AU667640B2 - CO2 snow discharge apparatus - Google Patents
CO2 snow discharge apparatus Download PDFInfo
- Publication number
- AU667640B2 AU667640B2 AU70214/94A AU7021494A AU667640B2 AU 667640 B2 AU667640 B2 AU 667640B2 AU 70214/94 A AU70214/94 A AU 70214/94A AU 7021494 A AU7021494 A AU 7021494A AU 667640 B2 AU667640 B2 AU 667640B2
- Authority
- AU
- Australia
- Prior art keywords
- carbon dioxide
- snow discharge
- snow
- discharge apparatus
- discharge tubes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 60
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 30
- 239000001569 carbon dioxide Substances 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims description 2
- 239000002184 metal Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- 238000000859 sublimation Methods 0.000 description 2
- 230000008022 sublimation Effects 0.000 description 2
- 241000212384 Bifora Species 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Landscapes
- Carbon And Carbon Compounds (AREA)
Description
i__ I' fj j' Y% 1
AUSTRALIA
PATENTS ACT 1990 COMPLETE SPECIFICATION FOR A STANDARD PATENT
ORIGINAL
oeo rooo oo co a o000 00 0 o o o oo a eooo 000 00 Name of Applicant: THE COMMONWEALTH INDUSTRIAL GASES LIMITED, A.C.N. 000 029 729 o 00 0 0 ?0 G0 oa0 a 6 I a 00 0000 Actual Inventors: Address for Service: Invention Title: Details of Associated Michael KARBANOWICZ and Michael BISHOP SHELSTON WATERS Clarence Street SYDNEY NSW 2000
"CO
2 SNOW DISCHARGE APPARATUS" Provisional Application No: PM0679 dated 18th August, 1993 The following statement is a full description of this invention, including the best method of performing it known to us:-
~W~
-2- The present invention relates to a carbon dioxide snow apparatus.
When molten metal contacts atmospheric air, oxides and nitrides are formed which create fumes and can reduce the metallurgical purity of the metal. In the past a number of shielding techniques have been used. For example, covering powders have been spread on the surface of the liquid metal to isolate the metal from the atmosphere. This technique is clearly ineffective when pouring molten metal in which case the problems of oxidation and fume generation are not prevented.
0c00 More recently, carbon dioxide snow has been used o0 for this application. The use of carbon dioxide has oo~ o 0 o o beneficial effects over other types of industrial gases.
o o 00 o°00 15 In practice, liquid carbon dioxide is expanded through a 00oooo00 00 o nozzle to atmospheric pressure to produce carbon dioxide 0 4 snow. This snow is then injected to the desired location.
It has been found that if the velocity of the snow 0 04 is too low, little or no snow reaches the surface of the 0 20 liquid metal because of a lack of jetting action. It has also been found that if the velocity of the snow is too high, air is entrained with the snow and this is undesirable as it results in ineffective shielding and furthermore thermal exchange occurs between the hot air and the snow which results in untimely sublimation of the snow. Furthermore, if the velocity of the snow upon exiting the tube is too high you get very poor snow production. This is because snow initially forms as -s
II
-3small pin point flakes. At very high velocities it will remain as pin point flakes and will tend to sublimate before effective shielding occurs. At lower velocities the pin point flakes merge to give snow flakes of sufficient size to resist untimely sublimination.
As a result of the criticality of injection velocity, the snow discharge pipe is dimensioned so that the outlet velocity of the particles of snow is such that the jet has the required kinetic energy for projecting or spraying the carbon dioxide snow to the desired location whilst avoiding air aspiration which would result in an untimely sublimation of a part of the snow and hence have an adverse effect on shielding efficiency.
Discharge tubes with a given internal diameter allow flow rates which are selected to provide the optimum velocity of the carbon dioxide snow passing therethrough for a given application. A given snow discharge tube therefore can operate only over a limited range of velocities. Thus, if different flow rates are required for different applications, it may be necessary to shut down the apparatus and change one or more of the discharge tubes. This procedure adds to the cost of operating the carbon dioxide snow discharge apparatus.
It is an object of the invention to provide a more flexible snow discharge apparatus.
According to the invention there is provided a carbon dioxide snow discharge apparatus comprising at least two snow discharge tubes adapted to be selectively operated either singly or in combination, each snow discharge tube being adapted to receive liquid carbon dioxide and including expansion means to expand the liquid carbon dioxide to form carbon dioxide snow wherein the at least two snow discharge tubes are of different internal diameters.
'0 17539-OO.DOC/mja 11 -4- In this manner, the smaller diameter snow discharge tube can be operated singly where a low flow rate of carbon dioxide snow is desired, the large diameter snow discharge pipe can be operated singly where a moderate flow rate is desired, and both snow discharge tubes can be operated in combination when a high flow rate is desired.
Preferably, the snow discharge tubes are juxtaposed and joined by conventional means at selected points along their length. This construction has been found to be advantageously rigid and stable and allows pipes to be unsupported over greater lengths.
This is particularly advantageous where the location to which the snow is to be delivered is relatively inaccessible.
A preferred embodiment of the invention will now be described, by way of example only, with reference to the accompanying drawing which is a side elevation of a carbon dioxide which is a side elevation of a carbon dioxide snow discharge apparatus according to the invention.
