AU705861B2 - Volatile materials treatment system - Google Patents

Description

P:\WPDOCS\DYS\SPECIE\680276.SPE- 15/3/99 -2chamber in the upper region thereof, an outlet for discharging the gaseous material from the second chamber, a solids collection zone adjacent the opening, a solids discharge outlet for discharging solids from the solids collection zone, a baffle opposite to and spaced from the inlet upon which incoming gases impinge and filter means for filtering the gaseous material passing out of the second chamber via the outlet.

In the high temperature filter according to the invention, the baffle is preferably defined by a wall which separates the said first and second chambers. Preferably, the wall extends from an upper internal wall of the chambers and terminates at a point spaced from a lower internal wall of the chambers, the space between the free end of the wall and the lower internal wall of the filter defining the opening. The wall may have fins thereon.

Preferably, the discharge outlet comprises a plurality of outlet ports in the upper wall of said second chamber. Preferably, the filter means comprises a plurality of ceramic candles, each ceramic candle being associated with a respect outlet, the ceramic candles extending into the second chamber.

There may further be provided a gas collecting chamber for receiving the gaseous material from the outlets and a discharge outlet for discharging the gaseous material from the 20 gas collecting chamber. Fan suction means may be provided for drawing the gaseous o material from the second chamber through the outlets.

V The filter may further include pulsing means for delivering a gas under pressure to the filter means in the opposite direction of normal flow for cleaning the filter means.

25 Preferably, the gas used in the pulsing means is nitrogen.

o A heat jacket is preferably provided which at least partially surrounds the main body of the filter.

A further embodiment of the invention is particularly suited for the treatment of P:\WPDOCS\DYS\SPECIE\680276.SPE -15/3/99 (,Sk-A -3material containing organochlorine pesticides such as DDT, DDE and DDD and various arsenic based compounds. Such material is found in soil from cattle dip sites.

To enable the invention to be fully understood, preferred embodiments of the invention in its various aspects will now be described with reference to the accompanying drawings in which: Figure 1 is a schematic circuit diagram of a first embodiment for the treatment of contaminated solids; Figure 2 is a schematic view of the retort of the first embodiment; Figure 3 is a more detailed schematic view of the retort of the first embodiment; Figure 4 is a schematic sectional side view of a high temperature filter according to the present invention; Figure 5 is a schematic side view of an afterburner for use in the present invention; Figure 6 is a schematic view of a second embodiment for the treatment of 20 .9 9*r 9 *9 9 9 9999 9 P:\WPDOCS\DYS\SPECIE\680276.SPE 13/3/99 contaminated liquids; Figure 7 is a schematic view of a third embodiment for the treatment of contaminated liquids; Figure 8 is a schematic view of a further embodiment particularly suited for the treatment of organochlorine pesticides and arsenic compounds; Figure 9 is a schematic side elevation of a part of a high temperature filter according to another form of the invention; Figure 10 is a side elevation of a manifold as shown in Figure 9; Figure 11 is a schematic side elevation of one form of condenser which can be used in the embodiment of Figure 8; Figure 12 is a schematic side elevation of another form of condenser which can be used in the embodiment of Figure 8; 20 Figure 13 is a sectional view of a retort according to one embodiment of the invention; and a Figure 14 is a modified form of the retort shown in Figure 13.

a a a a.

a Referring to Figures 1-3, the rotary retort 10 has a cylindrical retort wall 11 rotatably journalled within a combustion chamber 12 heated by a plurality of burners 13 to provide indirect heating to the interior of the retort Ceramic seals form an airproof seal between the moving retort wall 11 and the fixed ends of the combustion chamber 12 (or of a support structure for the retort), and also act as P:\WPDOCS\DYS\SPEC1E\680276SPE 151399 an explosion vent in case of a volatile mix release caused by oxygen in the retort. (Preferably, a nitrogen purge is provided for the retort to prevent the oxygen levels becoming dangerous.) As shown in Figure 3, fins, blades or the like 14 are provided on the inner face of the retort wall 11 to increase the agitation of materials passing through the retort and to improve the heat transfer from the retort wall 11 to the materials.

