AU731392B2 - Cleaning articles, substrates therefor, and method of substrate manufacture - Google Patents

Description

trlUU/u I I LW.VI Regulation 3.2(2) :V -6.

AUSTRALIA

Patents Act 1990

ORIGINAL

COMPLETE SPECIFICATION STANDARD PATENT Application Number: Lodged: Invention Title: CLEANING ARTICLES, SUBSTRATES THEREFOR, AND METHOD OF SUBSTRATE MANUFACTURE The following statement is a full description of this invention, including the best method of performing it known to us T

I

CLEANING ARTICLES. SUBSTRATE8 THEREFOR,

AND

ETHOD OQ SUBSTRATE MANUTACTuRE This invention relates to cleaning articles, substrates therefor, and a process for the manufacture of such substrates. The invention has particular application to substrates which are to be used to produce so-called vet wipes, i.e. small sheets, moistened with a liquid having cleansing or other relevant properties. Such wipes are sold, for example, in the form of baby wipes, adult incontinent wipes, and facial/skin cleaning wipes. It is to be understood, however, that the invention is also applicable to other forms of product used for cleaning areas of the human person, for example.moist toilet paper and dry wipes, and is also applicable to wipes intended for cleaning other surfaces, for example kitchen and bathroom surfaces, and surfaces which require cleaning in industry, for example surfaces of machinery or of automobiles. As will be apparent from the ensuing description, some, though not all, of the advantages afforded by the present invention and embodiments thereof are relevant to cleaning such inanimate surfaces.

For simplicity, the description below concentrates on vet wipes for cleaning the human skin, but what is said must be understood in the light of the foregoing comments about the wider applicability of the invention.

Wet wipes commonly comprise a substrate of a nonwoven fibrous material, wetted by a suitable liquid.

The non- woven substrate material is formed to have a high strength. Some limitations may be imposed on the strength of the substrate if it is desired that its density should be low enough to permit the presence of pores in which a significant amount of the wetting 2 liquid can be held. However, this is not much of a limitation, and it may be no limitation at all, since all or most of the wetting liquid can be held by virtue of the strongly hydrophilic surfaces of the fibres, rather than by the capillary action of any open pores between the fibres. This is true, for example in the case of cellulose/pulp air laid tissues. Typically, a known wet wipe substrate will have a breaking tensile strength of about 50 or 60 N in MD and about 8N in CD, where MD and CD refer to machine direction the direction of travel of the substrate through the machine which is producing it) and cross direction (a direction in the plane of the substrate and at 900 to machine direction).

An alternative method of defining strength, and one which may be more appropriate for the purpose of comparing these known substrates with substrates according to the invention described below, is the work, typically expressed in Nm (Newton-metres) required to stretch the substrate to breaking point. This is 15 referred to below as toughness. A test for measuring toughness is described in more detail below.

One method of manufacturing non-woven substrates involves a process known as hydroentangling. In this, a web of fibres, for example a carded web, S travels beneath at least one array of orifices, and preferably a plurality of 20 successive arrays, from which jets of water are emitted. Each array extends transversely with respect to the path of travel of the web, and provides a large number of closely spaced jets. These jets act like sharp needles, and entangle the fibres to form a substrate. This entanglement holds the fibres in a coherent substrate, without the need for adhesives or thermal bonding. In current equipment, the orifices typically have a diameter of from about 80 to about 180 micrometers, preferably about 90 to 150 micrometers, and there may typically be from about 800 to 1700 3 nozzles per metre of orifice array. The water is supplied to the orifice arrays at a pressure which generally increases stepwise from the first array, where it may be as little,as 30 bar, to the last array, where it may be as much as about 250 bar. This stepwise increase is provided to allow for the fact that the fibres are progressively more and more difficult to move as entanglement proceeds. The total energy supplied to the web by the liquid jets from all the orifice arrays combined is 0.5 to 1.0 kWh/kg of fibre material.

It has now surprisingly been found that wet wipes can be produced which have superior properties to known wet wipes, both as regards as their cleaning ability and as regards the softness which the user perceives them to have, if the substrate is one which is significantly less strong than the substrates of known wet wipes, and provided certain other conditions are S: fulfilled. In the case of substrates made using a S* hydroentangling process, the lower strength can be achieved by reducing total energy input of liquid jets.

It should be mentioned that although hydroentangling is preferred as the method of producing Sthe substrate, other methods known er se in the art can alternatively be used. For example, the water can be replaced by another liquid, or by a gas, for example air or steam. Alternatively, the fluid "needles" can *.be replaced by mechanical needles, in a process known as needlepunching. In this barbed needles, e.g. of steel, are punched through the web, hooking tufts of Sfibres across it and thereby bonding it in the needlepunched areas. The needles enter and leave the web while it is trapped between two plates, the web being pulled through the apparatus by draw rolls.

Another method which might be used is thermal bonding, in which the fibres are of thermoplastic material, or have an outer layer of thermoplastic material, and are bonded together in discrete spots by 4 heat. This bonding can be achieved using a drum which has at least one heating element in the interior thereof, and which has an exterior surface carrying an embossed pattern with which the fibrous layer is pressed into contact. However, a substrate produced in this way is unlikely to be as soft as one produced by hydrogentangling, or needlepunching, and may have a substantially proportion of completely loose fibres.

Yet another method involves wet-laying a mixture of fibres and chemical binder, somewhat in the manner employed, for example, in paper making.

Needlepunching, thermal bonding, and wet-laying are all known per se and will therefore not be described in detail below. Hydroentangling is also known per se, but is described further below, because it is the preferred method and for the purpose of mentioning a number of modifications to the hydrogentangling procedure as it is usually practised.

15 SUMMARY OF INVENTION Thus, according to the present invention there is provided a non-woven fibrous substrate for use in a cleaning article, wherein the substrate has a major surface for rubbing on a surface to be cleaned, a low strength in at least one direction, and includes about 50% by weight of hydrophobic fibres and about 20 by weight of hydrophilic fibers wherein a proportion of all the fibres are long fibres which are capable of protruding from said major surface as a result of said rubbing whilst remaining attached to the substrate.

In a preferred embodiment, the substrate includes 50% by weight of hydrophobic fibres and 50% by weight of hydrophilic fibers.

Preferably the substrate, as made, has a toughness of less than 0.6Nm in at least one direction, more preferably not more than 0.5 Nm. The toughness is preferably less than 1.2 Nm in each of two mutually perpendicular directions. The tensile strength is preferably not more than 45 N. After rubbing is applied, in a manner described below the toughness is preferably reduced by at least and is preferably less than 0.5 Nm, in at least one direction, and less than 0.6 in -each of two mutually perpendicular directions. The tensile strength after rubbing fp 4 is preferably not more than 1 ON in at least one direction, and not more than in each of two mutually perpendicular directions.

The invention further provides a wet wipe including a substrate as aforesaid and a cleaning liquid.

The invention also provides a method of producing a non-woven, fibrous substrate for use in a cleaning article, and having a major surface for rubbing on a surface to be cleaned, wherein a fibrous layer includes about 50% by weight of hydrophobic fibres and about 50% by weight of hydrophilic fibres of which a proportion of all the fibres are long fibres, is subjected to hydroentangling by means of jets of liquid which apply to the fibrous layer a force sufficient to produce a coherent substrate but low enough for at least some of said long fibres to be capable of protruding from said major surface as a result of said rubbing, :whilst remaining attached to the substrate.

In a preferred embodiment of the method, the fibrous layer includes .15 by weight of hydrophobic fibres and 50% by weight of hydrophilic fibres.

In order that the invention might be more fully understood, embodiments of Sthe invention will be described by way of example only as follows: A substrate according to an exemplary embodiment of the invention S possesses two significant characteristics identified as and below, and should desirably possess two others, identified as and These are: Low strength SfieThis is necessary in order to allow significant quantities of surface fibres to become separated from the surface plane of the substrate when the substrate is subjected to the friction which results from rubbing on the skin or other surface to be cleaned. The low strength may be in MD or CD or both.

The presence of relatively long fibres At least a certain proportion of the fibres, preferably at least more preferably at least 40%, still more preferably at least 60%, and yet more preferably at least 80%, are sufficiently long that even though they extend from the surface plane of the substrate as a result of the friction produced by rubbing, they nevertheless remain attached to the body of the substrate. In one preferred form, substantially 6 all the fibres are long fibres. Such fibres can either remain attached at one end, with the other end extending from the substrate surface, or they can remain attached at both ends, but have a central portion extending from the substrate surface. The fibres referred to herein as "long" have a length of at least 2cm, normally from 2 to 6cm, and more preferably at least 3cm, normally from 3 to The ablity loosene fibreortions to remain away fron the substrate surfnAceg The point here is that the desired effect is unlikely to be achieved if the loosened fibre portions have a tendency to remain against the substrate surface. One way in which this tendency can be avoided is if at least a proportion of the fibres concerned has a relatively high flexural stiffness, even when the .substrate is wetted by a cleaning liquid, if present, and so will tend to protrude from the substrate S: surface. To give this stiffness, such fibres should preferably have a tensile strength, when dry, of at least 2.5cN, more preferably at least 5cN, and still more preferably of the order of 10cN. However, they should not be so stiff, at least where the product is to be used on the skin, as to give the product an unacceptably abrasive feel, and the tensile strength should therefore preferably not exceed 30cN, and more preferably should not exceed Where the substrate is to be used for an article, such as a wet wipe, containing a cleaning liquid which 'is either an aqueous solution or an emulsion in which the continuous phase is aqueous, instead of, or in addition to, the fibres having at least a given flexural stiffness, the desired effect may be achieved if those fibres are hydrophobic, and thus resist the absorption of the cleaning liquid which the wet wipe contains. Fibre materials which have suitably hydrophobic properties include polyolefins such as polypropylene and polyethylene, polyamides such as nylon, and polyethylene terephthalate.

If the liquid carried by the wipe or cleaning article is oil-based, for example in the form of an emulsion in which the oil forms the continuous phase, the fibres could be caused to protrude from the surface of the substrate by their being hydrophilic, and suitable fibre materials for this purpose include viscose' fibres and cotton fibres. Yet another possibility is for the cleaning liquid to be a silicone emulsion, in which case the fibres must be such as will continue to protrude from the substrate in the presence of such an emulsion.

Texturing This is very desirable, for reasons which will be apparent from what is said below.

In the accompanying drawings of preferred embodiments: 15 Figure 1 is a diagrammatic perspective view of an example of an apparatus O: which can be used to produce a substrate according to the present embodiment, using hydroentangling; Table 2 is a set of graphs showing the strength of various substrates, some S according to the embodiment of the invention and some not; and oooo 20 Figures 2 and 3 are photographs with a 1.75:1 magnification, showing a substrate according to an embodiment of the invention before and after rubbing; Figures 4 and 5 are cross section, magnified x25, through a substrate according to an embodiment of the invention and a comparative substrate; Figures 6A to 6F are graphs generated by an Instron machine test (described further below) of various substrates; and Figure 7 shows a Lissajous curve, referred to below in connection with a rubbing test referred to below.

The apparatus 10 shown in Figure 1 comprises a continuous belt 12, on the upper run of which the 8 hydrogentangling process takes place. As viewed in Figure i, the upper run travels in a rightward direction and preferably does so at a speed of 25-75 m/min, more preferably 40-60 m/min. The belt is apertured, as described in more detail below. A layer of fibres 14, such as a nonwoven batt or other initial fibrous layer is fed on to the belt, as indicated diagrammatically by arrow 16. The initial fibrous layer may consist of any suitable web, mat or batt of loose fibres, disposed in random relationship with one another, or in any degree of alignment, such as might be produced by carding or the like. The initial fibrous layer may be made by any desired technique, such as by carding, random laydown, air or slurry deposition or the like.

The initial fibrous layer then passes beneath a plurality of orifice arrays 18. Each array externds transversely across the line of travel of the belt 12 and fibrous layer 14. In the drawing, five such arrays 18 are shown, but it must be emphasised that the number of arrays could be more or less than this, say from 2 to 15. There might be only a single nozzle array, but a plurality is preferable. Each array 18 has a perforated plate on the underside thereof in which is o formed at least one row of orifices. Typically, there is a single row or a pair of parallel rows, and where there is a pair of rows the orifices in one row may be staggered with respect to the orifices in the other row. The row, or each row, as the case may be, runs parallel to the length of the array 18. The orifices used in one preferred form of the present invention have a diameter of from 100-120 micrometers, and are arranged, for example, at about 0.6mm centres.

Water is fed to the arrays via a high pressure line 20 and individual pressure regulators 22, one per array. By this means the pressure can differ from array to array. Thus, as already mentioned, the pressure may increase stepwisQ from one array to the next, as considered from the upstream end to the downstream end of the belt. The sum total of the pressure applied to individual arrays is preferably from 40-1100 bars, more preferably from 40-200 bars.

The water flow rate through each array is preferably from 2-5 m 3 /hr for each metre length of the array. The flow velocity of each water jet is from 40 to 110 m/sec, more preferably from 40 to 100 m/sec, and the energy flow per water jet is preferably from 300-14000 bars.m/sec, more preferably at least 800 bars.m/sec.

The total power input to the web from all the arrays combined, is preferably from 1.0-120 kW/m of web width, and is more preferably not more than 100 kW/m. The total energy input to the web is preferably from 0.005 to 0.8 kWh/kg of material, and preferably less than kWh/kg. More preferably it is in a range of from 0.1 td less than 0.5 kWh/kg. Still more preferably the upper limit of this range is 0.4 or 0.3, and the lower limit of the range may be 0.2.

Vacuum boxes 24, one for each array 18, are provided beneath the belt, for the purpose of taking S* away the water after it has passed through the belt.

As already mentioned the belt is in the form of a v ire grid, preferably a rectangular, and, more preferably, square, grid, defining a corresponding array of apertures. For example, a grid may be used in which there are from 12 to 30 apertures per cm 2 preferably from 20 to 30 apertures per cm 2 It must be understood, however, that finer or coarser grids may be .used, and that the apertures may be arranged in ways which do not constitute square or rectangular grids.

As explained above, the water is used to supply an amount of energy which is low compared to that conventionally used, though sufficient to effect hydroentangling. One effect of this is that the substrate thuu formed does not have openings extending through it even at the locations where, during its formation, it is immediately above the wire crossing points in the belt, at least as regards a substantial proportion of those locations. Preferably, not more than 50% of the locations form open apertures, and more Preferably not more than open a p e r t u r e s a n d m o r e preferably not more than 30%. Generally, at least a few percent of the locations will provide open apertures, say at least Except where the apertures are open, the substrate consists of areas of reduced thickness formed above the wire crossing points and ridges elsewhere. Th absence of large numbers of openings in the substrate is an avantage where, for example, it is to be used as the substrate for a wet wipe. If many openings were present these could permit dirt and other ndesirable materials to pass through the substrate from the surface being cleaned to, fdr example, the hand of the user.

s The existence of the above mentioned ridges in the substrate has at least two significant advantages.- One is that it increases the caliper of the substrate material without a proportionate increase in the amount of material required to make it. The other is that the ridges form The other is that the ridges form initiation ar where friction produced during rubbing can start the partial break-up of the surface of the substrate, with the attendant desirable i".effects already described.

The amount, and nature, of the entangling produced by the water ets depends, on the belt speed and the direction of the jets. Regarding the direction of belt travel (MD) as the y direction the direction transverse thereto in the plane of the belt (CD) as the lf'eX direction and perpendicular to the plane of the belt as the z direction, the greater the difference between the component of belt velocity in the x or y direction, and the component of jet velocity in the same direction, the greater will be the entangling effect in that direction. Thus, when the belt is travelling at a high speed in the y direction, and the jets are aimed directly along the z axis, as is conventional in a hydroentangling apparatus, there is a 11 substantial amount of entangling in both directions, but much more in the y direction than in the x direction. Correspondingly, the resulting strength of the substrate in the x direction is much less than in the y direction. The faster the belt speed, the higher the proportion of the energy which goes into the y direction entangling, and the lower the proportion which goes into the x direction.

The respective strength in these two directions can be altered by angling the jets upstream (increasing the y direction entangling), downstream (decreasing the y direction entangling), laterally (increasing the x direction entangling), or in some combination thereof. For example, the jets can be angled upstream or downstream by up to 450 with respect to the normal to the belt, and/or laterally by up to 450. In addition, some jets could point in different directions to other jets, either within a given array or from one array to another. Further, some or all of Sthe orifices could be shaped to give a swirling motion to the jets issuing therefrom.

S: 15 In the foregoing description, the surface on which hydroentangling takes i place has been referred to as a belt. It is to be understood, however, this is only by way of example, and the surface could be any suitable travelling surface, whether travelling linearly or, in the case of a drum for example, circularly.

Also, the apparatus shown in Figure 1 has water jets only on one surface of the substrate. It may be desirable to effect hydroentangling from both S. surfaces. In that case, the web of Figure 1 can be passed through a second, oppositely disposed assembly of orifices arrays and vacuum boxes. Alternatively, the initial web can pass through an assembly in which orifice arrays on one side of the web alternate with orifice arrays on the other side.

Further general information about hydroentangling can be found, for example, in US-A-2862251 (Kalwaites), US-A-3025585 (Griswold), US-A- 3485706 (Evans), US-A-5204158 (Phillips et al), US-A-5320900 (Oathout) and EP-A-0418493 (Fiberwet), the contents of which are incorporated herein by reference. Hydroentangling equipment suitable for use in carrying out the present embodiment is obtainable from ICBT Perfojet, Z.A. Pre-Millet, 38330 Mont zlLATnnot. France.

Various fibre compositions can be used to produce the substrate, though the composition should include sufficient fibres a portion of which have the desired ability to protrude from the surface of the substrate. Examples of fibre compositions which can be used include mixtures of a hydrophilic fibre material viscose, cotton or flax) and a hydrophobic fibre material polyethylene terephthalate or polypropylene), which are present about 50% of a hydrophilic material and about 50% of a hydrophobic material. All these percentages are by weight. Two particularly preferred compositions are 50% viscose/50% PP and 50% viscose/50% PET. One advantage provided by having such a large amount of viscose fibres is that their surfaces are ridged, having ridges of the order of micrometers high, and their ridges provide additional friction to help initiate partial break-up of the substrate.