Referring to the drawing, there is illustrated a carbon dioxide snow discharge S o0 apparatus 2 comprising two snow discharge tubes 4 and 6 adapted to be selectively 0 o0 o o operated either singly or in combination.
*1 Each snow discharge tube 4, 6 is adapted to receive liquid carbon dioxide from a reservoir (not shown) via conduit 8. The discharge tubes 4 and 6 also each include 66 0 600 0o 0 0 0o o om a 17539-00.DOC/mja 1 an expansion nozzle 10 through which liquid carbon dioxide is expanded to atmospheric pressure to form carbon dioxide snow. It has been found experimentally that the optimum orifice tube internal diameter ratio is 1:12.5 for liquid supply pressures of 1200-1500 kPa. The preferred ratio range is from 1:9 to 1:5. The carbon dioxide snow is then discharged from the respective distal ends 12, 14 of snow discharge tubes 4, 6.
Valves 15 and 16 are provided intermediate the 1 0 conduit 8 and discharge tubes 4 and 6 which are 0. 0conventionally actuated via a control cabinet 18. For 00 example, valves 15 and 16 may be actuated electrically or oo 0000 pneumatically.
The snow discharge tubes 4 and 6 are juxtaposed and oo 0o o 15 joined by conventional means at selected points 20, 22, 24 and 26 along their length. The joins are provided by welded brackets but other conventional joining means are equally applicable. This construction has been 0000 surprisingly found to be advantageously rigid and stable and allows pipes to be unsupported over greater lengths.
In the illustrated embodiment, the snow discharge tubes 4 and 6 are mounted on a trailer 28 and are additionally supported by a post 30 and stay system 32.
Although the invention has been described with reference to a specific example, it will be appreciated by those skilled in the art that the invention may be embodied in many other forms.
Claims (7)
1. A carbon dioxide snow discharge apparatus comprising at least two snow discharge tubes adapted to be selectively operated either singly or in combination, each snow discharge tube being adapted to receive liquid carbon dioxide and including expansion means to expand the liquid carbon dioxide to form carbon dioxide snow wherein the at least two snow discharge tubes are of different internal diameters.
2. A carbon dioxide snow discharge apparatus according to claim 1, wherein the snow discharge tubes are juxtaposed and joined at selected points along their length.
3. A carbon dioxide snow discharge apparatus according to claim 4, wherein the snow discharge tubes are joined by welded brackets.
4. A carbon dioxide snow discharge apparatus according to any one of the preceding claims, wherein each expansion means includes an orifice and the orifice to discharge tube internal diameter ratio is in the range from 1: 9 to 1:
5. A carbon dioxide snow discharge apparatus according to any one of the preceding claims including control means to automatically selectively operate one or both of said discharge tubes.
6. A carbon dioxide snow discharge apparatus substantially as herein described with reference to the accompanying drawings. DATED this 14th Day of December, 1995 20 THE COMMONWEALTH INDUSTRIAL GASES LIMITED Attorney: CAROLINE M. BOMMER Fellow Institute of Patent Attorneys of Australia of SHELSTON WATERS OtI I I' II I C CIC~ I IC It I I C I III I 111111 I. I 17S39.OO.DOClMja
7 ABSTRACT A carbon dioxide snow discharge apparatus (2) comprising two snow discharge tubes 6) adapted to be selectively operated either singly or in combination. Snow discharge tubes 6) are joined at selected points 22, 24, 26) along their length. 00 a r oe k
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU70214/94A AU667640B2 (en) | 1993-08-18 | 1994-08-10 | CO2 snow discharge apparatus |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPM0679 | 1993-08-18 | ||
| AUPM067993 | 1993-08-18 | ||
| AU70214/94A AU667640B2 (en) | 1993-08-18 | 1994-08-10 | CO2 snow discharge apparatus |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU7021494A AU7021494A (en) | 1995-03-02 |
| AU667640B2 true AU667640B2 (en) | 1996-03-28 |
Family
ID=25636208
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU70214/94A Ceased AU667640B2 (en) | 1993-08-18 | 1994-08-10 | CO2 snow discharge apparatus |
Country Status (1)
| Country | Link |
|---|---|
| AU (1) | AU667640B2 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2489841A1 (en) * | 1980-09-09 | 1982-03-12 | Sib Metall Instit | Molten steel gas treatment appts. - introduces gas and powder through downward inclined fan-line nozzles |
| EP0274290A1 (en) * | 1986-11-26 | 1988-07-13 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process for casting steel comprising a protection of the metal bath by carbon dioxide snow |
| EP0544967A1 (en) * | 1991-11-28 | 1993-06-09 | Carbagas | Process for suppression of dust and fumes during electric steel production |
-
1994
- 1994-08-10 AU AU70214/94A patent/AU667640B2/en not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2489841A1 (en) * | 1980-09-09 | 1982-03-12 | Sib Metall Instit | Molten steel gas treatment appts. - introduces gas and powder through downward inclined fan-line nozzles |
| EP0274290A1 (en) * | 1986-11-26 | 1988-07-13 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process for casting steel comprising a protection of the metal bath by carbon dioxide snow |
| EP0544967A1 (en) * | 1991-11-28 | 1993-06-09 | Carbagas | Process for suppression of dust and fumes during electric steel production |
Also Published As
| Publication number | Publication date |
|---|---|
| AU7021494A (en) | 1995-03-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |