CN103666259A - Flame-retarding asphalt base mixing macromolecule waterproof paint and preparation method thereof - Google Patents
Flame-retarding asphalt base mixing macromolecule waterproof paint and preparation method thereof Download PDFInfo
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- CN103666259A CN103666259A CN201310414075.XA CN201310414075A CN103666259A CN 103666259 A CN103666259 A CN 103666259A CN 201310414075 A CN201310414075 A CN 201310414075A CN 103666259 A CN103666259 A CN 103666259A
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- 238000002156 mixing Methods 0.000 title claims abstract description 29
- 239000003973 paint Substances 0.000 title claims abstract description 29
- 239000010426 asphalt Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 229920002521 macromolecule Polymers 0.000 title abstract 2
- 239000003063 flame retardant Substances 0.000 claims abstract description 39
- 239000000463 material Substances 0.000 claims abstract description 19
- 239000000839 emulsion Substances 0.000 claims abstract description 17
- 239000003822 epoxy resin Substances 0.000 claims abstract description 12
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 12
- 230000002195 synergetic effect Effects 0.000 claims abstract description 8
- 229920001971 elastomer Polymers 0.000 claims abstract description 7
- 239000005060 rubber Substances 0.000 claims abstract description 7
- 238000005507 spraying Methods 0.000 claims abstract description 7
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 31
- 239000011295 pitch Substances 0.000 claims description 31
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 18
- 239000000344 soap Substances 0.000 claims description 15
- 229920000126 latex Polymers 0.000 claims description 13
- 239000004816 latex Substances 0.000 claims description 8
- 239000012874 anionic emulsifier Substances 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- 238000010276 construction Methods 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000010008 shearing Methods 0.000 claims description 6
- 239000013530 defoamer Substances 0.000 claims description 5
- 230000001804 emulsifying effect Effects 0.000 claims description 5
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 5
- 238000006277 sulfonation reaction Methods 0.000 claims description 5
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical group CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 4
- 238000004132 cross linking Methods 0.000 claims description 4
- 150000004985 diamines Chemical class 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000011301 petroleum pitch Substances 0.000 claims description 4
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical group CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims description 4
- 230000003068 static effect Effects 0.000 claims description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 4
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 3
- 239000002174 Styrene-butadiene Substances 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 3
- ITCAUAYQCALGGV-XTICBAGASA-M sodium;(1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound [Na+].C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O ITCAUAYQCALGGV-XTICBAGASA-M 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 239000011115 styrene butadiene Substances 0.000 claims description 3
- 239000003784 tall oil Substances 0.000 claims description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 2
- 239000003002 pH adjusting agent Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 210000000582 semen Anatomy 0.000 claims description 2
- 239000004711 α-olefin Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 3
- 239000000725 suspension Substances 0.000 abstract description 2
- 239000004530 micro-emulsion Substances 0.000 abstract 2
- 150000001450 anions Chemical class 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 239000013538 functional additive Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a flame-retarding asphalt base mixing macromolecule waterproof paint and preparation method thereof. The paint is prepared by using a plurality of functional additives of a synergistic flame-retarding system formed by compounding a plurality of synthesized microemulsion polymers such as high-concentration superfine suspension microemulsion type anion modified emulsified asphalt, rubber emulsion and epoxy resin, and a plurality of fire retardants as materials, and mixing by using a special production process. When a dope is applied, double-compound mechanical spraying is used, so that demulsification and condensation are quick; the low-temperature work temperature after forming film can reach -20 DEG C, the high temperature reaches 110 DEG C, the elastic recovery rate is greater than 90 percent, and flame-retarding grade reaches B grade.
Description
Technical field
The invention belongs to architectural waterproof material technical field, specifically, the double component high polymer modification water-latex type asphaltic base waterproof paint that belongs to a kind of flame retardant properties excellence is flame-retardant pitch base mixing high molecular water-proof paint and preparation method thereof.