*The substrate preferably has a basis weight of at least 30 gm 2 Where the 15 substrate is to be used for a wet wipe it is unlikely that a basis weight of more than 150 gm 2 will be required, though in theory higher basis weights could be employed. Indeed, given that the invention is concerned with what is, in essence, a surface effect, it can be seen that it is not unreasonable that, provided the ooooo substrate is not too thin, its thickness should be, at least largely, irrelevant to the °oo° 20 invention. For practical purposes, however, at least in the field of ordinary wet wipes, the basis weight is preferably in the range of 30-130 gm 2 more preferably 30-70 gm 2 and still more preferably 55 to 65 gm 2 A product having a basis weight of 55 to 65 gm 2 when made according to the present embodiment by a hydroentangling process, and with a textured surface, typically has a caliper of about 0.8mm, including the texturing. The texturing, as already mentioned can be achieved by carrying out the hydroentangling on an apertured surface. If the overall caliper is less than about 0.4 mm it may be difficult to incorporate a textured surface, and such a surface is advantageous, for the reasons already given. Preferably, the caliper of the substrate is from 0.4mm to 2.0mm, more preferably from 0.4 to 0.95mm. The bulk density of the substrate is preferably not ?_AL re than 0.lg/cm 3 preferably not more than 0.9g/cm 3 and still preferably not 13 more than 0.8g/cm 3 In determining the density, the volume of the substrate is calculated using the caliper of the substrate including the texturing.

As already indicated, a substrate produced according to the present embodiment results in superior cleaning properties to those obtained by substrates according to the prior art. The principle reason for this is believed to be the fact that the fibres which protrude from the substrate surface as the cleaning process proceeds provide additional cleaning surfaces. However, the actual cleaning mechanism may involve other effects in addition to, or instead of, the one just described, and no reliance is to be placed on the particular theoretical explanation just given.

As well as the improved cleaning effect, there is also an increase in substrate softness. This is believed to result from two mechanisms. Firstly, the low strength of the material results in a material-imposed limitation on the level of 15 friction which can be achieved between the substrate and the surface of which it is being rubbed, for example the skin. When the frictional force begins to exceed that limit, individual fibres partially tear from the surface of the substrate, thereby preventing any further increase in the frictional force. No such force-limiting effect S is present in prior art substrates, at least not until the frictional force is very high.

20 The second relevant mechanism is believed to be that as fibres are caused to protrude from the substrate they can be felt by the skin with which the substrate logo is in contact, and since these fibres, even if relatively stiff, are then free to bend, the sensation to the user is one of softness. However, the increased in perceived softness may result from other effects in addition to, or instead of, those just described, and no reliance is to be placed on the particular theoretical explanation just given.

Four substrates according to embodiments of the invention (Examples 1 to 4) will now be described, together with a comparative example (Example 5) of a substrate not according to the invention.

14 Examples 1 to 4 were made from the same fibre composition, namely viscose and 50% polypropylene, all the fibres having a length of 4cm and a diameter equivalent to 1.7dtex. Examples 1 to 4 were all made in the same way.

The only difference between them was basis weight of the substrate, which was as follows (the basis weight of Example 5 also being given for completeness): Ex 1 60.7 g/m 2 Ex2: 62.8 g/m 2 Ex 3: 55.8.g/m 2 Ex 4: 59.2 g/m 2 Ex 5: 63.2 g/m 2 It should be noted that Example 5 used the same fibre composition and fibre diameter as Examples 1-4.

i* The apparatus used in Examples 1 to 4 had an apertured belt with 25 apertures/cm arranged in a square grid. The line travelled at about 50 n/min. 13 orifice arrays were used, each having about 1666 orifices per metre of their length, with each orifice being about 100 micrometers in diameter. Example 5 was made using a belt which was not apertured. In all of Examples 1-5 the jets were directed perpendicularly to the fibrous web. Other process conditions for Examples 1 to 4 and comparative Example 5 are set out in the following Table 1.

Ex. 1-4Ex.5 Combined flow rate through all jet arrays (m 3 /hr/array/m) 50 Pressure (bar) 45-85 40-90 Jet velocity (m/sec) 60-90 60-90 Energy flux per jet (bars.m/sec) 3000-7500 2000- 8000 Total pressure across all arrays (bars) 620 970 Total power input from all arrays (kW/m web width) 62 107 Total energy input from all arrays (kWh/kg web) 0.34 0.59 The ranges given for pressure and jet velocity represent the fact that these increase for one array to the S: next, as considered in the direction of travel of the web.

It must be understood that all values are approximate, and are given as accurately as they are known to the applicants.

Various properties of the substrate of Examples 1 to were tested, and also a further comparative substrate, Example 6, which, like Examples 1-4, was a hydroentangled substrate, but, unlike comparative Example 5, was apertured.

Example 6 was produced using more energy than for Examples 1 to 4. Example 6 had a basis weight of 53.9 gm- 2 The results of theso tests are set out in Table 2. The way in which the various tests were carried out is described later in this specification.

0 S.0 0 apruepnEX I Ex 2 Rx 3 Ex 4 ExS5 Ex 6 %Caper ur s pen [10-20] [10-201 [10-201 [10-201 ia 100 CW e r (mm)it 0.8 0.79 0.79 0.79 0.56 0.68 Tensile strength (CD) 005.79.69.750.113 0. 079 at break 6.96 6. 1 6.5 7.7 9.07.

Tensile strengthi (MD)7.

at break 35.7 27.2 25.4 30.2 49.3 4.

