AU636077B2 - Extended mix life magnesia refractory aggregates for brick and gunning mixes - Google Patents

Extended mix life magnesia refractory aggregates for brick and gunning mixes Download PDF

Info

Publication number: AU636077B2
Authority: AU; Australia
Prior art keywords: resin; magnesia; aggregate; mixture; retarder
Prior art date: 1990-08-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Ceased

Application number

AU12116/92A

Other languages

English (en)

Other versions

AU1211692A (en

Inventor

Arthur Harry Gerber

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Hexion Inc

Original Assignee

Borden Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-08-02

Filing date

1992-03-06

Publication date

1993-04-08

1991-05-13 Priority claimed from US07/698,945 external-priority patent/US5180795A/en

1991-08-22 Priority claimed from US07/748,707 external-priority patent/US5179177A/en

1992-03-06 Application filed by Borden Inc filed Critical Borden Inc

1992-10-29 Publication of AU1211692A publication Critical patent/AU1211692A/en

1993-04-08 Application granted granted Critical

1993-04-08 Publication of AU636077B2 publication Critical patent/AU636077B2/en

1996-08-01 Assigned to BORDEN CHEMICAL, INC. reassignment BORDEN CHEMICAL, INC. Alteration of Name(s) in Register under S187 Assignors: BORDEN, INC.