Contaminated solids 20 are transferred via conveyor 21 to a grizzly 22 where oversized particles are removed. The acceptable particles are fed to the interior of the retort 10 via a rotary valve 23. As the contaminated solids move through the retort 10, volatile contaminants are given off as gases and are transferred via a gas line 15 to a high temperature filter 30 to be hereinafter described in more detail. The high temperature filter 30 is heated by the combustion gases from the combustion chamber 12 (being transferred via a line 16).

A rotary valve 17 discharges the treated solids to a product in 18 and a conveyor 19 may be provided to transfer the treated solids from the product bin 18 to a dump pile 19A.

Referring now to Figure 4, the high temperature filter 30 is maintained above 500'C above the combustion gases from the retort being fed via line 16 to a heat jacket 31 to prevent S: 20 condensation of the volatile gases 32. The volatile gases enter a first chamber 33 and impinge on a wall 34 which acts as a baffle and separates the first chamber 33 from a second chamber The wall 34 may have fins or plates thereon for the transfer of heat as well as to slow the gas stream down. As the volatile gases 32 sharply change path when passing from the first chamber 33 to the second chamber 35, most of the particulates 36 in the volatile gases 32 25 collect at the bottom of the high temperature filter 30 and can be selectively discharged by a rotary valve 37 and line 38 to the product bin 18. The combustion gases 32 then pass •through ceramic candles 39 which capture particles down to -1 micron. The interiors of the ceramic candles 39 are connected to a plenum or chamber 40 and the volatile gases 32 are i drawn from the plenum by a suction fan 41. The suction fan generates a partial vacuum in 0 the high temperature filter 30 (and the retort 10) and assists in causing the ceramic seals to P:\WPDOCSDYS\SPECIE\680276.SPE- 15/3/99 -6seal against the ends of the retort wall 11. An explosion vent in the form of a door 63 may be provided in the wall of the filter the door being arranged to open in the event of an explosion.

To prevent the oxygen level in the high temperature filter 30 reaching dangerous levels, sensor means (not shown) monitor the oxygen levels and if required, nitrogen from a supply tank 42 is injected into the line 15 via one or more nozzles connected to a valve 43.

To remove the particulates 36 which tend to coat the exterior of the ceramic candles 39, an air compressor 44 is connected to a manifold 45 via a valve 46. A respective pipe 47 extends from the manifold 45 into the interior of each ceramic candle 39 and sensor means (not shown) which monitor the gas flow through the ceramic candles, operate the valve 46 so that a blast of air is injected into the interior of the ceramic candles, via the pipes 47 to cause a countercurrent flow to the flow of the volatile gases 32 to dislodge the particulates from the candles for collection in the bottom of the high temperature filter Figures 9 and 10 show a modified form of apparatus for introducing nitrogen into the high temperature filter as well as for removing the particles from the candles. In the apparatus as shown nitrogen is fed from a manifold 401 having a plurality of outlets 402 to 406. Each outlet is connected to a transfer tube 407 which extends into the filter at a o S position above the candles 39. The tube has a series of downwardly facing holes 408 each hole being associated with a respective candle. The arrangement is such that a blast of nitrogen can be directed downwardly to clear the candles and at the same time deliver nitrogen to the filter.

The volatile gases 32 are conveyed via a line 48 to an afterburner 50 (see Figure ~in which combustion air is injected via a number of inclined injection pipes 51 to create a vortex for efficient combustion of the volatile gases. In one embodiment the combustion gases from the afterburner pass through a plenum 53 to a line 54 which is connected to a pipe Ir conduit 55 extending through the interior of the retort 10. In another embodiment the or conduit 55 extending through the interior of the retort 10. In another embodiment the P:\WPDOCS\DYS\SPECIE\680276.SPE 15/3/99 -7gases can pass along line 54 and instead of passing through the retort can be fed to the burners 13 as shown by dash line 62 in Figure 1.