Toughness (CD) (Nm) 0.4 0.6 0.60 Toughness (MD) (Nm) 0.9 1.0.5 Modulus elongation) 0.016 0.03 0.05 Modulus elongation) 0.3 1.0.5 %Elongaion at break(CD) 114.7 140.4 123.9 120.7 156 150 %Elongation at break (MD) 32.1 31 29.7 29.2 33 2.

Static friction 1.71 1.911 Static friction 1.54 1.91 1.77 Dynamlic friction coefficient (CD) 0.0 18 1.023 0.021 Dynamic 'friction coefficient (MD) 0.017 0.023 0.021 Air permeability (11m 2 /sec) 1000 0.0749 100 Absorption capacity (gH4 2 O/gweb) 9.07 9.57 9.35 17 The values given for modulus are those for initial modulus, as is also the case in Table 2 below.

From the above it will be particularly noted that in the embodiment the initial CD modulus is very low, and that even though there are relatively few apertures the density is also low.

A further set of tests were carried out, repeating some of those which are the subject of Table 2, on Examples 2, 5 and 6, after they had been subjected to a rubbing action. This action was intended to simulate what the substrate experiences when in use in, for example, a wet wipe. The results are set out in Table 3.

TABLE 3 Ex.2 Ex.5 Ex.6 S: apertures open <5 n/a 100 Caliper (mm) 1.05 0.66 0.68 Tensile strength (CD) at break 4.5 10 6.8 Tensile strength (MD) at break 18 47 63 Toughness (CD) (Nm) 0.3 0.6 0.7 a..

SToughness (MD) (Nm) 0.5 1.3 1.6 Modulus elongation) 0.008 0.024 0.093 a Modulus elongation) 0.89 1.6 6.7 a.

As can be seen from the above, rubbing substantially alters the properties of Example 2 (which is according to the embodiment), but has a much less marked effect on Examples 5 and 6 (which are not). In each case the alteration in Example 2 is consistent with its being significantly weaker than Examples 5 and 6, the effect of rubbing being to cause the substrate to beak up to an extent sufficient to produce the desired sensation to the user, but not such as to cause complete disintegration (which is undesired).

In particular, attention is drawn to the fact that in Example 2 the caliper is significantly increased and the toughness is significantly decreased, both of which Ict the partial break-up of the substrate.

18 A comparison of Figures 2 and 3 shows the extent to which rubbing causes a substrate according to the embodiment (Example 2) to being to break up.

A comparison of Figure 4 (Example 2 after rubbing) and Figure 5 (Example 6 after rubbing) shows how much lower is the density of the substrate of the present embodiment, at least after rubbing, and the presence of numerous protruding fibres.

Various modifications may be made to the embodiments as described above, and some of these will now be mentioned: Instead of using orifice arrays for hydroentangling in which the orifices are uniformly spaced at, say, 1 mm centres along the entire effective length of the array, each array may have a region of, say, 1cm, in which there are orifices spaced at 100 micrometer centres, alternately with regions of, say, in which there are no orifices. The effect of this is to produce a substrate which i 15 has alternating strips of entangled .fibres and non-entangled fibres. The former provide strength to the substrate, and the latter provide fibres which readily come S: loose from the substrate as a result of the friction of rubbing.

The substrate could be multi-layer. One possible construction is a S sandwich in which a central layer (which may be of hydroentangled fibres, but 20 could be of virtually any material, e.g. a woven material, with external layers of S* fibres formed therein by hydroentangling according to the embodiment. This would have the cleaning properties and softness associated with the present 9 embodiment, but the possibility of other properties, e.g. added strength, from the central layer. Another possible construction is one of two layers, of which at least one layer is formed by hydroentangling according to the embodiment.

There now follows a description of how certain tests referred to above are to be carried out.

The following tensile properties of the previous examples are evaluated with an Instron tester under the following conditions. All tests are conducted at laboratory conditions of 21 C and 65% relative humidity. The Instron gauge length is 10 cm.

Elongation rate is 10cm/min or 100%/minute. The Instron "jaws" that secure the sample are flat and rubber coated.

-Tensile stren -h initial mulus and to ness in both the MD and CD directions are determined from I" wide strips cut to 15 cm in length and fixed without slack but without tension on the Instron tester within jaws set at 10 cm distance. The energy input from the Instron machine to the sample is then plotted over time with the y axis indicating the force applied to-the sample in Newtons and the x axis indicating the elongation of the sample at the indicated elongation rate.

The tensile stren -th number is defined as the peak force from this force over elongation curve.

The initial modulus number is obtained from the graph produced from the same test. It is the initial slope of the force/elongation curve and is indicated as S. the y axis in units of Newtons/% elongation.

SThe t2uqhnies is the number obtained also from this same test and results graph. Toughness is defined :as the area under the entire curve indicated in Newtons by elongation.

