CN106009584A - PC (polycarbonate) composite material - Google Patents
PC (polycarbonate) composite material Download PDFInfo
- Publication number
- CN106009584A CN106009584A CN201610353892.2A CN201610353892A CN106009584A CN 106009584 A CN106009584 A CN 106009584A CN 201610353892 A CN201610353892 A CN 201610353892A CN 106009584 A CN106009584 A CN 106009584A
- Authority
- CN
- China
- Prior art keywords
- composite
- agent
- lubricant
- toughener
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 22
- 239000004417 polycarbonate Substances 0.000 title claims abstract description 21
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 7
- 239000000314 lubricant Substances 0.000 claims abstract description 14
- 239000003063 flame retardant Substances 0.000 claims abstract description 12
- 239000003822 epoxy resin Substances 0.000 claims abstract description 11
- 239000003365 glass fiber Substances 0.000 claims abstract description 11
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 11
- 239000012745 toughening agent Substances 0.000 claims abstract description 10
- 229920002545 silicone oil Polymers 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000000049 pigment Substances 0.000 claims description 9
- 239000003963 antioxidant agent Substances 0.000 claims description 8
- 230000003078 antioxidant effect Effects 0.000 claims description 8
- -1 Phenyl phosphate ester Chemical class 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 5
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000003429 antifungal agent Substances 0.000 claims description 2
- 239000004067 bulking agent Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 239000004088 foaming agent Substances 0.000 claims description 2
- 239000012760 heat stabilizer Substances 0.000 claims description 2
- 239000004611 light stabiliser Substances 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 8
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 abstract description 4
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 abstract description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 abstract 2
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- 239000004609 Impact Modifier Substances 0.000 description 2
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 1
- DMYOHQBLOZMDLP-UHFFFAOYSA-N 1-[2-(2-hydroxy-3-piperidin-1-ylpropoxy)phenyl]-3-phenylpropan-1-one Chemical compound C1CCCCN1CC(O)COC1=CC=CC=C1C(=O)CCC1=CC=CC=C1 DMYOHQBLOZMDLP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 241000208340 Araliaceae Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004843 novolac epoxy resin Substances 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a PC (polycarbonate) composite material which comprises 80-130 parts of polycarbonate, 10-20 parts of ABS (acrylonitrile-butadiene-styrene), 10-20 parts of glass fiber, 2-10 parts of flame retardant, 0.5-2 parts of epoxy resin and/or modified epoxy resin, 2-10 parts of toughener, 0.02-0.3 part of silicone oil and 0.1-0.5 part of lubricant. The cantilever beam notch impact strength of the PC composite material is greater than or equal to 10 KJ/m<2>, the melt index (MI) (260 DEG C, 2.16kg) is greater than or equal to 20 g/minute, and the PC composite material has favorable impact resistance and processability. The product can be used for electronic and electric appliance products with higher dimensional precision, such as casing and interior frame materials of laptops.
Description
Technical field
The present invention relates to a kind of polymeric material, particularly relate to a kind of Merlon (PC) composite.
Background technology
Merlon (Polycarbonate, PC) is the high molecular polymer in strand containing carbonate group,
Having good thermostability and mechanical performance, be one of five large-engineering plastics, the three of PC engineering plastics greatly should
It is glazing, auto industry and electronics, electrical equipment industry with field, secondly also has industrial machinery part, light
Office equipment, medical treatment and health care, thin film, leisure and protective equipment, the building materials etc. such as dish, packaging, computer.
Fiber reinforcement is the most conventional plastics Enhancement Method, and CN104497525A discloses a kind of glass fibers
Dimension strengthens PC material, including: Merlon 120-150 part, glass fibre 20-25 part, Nano graphite powder
3-8 part, tributyl citrate 10-16 part, dibutyl ester 5-10 part, epoxy resin 12-16 part, toughener
3-7 part, impact modifier 2-6 part and lubricant 5-9 part, improve the tensile property of polycarbonate plastic
Colleague, synergism makes extend the service life of polycarbonate plastic.CN104497513A discloses separately
A kind of glass fiber reinforcement PC material, including: Merlon is 45-55 part, polybutylene terephthalate
Ester is 12-18, glass fibre is 25-35, acidproof penetrating agent is 1-5 part, heat resisting flexibilizer is 1-4 part,
Antioxidant is 0.15-0.25 part, and acid resistance is substantially improved.