The pipe 55 has a plurality of helical flytes 56 to further promote the agitation of the laminated solids 50 in the retort 10, and to promote the transfer of heat from the combustion gases to the solids. As shown in Figure 1, the flow of the combustion gases 52 from the afterburner is concurrent with the flow of solids through the retort 10 and the heat from the combustion gases 52 reduces the heat requirements for the retort provided by the burners thereby reducing the input energy demand and cost. (This means that the volatile contaminants in the soil are used to provide a portion of the energy demands for the treatment of the soil and so the volatile materials, which normally have a highly negative economic value, are given at least a partial positive economic value.) From the pipe 55, a line 57 transfers the combustion gases 52 to a scrubber 58 and thereby to the end stack 59 for release to the atmosphere.

Referring now to a second embodiment of Figure 6, liquid contaminants from a pond 120 are fed to a concentrator 121 where the water content of the liquids is minimised and the concentrated contaminated liquid is transferred to a tank 122. The contaminated liquid is pumped via a pump 122a to spray nozzles 123 which inject the contaminated liquid into the retort 10. The contaminated liquid comes into contact with the interior of the retort wall 11 and the conduit 55 to cause the volatile contaminants to be given off as gases as hereinbefore described and any non-volatile solids are discharged via rotary valve 17 to the product bin 18.

It will be noted that line 54 connects the afterburner 50 to the conduit 55 so that the S 25 flow of combustion gases 52 from the afterburner is countercurrent to the flow of the contaminated liquids through the retort In the embodiment of Figure 7, which is particularly suitable for the treatment of refinery tank bottoms, the contaminated refinery products containing, eg. 50-80% water, is ,e umped from a refinery tank 220 to a preheater 222 where the water and light hydrocarbon PAWPDOCSOYS\SPECIE\60276.SPE 15/3/99 -8fraction(s) are boiled off at, eg. 120°C plus and fed by line 260 to the afterburner 50. A hot filtering device 261 removes particulates from the water/gas stream and feeds them to the high temperature filter 30 via a rotary valve 262. The concentrated liquid from the preheater 222 is sprayed into the retort 10 as hereinbefore described. The preheater 122 is heated by combustion gases from the retort 10 via line 223.

From the retort, the non-volatile solids are discharged via rotary valve 17 to the bin 18, and the volatile gases are transferred to the high temperature filter 30. The volatile gases are transferred from the filter 30 to a condenser 270 via line 271 at a temperature of, eg.

500°C. The gases are cooled and the condensate is collected as fuel oil, which is drawn off to tank 272 via line 273. By arranging the Condenser 270 as a "fractional distillation unit", the condensate may be separated into a lubrication oil component (drawn off at, eg.

300-500°C) to tank 274 via line 275, and a diesel substitute component (at, eg. 200-300 0

C)

via line 273 to tank 272.

The remaining volatiles from the condenser 270 are fed to the afterburner 50 via line 48. These volatiles, and the 222 water/light HC fraction from the preheater, may be burnt at, eg. 1200"C with a residence time of, eg. 20 seconds. The energy from the afterburner is recycled to heat the preheater 223 and the high temperature filter 30. The high temperature 20 filter and pre-treatment feed and product lines are surrounded by a heating jacket to maintain temperature and the heat is sourced from the combustion chamber excess gases.

This method markedly reduces the costs of treating the refinery tank bottoms, and the costs are offset by the recovery of the valuable condensates(s).

Figure 8 shows a further embodiment of the invention which is particularly suited for the treatment of material containing organochlorine pesticides such as DDT, DDE and DDD and various arsenic based compounds. Such material is found in soil from cattle dip sites.

In this particular arrangement the containated material is preferably firstly pretreated In this particular arrangement the contaminated material is preferably firstly pretreated P:\WPDOCS\DYS\SPECIE\680276.SPE- 15/3/99 -9to remove water from the material. This may be done by the use of a preheater 501. The material is then transferred to retort 503 where the contaminant compounds are vaporised.

The contaminants in the gas stream so formed are then transferred to high temperature filter 504 which may be which may be of the type described earlier where further particulate matter is separated from the gas. The remaining gaseous component is transferred to afterburner 506. The afterburner thermally destructs the organochlorine pesticides to produce simple products of combustion and hydrogen chloride gas. The arsenic component of the gas will pass through the after burner primarily as arsenic trioxide.