2011-04-26 Anticipated expiration legal-status Critical

Status Ceased legal-status Critical Current

Links

CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 title claims description 409
239000000395 magnesium oxide Substances 0.000 title claims description 207
239000011449 brick Substances 0.000 title claims description 11
239000000203 mixture Substances 0.000 claims description 399
229920005989 resin Polymers 0.000 claims description 147
239000011347 resin Substances 0.000 claims description 147
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 132
229920003987 resole Polymers 0.000 claims description 100
238000000034 method Methods 0.000 claims description 86
BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 75
150000001875 compounds Chemical class 0.000 claims description 56
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 54
235000011090 malic acid Nutrition 0.000 claims description 54
BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical group OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 53
239000001630 malic acid Substances 0.000 claims description 53
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 52
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 50
239000000654 additive Substances 0.000 claims description 47
229920003986 novolac Polymers 0.000 claims description 46
229920001568 phenolic resin Polymers 0.000 claims description 46
TXFPEBPIARQUIG-UHFFFAOYSA-N 4'-hydroxyacetophenone Chemical compound CC(=O)C1=CC=C(O)C=C1 TXFPEBPIARQUIG-UHFFFAOYSA-N 0.000 claims description 43
239000005011 phenolic resin Substances 0.000 claims description 42
-1 bifluoride Chemical compound 0.000 claims description 40
125000004432 carbon atom Chemical group C* 0.000 claims description 40
KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 38
JECYUBVRTQDVAT-UHFFFAOYSA-N 2-acetylphenol Chemical compound CC(=O)C1=CC=CC=C1O JECYUBVRTQDVAT-UHFFFAOYSA-N 0.000 claims description 35
125000003545 alkoxy group Chemical group 0.000 claims description 34
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 31
229910000077 silane Inorganic materials 0.000 claims description 31
230000000996 additive effect Effects 0.000 claims description 30
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 29
150000001450 anions Chemical class 0.000 claims description 26
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 26
239000002253 acid Substances 0.000 claims description 25
150000002148 esters Chemical class 0.000 claims description 25
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 24
239000003795 chemical substances by application Substances 0.000 claims description 23
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 21
229940049920 malate Drugs 0.000 claims description 20
230000000979 retarding effect Effects 0.000 claims description 20
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 18
229940002520 2'-hydroxyacetophenone Drugs 0.000 claims description 17
ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 claims description 17
239000007787 solid Substances 0.000 claims description 17
229940095064 tartrate Drugs 0.000 claims description 17
CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims description 15
239000000292 calcium oxide Substances 0.000 claims description 15
WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 claims description 13
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 13
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 13
229940009098 aspartate Drugs 0.000 claims description 13
229940001468 citrate Drugs 0.000 claims description 13
235000002906 tartaric acid Nutrition 0.000 claims description 13
239000003054 catalyst Substances 0.000 claims description 12
238000002156 mixing Methods 0.000 claims description 12
239000011975 tartaric acid Substances 0.000 claims description 12
229940091249 fluoride supplement Drugs 0.000 claims description 11
239000011777 magnesium Substances 0.000 claims description 11
150000001412 amines Chemical class 0.000 claims description 9
229910052749 magnesium Inorganic materials 0.000 claims description 9
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
229910019142 PO4 Inorganic materials 0.000 claims description 8
239000010452 phosphate Substances 0.000 claims description 8
239000010439 graphite Substances 0.000 claims description 7
229910002804 graphite Inorganic materials 0.000 claims description 7
238000001029 thermal curing Methods 0.000 claims description 7
150000002596 lactones Chemical class 0.000 claims description 6
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 6
239000000843 powder Substances 0.000 claims description 6
239000011734 sodium Substances 0.000 claims description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 5
150000001733 carboxylic acid esters Chemical class 0.000 claims description 5
229910052751 metal Inorganic materials 0.000 claims description 5
239000002184 metal Substances 0.000 claims description 5
239000010703 silicon Substances 0.000 claims description 5
229910052710 silicon Inorganic materials 0.000 claims description 5
229910052708 sodium Inorganic materials 0.000 claims description 5
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
229910052782 aluminium Inorganic materials 0.000 claims description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
238000009833 condensation Methods 0.000 claims description 4
230000005494 condensation Effects 0.000 claims description 4
229910052700 potassium Inorganic materials 0.000 claims description 4
239000011591 potassium Substances 0.000 claims description 4
239000003960 organic solvent Substances 0.000 claims description 3
239000007859 condensation product Substances 0.000 claims 3
235000012245 magnesium oxide Nutrition 0.000 description 172
230000000694 effects Effects 0.000 description 44
235000013824 polyphenols Nutrition 0.000 description 42
239000000243 solution Substances 0.000 description 28
238000012360 testing method Methods 0.000 description 19
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 18
239000011230 binding agent Substances 0.000 description 17
235000015165 citric acid Nutrition 0.000 description 17
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
239000012530 fluid Substances 0.000 description 14
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 13
BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 12
150000004756 silanes Chemical class 0.000 description 12
235000002639 sodium chloride Nutrition 0.000 description 12
MIMUSZHMZBJBPO-UHFFFAOYSA-N 6-methoxy-8-nitroquinoline Chemical compound N1=CC=CC2=CC(OC)=CC([N+]([O-])=O)=C21 MIMUSZHMZBJBPO-UHFFFAOYSA-N 0.000 description 11
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 10
YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 10
150000003839 salts Chemical class 0.000 description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
125000000217 alkyl group Chemical group 0.000 description 9
238000004519 manufacturing process Methods 0.000 description 9
239000000463 material Substances 0.000 description 9
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 8
150000001299 aldehydes Chemical class 0.000 description 8
150000002989 phenols Chemical class 0.000 description 8
239000000047 product Substances 0.000 description 8
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 8
150000007513 acids Chemical class 0.000 description 7
239000011575 calcium Substances 0.000 description 7
230000000052 comparative effect Effects 0.000 description 7
UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 6
150000001768 cations Chemical class 0.000 description 6
239000012972 dimethylethanolamine Substances 0.000 description 6
XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 6
VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 6
229910052739 hydrogen Inorganic materials 0.000 description 6
239000001257 hydrogen Substances 0.000 description 6
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 6
239000001095 magnesium carbonate Substances 0.000 description 6
235000014380 magnesium carbonate Nutrition 0.000 description 6
229910000021 magnesium carbonate Inorganic materials 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
239000011819 refractory material Substances 0.000 description 6
SMQUZDBALVYZAC-UHFFFAOYSA-N salicylaldehyde Chemical compound OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 description 6
239000002904 solvent Substances 0.000 description 6
IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical compound OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 description 5
BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 5
SKZKKFZAGNVIMN-UHFFFAOYSA-N Salicilamide Chemical compound NC(=O)C1=CC=CC=C1O SKZKKFZAGNVIMN-UHFFFAOYSA-N 0.000 description 5
238000001354 calcination Methods 0.000 description 5
229910052791 calcium Inorganic materials 0.000 description 5
235000019253 formic acid Nutrition 0.000 description 5
125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
239000007788 liquid Substances 0.000 description 5
FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 5
235000011007 phosphoric acid Nutrition 0.000 description 5
229960000581 salicylamide Drugs 0.000 description 5
229960004889 salicylic acid Drugs 0.000 description 5
239000004576 sand Substances 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
239000001361 adipic acid Substances 0.000 description 4
235000011037 adipic acid Nutrition 0.000 description 4
150000001298 alcohols Chemical class 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
229910000147 aluminium phosphate Inorganic materials 0.000 description 4
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
238000001723 curing Methods 0.000 description 4
230000007423 decrease Effects 0.000 description 4
SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 4
HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 4
150000004679 hydroxides Chemical class 0.000 description 4
PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 4
239000002244 precipitate Substances 0.000 description 4
230000002028 premature Effects 0.000 description 4
PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 4
239000001384 succinic acid Substances 0.000 description 4
URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 4
ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 3
HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 description 3
DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
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XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
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KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 3
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
239000003513 alkali Substances 0.000 description 3
229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
RMIOHTPMSWCRSO-UHFFFAOYSA-N azane;2-hydroxybutanedioic acid Chemical compound N.OC(=O)C(O)CC(O)=O RMIOHTPMSWCRSO-UHFFFAOYSA-N 0.000 description 3
239000000919 ceramic Substances 0.000 description 3
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239000000945 filler Substances 0.000 description 3
SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 3
239000011521 glass Substances 0.000 description 3
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239000004220 glutamic acid Substances 0.000 description 3
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BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
235000006408 oxalic acid Nutrition 0.000 description 3
239000002245 particle Substances 0.000 description 3
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 3
150000003009 phosphonic acids Chemical class 0.000 description 3
150000003141 primary amines Chemical class 0.000 description 3
230000000717 retained effect Effects 0.000 description 3
150000003335 secondary amines Chemical class 0.000 description 3
WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 description 2
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Natural products OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
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HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
239000002893 slag Substances 0.000 description 1
HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
235000011083 sodium citrates Nutrition 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
229910000162 sodium phosphate Inorganic materials 0.000 description 1
229960004025 sodium salicylate Drugs 0.000 description 1
239000001433 sodium tartrate Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
150000003892 tartrate salts Chemical class 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
LEIGGMIFKQLBRP-UHFFFAOYSA-N tetraethyl silicate Chemical compound CCO[Si](OCC)(OCC)OCC.CCO[Si](OCC)(OCC)OCC LEIGGMIFKQLBRP-UHFFFAOYSA-N 0.000 description 1
229920001187 thermosetting polymer Polymers 0.000 description 1
230000009974 thixotropic effect Effects 0.000 description 1
238000001721 transfer moulding Methods 0.000 description 1
ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1
229910052845 zircon Inorganic materials 0.000 description 1
GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1