But PC remains desired by this area as one of important engineering material, the raising of its mechanical performance
's.
Summary of the invention
The problem and shortage existed in mechanical properties for current PC material, the invention provides a kind of new
PC composite and combinations thereof thing.
The invention provides a kind of PC composite, according to weight proportion, including:
Merlon 80-130 part, 100-130 part, preferably 105-120 part, preferably 110-115 part；
ABS 10-20 part, preferably 12-17 part, preferably 13-16 part, preferably 14-15 part；
Glass fibre 10-20 part, preferably 12-18 part, preferably 13-17 part, preferably 14-16 part；
Fire retardant 2-10 part, preferably 3-9 part, preferably 4-8 part；It is preferably 5-7 part；
Epoxy resin and/or modified epoxy 0.5-2 part, preferably 0.8-1.7 part, preferably 1-1.5 part is excellent
Elect 1.2-1.3 part as；
Toughener 2-10 part, preferably 3-8 part, preferably 4-7 part, preferably 5-6 part；
Silicone oil 0.02-0.3 part, preferably 0.05-0.25 part, preferably 0.07-0.2 part, preferably 0.09-0.15
Part；
Lubricant 0.1-0.5 part, more preferably 0.15-0.4 part, more preferably 0.2-0.3 part.
In a kind of preferred embodiment of PC composite of the present invention, it is also possible to include auxiliary agent, described in help
Agent at least includes: antioxidant, heat stabilizer, UV light stabilizing agent, filler, pigment, anti-dripping agent, plasticising
Any one or a few in agent, bulking agent, antifungus agent, releasing agent, foaming agent, antistatic additive.
Wherein, according to weight proportion, described auxiliary agent is 0-8 part, more preferably 0.01-6 part, more preferably
0.1-5 part, more preferably 0.5-4 part, more preferably 1-3 part.
Wherein, in a kind of preferred embodiment of PC composite of the present invention, according to weight proportion, bag
Include:
Merlon 80-130 part, 100-130 part, preferably 105-120 part, preferably 110-115 part；
ABS 10-20 part, preferably 12-17 part, preferably 13-16 part, preferably 14-15 part；
Glass fibre 10-20 part, preferably 12-18 part, preferably 13-17 part, preferably 14-16 part；
Fire retardant 2-10 part, preferably 3-9 part, preferably 4-8 part；It is preferably 5-7 part；
Epoxy resin and/or modified epoxy 0.5-2 part, preferably 0.8-1.7 part, preferably 1-1.5 part is excellent
Elect 1.2-1.3 part as；
Toughener 2-10 part, preferably 3-8 part, preferably 4-7 part, preferably 5-6 part；
Silicone oil 0.02-0.3 part, preferably 0.05-0.25 part, preferably 0.07-0.2 part, preferably 0.09-0.15
Part；
Lubricant 0.1-0.5 part, more preferably 0.15-0.4 part, more preferably 0.2-0.3 part；
Antioxidant 0.1-1 part, preferably 0.2-0.8 part, preferably 0.3-0.6 part, preferably 0.4-0.5 part；
Anti-dripping agent 0.05-0.5 part, more preferably 0.1-0.4 part, more preferably 0.2-0.3 part；
Pigment 0.1-5 part, more preferably 0.5-4 part, more preferably 1-3 part, more preferably 1.5-2 part.
In foregoing of the present invention, described Merlon preferably number-average molecular weight is 25000-40000, more
It is preferably 28000-36000, more preferably 29000-34000, more preferably 30000-33000.
In foregoing of the present invention, described Merlon is preferably melt index MI (300 DEG C, 2.16kg)
For 5-15g/10min, more preferably 7-13g/10min, more preferably 8-10g/10min.
