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AU756931B2 - Assay devices with non-woven sample collection zone - Google Patents
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AU756931B2 - Assay devices with non-woven sample collection zone - Google Patents

Assay devices with non-woven sample collection zone Download PDF

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Publication number
AU756931B2
AU756931B2 AU50147/99A AU5014799A AU756931B2 AU 756931 B2 AU756931 B2 AU 756931B2 AU 50147/99 A AU50147/99 A AU 50147/99A AU 5014799 A AU5014799 A AU 5014799A AU 756931 B2 AU756931 B2 AU 756931B2
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Australia
Prior art keywords
wick
woven fabric
fabric material
fibres
flow
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AU5014799A (en
Inventor
Carole Robinson Cunningham
Stewart John Wilson
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Alere Switzerland GmbH
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Unipath Ltd
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Priority claimed from AU36513/95A external-priority patent/AU3651395A/en
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Assigned to UNIPATH LIMITED reassignment UNIPATH LIMITED Alteration of Name(s) in Register under S187 Assignors: UNIPATH LIMITED
Assigned to INVERNESS MEDICAL SWITZERLAND GMBH reassignment INVERNESS MEDICAL SWITZERLAND GMBH Alteration of Name(s) in Register under S187 Assignors: UNIPATH LIMITED
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Description

WO 96/09546 PCT/EP95/03722 1 ASSAY DEVICES WITH NON-WOVEN SAMPLE COLLECTION ZONE.
FIELD OF THE INVENTION This invention relates to assay devices.
BACKGROUND OF THE INVENTION Many assay devices are designed to be "self-sampling" so that the user merely needs to contact the device with a liquid sample such as a body fluid in order to initiate the assay procedure. In many such devices this is the only action that the user needs to perform before the result of the assay becomes visible or readable. Many of such devices are based on the principle of "immunochromatography" in which the device contains a strip of porous carrier material along which the applied liquid sample can move. While such movement is occurring, one or more reagents within the device are carried into a detection zone on the strip and cause the assay result to revealed. Commonly a labelled material is mobile within the strip when moist and the binding of this labelled material in the detection zone provides the means whereby the assay result becomes readable. Examples of such 25 devices are described in EP 291 194 and EP 383 619.
The "self-sampling" facility can be provided by means of a bibulous sample receiving member or "wick". The material from which the wick is made is chosen such that applied liquid is absorbed very rapidly into the wick. The wick then acts as a reservoir of sample liquid which feeds progressively into the porous strip to drive the immunochromatographic process. The mobile labelled reagent may be incorporated in the strip itself or elsewhere within the device, upstream from the detection zone. In EP 291 194 it is suggested that the labelled reagent can be incorporated in the wick. Ideal labelled reagents useful WO 96/09546 PCTrEP95/03722 2 in these assay devices are reagents (generally specific binding reagents) labelled directly or indirectly with solid water-insoluble particulate direct labels such as dye sols, metallic (eg. gold) sols, non-metallic elemental particles such as selenium and carbon, and other minute coloured particles such as coloured latex (polystyrene) particles, all known per se for this purpose.
SUMMARY OF THE INVENTION The present invention provides an improved assay device in which the wick comprises non-woven fabric.
Preferred non-woven material is made by the process known 15 as hydroentanglement. Ideally no chemical treatment or chemical curing is used during the manufacturing process.
Such materials are already known per se and are widely used to make cleaning cloths and wipes.
For the purposes of the invention the non-woven wick material is preferably hydrophilic. If the overall character of the fabric is hydrophobic, it can be treated for example with surface active agent to render it hydrophilic in use. It will usually be made from a blend of fibres. This blend can be a mixture of hydrophobic fibres and hydrophilic fibres, but the overall character of the material preferably hydrophilic. An ideal blend comprises a mixture of viscose and polyester. Preferably, the blend is about 30% viscose and about 70% polyester.
An important preferred aspect of the invention is that the wick should comprise only a single sheet or layer of the non-woven fabric. This considerably facilitates manufacture and quality control of an assay device when the wick is used to contain one or more reagents important to the assay chemistry, such as a mobile labelled reagent. If the wick is constructed of multiple layers of bibulous material, it WO 96/09546 PCT1EP95/03722 3 is difficult to ensure that the reagent(s) are deposited consistently in the wick during manufacture, and flow of sample liquid through the multi-layer structure may be uneven, and lead to inefficient or variable uptake of the reagent(s) In order to constitute an effective wick when used in an immunochromatographic assay device, the wick should have sufficient absorptive capacity. The wick liquid capacity should exceed the capacity of the strip (together with any sink at the'distal end of the strip, if provided). The "weight" of the non-woven material is important. The weight of the material is preferably at least about 50 g/m 2 and more preferably at least about 70 g/m 2 Generally it is 15 not necessary for the weight to exceed about 120 g/m 2 eeo* Preferably, the non-woven fabric layer is bonded to a supporting layer of non-water-absorbent material, such as plastics sheet. Polyester sheet is ideal. Bonding can readily be achieved using a variety of adhesives, known per se in the lamination art, the adhesion step being induced by pressure, heat or the use of two-component adhesives.
It is self-evident that the quantity and nature of the adhesive should not significantly impair the absorbency and S. 25 flow properties of the non-woven fabric when bonded to the support. Neither should the adhesive contain any reagents, such as unreacted excess monomers, in amounts that could interfere with the efficiency of the specific binding or other reactions that must occur within the assay device during use.