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Compositions Of Macromolecular Compounds (AREA)

AU12116/92A 1990-08-02 1992-03-06 Extended mix life magnesia refractory aggregates for brick and gunning mixes Ceased AU636077B2 (en)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
US562206		1990-08-02
US07/698,945 US5180795A (en)	1990-08-02	1991-05-13	Retarders for hardening phenolic resins
US698945		1991-05-13
US07/748,707 US5179177A (en)	1990-08-02	1991-08-22	Method for retarding ambient temperature hardening of a phenolic resin composition
US748707		1991-08-22

Related Parent Applications (2)

Application Number	Title	Priority Date	Filing Date
AU75981/91A Division AU635475B2 (en)	1990-08-02	1991-04-26	Method for making a phenolic resole resin composition having extended work life
AU81294/91A Division AU634077B2 (en)	1990-08-02	1991-07-23	Retarders for hardening phenolic resins

Publications (2)

Publication Number	Publication Date
AU1211692A AU1211692A (en)	1992-10-29
AU636077B2 true AU636077B2 (en)	1993-04-08

Family

ID=27106310

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AU12116/92A Ceased AU636077B2 (en)	1990-08-02	1992-03-06	Extended mix life magnesia refractory aggregates for brick and gunning mixes

Country Status (4)

Country	Link
JP (1)	JP2554820B2 (ja)
AU (1)	AU636077B2 (ja)
BR (1)	BR9200874A (ja)
CA (1)	CA2062358A1 (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US8399597B2 (en)	2007-09-21	2013-03-19	Saint-Gobain Abrasives, Inc.	Phenolic resin formulation and coatings for abrasive products