Substrate ClLper is measured using standard

EDANA

non-woven industry methodology, reference method #30-4- 89.

Entanglement frequency is evaluated from the following data produced on the Instron tester with strips of va-ying widths, as indicated.

Strip Width Av CD Sm Inan Elonation Rate indicatin TenileStriD Width Gare fin/minute) E~~arnD~e42 (i)Lnh(n 1.4. 8.0 0.8 0 W1 8.2 0.3 1.5 w2 17.1 .1.9 1.5 From example 12, the entanglement frequency is calculated from the following equation.

entanglement frequency CID

LZ-

V1T2-v2Tl.

From this, then the entanglement frequency for example #F2 in the CD direction -is calculated to be 11.7. Further details of the concept of entanglement frequency can be found in the above cited reference

US-

A-3485706.

Abrasion or Rubbing T=s In this test the substrate to be tested is rubbed against another fixed piece of the same substrate to be tested.

One standard piece of equipment appropriate to do this is a "Satra M{artindale Abrasion Machine" as described in the Journal of Textile Instruments; Vol 33 No 9 Sept 1942. However, any machine or laboratory set up that provides the following conditions may be used.

The test substrate to be evaluated is clamped into a fixed, taught but not stretched position on a horionta surf ace, Th circular clamp holding this .material in place is 50 in diameter. The rubbing test is than conducted on the area of the sample within this fixed circula-r clamp.

A second sample of the test material is then clamped taught but not stretched in a fixed position on .a 1.750 diameter flat and solid ended cylinder. This second sample is then rubbed on the first sample for the purpose of the test. The vertical force, or absolute mass (weight) of the second sample against the first sample is 0.68 Kg.

The second sample with this weight is then rubbed against the first sample in a repeating pattern, known as a Lissajous pattern, that fully covers the test sample, as shown in Figure 7.

There are 10 cycles of this pattern for the test where one cycle is represented by the full pattern shown above. One cycle consists of oscillations in one direction and a second 15 oscillations at right angles to the first set of oscillations. One full cycle of these 30 oscillations is done over 18 seconds.

The substrate within the 5" fixed ring is then considered the treated sample. For the purposes of the Instron testing of the rubbed or treated sample, this piece of substrate is then cut in the CD or MD direction into strips of the appropriate width and length for the Instron test.

For example, for the tensile, initial modulus and toughness tests on the S Instron machine, this treated strip is cut to 1" wide by 15 cm long strips.

Figure 6a to 6e are curves of the type just mentioned derived from three 15 different materials, as follows: Figure 6a/6b: Substrate according to comparative Example Figure 6c/dc: Substrate according to the embodiment (Example 2) Figure 6e/6f: Substrate according to comparative Example 6.

Figures 6a, 6c and 6e are for MD, and Figures 6b, 6d and 6f are for CD.

20 The rotation "NORMAL" means before rubbing and "RUBBED" means after 0..

rubbing.

r The ordinate in each the graphs is in N, and the abscissa is in S: S elongation of the sample. For the purposes of calculating the toughness in Nm, the value is converted into m by %/100 x O.lm, with 0.lm being the length of the strips being tested.

The terms "comprise", "comprises", "comprised" and "comprising" when used in this specification are taken to specify the presence of stated features, integers, steps or components but does not preclude the presence or addition of one or more other features, integers, steps, components or groups thereof.

S -1u S

//F

Claims (35)

1. A non-woven fibrous substrate for use in a cleaning article, wherein the substrate has a major surface for rubbing on a surface to be cleaned, a low strength in at least one direction, and includes about 50% by weight of hydrophobic fibres and about 50% by weight of hydrophilic fibers wherein a proportion of all the fibres are long fibres which are capable of protruding from said major surface as a result of said rubbing whilst remaining attached to the substrate. s2. A substrate according to claim 1 wherein the substrate includes 50% by 0 defined herein, of less than 0.6 Nm in at least one direction.

4. A substrate according to claim 1 or 2, which, as made, has a toughness, as ease 0: defined herein, of not more than 0.5 Nm in at least one direction. *0

5. A substrate according to any one of the preceding claims, which, as made, o° has a toughness, as defined herein, of less than 1.2Nm in each of two mutually perpendicular directions.

6. A substrate according to any one of the preceding claims, which has a toughness, as defined herein, after rubbing, as also defined herein, of less than Nm in at least one direction.

7. A substrate according to any one of the preceding claims, which has a toughness, as defneed herein, after rubbing, as also defined herein, of less than d 6 Nm in each of two mutually perpendicular directions. 23

8. A substrate according to any one of the preceding claims, wherein rubbing, as herein defined, reduces the toughness, as also defined herein, by at least

9. A substrate according to any one of the preceding claims, which, as made, has a tensile strength, as defined herein, of not more than 45N in any direction. A substrate according to any one of the preceding claims, which has a tensile strength, as defined herein, after rubbing, as also defined herein, of not more than 1ON in at least one direction, and/or not more than 30N in each of two S• mutually perpendicular directions.