If desired water vapour which may be conveniently drawn from the preheater 501 is fed into the afterburner 506 via line 510. The introduction of the water vapour causes a water/gas reaction which assists in the production of hydrogen chloride and arsenates.

The gas stream then passes to condenser 512 wherein the gas is rapidly cooled so as to condense the arsenates for collection as particulate matter at vessel 514. After the gas stream leaves the condenser 512 calcium carbonate can be added to the stream via hopper 516 to neutralise the hydrogen chloride.

The gas can be finally passed through a dust collector device 518 whereafter the gas 20 can pass to atmosphere. The dust collector 518 which may be in the form of a baghouse will remove the particulate arsenic trioxide which condenses below at approximately 120 0 C and collects on the filter media. The gas stream will exit the baghouse at approximately 100 0

C

and be vented to atmosphere. An auxiliary fan on the baghouse will be used in conjunction with the high temperature filter fan in order to overcome the additional pressure loss in the 25 system. The fans will be balanced using dampers in the system. The contaminated particulate (arsenic trioxide, spent lime) will be collected in plastic lined 200 L drums for disposal at authorised landfills.

OW.*

:o Two examples of condensers which can be used are shown in Figures 11 and 12.

n 0 Figure 11 shows an evaporate cooling arrangement wherein the gases leave the afterburner P:\WPDOCS\DYS\SPECIE\680276.SPE- 15/3/99 and travel along an inverted U-tube 601. Water spray a fed from reservoir 602 to spray heads 603 by pump 604 so as to rapidly cool the gas before it leaves the condenser.

Figure 12 shows an indirect air cooled arrangement where gases enter the top of the condenser 700. A series of fans 701 create an air flow across the condenser thereby cooling the gases before they exit at the bottom.

Figures 13 and 14 show two arrangements of a retort which is suitable for use in various forms of apparatus described herein. Referring to the drawings the retort 800 includes a cylindrical body 801 which is mounted for rotation about its central axis for example on shaft 810. The retort 800 is disposed within a combustion chamber (not shown) the ends being sealed by ceramic seals (not shown). The retort has an infeed end 802 through contaminated material is fed into the retort and an outlet 803. A plurality of flytes 808 are formed on the internal wall of the cylindrical body 801 the flytes preferably having a 5 0 pitch.

The retort 800 further includes a cage 815 which is mounted within the cylindrical body 801. The cage 815 comprises a series of horizontal elements or rods 816 and a series of circumferential elements 817 connected together to form a unitary structure. The S 20 circumferential elements 817 are arranged in pairs on the region of the space between adjacent flytes 808. The cross-sectional diameter of the cage 815 is less than that of the internal a cross-sectional diameter of cylindrical body 801 thereby forming an annular space 818 between the cylindrical body 801 and the cage 815.

25 The cage 815 is mounted for rotation and preferably is arranged to rotate in the opposite direction to that of the cylindrical body.

o: A plurality of balls 806 or like elements are disposed in the space 818 and are arranged to interact with contaminated material when the parts are rotating to break down the ,j naerial and dislodge carbonised material which may form on the internal wall of the P:\WPDOCS\DYS\SPECIE\680276.SPE 15/3/99 -11cylindrical body 801. The balls 806 are arranged in groups disposed at spaced intervals along the cylindrical body and are retained in position by respective pairs of circumferential elements 817 In the embodiment shown in Figure 14 there is further provided a series of arms 820 which can assist in moving the balls during rotation of the parts. The arms 820 can either rotate with the cage on shaft 810 or can be fixed to the internal wall of the cylindrical body 801.

The balls are arranged in groups each group which are held in place by the cage 815 and more particularly by the element 817 projecting into space 818. The groups of balls are being disposed at spaced intervals along the cylindrical body.

NB: For both contaminated solids or liquids, the flow of the combustion gases 52 through the retort may be either concurrent or countercurrent to the flow of the contaminated materials.

The recycling of the afterburner gases back into the retort 10 via the tube, pipe or 20 conduit 55 minimises the energy input to the retort by the burners.

