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CN116623104A - A kind of inlet guide vane material for air separation unit and its preparation method - Google Patents
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CN116623104A - A kind of inlet guide vane material for air separation unit and its preparation method - Google Patents

A kind of inlet guide vane material for air separation unit and its preparation method Download PDF

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CN116623104A
CN116623104A CN202310521716.5A CN202310521716A CN116623104A CN 116623104 A CN116623104 A CN 116623104A CN 202310521716 A CN202310521716 A CN 202310521716A CN 116623104 A CN116623104 A CN 116623104A
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guide vane
inlet guide
equivalent
forging
heat treatment
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支金花
张海存
韩增福
魏怡航
师尧
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Xian Shaangu Power Co Ltd
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Xian Shaangu Power Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

本发明提供一种用于空分装置的进口导叶材料及其制备方法,主要解决现有马氏体不锈钢2Cr13作为进口导叶材料时,所加工导叶的焊接工艺性、强度及耐蚀性均不理想的技术问题。本发明基于工艺性需求同时结合适用条件,按重量百分比精确限定各原料的用量,各成分以重量百分比计包括:0.05%≤C≤0.12%;0.1%≤Si≤0.6%;0.1%≤Mn≤0.6%;P≤0.040%;S≤0.030%;10.0%≤Cr≤12.0%;0.2%≤Ni≤0.5%;0.2%≤Mo≤0.5%;0.01%≤Cu≤0.35%;0.01%≤V≤0.05%;其余为Fe。另外,C当量为<0.8;Cr当量为6~10;Ni当量为2~4。通过冶炼、锻造、热处理进行制备,进而得到与马氏体不锈钢2Cr13相比,焊接工艺性好且强度及耐蚀性能均有所提升的进口导叶材料。The invention provides an inlet guide vane material for an air separation unit and a preparation method thereof, which mainly solves the welding manufacturability, strength and corrosion resistance of the processed guide vane when the existing martensitic stainless steel 2Cr13 is used as the inlet guide vane material Both unsatisfactory technical issues. Based on the requirements of manufacturability and combined with applicable conditions, the present invention accurately limits the dosage of each raw material by weight percentage, and each component includes by weight percentage: 0.05%≤C≤0.12%; 0.1%≤Si≤0.6%; 0.1%≤Mn≤ 0.6%; P≤0.040%; S≤0.030%; 10.0%≤Cr≤12.0%; 0.2%≤Ni≤0.5%; 0.2%≤Mo≤0.5%; 0.01%≤Cu≤0.35%; 0.05%; the rest is Fe. In addition, the C equivalent is <0.8; the Cr equivalent is 6-10; and the Ni equivalent is 2-4. Prepared by smelting, forging, and heat treatment, compared with martensitic stainless steel 2Cr13, the imported guide vane material has better welding processability and improved strength and corrosion resistance.

Description

一种用于空分装置的进口导叶材料及其制备方法A kind of inlet guide vane material for air separation unit and its preparation method

技术领域technical field

本发明涉及一种导叶材料,尤其涉及一种用于空分装置的进口导叶材料及其制备方法。The invention relates to a guide vane material, in particular to an inlet guide vane material for an air separation device and a preparation method thereof.

背景技术Background technique

空分装置是一种将空气各气体组份分离的工业设备,其在一定工况范围内运行,通过提高装置的调节性能可有效节约能源。导叶调节是通过改变进口导叶角度从而改变气流预旋的调节方法,与其它调节方法相比,导叶调节机构具有结构简单、可以在不停车条件下调节及可实现自动化调节等优点,具有广阔的应用前景与研究价值。The air separation unit is an industrial equipment that separates the various gas components of the air. It operates within a certain range of conditions and can effectively save energy by improving the adjustment performance of the unit. Guide vane adjustment is an adjustment method that changes the airflow pre-swirl by changing the angle of the inlet guide vane. Compared with other adjustment methods, the guide vane adjustment mechanism has the advantages of simple structure, can be adjusted without stopping the vehicle, and can realize automatic adjustment. Broad application prospects and research value.

采用导叶调节机构调节时,进口导叶承受了气流压力和反射作用产生的弯曲应力,以及叶型表面不对称曲线和气流压力交互作用产生的扭应力等交变载荷,受力复杂且受力变化较大,因此要求进口导叶的材料需有一定的强度。同时,由于工作介质为空气,空气中含有水分、二氧化碳、碳氢化合物等杂质,且空分装置管道或入口经常会设置喷淋装置,因此要求材料具有一定的耐蚀性。When the guide vane adjustment mechanism is used for adjustment, the inlet guide vane is subjected to alternating loads such as bending stress generated by airflow pressure and reflection, as well as torsional stress generated by the interaction between the asymmetrical curve of the blade surface and the airflow pressure, and the force is complex and The change is large, so the material of the inlet guide vane needs to have a certain strength. At the same time, since the working medium is air, which contains impurities such as moisture, carbon dioxide, and hydrocarbons, and the pipes or inlets of the air separation plant are often equipped with spraying devices, the material is required to have certain corrosion resistance.

现有进口导叶的外轮廓通常如图1所示,其长约660mm、宽约100mm、高约100mm,整体尺寸规格比较大;从截面变化情况可以分为叶柄、凸台、叶身三部分,每部分之间的截面尺寸变化均较大。现有进口导叶的材料一般选用透平旋转机械叶片常用材料马氏体不锈钢2Cr13,该材料的屈服强度要求为≥450MPa,成型方式为自由锻,形成整体大锻件。但该类材质同时也存在以下缺陷:The outer contour of the existing inlet guide vane is usually shown in Figure 1. It is about 660mm long, 100mm wide, and 100mm high. , the cross-sectional dimensions of each part vary greatly. The material of the existing imported guide vanes is generally martensitic stainless steel 2Cr13, which is commonly used in turbine rotating machinery blades. The yield strength of this material is required to be ≥ 450 MPa, and the forming method is free forging to form a large overall forging. However, this type of material also has the following disadvantages:

(1)现有的马氏体不锈钢2Cr13由大块锻件材料加工而成,大块锻件在经过热处理后,材料表面与芯部的力学性能和组织性能存在差异,而在加工过程中,将材料强度较好的表面部分加工除去,所剩部分为强度稍差的芯部,由此导致进口导叶的强度等力学性能并不理想。(1) The existing martensitic stainless steel 2Cr13 is processed from large forging materials. After heat treatment of large forgings, there are differences in the mechanical properties and structural properties of the material surface and the core. In the process of processing, the material The surface part with better strength is processed and removed, and the remaining part is the core part with slightly weaker strength, which leads to unsatisfactory mechanical properties such as strength of the inlet guide vane.

(2)现有的马氏体不锈钢2Cr13的焊接工艺性较差。(2) The welding processability of the existing martensitic stainless steel 2Cr13 is poor.

(3)机组会不定期喷水,由空分装置现场运行反馈,进口导叶的耐水腐蚀性能并不理想。(3) The unit will spray water from time to time, and the feedback from the on-site operation of the air separation unit shows that the water corrosion resistance of the inlet guide vane is not ideal.

发明内容Contents of the invention

本发明的目的在于提供一种用于空分装置的进口导叶材料及其制备方法,主要解决现有的马氏体不锈钢2Cr13作为进口导叶材料时,所加工导叶的焊接工艺性、强度及耐蚀性均不理想等技术问题。The purpose of the present invention is to provide a kind of inlet guide vane material and preparation method thereof for air separation unit, mainly solve the welding manufacturability and strength of the processed guide vane when the existing martensitic stainless steel 2Cr13 is used as the inlet guide vane material And technical problems such as unsatisfactory corrosion resistance.

为解决上述技术问题,本发明的技术解决方案为:In order to solve the problems of the technologies described above, the technical solution of the present invention is:

一种用于空分装置的进口导叶材料,其特殊之处在于,成分以重量百分比计包括:0.05%≤C≤0.12%;0.1%≤Si≤0.6%;0.1%≤Mn≤0.6%;P≤0.040%;S≤0.030%;10.0%≤Cr≤12.0%;0.2%≤Ni≤0.5%;0.2%≤Mo≤0.5%;0.01%≤Cu≤0.35%;0.01%≤V≤0.05%;其余为Fe;An inlet guide vane material for an air separation unit, which is special in that the composition includes: 0.05%≤C≤0.12%; 0.1%≤Si≤0.6%; 0.1%≤Mn≤0.6%; P≤0.040%; S≤0.030%; 10.0%≤Cr≤12.0%; 0.2%≤Ni≤0.5%; 0.2%≤Mo≤0.5%; 0.01%≤Cu≤0.35%; 0.01%≤V≤0.05%; The rest is Fe;

其中,C当量<0.8;Cr当量为6-10;Ni当量为2~4;Among them, the equivalent of C is less than 0.8; the equivalent of Cr is 6-10; the equivalent of Ni is 2-4;

所述C当量是指将成分中的各种元素对共晶点实际碳量的影响折算成碳的增减,C当量=C+Si/30+Mn/20+Cu/20+Ni/60+Cr/20+Mo/15+V/10;所述Ni当量表示奥氏体形成元素的总含量,Ni当量=Ni+30C+0.5Mn+0.25Cu;所述Cr当量表示马氏体形成元素的总含量,Cr当量=20-(Cr+1.5Ni+0.7Si+0.75Mn+0.6Mo+1.5V+0.2Cu)。The C equivalent refers to the conversion of the influence of various elements in the composition on the actual carbon content of the eutectic point into the increase or decrease of carbon, C equivalent=C+Si/30+Mn/20+Cu/20+Ni/60+ Cr/20+Mo/15+V/10; said Ni equivalent means the total content of austenite-forming elements, Ni equivalent=Ni+30C+0.5Mn+0.25Cu; said Cr equivalent means the content of martensite-forming elements Total content, Cr equivalent=20-(Cr+1.5Ni+0.7Si+0.75Mn+0.6Mo+1.5V+0.2Cu).

进一步地,进口导叶材料的成分以重量百分比计包括:C:0.08%;Si:0.3%;Mn:0.5%;P:0.020%;S:0.005%;Cr:11.0%;Ni:0.3%;Mo:0.3%;Cu:0.20%;V:0.01%;其余为Fe。Further, the composition of the inlet guide vane material includes: C: 0.08%; Si: 0.3%; Mn: 0.5%; P: 0.020%; S: 0.005%; Cr: 11.0%; Ni: 0.3%; Mo: 0.3%; Cu: 0.20%; V: 0.01%; the rest is Fe.

此外,本发明还提供了一种用于空分装置的进口导叶材料的制备方法,其特殊之处在于,包括以下步骤:In addition, the present invention also provides a preparation method for the inlet guide vane material of the air separation unit, which is special in that it includes the following steps:

步骤1】冶炼Step 1] Smelting

1.1)按照所述进口导叶材料的成分及其重量百分比称取原料;1.1) Weigh raw materials according to the composition and weight percentage of the imported guide vane material;

1.2)对所称取的原料混合后进行冶炼和铸造,获得一次钢锭;1.2) Smelting and casting after mixing the weighed raw materials to obtain a steel ingot;

1.3)对一次钢锭在真空状态下进行二次冶炼和浇注,获得二次钢锭;1.3) Carry out secondary smelting and pouring on the primary steel ingot in a vacuum state to obtain the secondary steel ingot;

步骤2】锻造Step 2] Forging

将步骤1.3)得到的二次钢锭在奥氏体单相区进行锻造,堆冷到室温,即获得进口导叶的锻件;Forging the secondary steel ingot obtained in step 1.3) in the austenite single-phase region, and cooling it to room temperature to obtain the forging of the inlet guide vane;

步骤3】热处理Step 3] heat treatment

对进口导叶的锻件依次进行淬火热处理、回火热处理,得到用于空分装置的进口导叶材料。The forging of the inlet guide vane is sequentially subjected to quenching heat treatment and tempering heat treatment to obtain the inlet guide vane material for the air separation unit.

进一步地,步骤2】中,所述奥氏体单相区的始锻温度为1100℃~1150℃,终锻温度为850℃~900℃,锻造比4~6。Further, in step 2], the initial forging temperature of the austenite single-phase region is 1100°C-1150°C, the final forging temperature is 850°C-900°C, and the forging ratio is 4-6.

进一步地,步骤3】中,所述淬火热处理具体为,将锻件在低于250℃的温度下入炉,加热至930~980℃,保温3h~6h,出炉后油冷至低于150℃。Further, in step 3], the quenching heat treatment specifically includes putting the forging into the furnace at a temperature lower than 250°C, heating it to 930-980°C, keeping it warm for 3h-6h, and oil cooling to lower than 150°C after being released from the furnace.

进一步地,步骤3】中,所述回火热处理具体为,将淬火热处理后的锻件在低于250℃的温度下入炉,加热至730~770℃,保温2h~4h,出炉后空冷至低于150℃。Further, in step 3], the tempering heat treatment specifically includes putting the quenched forging into the furnace at a temperature lower than 250°C, heating it to 730-770°C, keeping it warm for 2h-4h, and air-cooling to a low temperature after being released from the furnace. at 150°C.

与现有技术相比,本发明具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:

1、本发明的进口导叶材料,基于提高导叶零件的材料利用率,结合工艺性需求和零件适用条件,按重量百分比限定各原料成分的含量,尤其是铬、镍、钼、铜、钒元素的含量,同时,控制碳当量、铬当量、镍当量,保证了大型、大截面变化对材料焊接工艺性的要求以及空分装置调节时对零件强度的要求和喷水设置对材料的耐腐蚀性能要求。另外,本发明的进口导叶材料的强度等力学性能略优于2Cr13材料,焊接工艺性、耐腐蚀性优于2Cr13材料。1. The imported guide vane material of the present invention is based on improving the material utilization rate of guide vane parts, combined with manufacturability requirements and parts application conditions, and limits the content of each raw material component by weight percentage, especially chromium, nickel, molybdenum, copper, vanadium At the same time, the carbon equivalent, chromium equivalent, and nickel equivalent are controlled to ensure the welding processability of materials with large and large cross-section changes, as well as the requirements for the strength of parts during the adjustment of air separation units and the corrosion resistance of materials for water spray settings. performance requirements. In addition, the strength and other mechanical properties of the inlet guide vane material of the present invention are slightly better than those of 2Cr13 material, and its welding processability and corrosion resistance are better than those of 2Cr13 material.

2、本发明在现有2Cr13材料的基础上,结合理论研究和导叶零件的工艺性要求,通过反复试验、验证,优化了原料成分及其制造工艺,得到了一种新型焊接工艺性好且耐腐蚀性优的不锈钢材料,适用于空分装置进口导叶,能够有效解决目前空分装置进口导叶材料2Cr13自由锻成型时加工量大而导致材料的力学性能变差等问题,具有使用寿命长的优点。2. On the basis of the existing 2Cr13 material, combined with theoretical research and manufacturability requirements of the guide vane parts, through repeated tests and verifications, the raw material composition and its manufacturing process are optimized, and a new type of welding manufacturability is obtained. The stainless steel material with excellent corrosion resistance is suitable for the inlet guide vane of the air separation unit, which can effectively solve the problems of the current air separation unit inlet guide vane material 2Cr13 free forging, which leads to the deterioration of the mechanical properties of the material and other problems, and has a long service life. long advantage.

3、本发明进口导叶材料的制备方法,整体工艺简单,尤其是冶炼工艺,不同于2Cr13的常规电渣重熔冶炼,仅经过真空冶炼,然后依次经锻造以及淬火热处理和回火热处理,降低了制造工艺的难度,更有利于推广使用。3. The preparation method of the imported guide vane material of the present invention has a simple overall process, especially the smelting process, which is different from the conventional electroslag remelting smelting of 2Cr13, which only undergoes vacuum smelting, and then sequentially undergoes forging, quenching heat treatment and tempering heat treatment, reducing It reduces the difficulty of the manufacturing process and is more conducive to popularization and use.

附图说明Description of drawings

图1为进口导叶的结构示意图;Fig. 1 is the structure diagram of inlet guide vane;

图2为采用本发明实施例一制备得到的进口导叶材料的金相组织图;Fig. 2 is a metallographic structure diagram of the inlet guide vane material prepared by using Embodiment 1 of the present invention;

图3为现有马氏体不锈钢2Cr13的金相组织图。Fig. 3 is a metallographic structure diagram of the existing martensitic stainless steel 2Cr13.

具体实施方式Detailed ways

本发明的设计原理为:通过进口导叶材料及其制备方法的研究,获得与马氏体不锈钢2Cr13相比,焊接工艺性更优、强度和耐蚀性有所提升及材料成本相当的新型进口导叶材料。The design principle of the present invention is: through the research on the imported guide vane material and its preparation method, a new type imported imported guide vane with better welding processability, improved strength and corrosion resistance and equivalent material cost is obtained compared with martensitic stainless steel 2Cr13. Guide vane material.

以下结合具体实施例及附图对本发明的技术方案做进一步详细的描述。The technical solutions of the present invention will be further described in detail below in conjunction with specific embodiments and accompanying drawings.

本发明提供一种用于空分装置的进口导叶材料,主要成分以重量百分比计,具体包括:0.05%≤C≤0.12%;0.1%≤Si≤0.6%;0.1%≤Mn≤0.6%;P≤0.040%;S≤0.030%;10.0%≤Cr≤12.0%;0.2%≤Ni≤0.5%;0.2%≤Mo≤0.5%;0.01%≤Cu≤0.35%;0.01%≤V≤0.05%;其余为Fe和不可避免的杂质。其中,C当量<0.8;Cr当量为6-10;Ni当量为2~4。The invention provides an inlet guide vane material for an air separation unit. The main components are calculated by weight percentage and specifically include: 0.05%≤C≤0.12%; 0.1%≤Si≤0.6%; 0.1%≤Mn≤0.6%; P≤0.040%; S≤0.030%; 10.0%≤Cr≤12.0%; 0.2%≤Ni≤0.5%; 0.2%≤Mo≤0.5%; 0.01%≤Cu≤0.35%; 0.01%≤V≤0.05%; The rest is Fe and unavoidable impurities. Wherein, the C equivalent is <0.8; the Cr equivalent is 6-10; and the Ni equivalent is 2-4.

本发明为了满足材料的焊接工艺性,降低了C、Cr的含量,C含量的降低虽然使耐蚀性进一步提高、但却使强度降低,Cr含量降低则使耐蚀性、强度都降低,因此,为了保证材料的强度和耐蚀性,本发明增加了Ni、Mo、Cu、V元素及含量,但这些元素的增加会影响焊接工艺性且可在一定程度上提高成本,因而进一步控制了Ni、Mo的含量。本发明对碳当量、铬当量、镍当量进行综合控制,各元素的组成,并不是简单的拼凑,其含量范围也不是简单的单一试验能够获得的,是充分考虑了材料的焊接工艺性需求和强度、耐蚀性等适用条件,经过反复试验和实际验证,结合理论研究确定的。In order to meet the welding processability of the material, the present invention reduces the content of C and Cr. Although the reduction of C content further improves the corrosion resistance, it reduces the strength, and the reduction of Cr content reduces both the corrosion resistance and the strength. Therefore , in order to ensure the strength and corrosion resistance of the material, the present invention increases Ni, Mo, Cu, V elements and content, but the increase of these elements will affect the welding process and can increase the cost to a certain extent, thus further controlling the Ni , Mo content. The present invention comprehensively controls the carbon equivalent, chromium equivalent and nickel equivalent. The composition of each element is not a simple patchwork, and its content range cannot be obtained by a simple single test. It fully considers the welding process requirements of materials and Applicable conditions such as strength and corrosion resistance are determined through repeated tests and actual verification, combined with theoretical research.

本发明通过对各元素种类及配比进行合理设计,进而得到综合性能较优的进口导叶材料。其中,C当量表示焊接熔池形成时各种合金元素对共晶点实际碳量的影响,包含C(主要)、Si、Cr、Mo、V等,其控制主要用于保证焊接工艺性;Cr当量表示马氏体形成元素包括Cr(主要)、Ni、Mo、V,其控制主要用于保证材料的耐蚀性和强度;Ni当量表示奥氏体形成元素包含Ni(主要)、C、Mn、Cu等,其控制主要用于保证材料的耐蚀性、改善焊接工艺性。上述C当量、Ni当量、Cr当量,能够同时影响焊接工艺性、强度和耐蚀性,通过各元素的相互作用,满足进口导叶的制造及使用要求。In the present invention, the imported guide vane material with better comprehensive performance is obtained by rationally designing the types and proportions of each element. Among them, the C equivalent represents the influence of various alloy elements on the actual carbon content of the eutectic point when the weld pool is formed, including C (main), Si, Cr, Mo, V, etc., and its control is mainly used to ensure the welding process; Cr The equivalent means that the martensite-forming elements include Cr (main), Ni, Mo, and V, and its control is mainly used to ensure the corrosion resistance and strength of the material; the Ni equivalent means that the austenite-forming elements include Ni (main), C, and Mn , Cu, etc., and its control is mainly used to ensure the corrosion resistance of the material and improve the welding process. The above-mentioned C equivalent, Ni equivalent, and Cr equivalent can simultaneously affect the welding processability, strength and corrosion resistance, and through the interaction of various elements, it can meet the manufacturing and use requirements of the imported guide vane.

本发明的进口导叶材料组成中,Cr元素是具有代表性的马氏体形成元素,它的主要作用是提高强度和耐蚀性,当Cr含量大于10%时,进口导叶材料的耐腐蚀性会急剧变好,另外Cr含量还能够提高进口导叶材料的淬透性从而提高强度但焊接性会变差,综上结合进口导叶材料的实际应用进行研究,确定Cr含量应当控制在10.0-12.0%。Ni元素是具有代表性的奥氏体稳定元素,能够增强进口导叶材料的抗腐蚀能力,同时,有利于叶片材料拥有优良的韧性和延展性,从而改善材料的焊接工艺性,若Ni含量过高,材料的强度会变低。Mo元素和V元素是铁素体的形成元素,可以提高淬透性、细化晶粒从而提高材料的强度,一定量的Mo还可以有效提高材料钝化膜的强度,从而增强材料的抗腐蚀能力,但是,当Mo和V含量过高时,铁素体数量就会增加,严重影响进口导叶材料的焊接工艺性。Cu元素是奥氏体形成元素,突出的作用是改善耐蚀性,特别是和磷配合使用时能够显著提高进口导叶材料的耐蚀性,但是,过高的Cu元素则会导致材料的塑性急剧下降而影响焊接工艺性,Cu≤0.5时对焊接性能影响不大。Mn元素是扩大及稳定奥氏体元素,还可提高进口导叶材料的淬透性从而提高强度,但是,过高的Mn含量可促进б相析出,使进口导叶材料具有脆性,对进口导叶的可焊性不利。Si是铁素体形成元素,含量越高,进口导叶材料的强度越高,其与Mo、Cr结合提高耐蚀性,但含量越高焊接性越差。C元素为扩大奥氏体区域元素,为保证耐蚀性和焊接工艺性其含量应控制在0.12%以下。In the composition of the inlet guide vane material of the present invention, the Cr element is a representative martensite forming element, and its main function is to improve the strength and corrosion resistance. When the Cr content is greater than 10%, the corrosion resistance of the inlet guide vane material In addition, the Cr content can also improve the hardenability of the imported guide vane material, thereby increasing the strength, but the weldability will deteriorate. In summary, combined with the actual application of the imported guide vane material, it is determined that the Cr content should be controlled at 10.0 -12.0%. Ni element is a representative austenite stable element, which can enhance the corrosion resistance of imported guide vane materials. Higher, the strength of the material will be lower. Mo element and V element are the forming elements of ferrite, which can improve the hardenability and refine the grain to improve the strength of the material. A certain amount of Mo can also effectively improve the strength of the passivation film of the material, thereby enhancing the corrosion resistance of the material However, when the content of Mo and V is too high, the amount of ferrite will increase, which seriously affects the welding processability of imported guide vane materials. Cu element is an austenite-forming element, and its prominent role is to improve corrosion resistance, especially when used in conjunction with phosphorus, it can significantly improve the corrosion resistance of imported guide vane materials. However, excessive Cu elements will lead to plasticity of the material. A sharp drop will affect the welding process, and when Cu≤0.5 has little effect on the welding performance. Mn element is an element that expands and stabilizes austenite, and can also improve the hardenability of the imported guide vane material and thereby increase the strength. However, too high a Mn content can promote the precipitation of the б phase, making the imported guide vane material brittle and harmful to the imported guide vane. The weldability of the leaf is disadvantageous. Si is a ferrite forming element, the higher the content, the higher the strength of the inlet guide vane material, and its combination with Mo and Cr improves the corrosion resistance, but the higher the content, the worse the weldability. C element is an element that expands the austenite region, and its content should be controlled below 0.12% in order to ensure corrosion resistance and welding processability.

综上,各原料成分共同作用形成了本发明叶片材料的原料,各原料的比例也是相辅相成的。In summary, the components of the raw materials work together to form the raw materials of the blade material of the present invention, and the ratios of the raw materials are also complementary.

基于上述进口导叶材料,本发明还提供了一种用于空分装置的进口导叶材料的制备方法,具体如下:Based on above-mentioned inlet guide vane material, the present invention also provides a kind of preparation method for the inlet guide vane material of air separation unit, specifically as follows:

步骤1】冶炼Step 1] Smelting

1.1)按照上述进口导叶材料的成分及其重量百分比称取原料;1.1) Take the raw material according to the composition and weight percentage of the above-mentioned imported guide vane material;

1.2)对所称取的原料混合后进行冶炼和铸造,获得一次钢锭;1.2) Smelting and casting after mixing the weighed raw materials to obtain a steel ingot;

1.3)对一次钢锭在真空状态下进行二次冶炼和浇注,获得二次钢锭,即坯料。1.3) Perform secondary smelting and pouring on the primary steel ingot in a vacuum state to obtain the secondary steel ingot, ie billet.

本发明的冶炼工艺简单,而2Cr13材料通常需要经电炉+电渣重熔方式进行冶炼,工艺较为复杂。The smelting process of the present invention is simple, but the 2Cr13 material usually needs to be smelted by electric furnace + electroslag remelting, and the process is relatively complicated.

步骤2】锻造Step 2] Forging

将步骤1.3)得到的二次钢锭在奥氏体单相区进行锻造,堆冷到室温,即获得进口导叶的锻件。其中,奥氏体单相区的始锻温度为1100℃~1150℃,终锻温度为850℃~900℃,锻造比4~6。The secondary steel ingot obtained in step 1.3) is forged in the austenite single-phase region, and cooled to room temperature to obtain the forging of the inlet guide vane. Among them, the initial forging temperature of the austenite single-phase region is 1100°C-1150°C, the final forging temperature is 850°C-900°C, and the forging ratio is 4-6.

步骤3】热处理Step 3] heat treatment

对进口导叶的锻件依次进行淬火热处理、回火热处理,得到用于空分装置的进口导叶材料。The forging of the inlet guide vane is sequentially subjected to quenching heat treatment and tempering heat treatment to obtain the inlet guide vane material for the air separation unit.

淬火热处理的过程为,将锻件在低于250℃的温度下入炉,加热至930~980℃,保温3h~6h,出炉后油冷至低于150℃。The process of quenching heat treatment is that the forging is put into the furnace at a temperature lower than 250°C, heated to 930-980°C, kept for 3h-6h, and oil-cooled to lower than 150°C after being released from the furnace.

回火热处理的过程为,将淬火热处理后的锻件在低于250℃的温度下入炉,加热至730~770℃,保温2h~4h,出炉后空冷至低于150℃,进而得到强度及耐蚀性等较优的进口导叶材料。The process of tempering heat treatment is that the forging after quenching heat treatment is put into the furnace at a temperature lower than 250°C, heated to 730-770°C, kept for 2h-4h, and air-cooled to below 150°C after being released from the furnace, so as to obtain strength and durability. Imported guide vane materials with superior corrosion resistance.

采用该进口导叶材料可进行后续进口导叶的焊接加工,该材料具有良好的焊接工艺性。进而可获得综合性能较优的进口导叶成品。The imported guide vane material can be used for subsequent welding processing of the imported guide vane, and the material has good welding processability. In turn, imported guide vane finished products with better comprehensive performance can be obtained.

实施例一Embodiment one

1、按重量百分比称取以下原料:1. Weigh the following raw materials by weight percentage:

C:0.08%;Si:0.3%;Mn:0.5%;P:0.020%;S:0.005%;Cr:11.0%;Ni:0.3%;Mo:0.3%;Cu:0.20%;V:0.01%;其余为Fe。其中,C当量为0.70,Cr当量为7.7,Ni当量为3.0。C:0.08%;Si:0.3%;Mn:0.5%;P:0.020%;S:0.005%;Cr:11.0%;Ni:0.3%;Mo:0.3%;Cu:0.20%;V:0.01%; The rest is Fe. Among them, the C equivalent is 0.70, the Cr equivalent is 7.7, and the Ni equivalent is 3.0.

将称取的上述原料混合后进行冶炼和铸造,获得一次钢锭;再对一次钢锭在真空状态下进行二次冶炼和浇注,获得二次钢锭。具体的冶炼和铸造工艺可根据实际情况进行设定或调整。The above raw materials weighed are mixed and then smelted and cast to obtain a primary steel ingot; the primary steel ingot is subjected to secondary smelting and pouring in a vacuum state to obtain a secondary steel ingot. The specific smelting and casting process can be set or adjusted according to the actual situation.

2、锻造2. Forging

将得到的二次钢锭在奥氏体单相区进行锻造,将始锻温度设为1100℃,终锻温度设为850℃,锻造比为5,之后堆冷到室温,即获得进口导叶的锻件。The obtained secondary steel ingot is forged in the austenite single-phase region, the initial forging temperature is set to 1100°C, the final forging temperature is set to 850°C, the forging ratio is 5, and then the stack is cooled to room temperature to obtain the inlet guide vane. Forgings.

3、热处理3. Heat treatment

对进口导叶的锻件依次进行淬火热处理、回火热处理,得到用于空分装置的进口导叶材料。The forging of the inlet guide vane is sequentially subjected to quenching heat treatment and tempering heat treatment to obtain the inlet guide vane material for the air separation unit.

淬火热处理的具体过程为,将进口导叶的锻件在220℃的温度下入炉进行淬火处理,加热至950℃,保温3h,出炉后油冷至130℃。The specific process of quenching heat treatment is that the forging of the inlet guide vane is put into the furnace at 220°C for quenching treatment, heated to 950°C, kept for 3 hours, and oil-cooled to 130°C after being released from the furnace.

回火热处理的具体过程为,将淬火热处理后的锻件在220℃的温度下入炉,加热至730℃,保温2h,出炉后空冷至130℃。The specific process of tempering heat treatment is that the forging after quenching heat treatment is put into the furnace at a temperature of 220 ° C, heated to 730 ° C, kept for 2 hours, and air-cooled to 130 ° C after being released from the furnace.

实施例二Embodiment two

1、按重量百分比称取以下原料:1. Weigh the following raw materials by weight percentage:

C:0.10%,Si:0.5%,Mn:0.2%,P:0.010%,S:0.009%,Cr:12%,Ni:0.5%,Mo:0.2%,Cu:0.30%,V:0.05%,其余为Fe。其中,C当量为0.77,Cr当量为6.5,Ni当量为3.7。C: 0.10%, Si: 0.5%, Mn: 0.2%, P: 0.010%, S: 0.009%, Cr: 12%, Ni: 0.5%, Mo: 0.2%, Cu: 0.30%, V: 0.05%, The rest is Fe. Among them, the C equivalent is 0.77, the Cr equivalent is 6.5, and the Ni equivalent is 3.7.

将称取的上述原料混合后进行冶炼和铸造,获得一次钢锭;再对一次钢锭在真空状态下进行二次冶炼和浇注,获得二次钢锭。具体的冶炼和铸造工艺可根据实际情况进行设定或调整。The above raw materials weighed are mixed and then smelted and cast to obtain a primary steel ingot; the primary steel ingot is subjected to secondary smelting and pouring in a vacuum state to obtain a secondary steel ingot. The specific smelting and casting process can be set or adjusted according to the actual situation.

2、锻造2. Forging

将得到的二次钢锭在奥氏体单相区进行锻造,将始锻温度设为1150℃,终锻温度设为900℃,锻造比为4,之后堆冷到室温,即获得进口导叶的锻件。The obtained secondary steel ingot is forged in the austenite single-phase region, the initial forging temperature is set to 1150°C, the final forging temperature is set to 900°C, the forging ratio is 4, and then the stack is cooled to room temperature to obtain the inlet guide vane. Forgings.

3、热处理3. Heat treatment

对进口导叶的锻件依次进行淬火热处理、回火热处理,得到用于空分装置的进口导叶材料。The forging of the inlet guide vane is sequentially subjected to quenching heat treatment and tempering heat treatment to obtain the inlet guide vane material for the air separation unit.

淬火热处理的具体过程为,将进口导叶的锻件在200℃的温度下入炉进行淬火处理,加热至930℃,保温6h,出炉后油冷至100℃。The specific process of quenching heat treatment is that the forging of the inlet guide vane is put into the furnace at 200°C for quenching treatment, heated to 930°C, kept for 6 hours, and oil-cooled to 100°C after being released from the furnace.

回火热处理的具体过程为,将淬火热处理后的锻件在200℃的温度下入炉,加热至770℃,保温4h,出炉后空冷至100℃。The specific process of tempering heat treatment is that the forging after quenching heat treatment is put into the furnace at a temperature of 200 ° C, heated to 770 ° C, kept for 4 hours, and air-cooled to 100 ° C after being released from the furnace.

实施例三Embodiment three

1、按重量百分比称取以下原料:1. Weigh the following raw materials by weight percentage:

C:0.12%,Si:0.6%,Mn:0.1%,P:0.020%,S:0.018%,Cr:10%,Ni:0.2%,Mo:0.3%,Cu:0.10%,V:0.025%,其余为Fe。其中,C当量为0.68,Cr当量为9.0,Ni当量为3.9。C: 0.12%, Si: 0.6%, Mn: 0.1%, P: 0.020%, S: 0.018%, Cr: 10%, Ni: 0.2%, Mo: 0.3%, Cu: 0.10%, V: 0.025%, The rest is Fe. Among them, the C equivalent is 0.68, the Cr equivalent is 9.0, and the Ni equivalent is 3.9.

将称取的上述原料混合后进行冶炼和铸造,获得一次钢锭;再对一次钢锭在真空状态下进行二次冶炼和浇注,获得二次钢锭。具体的冶炼和铸造工艺可根据实际情况进行设定或调整。The above raw materials weighed are mixed and then smelted and cast to obtain a primary steel ingot; the primary steel ingot is subjected to secondary smelting and pouring in a vacuum state to obtain a secondary steel ingot. The specific smelting and casting process can be set or adjusted according to the actual situation.

2、锻造2. Forging

将得到的二次钢锭在奥氏体单相区进行锻造,将始锻温度设为1100℃,终锻温度设为900℃,锻造比为6,之后堆冷到室温,即获得进口导叶的锻件。The obtained secondary steel ingot is forged in the austenite single-phase region, the initial forging temperature is set to 1100°C, the final forging temperature is set to 900°C, the forging ratio is 6, and then the stack is cooled to room temperature to obtain the inlet guide vane. Forgings.

3、热处理3. Heat treatment

对进口导叶的锻件依次进行淬火热处理、回火热处理,得到用于空分装置的进口导叶材料。The forging of the inlet guide vane is sequentially subjected to quenching heat treatment and tempering heat treatment to obtain the inlet guide vane material for the air separation unit.

淬火热处理的具体过程为,将进口导叶的锻件在180℃的温度下入炉进行淬火处理,加热至950℃,保温4h,出炉后油冷至100℃。The specific process of quenching heat treatment is that the forging of the inlet guide vane is put into the furnace at a temperature of 180°C for quenching treatment, heated to 950°C, kept for 4 hours, and oil-cooled to 100°C after being released from the furnace.

回火热处理的具体过程为,将淬火热处理后的锻件在180℃的温度下入炉,加热至750℃,保温3h,出炉后空冷至100℃。The specific process of tempering heat treatment is that the forging after quenching heat treatment is put into the furnace at a temperature of 180 ° C, heated to 750 ° C, kept for 3 hours, and air-cooled to 100 ° C after being released from the furnace.

实施例四Embodiment four

1、按重量百分比称取以下原料:1. Weigh the following raw materials by weight percentage:

C:0.05%,Si:0.2%,Mn:0.2%,P:0.010%,S:0.015%,Cr:10%,Ni:0.5%,Mo:0.5%,Cu:0.2%,V:0.03%,其余为Fe。其中,C当量为0.62,Cr当量为8.6,Ni当量为2.2。C: 0.05%, Si: 0.2%, Mn: 0.2%, P: 0.010%, S: 0.015%, Cr: 10%, Ni: 0.5%, Mo: 0.5%, Cu: 0.2%, V: 0.03%, The rest is Fe. Among them, the C equivalent is 0.62, the Cr equivalent is 8.6, and the Ni equivalent is 2.2.

将称取的上述原料混合后进行冶炼和铸造,获得一次钢锭;再对一次钢锭在真空状态下进行二次冶炼和浇注,获得二次钢锭。具体的冶炼和铸造工艺可根据实际情况进行设定或调整。The above raw materials weighed are mixed and then smelted and cast to obtain a primary steel ingot; the primary steel ingot is subjected to secondary smelting and pouring in a vacuum state to obtain a secondary steel ingot. The specific smelting and casting process can be set or adjusted according to the actual situation.

2、锻造2. Forging

将得到的二次钢锭在奥氏体单相区进行锻造,将始锻温度设为1150℃,终锻温度设为870℃,锻造比为6,之后堆冷到室温,即获得进口导叶的锻件。The obtained secondary steel ingot is forged in the austenite single-phase region, the initial forging temperature is set to 1150°C, the final forging temperature is set to 870°C, the forging ratio is 6, and then the stack is cooled to room temperature to obtain the inlet guide vane. Forgings.

3、热处理3. Heat treatment

对进口导叶的锻件依次进行淬火热处理、回火热处理,得到用于空分装置的进口导叶材料。The forging of the inlet guide vane is sequentially subjected to quenching heat treatment and tempering heat treatment to obtain the inlet guide vane material for the air separation unit.

淬火热处理的具体过程为,将进口导叶的锻件在240℃的温度下入炉进行淬火处理,加热至970℃,保温5h,出炉后油冷至120℃。The specific process of quenching heat treatment is that the forging of the inlet guide vane is put into the furnace at 240°C for quenching treatment, heated to 970°C, kept for 5 hours, and oil-cooled to 120°C after being released from the furnace.

回火热处理的具体过程为,将淬火热处理后的锻件在240℃的温度下入炉,加热至750℃,保温4h,出炉后空冷至120℃。The specific process of tempering heat treatment is that the forging after quenching heat treatment is put into the furnace at a temperature of 240 ° C, heated to 750 ° C, kept for 4 hours, and air-cooled to 120 ° C after being released from the furnace.

经过试验验证,本发明的方法可行且制备得到的进口导叶材料综合性能较优,以下结合本发明得到的进口导叶材料与马氏体不锈钢2Cr13,对其强度韧性、金相组织及耐蚀性进行对比说明。After test verification, the method of the present invention is feasible and the comprehensive performance of the imported guide vane material prepared is better. The following combines the imported guide vane material obtained by the present invention with the martensitic stainless steel 2Cr13 for its strength, toughness, metallographic structure and corrosion resistance. sex for comparison.

1、强度韧性指标对比(表1所示)1. Comparison of strength and toughness indicators (shown in Table 1)

表1Table 1

由表1可知,本申请制备得到的进口导叶材料与马氏体不锈钢2Cr13相比,强度及韧性指标均更优。It can be seen from Table 1 that, compared with the martensitic stainless steel 2Cr13, the inlet guide vane material prepared by this application has better strength and toughness indicators.

2、金相组织(控制铁素体)对比2. Comparison of metallographic structure (control ferrite)

如图2和图3所示,实施例一得到的进口导叶材料与马氏体不锈钢2Cr13相比,组织接近甚至更细密。As shown in Fig. 2 and Fig. 3, the structure of the inlet guide vane material obtained in Example 1 is close to or even finer than that of martensitic stainless steel 2Cr13.

3、耐蚀性对比(表2所示)3. Corrosion resistance comparison (shown in Table 2)

进行6%FeCl3盐溶液的电化学腐蚀性能测试,即自腐蚀电流密度越小,腐蚀倾向越小,越不容易发生腐蚀。The electrochemical corrosion performance test of 6% FeCl 3 salt solution is carried out, that is, the smaller the self-corrosion current density, the smaller the corrosion tendency, and the less prone to corrosion.

表2Table 2

材料Material 自腐蚀电流密度(A)Self-corrosion current density (A) 马氏体不锈钢2Cr13Martensitic stainless steel 2Cr13 0.00135360.0013536 实施例一得到的进口导叶材料The inlet guide vane material that embodiment one obtains 0.00076450.0007645

由表2可知,实施例一得到的进口导叶材料与马氏体不锈钢2Cr13相比,耐蚀性显著提升。对其他实施例进行相应的测试,所得结果与实施例一基本相近。It can be seen from Table 2 that the corrosion resistance of the inlet guide vane material obtained in Example 1 is significantly improved compared with the martensitic stainless steel 2Cr13. Carry out corresponding test to other embodiment, the obtained result is basically similar to embodiment one.

综上可知,本发明通过控制材料中主要成分的含量,尤其是碳、铬、镍、钼元素含量,进而控制碳当量,使得制备得到的进口导叶材料获得良好的焊接工艺性。同时,通过控制热处理制度来调整金相组织,进而保证了进口导叶材料的强度、耐蚀性,提升了其综合性能。In summary, the present invention controls the content of main components in the material, especially the content of carbon, chromium, nickel, and molybdenum, and then controls the carbon equivalent, so that the prepared inlet guide vane material can obtain good welding processability. At the same time, the metallographic structure is adjusted by controlling the heat treatment system, thereby ensuring the strength and corrosion resistance of the imported guide vane material, and improving its comprehensive performance.

以上,尽管已经示出和描述了本发明的实施例,但对于本技术领域中的普通技术人员来说,只要在本发明的实质精神范围之内,对以上实施例的变化和变型都应当视为落入本发明的保护范围内。Above, although the embodiments of the present invention have been shown and described, for those of ordinary skill in the art, as long as they are within the scope of the spirit of the present invention, changes and modifications to the above embodiments should be regarded as In order to fall within the protection scope of the present invention.

Claims (6)

1.一种用于空分装置的进口导叶材料,其特征在于,成分以重量百分比计包括:1. a kind of inlet guide vane material for air separation unit is characterized in that, composition comprises by weight percent: 0.05%≤C≤0.12%;0.1%≤Si≤0.6%;0.1%≤Mn≤0.6%;P≤0.040%;S≤0.030%;10.0%≤Cr≤12.0%;0.2%≤Ni≤0.5%;0.2%≤Mo≤0.5%;0.01%≤Cu≤0.35%;0.01%≤V≤0.05%;其余为Fe;0.05%≤C≤0.12%; 0.1%≤Si≤0.6%; 0.1%≤Mn≤0.6%; P≤0.040%; S≤0.030%; 10.0%≤Cr≤12.0%; 0.2%≤Ni≤0.5%; 0.2%≤Mo≤0.5%; 0.01%≤Cu≤0.35%; 0.01%≤V≤0.05%; the rest is Fe; 其中,C当量<0.8;Cr当量为6~10;Ni当量为2~4;Among them, the equivalent of C is less than 0.8; the equivalent of Cr is 6-10; the equivalent of Ni is 2-4; 所述C当量是指将成分中的各种元素对共晶点实际碳量的影响折算成碳的增减,C当量=C+Si/30+Mn/20+Cu/20+Ni/60+Cr/20+Mo/15+V/10;所述Ni当量表示奥氏体形成元素的总含量,Ni当量=Ni+30C+0.5Mn+0.25Cu;所述Cr当量表示马氏体形成元素的总含量,Cr当量=20-(Cr+1.5Ni+0.7Si+0.75Mn+0.6Mo+1.5V+0.2Cu)。The C equivalent refers to the conversion of the influence of various elements in the composition on the actual carbon content of the eutectic point into the increase or decrease of carbon, C equivalent=C+Si/30+Mn/20+Cu/20+Ni/60+ Cr/20+Mo/15+V/10; said Ni equivalent means the total content of austenite-forming elements, Ni equivalent=Ni+30C+0.5Mn+0.25Cu; said Cr equivalent means the content of martensite-forming elements Total content, Cr equivalent=20-(Cr+1.5Ni+0.7Si+0.75Mn+0.6Mo+1.5V+0.2Cu). 2.根据权利要求1所述的用于空分装置的进口导叶材料,其特征在于,成分以重量百分比计包括:2. the inlet guide vane material for air separation unit according to claim 1, is characterized in that, composition comprises by weight percent: C:0.08%;Si:0.3%;Mn:0.5%;P:0.020%;S:0.005%;Cr:11.0%;Ni:0.3%;Mo:0.3%;Cu:0.20%;V:0.01%;其余为Fe。C:0.08%;Si:0.3%;Mn:0.5%;P:0.020%;S:0.005%;Cr:11.0%;Ni:0.3%;Mo:0.3%;Cu:0.20%;V:0.01%; The rest is Fe. 3.一种权利要求1或2所述的用于空分装置的进口导叶材料的制备方法,其特征在于,包括以下步骤:3. a preparation method for the inlet guide vane material of claim 1 or 2, is characterized in that, comprises the following steps: 步骤1】冶炼Step 1] Smelting 1.1、按照所述进口导叶材料的成分及其重量百分比称取原料;1.1. Weigh raw materials according to the composition and weight percentage of the imported guide vane material; 1.2、对所称取的原料混合后进行冶炼和铸造,获得一次钢锭;1.2. After mixing the weighed raw materials, smelting and casting are carried out to obtain a steel ingot; 1.3、对一次钢锭在真空状态下进行二次冶炼和浇注,获得二次钢锭;1.3. Perform secondary smelting and pouring on the primary steel ingot in a vacuum state to obtain secondary steel ingots; 步骤2】锻造Step 2] Forging 将步骤1.3)得到的二次钢锭在奥氏体单相区进行锻造,堆冷到室温,即获得进口导叶的锻件;Forging the secondary steel ingot obtained in step 1.3) in the austenite single-phase region, and cooling it to room temperature to obtain the forging of the inlet guide vane; 步骤3】热处理Step 3] heat treatment 对进口导叶的锻件依次进行淬火热处理、回火热处理,得到用于空分装置的进口导叶材料。The forging of the inlet guide vane is sequentially subjected to quenching heat treatment and tempering heat treatment to obtain the inlet guide vane material for the air separation unit. 4.根据权利要求3所述的用于空分装置的进口导叶材料的制备方法,其特征在于:4. the preparation method for the inlet guide vane material of air separation plant according to claim 3, is characterized in that: 步骤2】中,所述奥氏体单相区的始锻温度为1100℃~1150℃,终锻温度为850℃~900℃,锻造比4~6。In step 2], the initial forging temperature of the austenite single-phase region is 1100°C-1150°C, the final forging temperature is 850°C-900°C, and the forging ratio is 4-6. 5.根据权利要求4所述的用于空分装置的进口导叶材料的制备方法,其特征在于:5. the preparation method for the inlet guide vane material of air separation plant according to claim 4, is characterized in that: 步骤3】中,所述淬火热处理具体为,将锻件在低于250℃的温度下入炉,加热至930~980℃,保温3h~6h,出炉后油冷至低于150℃。In step 3], the quenching heat treatment specifically includes putting the forging into the furnace at a temperature lower than 250°C, heating it to 930-980°C, keeping it warm for 3h-6h, and oil cooling to lower than 150°C after it comes out of the furnace. 6.根据权利要求5所述的用于空分装置的进口导叶材料的制备方法,其特征在于:6. the preparation method for the inlet guide vane material of air separation plant according to claim 5, is characterized in that: 步骤3】中,所述回火热处理具体为,将淬火热处理后的锻件在低于250℃的温度下入炉,加热至730~770℃,保温2h~4h,出炉后空冷至低于150℃。In step 3], the tempering heat treatment specifically includes putting the quenched forging into the furnace at a temperature lower than 250°C, heating it to 730-770°C, keeping it warm for 2h-4h, and air-cooling it to lower than 150°C after being released from the furnace .
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CN117840713A (en) * 2024-02-04 2024-04-09 西安陕鼓动力股份有限公司 A method for preparing inlet guide vanes for large air separation compressors

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CN112410687A (en) * 2020-10-14 2021-02-26 沈阳透平机械股份有限公司 Sulfide stress corrosion resistant martensitic stainless steel material and preparation method thereof
CN114438402A (en) * 2021-12-24 2022-05-06 西安陕鼓动力股份有限公司 Energy recovery turbine blade material for low-temperature high-acidity working condition and preparation method

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CN105624586A (en) * 2015-12-29 2016-06-01 钢铁研究总院 Corrosion-resisting steel special for bridge support and suitable for marine environment
CN112410687A (en) * 2020-10-14 2021-02-26 沈阳透平机械股份有限公司 Sulfide stress corrosion resistant martensitic stainless steel material and preparation method thereof
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