11. A substrate according to any one of the preceding claims, wherein the said long fibres have a length of at least 2cm

12. A substrate according to claim 11, wherein the long fibres have a length of 2 to 6 cm.

13. A substrate according to claim 11, wherein the long fibres have a length of at least 3 cm.

14. A substrate according to claim 11, wherein the long fibres have a length of 3 to 5 cm. A substrate according to any one of the preceding claims, wherein the long fibres have a tensile strength of at least 2.5 cN.

16. A substrate according to claim 15, wherein the long fibres have a tensile strength of at least 5 cN.

17. A substrate according to any one of the preceding claims, wherein said major surface is textured.

18. A substrate according to claim 17, wherein said texture is in the form of a grid of depressions and ridges, of which not more than

19. A substrate according to claim 18, wherein not more than 50%, of the depressions form apertures open to the opposite face of the substrate. A substrate according to either of claims 18 or 19, wherein there are 12-30 depressions/cm 2

21. A substrate according to any one of the preceding claims, wherein the substrate is hydroentangled. °oo*

22. A wet wipe which includes a substrate according to any one of the preceding claims, and a cleaning liquid carried thereby. ogle

23. A wet wipe according to claim 22, wherein the substrate has density, when dry of not more than 0.1 g/cm 3

24. A wet wipe according to either claim 22 or 23, wherein the cleansing liquid is aqueous, or has an aqueous continuous phase. A substrate according to any one of claims 1 to 21, or a wet wipe according to claim 22, wherein the hydrophobic fibres are of polyethylene terephthalate or polypropylene, or have an external layer thereof.

26. A wet wipe according to claim 22, wherein the cleaning liquid is an oil or has an oily continuous phase. Cb ~'VflP

27. A wet wipe according to claim 22, wherein the cleaning liquid is a silicone emulsion.

28. A substrate according to any one of claims 1. to 21, or a wet wipe according to claim 22, wherein the hydrophilic fibres are of viscose, cotton or flax.

29. A wet wipe according to any one of claims 22 to 28, wherein all or substantially all the fibres of the substrate are long fibres. A method of producing a non-woven, fibrous substrate for use in a cleaning article, and having a major surface for rubbing on a surface to be cleaned, wherein a fibrous layer including about 50% by weight of hydrophobic fibres and about 50% by weight of hydrophilic fibres of which a proportion of all i:: the fibres are long fibres, is subjected to hydroentangling by means of jets of liquid which apply to the fibrous layer a force sufficient to produce a coherent substrate but low enough for at Ilast some of said long fibres to be capable of protruding from said major surface as a result of said rubbing, whilst remaining e attached to the substrate.

31. A method according to claim 30 wherein the fibrous layer includes 50% by weight of hydrophobic fibres and 50% by weight of hydrophilic fibres eoooo

32. A method according to claim 30 or 31, wherein the jets of liquid apply to the fibrous layer an energy of not more than 0.8 kWh/kg of fibrous layer material.

33. A method according to claim 30 or 31, wherein the jets of liquid apply to the fibrous layer an energy of not more than 0.5 kWh/kg of fibrous layer material.

34. A method according to either claim 32 or 33, wherein the said energy is at least 0.0005 kWh/kg. A method according to any one of claims 30 to 34, wherein the jets of liquid are directed at the fibrous layer while the layer is travelling in a first direction at a speed of at least 25 m/min.

36. A method according to claim 35, wherein the fibrous layer is travelling at a speed of at least 40 m/min.

37. A method according to either claim 35 or 36, wherein the jets of liquid are directed at the fibrous layer at an angle which, as viewed in said first direction and/or as viewed perpendicular to said first direction, departs from the normal to the fibrous layer by a predetermined amount.

38. A method according to claim 37, wherein the predetermined amount is up ii g to 450.

39. A method according to any one of claims 30 to 38, wherein the fibrous layer is positioned on a carrier surface having apertures therein.

40. A method according to claim 39 wherein there are 12 to 30 apertures/cm 2 ooo.

41. A non-woven fibrous substrate for use in a cleaning article, the substrate substantially as hereinbefore described and illustrated with reference to the accompanying drawings.

42. A wetwipe which includes a substrate, the wet wipe and the substrate substantially as hereinbefore described and illustrated with reference to the accompanying drawings.

43. A method of producing a non-woven, fibrous substrate for use in a cleaning article, the method substantially as hereinbefore described and illustrated with reference to the accompanying drawings. DATED this 15th day of January, 2001 THE PROCTER GAMBLE COMPANY WATERMARK PATENT TRADEMARK ATTORNEYS 290 BURWOOD ROAD HAWTHORN VICTORIA 3122 AUSTRALIA LCG/RJS/MEH P 1137AU01.DOC