In foregoing of the present invention, glass fibre is preferably chopped strand, and length is preferably 2-40mm, more excellent
Elect 3-30mm as, more preferably 4.5-25mm, more preferably 6-20mm, more preferably 8-15mm,
More preferably 10-12mm.
In foregoing of the present invention, glass fibre is preferably a diameter of 5-20 μm, more preferably 8-16 μm,
More preferably 6-15 μm, more preferably 10-13 μm.
In foregoing of the present invention, fire retardant can be in organic fire-retardant and inorganic combustion inhibitor any one or
Several, such as halogenated flame retardant, phosphorus flame retardant, nitrogenated flame retardant, antimony oxide, magnesium hydroxide, hydrogen-oxygen
Changing aluminum, silicon-series five-retardant etc., the present invention is preferably bisphenol-A-bis-(diphenyl phosphoesters).
In foregoing of the present invention, toughener (includes anti-impact modifier), can be rubber, thermoplastic elastic
Any one or a few in body, as thiorubber., liquid propene acid esters rubber, liquid polybutadiene rubber,
Nitrile rubber, EP rubbers, butadiene-styrene rubber, polyurethanes, phenylethylene, TPO, polyesters,
Rule 1,2-polybutadiene and polyamide-based in one or more.As EMA 1330 (Du Pont),(Japan Zhong Yuan) and toughener E518 series, E516 series be (Ningbo energy
Light new material Science and Technology Ltd.).
In foregoing of the present invention, lubricant can be selected from lubricant EBFF, Lubricate EBS, lubricant
Any one or a few in PETS, lubricant L OCIWAX E silicone powder.
In foregoing of the present invention, anti-dripping agent preferably at least includes fluoro-containing macromolecule material, such as polytetrafluoroethyl-ne
Alkene, such as anti-dripping agent TN3500.
In foregoing of the present invention, pigment can be titanium dioxide, iron oxide red, iron oxide yellow, iron oxide black,
Lithopone, white carbon black, cadmium red, cadmium yellow, lead chromate yellow, chrome oxide green, barba hispanica, zinc oxide, zinc yellow, cobalt blue,
And agent structure be the pigment of phthalocyanine, azo pigment, agent structure be any in the pigment of quinacridone
The mixture of one or more.Such as titanium dioxide 902,706 titanium dioxide, charcoal blacks 660R, golden pearly-lustre
Powder pigment 305 etc..
In foregoing of the present invention, described modified epoxy can be that halogenated epoxy resin is (such as brominated oxygen tree
Fat), glycidyl ether type epoxy resin, novolac epoxy resin, glycidyl ester epoxy resin, shrink sweet
Any one in oleyl amine based epoxy resin.
In foregoing of the present invention, described antioxidant can be aromatic amine, Hinered phenols antioxidant, it is also possible to
It is to compound, such as irgasfos 168, antioxidant 1010 with auxiliary antioxidant.
PC composite of the present invention, Izod notched impact strength >=10kJ/m2, melt index MI (260 DEG C,
2.16kg) >=20g/10min, has good shock resistance and processing characteristics, is unlikely to deform, simultaneously anti-flammability
Energy and ageing resistace, can be used for electric, auto industry, motion medical apparatus and instruments and mechanical apparatus field.
Detailed description of the invention
Embodiment 1
PC (number-average molecular weight 29000, MI=10g/10min (2.16kg, 300 DEG C)) 115kg；
Said components is mixed by screw extruder extrusion molding.
Embodiment 2
PC (number-average molecular weight 33000, MI=12g/10min (2.16kg, 300 DEG C)) 120kg；
Said components is mixed by screw extruder extrusion molding.
Embodiment 3
PC (number-average molecular weight 30000, MI=11g/10min (2.16kg, 300 DEG C)) 110kg；
Said components is mixed by screw extruder extrusion molding.