Background technology
On market, there is in recent years a kind of spraying rapid-hardening rubber asphalt waterproof coating, because of the conveniency of its construction, excellent rebound resilience and high temperature performance and enjoy favor, but in fire prevention, have inborn deficiency as the material of asphaltic base.And common asphalt flame-retardant agent or do not reach desirable flame retardant effect on market, or have a strong impact on low-temperature performance, or cannot stably be present in emulsification system.
Summary of the invention
The present invention is directed to the above-mentioned deficiency of prior art, provide a kind of flame retardant properties good, in emulsification system, can evenly store and can take into account the flame-retardant pitch base mixing high molecular water-proof paint of low-temperature performance.
In order to solve the problems of the technologies described above, the technical solution used in the present invention is: a kind of flame-retardant pitch base mixing high molecular water-proof paint, and this coating is mainly prepared by each component of following weight percent:
As further preferred, the flame-retardant pitch base mixing high molecular water-proof paint that the present invention is above-mentioned, this coating is prepared by each component of following weight percent:
The above-mentioned petroleum pitch of the present invention as pitch 60 be that 60# pitch or pitch 70 are 70# pitch.
The above-mentioned rubber latex of the present invention is as polychloroprene latex (solid content 60%) or styrene-butadiene latex or SBS rubber, or in above-mentioned two kinds is any than mixing.
The above-mentioned epoxy resin of the present invention is epoxy resin E-44 or epoxy resin E-51.
The above-mentioned diamine crosslinking and curing agent of the present invention is quadrol, 1,3-propylene diamine or 1,6-hexanediamine.
The above-mentioned anionic emulsifier of the present invention is a kind of in Yatall MA, sulfonation tall oil soap, sodium abietate, OA salt, sulfosuccinate, sulfonated α-olefin, sulfate rosin, sulfonation Oleum Gossypii semen.
The above-mentioned stablizer of the present invention is AEO-9 (fatty alcohol-polyoxyethylene ether).
The above-mentioned synergistic fire retardant ZR-01 of the present invention is TDE (DBPE): antimonous oxide: zinc borate: the compound that aluminium hydroxide mass ratio is 3:1:1:5.
The above-mentioned pH adjusting agent of the present invention is sodium hydroxide or potassium hydroxide etc.
The present invention also discloses a kind of preparation method of above-mentioned flame-retardant pitch base mixing high molecular water-proof paint, and preparation process comprises:
(1) according to formula rate, petroleum pitch is pumped into asphalt tank and be heated to 160 ℃～180 ℃, drop into synergistic fire retardant ZR-01,80-120 rev/min is stirred 1.5-2.5 hour, then add epoxy resin, stir and by colloidal mill, grind for 20-40 minute, the polymer-modified asphalt material preparing stirs 1-3 hour de-soak, stand-by;
(2) in Soap liquid pot, pump into the hot water of 50-70 ℃ of formula rate, drop into anionic emulsifier, stablizer and diamine crosslinking and curing agent, with pH, reconcile pH value to 10-11 simultaneously, make soap lye;
(3) soap lye that polymer-modified asphalt step (1) being prepared and step (2) prepare makes through high-speed shearing machine the modified emulsifying asphalt emulsion that mass concentration is 55-65% simultaneously, and the rotating speed of high-speed shearing machine is 100～10000r/min; Then in this emulsion, add rubber latex, keep stirring 8-12 minute, then stop stirring, add a small amount of defoamer and within static 3-6 minute, carry out obtaining flame-retardant pitch base mixing high molecular water-proof paint after defoaming treatment.
The preparation method of the above-mentioned flame-retardant pitch base of the present invention mixing high molecular water-proof paint, while also comprising construction, by CaCl
2be dissolved into mass concentration and be 10% the aqueous solution, then by flame-retardant pitch base mixing high molecular water-proof paint and CaCl
2the aqueous solution adopts two component spray gun mechanically sprayings constructions to make above-mentioned two kinds of material fast emulsion breakings film forming step of condensing.
Above-mentioned flame-retardant pitch base mixing high molecular water-proof paint and CaCl
2the volume ratio of the aqueous solution is 1-2:1.
Advantage of the present invention and beneficial effect:
1. the present invention has allocated the synergistic fire retardant ZR-01 that a kind of pitch is used specially, TDE in its compounded formula (DBPE): antimonous oxide: zinc borate: aluminium hydroxide mass ratio is 3:1:1:5; It has good flame retardant effect.
2. product emulsifying system of the present invention adopts anionic emulsifier, and finished product emulsified bitumen is stable emulsion state under alkaline condition, runs into acid emulsion splitter (as CaCl
2) moment breakdown of emulsion, the two components of employing (A material is flame-retardant pitch base mixing high molecular water-proof paint, and B material is certain density acid emulsion splitter) mechanically spraying so just guaranteed when construction as long as just can rapid coagulation become complete rubber asphalt film, construct convenient, time saving and energy saving; Meanwhile, we have added epoxy resin and corresponding solidifying agent in formula, and this has improved the adhesive power of material and base material widely, and high-temperature behavior and non-corrosibility also increase simultaneously; We improve the indexs such as low temperature flexibility, tensile strength, elongation at break and elastic recovery rate as chloroprene rubber, styrene-butadiene rubber(SBR) or SBS rubber at the composite rubber latex of having added in formula.
3. the present invention adopts the anion-modified emulsified bitumen of ultra-fine microactuator suspension emulsion-type and multiple rubber high molecular polymer and functional agent as raw material, use special producing technique to be mixed with this material of making, adopt two component mechanically spraying constructions, fast emulsion breaking condenses, and after film forming, low-temperature working temperature can reach-20 ℃, high temperature reaches 110 ℃, and elastic recovery rate surpasses 90%, and flame retardant rating reaches B level.
Embodiment
The cited embodiment of the present invention further illustrates of the present invention, but embodiment is not all limitation of the present invention.
Embodiment 1
A component: 60# water-proof material special asphalt is pumped into asphalt tank and be heated to 160 ℃～180 ℃, drop into 5% synergistic fire retardant ZR-01,100r/min stirs 2 hours, then add 2% epoxy resin E-51, stir and by colloidal mill, grind for 30 minutes, the polymer-modified asphalt material preparing stirs 2 hours de-soaks, stand-by.In Soap liquid pot, pump into the hot water of 60 ℃, the amount that drops into Yatall MA anionic emulsifier (Yatall MA or sulfonation tall oil soap or sulfosuccinate) 1%, AEO-9 is 0.02% and quadrol 0.6%, reconciles pH value to 11 with NaOH simultaneously, makes soap lye.The polymer-modified asphalt preparing and soap lye are made to the modified emulsifying asphalt emulsion that concentration is 60% left and right through high-speed shearing machine simultaneously, in this emulsion, add 25% polychloroprene latex, keep stirring 10 minutes, then stop stirring, add a small amount of defoamer (commercially available prod, as paint antifoaming agent defoamer FBX-02, according to how many additions of foam, be generally 5/10000ths to 5/1000ths, addition is little, in coating raw materials, can ignore) and within static 5 minutes, carry out finished product barrelling after defoaming treatment.
B component: by technical grade CaCl
2be dissolved into concentration and be 10% the aqueous solution and make B material.
Embodiment 2
A component: 70# road heavy traffic paving asphalt is pumped into asphalt tank and be heated to 160 ℃～180 ℃, drop into 5% synergistic fire retardant ZR-01,90r/min stirs 2 hours, then add 2% epoxy resin E-44, stir and by colloidal mill, grind for 30 minutes, the polymer-modified asphalt material preparing stirs 2 hours de-soaks, stand-by.In Soap liquid pot, pump into the hot water of 60 ℃, the amount that drops into Yatall MA anionic emulsifier (sodium abietate or sulfate rosin) 1%, AEO-9 is 0.02% and quadrol 0.6%, reconciles pH value to 11 with NaOH simultaneously, makes soap lye.The polymer-modified asphalt preparing and soap lye are made to the modified emulsifying asphalt emulsion that concentration is 60% left and right through high-speed shearing machine simultaneously, in this emulsion, add 15% polychloroprene latex and 10% styrene-butadiene latex, keep stirring 10 minutes, then stop stirring finished product barrelling after adding a small amount of defoamer and carrying out defoaming treatment for static 5 minutes.
B component: by technical grade CaCl
2be dissolved into concentration and be 10% the aqueous solution and make B material.
During construction, adopt two component spray gun mechanically sprayings to construct in A material and B material, the fast emulsion breaking film forming of condensing.
Table 1 embodiment properties of sample index
As can be known from the above table, coating of the present invention has good flame retardant effect, and flame retardant rating can reach B level.
Claims (10)
1. a flame-retardant pitch base mixing high molecular water-proof paint, is characterized in that: this coating is mainly prepared by each component of following weight percent:
2. flame-retardant pitch base mixing high molecular water-proof paint according to claim 1, is characterized in that: this coating is prepared by each component of following weight percent:
3. flame-retardant pitch base mixing high molecular water-proof paint according to claim 1 and 2, is characterized in that: described petroleum pitch is pitch 60 or pitch 70.
4. flame-retardant pitch base mixing high molecular water-proof paint according to claim 1 and 2, is characterized in that: described rubber latex is polychloroprene latex or styrene-butadiene latex or SBS rubber, or any two kinds any than mixing in above-mentioned.
5. flame-retardant pitch base mixing high molecular water-proof paint according to claim 1 and 2, is characterized in that: described epoxy resin is epoxy resin E-44 or epoxy resin E-51.
6. flame-retardant pitch base mixing high molecular water-proof paint according to claim 1 and 2, is characterized in that: described diamine crosslinking and curing agent is quadrol 1,3-propylene diamine or 1,6-hexanediamine.
7. flame-retardant pitch base mixing high molecular water-proof paint according to claim 1 and 2, is characterized in that: described anionic emulsifier is a kind of in Yatall MA, sulfonation tall oil soap, sodium abietate, OA salt, sulfosuccinate, sulfonated α-olefin, sulfate rosin, sulfonation Oleum Gossypii semen; Described stablizer is AEO-9; Described pH adjusting agent is sodium hydroxide or potassium hydroxide.
8. flame-retardant pitch base mixing high molecular water-proof paint according to claim 1 and 2, is characterized in that: described synergistic fire retardant ZR-01 is TDE: antimonous oxide: zinc borate: the compound that aluminium hydroxide mass ratio is 3:1:1:5.
9. a preparation method for flame-retardant pitch base mixing high molecular water-proof paint, is characterized in that: preparation process comprises:
(1) according to formula rate, petroleum pitch is pumped into asphalt tank and be heated to 160 ℃～180 ℃, drop into synergistic fire retardant ZR-01,80-120 rev/min is stirred 1.5-2.5 hour, then add epoxy resin, stir and by colloidal mill, grind for 20-40 minute, the polymer-modified asphalt material preparing stirs 1-3 hour de-soak, stand-by;
(2) in Soap liquid pot, pump into the hot water of 50-70 ℃ of formula rate, drop into anionic emulsifier, stablizer and diamine crosslinking and curing agent, with pH, reconcile pH value to 10-11 simultaneously, make soap lye;
(3) soap lye that polymer-modified asphalt step (1) being prepared and step (2) prepare makes through high-speed shearing machine the modified emulsifying asphalt emulsion that mass concentration is 55-65% simultaneously, and the rotating speed of high-speed shearing machine is 100～10000r/min; Then in this emulsion, add rubber latex, keep stirring 8-12 minute, then stop stirring, add a small amount of defoamer and within static 3-6 minute, carry out obtaining flame-retardant pitch base mixing high molecular water-proof paint after defoaming treatment.
