aluminum chloride solution.
(The "percentage: is all by weight.) 10 04, Test Method: 1 ml of the first solution of each of Samples (1) to was applied to the hair of the back of a ddy mouse (male, 7 to 10-week age). After left as it was for about 5 minutes, the hair was dried with hot air from a drier, and about 1 ml of the corresponding second solution was applied to the hair. The hue of the dye formed and the color of the hair dyed with the dye were observed.
Test Result: The test result was shown in Table below.
0 0 4* 4 4 4 Sample No. Hue of Dye Color of Dyed Hair .49.
a.
4.
0 44 4 4 4* 4* 4 4 4 4.
(1) (2) (3) (4) (6) (7) (8) (9) pale yellowish brown ocher yellow ocher yellow yellowish green dark green liver brown yellowish brown reddish brown ocher yellow pale yellow yellow gold pale yellowish green pale green ultra-pale yellow ultra-pale yellow ultra-pale light brown pale yellow The hair-dyeing composition of the present invention is safe, without damaging the skin or hair, and it can easily be used for dyeing a hair into various colors. The composition is therefore an extremely useful dressing hair-dyeing composition.
11
A
t While the invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.
*r a a a a oI a a, 9 9 a. a 49 a a 9* 12
Claims (1)
13- THE CLAIMS DEFINING THE INVENTION ARE AS FOLLOWS: 1. A hair-dyeing composition comprising geraniintannin or catechin-tannin and one or more compounds selected from water-soluble zinc, copper, tin magnesium and aluminum salt. 2. A kit, whenever used for preparing a hair-dyeing composition according to claim 1, composed of a first solution containing geraniintannin or catechin-tannin and a second solution which is an aqueous solution of one or more compounds selected from water-soluble zinc, copper, tin, magnesium and aluminum salt. 15 3. A hair-dyeing composition according to claim 1, which further contains one or more substances selected from L-cysteine, salts of L-cysteine and resins for hair. S 4. A hair-dyeing composition according to claim 1 or claim 3, in which t.e water-soluble zinc, copper, tin, magnesium and aluminum salts are selected from zinc, acetate, cupric chloride, cuprous chloride, magnesium chloride and aluminum chloride. 25 5. A hair-dyeing composition according to claim 3 or claim 4, which further contains one or more resins for hair selected from ethoxyethyl acrylate/hydroxyethyl acrylate copolymer and cationated cellulose. 9* 30 6. A hair-dyeing composition substantially as S disclosed herein in conjunction with any one of the examples. DATFD this 25th day of June 1991 SANSHO SEIYAKU CO., LTD AND TERUAKI HAYASHI By Their Patent Attorneys GRIFFITH HACK CO 8779S/SLT/26. 6. 91
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63-78731 | 1988-03-30 | ||
| JP7873188A JPH01251139A (en) | 1988-03-31 | 1988-03-31 | Knowledge increasing method for knowledge base |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU3173889A AU3173889A (en) | 1989-10-05 |
| AU614822B2 true AU614822B2 (en) | 1991-09-12 |
Family
ID=13670031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU31738/89A Ceased AU614822B2 (en) | 1988-03-30 | 1989-03-28 | Hair-dyeing composition |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH01251139A (en) |
| AU (1) | AU614822B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU655234B2 (en) * | 1991-03-07 | 1994-12-08 | Clairol Incorporated | Oxidative hair dyeing process with catalytic pretreatment |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03132826A (en) * | 1989-10-19 | 1991-06-06 | Agency Of Ind Science & Technol | Knowledge processing back-up device |
| JPH0855029A (en) * | 1994-08-09 | 1996-02-27 | Komatsu Ltd | Reasoning device |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0124393A1 (en) * | 1983-04-01 | 1984-11-07 | Alban Muller International, S.A.R.L. | Hair dyeing composition and process |
| EP0133129A2 (en) * | 1983-07-28 | 1985-02-13 | Secta-Laboratoires De Cosmetologie Yves Rocher | Process and compositions for dyeing the annexes of the epidermis |
-
1988
- 1988-03-31 JP JP7873188A patent/JPH01251139A/en active Pending
-
1989
- 1989-03-28 AU AU31738/89A patent/AU614822B2/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0124393A1 (en) * | 1983-04-01 | 1984-11-07 | Alban Muller International, S.A.R.L. | Hair dyeing composition and process |
| EP0133129A2 (en) * | 1983-07-28 | 1985-02-13 | Secta-Laboratoires De Cosmetologie Yves Rocher | Process and compositions for dyeing the annexes of the epidermis |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU655234B2 (en) * | 1991-03-07 | 1994-12-08 | Clairol Incorporated | Oxidative hair dyeing process with catalytic pretreatment |
Also Published As
| Publication number | Publication date |
|---|---|
| AU3173889A (en) | 1989-10-05 |
| JPH01251139A (en) | 1989-10-06 |
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