Above-described embodiment 1-3 gained PC composite physical property
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Izod notched impact strength | 15kJ/m2 | 14kJ/m2 | 13kJ/m2 |
| Bending strength | 123.8MPa | 124.5MPa | 124.6MPa |
| Hot strength | 119.2MPa | 121.8MPa | 120.6MPa |
| Elongation at break | 2.4% | 2.2% | 2.5% |
| Fire-retardant rank | V-0 | V-0 | V-0 |
| Heat distortion temperature (1.82MPa) | 166.5℃ | 168.3℃ | 165.7℃ |
| Melt index MI (260 DEG C, 2.16kg) | 22.1g/10min | 24.2g/10min | 22.9g/10min |
Wherein: Izod notched impact strength test is with reference to ASTM D256-2010 standard；Bending strength test ginseng
According to GB/T9431-2000 standard, hot strength test is with reference to GB/T1040-2006 standard, fire-retardant rank
Test is with reference to UL94 standard, and heat distortion temperature test is with reference to ASTM D648-2007 standard, melt index
Test is with reference to ASTM D1238-2004 standard.
Being described in detail the specific embodiment of the present invention above, but it is intended only as example, the present invention is also
It is not restricted to particular embodiments described above.To those skilled in the art, any the present invention is carried out
Equivalent modifications and substitute the most all among scope of the invention.Therefore, without departing from the spirit of the present invention and model
Enclose lower made impartial conversion and amendment, all should contain within the scope of the invention.
Claims (10)
1. a PC composite, it is characterised in that according to weight proportion, including:
Merlon 80-130 part；
ABS 10-20 part；
Glass fibre 10-20 part；
Fire retardant 2-10 part；
Epoxy resin and/or modified epoxy 0.5-2 part；
Toughener 2-10 part；
Silicone oil 0.02-0.3 part；
Lubricant 0.1-0.5 part.
PC composite the most according to claim 1, it is characterised in that auxiliary agent can also be included, described
Auxiliary agent at least includes: antioxidant, heat stabilizer, UV light stabilizing agent, filler, pigment, anti-dripping agent, increasing
Mould in agent, bulking agent, antifungus agent, releasing agent, foaming agent, antistatic additive any one or a few.
PC composite the most according to claim 2, it is characterised in that according to weight proportion, described in help
Agent is 0-8 part.
PC composite the most according to claim 2, it is characterised in that according to weight proportion, including:
Merlon 80-130 part；
ABS 10-20 part；
Glass fibre 10-20 part；
Fire retardant 2-10 part；
Epoxy resin and/or modified epoxy 0.5-2 part；
Toughener 2-10 part；
Silicone oil 0.02-0.3 part；
Lubricant 0.1-0.5 part；
Antioxidant 0.1-1 part；
Anti-dripping agent 0.05-0.5 part；
Pigment 0.1-5 part.
PC composite the most according to claim 1, it is characterised in that the described equal molecule of Merlon number
Amount is 25000-40000.
PC composite the most according to claim 1, it is characterised in that described polycarbonate melt index
MI (300 DEG C, 2.16kg) is 5-15g/10min.
PC composite the most according to claim 1, it is characterised in that glass chopped fiber, long
Degree is preferably 2-40mm, a diameter of 5-20 μm.
PC composite the most according to claim 1, it is characterised in that lubricant selected from lubricant EBFF,
Any one or a few in Lubricate EBS, lubricant PETS, lubricant L OCIWAX E silicone powder.
PC composite the most according to claim 1, it is characterised in that toughener is selected from Du Pont EMA
1330、M-701, toughener E518H.
PC composite the most according to claim 3, it is characterised in that fire retardant is bisphenol-A-bis-(two
Phenyl phosphate ester).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610353892.2A CN106009584A (en) | 2016-05-25 | 2016-05-25 | PC (polycarbonate) composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610353892.2A CN106009584A (en) | 2016-05-25 | 2016-05-25 | PC (polycarbonate) composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106009584A true CN106009584A (en) | 2016-10-12 |
Family
ID=57093644
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610353892.2A Pending CN106009584A (en) | 2016-05-25 | 2016-05-25 | PC (polycarbonate) composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106009584A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106751663A (en) * | 2016-12-13 | 2017-05-31 | 德阳力久云智知识产权运营有限公司 | A kind of flame-retardant modified plastics of high tenacity and preparation method thereof |
| CN106928684A (en) * | 2017-03-31 | 2017-07-07 | 合肥民众亿兴软件开发有限公司 | A kind of plastics for computer fan and preparation method thereof |
| CN107163540A (en) * | 2017-07-11 | 2017-09-15 | 合肥东恒锐电子科技有限公司 | A kind of notebook computer special engineering plastic alloy material |
| CN107189335A (en) * | 2017-07-12 | 2017-09-22 | 合肥思博特软件开发有限公司 | A kind of computer mouse case material and preparation method thereof |
| CN107629431A (en) * | 2017-09-21 | 2018-01-26 | 中广核俊尔新材料有限公司 | Ageing-resistant halogen-free flame-retardant polycarbonate composite material of a kind of oil-resisting and heat-resisting and preparation method thereof |
| US20190194446A1 (en) * | 2017-12-27 | 2019-06-27 | Canon Kabushiki Kaisha | Resin composition, resin molded article, method for manufacturing resin molded article, and electronic apparatus |
| CN110643161A (en) * | 2019-09-04 | 2020-01-03 | 天津金发新材料有限公司 | Polycarbonate composition and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101230188A (en) * | 2007-01-26 | 2008-07-30 | 佛山市顺德区汉达精密电子科技有限公司 | Polycarbonate/acrylonitrile-butadiene-phenylethene copolymer alloy |
| CN102558814A (en) * | 2011-12-17 | 2012-07-11 | 铜陵市新泰电容电器有限责任公司 | Modified polymeric carbon ester material for preparing capacitor housing |
| CN103613916A (en) * | 2013-10-30 | 2014-03-05 | 东莞市卡帝德塑化科技有限公司 | A kind of special PC/ABS alloy modified engineering plastics for notebook computer case and production method thereof |
| CN104403295A (en) * | 2014-12-17 | 2015-03-11 | 安徽科聚新材料有限公司 | Halogen-free flame-retardant high-gloss inorganic-fiber-reinforced PC/ABS material and preparation method thereof |
-
2016
- 2016-05-25 CN CN201610353892.2A patent/CN106009584A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101230188A (en) * | 2007-01-26 | 2008-07-30 | 佛山市顺德区汉达精密电子科技有限公司 | Polycarbonate/acrylonitrile-butadiene-phenylethene copolymer alloy |
| CN102558814A (en) * | 2011-12-17 | 2012-07-11 | 铜陵市新泰电容电器有限责任公司 | Modified polymeric carbon ester material for preparing capacitor housing |
| CN103613916A (en) * | 2013-10-30 | 2014-03-05 | 东莞市卡帝德塑化科技有限公司 | A kind of special PC/ABS alloy modified engineering plastics for notebook computer case and production method thereof |
| CN104403295A (en) * | 2014-12-17 | 2015-03-11 | 安徽科聚新材料有限公司 | Halogen-free flame-retardant high-gloss inorganic-fiber-reinforced PC/ABS material and preparation method thereof |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106751663A (en) * | 2016-12-13 | 2017-05-31 | 德阳力久云智知识产权运营有限公司 | A kind of flame-retardant modified plastics of high tenacity and preparation method thereof |
| CN106928684A (en) * | 2017-03-31 | 2017-07-07 | 合肥民众亿兴软件开发有限公司 | A kind of plastics for computer fan and preparation method thereof |
| CN107163540A (en) * | 2017-07-11 | 2017-09-15 | 合肥东恒锐电子科技有限公司 | A kind of notebook computer special engineering plastic alloy material |
| CN107189335A (en) * | 2017-07-12 | 2017-09-22 | 合肥思博特软件开发有限公司 | A kind of computer mouse case material and preparation method thereof |
| CN107629431A (en) * | 2017-09-21 | 2018-01-26 | 中广核俊尔新材料有限公司 | Ageing-resistant halogen-free flame-retardant polycarbonate composite material of a kind of oil-resisting and heat-resisting and preparation method thereof |
| CN109971145A (en) * | 2017-12-27 | 2019-07-05 | 佳能株式会社 | Resin combination, resin molded body, the method for manufacturing resin molded body and electronic equipment |
| US20190194446A1 (en) * | 2017-12-27 | 2019-06-27 | Canon Kabushiki Kaisha | Resin composition, resin molded article, method for manufacturing resin molded article, and electronic apparatus |
| JP2019116562A (en) * | 2017-12-27 | 2019-07-18 | キヤノン株式会社 | Resin composition, method of producing resin composition and electronic equipment |
| US10920066B2 (en) * | 2017-12-27 | 2021-02-16 | Canon Kabushiki Kaisha | Resin composition with polycarbonate resin, acrylonitrile-butadiene-styrene resin, and inorganic filler, resin molded article, method for manufacturing resin molded article, and electronic apparatus |
| CN109971145B (en) * | 2017-12-27 | 2021-12-31 | 佳能株式会社 | Resin composition, resin molded body, method for producing resin molded body, and electronic device |
| JP7118638B2 (en) | 2017-12-27 | 2022-08-16 | キヤノン株式会社 | Resin composition, method for producing resin composition, and electronic device |
| CN110643161A (en) * | 2019-09-04 | 2020-01-03 | 天津金发新材料有限公司 | Polycarbonate composition and preparation method thereof |
| CN110643161B (en) * | 2019-09-04 | 2022-02-25 | 天津金发新材料有限公司 | Polycarbonate composition and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106009584A (en) | PC (polycarbonate) composite material | |
| CN102485792B (en) | Environment-friendly flame-retardant cable material and preparation method thereof | |
| TWI492987B (en) | Non-halogen flame retardant and high rigidity polycarbonate resin composition | |
| KR101328296B1 (en) | Polycarbonate retardant resin composition comprising glass fiber | |
| CN102863788A (en) | Low-surface-resistance high-glass-fiber reinforced flame-retardant nylon resin composition and preparation method thereof | |
| CN102757622B (en) | Low-smoke halogen-free flame-retardant thermoplastic polyester elastomer and preparation method thereof | |
| CN101580632A (en) | High-gloss high-performance fiber glass reinforced PBT material and preparation method thereof | |
| CN102690515A (en) | Flame-retardant composite material with easy dyeing and laser marking and preparation method thereof | |
| CN102241859A (en) | Flame-retardant reinforced PP (polypropylene)/PA (polyamide) composite material and preparation method thereof | |
| KR20120075053A (en) | Flameproof thermoplastic resin composition | |
| EP2989166B1 (en) | Flame retardant composition and molded article including the same | |
| CN103289293A (en) | Transparent flame-retardant antistatic ABS material, and preparation method and application thereof | |
| CN102002199A (en) | Polyethylene sheath material with high flame resistance at 90 DEG C | |
| CN112004885A (en) | High modulus ductile thermoplastic composition having transparency to radio frequency signals | |
| CN105802183A (en) | Polyethylene-modified polycarbonate composite material composition | |
| CN104725797B (en) | Method for preparing flame-retardant plastic composite material | |
| CN106084751A (en) | A kind of high-performance environment protection high flame resistance polyurethane CABLE MATERIALS and preparation method | |
| CN103408914A (en) | Modified PC (polycarbonate) resin composite material used for household appliances and preparation method | |
| US20150048552A1 (en) | Polymer composition and method for manufacturing the same | |
| CN103756268A (en) | Polyimide fiber enhanced PBT (Polybutylece Terephthalate) composite material and preparation method thereof | |
| TWI480327B (en) | Flame retardant polycarbonate resin composition having high infrared transmission | |
| US12606702B2 (en) | Polycarbonate compositions | |
| KR101526009B1 (en) | Flame-retardant resin composition with conductivity | |
| CN103214815A (en) | Light-colored halogen-free flame retardant polycarbonate mould plastic | |
| CN113024983B (en) | High-transparency high-impact flame-retardant MABS composite material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161012 |