Although the fabric materials used in this invention are conventionally described as being "non-woven", this does not necessarily mean that the fibres that make up such fabric are arranged in a totally random manner. It is generally found, as a result of the process by which the fabric is made, that a distinct proportion of the fibres lie predominately in one direction and that the remainder lie predominately in a direction at right angles to the first direction. In constructing a device in accordance with the invention, the non-woven fabric is preferably selected and. arranged such that the majority of the fibres lie parallel to the direction in which liquid should flow along the wick into the device. Preferably, the numerical ratio of flow-parallel fibres to flow-orthogonal fibres should be about 2:1 or greater, provided that there are sufficient flow-orthogonal fibres present to maintain the mechanical integrity of the non-woven material for manufacturing purposes.
If desired, the wick can incorporate components that assist 15 the performance of the assay, such as buffering agents and surfactants.
Use of a wick made from non-woven fabric material of the preferred weight as described above, leads to much improved 20 wicking properties and to very efficient release of any S[ dried labelled reagent which may be incorporated in the wick.
As now claimed, according to one aspect, the present invention provides an immunochromatographic assay device having a self-sampling facility, i.e. a wick, comprising a hydrophilic non-woven fabric material, the wick liquid capacity exceeds the liquid capacity of the strip together 30 with any sink at the distal end of the strip, if provided, wherein said non-woven fabric material comprises fibres the majority of which lie parallel to the flow direction being that in which applied liquid sample must flow along said wick into said assay device, the wick incorporates a dried labelled reagent which becomes mobile under the influence of sample liquid applied to said wick, wherein :3 4a said labelled regent incorporates a particulate direct label and the non-woven fabric material has a weight of at least 50 g/m 2 As now claimed, according to another aspect, the present invention provides an assay device having a sample receiving member ("wick") comprising a single layer or sheet of non-woven fabric material bonded to a supporting layer on non-water-absorbant material, and said non-woven 10 fabric being a blend of viscose and polyester and said non-woven fabric having a weight of at least 50 g/m 2 said wick incorporating a dried labelled reagent which becomes mobile under the influence of sample liquid applied to said wick.
BRIEF DESCRIPTION OF THE DRAWINGS The accompanying drawings illustrate, by way of example only, an assay device constructed according to the invention: Figure 1 shows a general view of the device exterior.
Figure 2 shows an "exploded" view of the device of Figure 1.
Figure 3 shows a longitudinal cross-sectional elevation of the device of Figure i.
WO 96/09546 PCT/EP95/03722 Figure 4 shows the detailed construction of a wick in accordance with the invention.
DETAILED DISCLOSURE OF THE INVENTION Referring to Figure i, the device comprises a substantially rectangular elongate casing 100 formed from upper and lower halves 101 and 102. Typically, the two halves of the casing will be moulded from plastics material or similar water-impervious material. The upper surface 103 of the casing (as seen in Figure 1) incorporates an aperture or window 104 through which the interior of the casing can be viewed. Projecting from the left hand end 105 of the casing is a wick 106. The wick comprises an upper layer 107 of non-woven fabric -material, bonded to a supporting layer 108 of plastics material such as polyester sheet.
Referring to Figure 2 which shows an exploded view of the device, the contents of the casing comprise an assay strip 200, a sink 201 and the non-exposed portion 202 of wick 106.
o* The assay strip 200 comprises a narrow rectangular strip 203 of porous material, such as nitrocellulose sheet, S: 25 bonded to a supporting strip 204 of identical rectangular dimensions. Supporting strip 204 can be of plastics material or similar moisture-impervious material which will not affect the flow of moisture along the strip in use.
The supporting strip can be transparent or translucent, so that the assay strip can be viewed through it. The assay strip can be placed against the interior of the casing adjacent aperture 104, the moisture-impervious supporting strip being used to inhibit ingress of moisture via the aperture.
The assay strip includes one or more detection zones within which the assay result is revealed by the formation or WO 96/09546 PCT/EP95/03722 6 accumulation of a detectable reagent such as a coloured label which reveals the zone as a line, spot or other symbol. If desired, the assay strip can also include a control zone (generally downstream from the detection zone) to indicate to the user that the test has been performed correctly. These zones are not shown in the drawings, but will be in the region of the strip generally indicated by the letter A in Figure 2, and therefore visible from the exterior of the casing through aperture 104. The assay strip and supporting strip are pierced by a locating hole 205.
Sink 201 can comprise any moisture-absorbent material having sponge-like properties to take up excess fluid that has progressed along the. assay strip.
Wick 106 extends for a considerable distance inside the casing, and includes a region 206 towards its right hand end in which a labelled mobile component has been pre-dosed and awaits the presence of sample liquid in the wick which will render the labelled reagent mobile and transfer it o a elsewhere within the device. The wick is also pierced by a locating hole 207.
S: 25 Lower half 102 of casing 100 acts as a tray to accomodate the various internal components. The lower half of the casing is provided with two pins or pegs 208 and 209 which extend upwards from the floor 210 of the casing. During manufacture, wick 106 is placed in the lower casing and located in a predetermined place by pin 208 passing through hole 207. The sink 201 is placed at the opposite end of the casing. The assay strip is placed over these components and located in a predetermined place by allowing pin 209 to pass through hole 205.
Referring to Figure 3, which shows a cross-section of the WO 96/09546 PCT/EP95/03722 7 fully assembled device, iz can be seen that the assay strip 203 overlaps the right hand end 300 of the wick 107 so that liquid can flow along the length of the wick and then into the left hand end 301 of the assay strip. The right hand end 302 of the assays strip overlaps the sink 201.