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
KR101663456B1 (ko) *	2015-09-04	2016-10-14	대광기업 주식회사	와이어로프슬링 및 와이어로프슬링 제조 방법
JP7465137B2 (ja) *	2020-04-08	2024-04-10	アイカ工業株式会社	水溶性フェノール樹脂組成物

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4495316A (en) *	1976-09-23	1985-01-22	Acme Resin Corporation	Acid-curable fluoride-containing no-bake foundry resins
US4939187A (en) *	1988-08-22	1990-07-03	Tadao Fujita	Pattern material for making foundry patterns for use in investment casting process

1992
- 1992-03-05 CA CA 2062358 patent/CA2062358A1/en not_active Abandoned
- 1992-03-06 AU AU12116/92A patent/AU636077B2/en not_active Ceased
- 1992-03-13 BR BR929200874A patent/BR9200874A/pt not_active Application Discontinuation
- 1992-05-13 JP JP12073992A patent/JP2554820B2/ja not_active Expired - Lifetime

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4495316A (en) *	1976-09-23	1985-01-22	Acme Resin Corporation	Acid-curable fluoride-containing no-bake foundry resins
US4939187A (en) *	1988-08-22	1990-07-03	Tadao Fujita	Pattern material for making foundry patterns for use in investment casting process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US8399597B2 (en)	2007-09-21	2013-03-19	Saint-Gobain Abrasives, Inc.	Phenolic resin formulation and coatings for abrasive products

Also Published As

Publication number	Publication date
BR9200874A (pt)	1993-01-05
CA2062358A1 (en)	1992-11-14
AU1211692A (en)	1992-10-29
JPH05132608A (ja)	1993-05-28
JP2554820B2 (ja)	1996-11-20

Legal Events

Date	Code	Title	Description
2000-11-30	MK14	Patent ceased section 143(a) (annual fees not paid) or expired

Publication	Publication Date	Title
CA1337882C (en)	1996-01-02	Lithium-containing resole composition for making a shaped refractory article and other hardened articles
US5096983A (en)	1992-03-17	Method for making a phenolic resole resin composition having extended work life
US5179177A (en)	1993-01-12	Method for retarding ambient temperature hardening of a phenolic resin composition
EP0469811B1 (en)	1994-11-30	Accelerators for curing phenolic resole resins
US5214111A (en)	1993-05-25	Retarders for curing phenolic resole resins
US5248707A (en)	1993-09-28	Accelerators for refractory magnesia
AU636077B2 (en)	1993-04-08	Extended mix life magnesia refractory aggregates for brick and gunning mixes
US5262495A (en)	1993-11-16	Retarders for curing phenolic resole resins containing an aggregate material
EP0469785B1 (en)	1995-01-11	Retarders for curing/hardening resole resins
US5218010A (en)	1993-06-08	Accelerators for refractory magnesia
US5223554A (en)	1993-06-29	Accelerators for curing phenolic resole resins
US5182347A (en)	1993-01-26	Accelerators for refractory magnesia
US5208274A (en)	1993-05-04	Retarders for hardening phenolic resins
EP0469786B1 (en)	1995-01-25	High surface area magnesia as hardener for phenolic resins
US20030153648A1 (en)	2003-08-14	High surface area magnesia curing agent
US5145887A (en)	1992-09-08	High surface area magnesia as hardener for phenolic resins
CA2046060C (en)	1997-09-23	Retarders for hardening phenolic resins
JPH04300948A (ja)	1992-10-23	フェノールレゾール樹脂の硬化促進剤
CA1339943C (en)	1998-07-07	Ambient tempetature curing, high carbon contributing composition
JPS606302B2 (ja)	1985-02-16	耐火物用結合剤
JPH02204370A (ja)	1990-08-14	自硬化型不定形耐火物
JPH0365551A (ja)	1991-03-20	耐火物の製造方法

AU636077B2 - Extended mix life magnesia refractory aggregates for brick and gunning mixes - Google Patents

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Applications Claiming Priority (5)

Related Parent Applications (2)

Publications (2)

Family

ID=27106310

Family Applications (1)

Country Status (4)

Cited By (1)

Families Citing this family (2)

Citations (2)

Patent Citations (2)

Cited By (1)

Also Published As

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