•The provision of the heat fins or flytes 56 on the pipe or conduit 55 not only increases the radiant surface area of the retort, but also assists in breaking up any large particles. In p addition, the recycling pipe or conduit also helps create a convection environment with improves the volatile removal process, the convection improvement being created by the 25 moving retort wall and by rotation of the pipe or conduit The energy sources for the burners 13 may include liquid petroleum gas, propane, natural gas, recycled hydrocarbons or other readily available energy sources.

w yThe volatiles which may be treated by the method and apparatus of the present P:\WPDOCS\DYS\SPECIE\680276.SPE 15/3/99 12invention include hydrocarbons, organo-chlorides, arsenics, hydrogenated hydrocarbons, PCB's, coaltars and the like.

The operating temperature in the retort will be dependent on the volatile contaminants being treated and the retort may be operated at different temperatures to enable different volatiles to be treated on a fractional basis.

Various changes and modifications may be made to the embodiments described without departing from the present invention.

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S S. S S P:\WPDOCSDYS\SPECIE\68U276.SPE 15/3/99 13-

1. A high temperature filter for use in the treatment of volatile gaseous contaminated material, the filter including a main body having an internal space therein, when the filter is in its operative position includes an upper region and a lower region, said internal space being separated into first and second chambers, an opening providing communication between the chambers, said opening being at the lower region of the internal space, an inlet for delivering the gaseous contaminated material to the first chamber in the upper region of the internal space, an outlet for discharging the gaseous material from the second chamber in the upper region of the internal space, a solids collection zone adjacent the opening, a solids discharge outlet for discharging solids from the solids collection zone, a baffle opposite to and spaced from the inlet upon which incoming gases impinge and filter means for filtering the gaseous material passing out of the second chamber via the outlet.

2. A high temperature filter according to claim 1 wherein said baffle is defined by a wall which separates said first and second chambers.

3. A high temperature filter according to claim 2 wherein said wall extends from an 20upper internal wall of the chambers and terminates at a point spaced from a lower internal 20 wall of said chambers, the space between the wall and the lower internal wall defining said opening.

4. A high temperature filter according to claim any one of claims 1 to 3 wherein said discharge outlet comprises a plurality of outlet ports in the upper wall of said second 25 chamber.

5. A high temperature filter according to claim 4 wherein said filter means comprises a plurality of ceramic candles, each ceramic candle being associated with a respective outlet oi .port, said ceramic candles extending into said second chamber.

Claims (5)

1. 6. A high temperature filter according to claim any one of claims 1 to 5 including a gas collecting chamber for receiving the gaseous material from the outlet ports and a discharge outlet for discharging the gaseous material from the gas collecting chamber.
2. 7. A high temperature filter according to claim any one of claims 1 to 6 further including a fan suction means for drawing the gaseous material from the second chamber through the outlet ports.
3. 8. A high temperature filter according to claim any one of claims 1 to 7 further including pulsing means for delivering a gas pressure to the filter means in the opposite direction of normal flow for cleaning the filter means.
4. 9. A high temperature filter according to claim any one of claims 1 to 8 wherein the gas used in the pulsing means is nitrogen. A high temperature filter according to claim any one of claims 1 to 9 further including a heat jacket which at least partially surrounds the main body of the filter.
5. 11. A high temperature filter according to any one of claims 1 to 10 including fins or 20 plates on said baffle for the transfer of heat and for slowing the passage of the gaseous stream down through the first chamber. S. Dated this 15th day of March, 1999 TOX FREE SYSTEMS LIMITED AND TOX FREE SYSTEMS, INC. *By Its Patent Attorneys S COLLISON CAVE a DAVIES COLLISON CAVE P:\WPDOCS\DYS\SPECIE\680276.SPE 15/3/99 ABSTRACT Apparatus for the treatment of volatile material(s) in contaminated material(s) including a retort assembly which includes a rotatable retort disposed at least partially within a combustion chamber with heating means to indirectly heat the rotatable retort; feeding means to feed the contaminated material(s) to the retort. The apparatus further includes means for passing the combustion gases from an afterburner to the retort assembly to provide additional heat for use in the heating of contaminated material in the retort. The apparatus further includes a high temperature filter which can filter the volatiles before entering the afterburner. -ft *t ft* 9*ft* ft. t ft. ft. ft... 4 ft ft ft. 4 ft f 4. 4 ft