Therefore there is a continuous liquid flow-path from the exposed left hand portion 303 of the wick through to the sink. The upper and lower halves of the casing provide a tight seal against the wick so that moisture cannot enter the device other than by flowing through the wick material itself.
It will be appreciated that the device as illustrated in these drawings and as just described, can be modified very considerably without departing from the scope of the invention. The proportions and overall shape of the casing and other components can be altered and is largely a matter of asthetics. More than one aperture or window can be provided. The sink is an optional feature and can be 20 discarded if the downstream portion of the assay strip has sufficient liquid capacity. It will also be appreciated that the manner in which the components within the casing are held in place is not critical to the invention, and the arrangement as shown in the drawings is provided purely by way of example.
The general construction of a wick in accordance with the invention is illustrated, by way of example, in Figure 4 of the accompanying drawings. This figure shows a layer 400 of non-woven fabric material bonded to a supporting layer 401 of plastics sheet. The non-woven fabric has a fibrous structure 402. The wick is of rectangL ar form and the majority of the fibres makingup the non-woven material lie substantially parallel to the long axis of the wick.
Adjacent one end of the wick is a broad line 403 of deposited labelled reagent (represented by dots although WO 96/09546 PCT/EP95/03722 8 the individual labelled components will not be seperately visible to the human eye). The line runs across the width of the wick. The cut edge 404 of the wick reveals that the labelled component is substantially on the surface of the wick. Deposition of the labelled reagent in. this manner can readily be achieved, for example, by glazing the strip material prior to application of the labelled reagent.
EXAMPLE
The following Example demonstrates the improved properties of a wick made in accordance with the invention.
An assay device as generally described above with reference 15 to the accompanying drawings is constructed as follows: .0* The device is intended to detect the presence of luteinizing hormone (LH) in urine for the purposes of an ovulation detection test. The wick is made from a S 20 commercially available non-woven fabric material consisting of a blend of viscose/polyester (30:70) having a weight of The fabric is selected such that its fibrous structure is distinctly directional, with more than two thirds of the fibres running substantially parallel to one dimension. The non-woven material is infused with an aqueous. Tris buffer containing by weight about 0.01% Tween detergent. After drying, the non-woven material is laminated onto a polyester backing sheet of thickness about 175 Am, using a heat-sensitive adhesive. A reagent comprising anti-LH monoclonal antibodies adsorbed onto latex (polystyrene) spheres of diameter about 0.3 Am is deposited as a broad line on the non-woven material using an airbrush, as generally described in EP 291194.
Subsequent mobility (under the influence of urine) of the deposited labelled reagent is enhanced by pre-treatment of the non-woven material with sucrose or other sugar to form WO 96/09546 PCT/EP95103722 9 a glaze in the region to which the latex-labelled reagent is to be applied. Alternatively, the sucrose or other sugar can be included in the deposition buffer with the labelled reagent. This is also described in greater detail in EP 291194. The line of deposited labelled reagent is orthogonal to the direction in which the fibres in the nonwoven material predominantly lie.
After reagent deposition, the laminated wick is cut mechanically into strips 6 mm wide and of length about mm. The long axis of the cut strip is parallel to the direction in which the majority of fibres run. The line of deposited labelled material therefore runs across the strip, and the strip is cut such that the line of deposited ooooo S 15 labelled material is adjacent one end of the strip.
Polyester-backed nitrocellulose sheet of pore size approximately 8A is converted into immunochromatographic test strips, as generally described in EP 291194, by the deposition of a line of anti-LH monoclonal antibody by a microsyringe and subsequent blocking of the nitrocellulose using polyvinyl alcohol. The treated nitrocellulose sheet is cut into test strips of width 6 mm and length about mm.
The test strip and the wick are assembled within a two-part polystyrene casing in the manner described above with reference to the drawings. The casing also contains a sink comprising a pad of conventional filter paper. The test line which runs across the test strip is situated beneath the aperture in the casing.
If desired, the test strip can also incorporate a control zone (for example downstream from the detection zone) which may comprise, for example, a deposited line of anti-species antibody (such as an anti-mouse monoclonal antibody if the labelled reagent comprises a murine monoclonal) Contact of. the exposed portion of the wick with a urine sample (eg. a urine stream) causes immediate saturation of the non-woven material. The labelled reagent (protected within the casing from being washed out of the wick by contact with the external sample) is released into suspension by the absorbed urine, and the urine migrates by capillary action from the wick along the length of the nitrocellulose strip and into the sink. The labelled reagent is carried with the migrating urine. If the urine contains LH, a sandwich reaction occurs and the labelled reagent can become bound in the detection zone to reveal the presence of LH.
oooo In a device constructed as just described, it is found that release of the deposited labelled reagent is rapid and effective and the sensitivity and reliability of the assay result is enhanced.
oo Throughout this specification and the claims which follow, Sunless the context requires otherwise, the word "comprise", or variations such as "comprises" or "comprising", will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.
The reference to any prior art in this specification is not, and should not be taken as, an acknowledgment or any form of suggestion that the prior art forms part of the common general knowledge in Australia.