10. the preparation method of flame-retardant pitch base mixing high molecular water-proof paint according to claim 1, is characterized in that: the preparation method of described flame-retardant pitch base mixing high molecular water-proof paint, also comprises while constructing, by CaCl
2be dissolved into mass concentration and be 10% the aqueous solution, then by flame-retardant pitch base mixing high molecular water-proof paint and CaCl
2the aqueous solution adopts two component spray gun mechanically sprayings constructions to make the condense step of film forming of above-mentioned two kinds of material fast emulsion breakings.
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| CN201310414075.XA CN103666259B (en) | 2013-09-12 | 2013-09-12 | Flame-retardant pitch base mixing high molecular water-proof paint and preparation method thereof |
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| CN201310414075.XA CN103666259B (en) | 2013-09-12 | 2013-09-12 | Flame-retardant pitch base mixing high molecular water-proof paint and preparation method thereof |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104058625A (en) * | 2014-06-17 | 2014-09-24 | 长沙理工大学 | Flame retardant for bituminous mixture based on decabromodiphenylethane |
| CN105462273A (en) * | 2015-12-27 | 2016-04-06 | 安徽路达泰克沥青新材料有限公司 | Epoxy modified emulsified asphalt material and preparation method thereof |
| WO2016078156A1 (en) * | 2014-11-19 | 2016-05-26 | 袁隆洲 | Epoxy rubber asphalt-modified coating and preparation method |
| CN105733282A (en) * | 2016-03-29 | 2016-07-06 | 苏州蔻美新材料有限公司 | Smoke-inhibition modified epoxy resin asphalt and preparation method thereof |
| CN105968729A (en) * | 2016-07-18 | 2016-09-28 | 四川蜀羊防水材料有限公司 | Flame-retardant asphalt material |
| CN107099181A (en) * | 2017-04-17 | 2017-08-29 | 上海禹术防水工程技术有限公司 | One kind spraying rapid hardening rubber asphalt waterproof coating fire retardant and preparation method thereof |
| CN107129759A (en) * | 2017-04-17 | 2017-09-05 | 上海禹术防水工程技术有限公司 | A kind of flame retardant type spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof |
| CN108047951A (en) * | 2017-11-21 | 2018-05-18 | 广西武宣金牌防水材料科技有限公司 | Flame-retardant modified asphalt waterproofing paint and its production method |
| CN108587463A (en) * | 2018-05-17 | 2018-09-28 | 安徽朗凯奇防水科技股份有限公司 | A kind of flame retardant type Emulsificated asphalt water-proof painting material and preparation method thereof |
| CN109161341A (en) * | 2018-09-10 | 2019-01-08 | 雨中情防水技术集团有限责任公司 | A kind of anti-viscous type spraying rubber asphalt waterproof coating of fire-retardant, the pre- spray of not chloride ion-containing |
| CN110408320A (en) * | 2018-04-26 | 2019-11-05 | 北京百耐尔防水工程有限公司 | Spray rapid hardening rubber asphalt root-resistant type water-repellent paint and preparation method thereof |
| CN111592826A (en) * | 2020-05-19 | 2020-08-28 | 厦门稀土材料研究所 | Reactive self-adhesive flame-retardant waterproof asphalt coating |
| CN111607261A (en) * | 2020-07-04 | 2020-09-01 | 富华防水科技股份有限公司 | Efficient and rapid leaking stoppage waterproof coating and preparation method thereof |
| CN111690342A (en) * | 2020-07-01 | 2020-09-22 | 连云港宏坤建材有限公司 | Preparation method of high-performance SBS (styrene butadiene styrene) modified asphalt waterproof coiled material |
| CN113088115A (en) * | 2021-04-12 | 2021-07-09 | 上海应用技术大学 | Modified asphalt for fire prevention of sleeper and preparation method thereof |
| CN114000595A (en) * | 2021-12-09 | 2022-02-01 | 中铁建设集团有限公司 | Construction process for spraying quick-setting rubber asphalt waterproof paint |
| CN117777860A (en) * | 2023-12-22 | 2024-03-29 | 波力尔（北京）科技发展有限公司 | An anionic quick-setting SBS modified emulsified asphalt coating with flame retardant and antistatic functions and its preparation method |
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