Claims (13)

1. An immunochromatographic assay device having a self-sampling facility, i.e. a wick. comprising a hydrophilic non-woven fabric material, the wick liquid capacity exceeds the liquid capacity of the strip together with any sink at the distal end of the strip, if provided, wherein said non-woven fabric material comprises fibres the majority of which lie parallel to the flow direction being that in which applied liquid sample must flow along said wick 15 into said assay device, the wick incorporates a dried labelled reagent which becomes mobile under the influence of sample liquid applied to said wick, wherein said labelled *reagent incorporates a particulate direct label and the non-woven fabric material has a weight of at least 50 g/m 2 0* 20
2. A device according to claim 1, in which said wick comprising a single layer or sheet
3. A device according to claim 1, in which said non-woven fabric material is a blend of viscose and polyester.
4. A device according to claim 3, in which said non-woven fabric material comprises viscose and 70% polyester.
A device according to claim 1, in which said non-woven fabric material has a weight of at least 70 g/m 2
6. A device according to claim 1, wherein said non-woven fabric material is bonded to a supporting layer of non-water-absorbent material. 12
7. A device according to claim 6, wherein said supporting layer is polyester sheet.
8. A device according to claim 1, wherein said non-woven fabric material comprises fibres, and the numerical ratio of flow-parallel fibres to flow-orthogonal fibres is 2:1 or greater, the flow direction being that in which applied liquid sample must flow along said wick into said assay device.
9. A device according to claim 1, wherein said label is coloured latex.
10. An assay device having a sample receiving member ("wick") comprising a single layer or sheet of non-woven fabric material bonded to a supporting layer on non-water- absorbant material, and said non-woven fabric being a blend of viscose and polyester and said non-woven fabric having a weight of at least 50 g/m 2 said wick incorporating a dried :labelled reagent which becomes mobile under the influence of sample liquid applied to said wick.
11. A device according to claim 10 wherein said non-woven fabric material comprises fibres and the numerical ratio of flow-parallel fibres to flow-orthogonal fibres is 2:1 or greater, the flow direction being that in which applied liquid sample must flow along said 20 wick into said assay device.
12. A device according to claim 11, wherein said labelled reagent is labelled with a particulate direct label.
13. An immunochromatographic assay device as herein described with reference to the example. DATED THIS 11th day of November, 2002. UNIPATH LIMITED By Its Patent Attorneys x4, DAVIES COLLISON CAVE
AU50147/99A 1994-09-23 1999-09-24 Assay devices with non-woven sample collection zone Expired AU756931B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9419267 1994-09-23
AU36513/95A AU3651395A (en) 1994-09-23 1995-09-21 Assay devices with non-woven sample collection zone

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AU756931B2 true AU756931B2 (en) 2003-01-30

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0560411A2 (en) * 1987-04-27 1993-09-15 Unilever N.V. A test device for performing specific binding assays

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0560411A2 (en) * 1987-04-27 1993-09-15 Unilever N.V. A test device for performing specific binding assays

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