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CA2685084A1 - Oil sands flotation - Google Patents
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CA2685084A1 - Oil sands flotation - Google Patents

Oil sands flotation Download PDF

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Publication number
CA2685084A1
CA2685084A1 CA002685084A CA2685084A CA2685084A1 CA 2685084 A1 CA2685084 A1 CA 2685084A1 CA 002685084 A CA002685084 A CA 002685084A CA 2685084 A CA2685084 A CA 2685084A CA 2685084 A1 CA2685084 A1 CA 2685084A1
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CA
Canada
Prior art keywords
stream
flotation
tailings
oil sands
rougher
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002685084A
Other languages
French (fr)
Other versions
CA2685084C (en
Inventor
Michael Francis Young
Le Vi Huynh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Glencore Technology Pty Ltd
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AU2007902865A external-priority patent/AU2007902865A0/en
Application filed by Individual filed Critical Individual
Publication of CA2685084A1 publication Critical patent/CA2685084A1/en
Application granted granted Critical
Publication of CA2685084C publication Critical patent/CA2685084C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/02Froth-flotation processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/04Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
    • C10G1/047Hot water or cold water extraction processes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Solids By Using Liquids Or Pneumatic Power (AREA)
  • Physical Water Treatments (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Treatment Of Sludge (AREA)

Abstract

An oil sands flotation circuit wherein a feed stream is fed to a bank comprising at least one rougher flotation cell producing a rougher concentrate stream and a rougher tailings stream, said rougher concentrate stream being fed to a bank comprising at least one cleaner flotation cell producing a cleaner concentrate stream and a cleaner tailings stream.

Description

Oil Sands Flotation Field of the Invention.
The present invention relates to a process and plant for the flotation of oil sands.
Background Art.
Oil sands, also known as tar sands or bitumen sands, are one of the world's largest sources of crude oil. The vast majority of the world's oil sands reserves are found in North America, and Canada in particular, with some further reserves in South America.

Oil sands exist as a grain of sand surrounded by a thin layer of water and further surrounded by a layer of bitumen. Bitumen is a heavy, viscous crude oil that may be processed into high-quality synthetic oils used, for example, as automotive or jet fuel.
The process for extracting bitumen from the sand particles involves using a hot water flotation process. The collected bitumen concentrate is mixed with naphtha to thin the bitumen sufficiently to allow it to be pumped.

Typically, the flotation process used in oil sands processing comprises a single stage only, and no subsequent upgrading of concentrate quality is carried out in the flotation section. As a result, uncollected bitumen reports to the tailings stream, and significant amounts of sand are collected in the bitumen concentrate. This leads to two equally unattractive outcomes: the loss of unrecovered bitumen to tailings and additional downstream costs associated with removing entrained sand from the bitumen concentrate.

It will be clearly understood that, if a prior art publication is referred to herein, this reference does not constitute an admission that the publication forms part of the common general knowledge in the art in Australia or in any other country.

Object of the Invention.
It is an object of the present invention to provide a process and plant for the flotation of oil sands which may overcome at least some of the abovementioned disadvantages, or provide a useful or commercial choice.

In a first aspect of the present invention there is provided an oil sands flotation circuit wherein a feed stream is fed to a bank comprising at least one rougher flotation cell, producing a rougher concentrate stream and a rougher tailings stream, said rougher concentrate stream being fed to a bank comprising at least one cleaner flotation cell, producing a cleaner concentrate stream and a cleaner tailings stream.

The cleaner tailings steam may be partly or wholly recycled to any suitable point in the flotation circuit. The point in the flotation circuit to which the cleaner tailings stream may be recycled may typically be chosen based on the metallurgical conditions in, and the performance of, the flotation circuit. However, in some preferred embodiments of the present invention, the cleaner tailings stream may be partly or wholly recycled to the head of the bank comprising the at least one rougher flotation cell, or to any other suitable point within the bank comprising at least one rougher flotation cell, and the cleaner concentrate stream may comprise the final flotation product.

In some embodiments of the present invention, the rougher tailings stream may be dewatered and the discharged to a tailings storage area. In an alternative embodiment of the invention, however, the rougher tailings stream may be discharged directly to a tailings storage area and the water may be decanted from the settled solids.
The tailings storage area may comprise any suitable storage area, such as, but not limited to, a tank or dam.

In another preferred embodiment of the present invention, the rougher tailings stream may be fed to a bank comprising at least one scavenger flotation cell, producing a scavenger concentrate stream and a scavenger tailings stream. The rougher tailings stream may be fed to the head of the bank comprising at least one scavenger flotation cell, or to any other suitable point within the bank comprising at least one scavenger flotation cell.

Preferably, the scavenger concentrate stream is partly or wholly fed to either the bank comprising at least one cleaner flotation cell or the bank comprising at least one rougher flotation cell. The scavenger concentrate stream may be fed to either the head of the respective banks, or to any other suitable point within the banks.

In some embodiments of the present invention, the scavenger tailings stream may be dewatered and the discharged to a tailings storage area. In an alternative embodiment of the invention, however, the scavenger tailings stream may be discharged directly to a tailings storage area and the water may be decanted from the settled solids.
The tailings storage area may comprise any suitable storage area, such as, but not limited to, a tank or dam.

In another embodiment of the present invention, the cleaner tailings stream may be partly or wholly combined with the scavenger tailings stream, said combined stream being partly or wholly dewatered then discharged to a tailings storage area.
In an alternative embodiment of the invention, however, the partly or wholly combined cleaner and scavenger tailings stream may be discharged directly to a tailings storage area and the water may be decanted from the settled solids. The tailings storage area may comprise any suitable storage area, such as, but not limited to, a tank or dam.

In another embodiment of the present invention, the scavenger tailings stream may be partly or wholly recycled to the head of the bank comprising at least one scavenger flotation cell. Alternatively, the scavenger tailings stream may be fed to any other suitable point within the bank comprising at least one scavenger flotation cell.

Preferably, dewatering is carried out using a thickener. The thickener overflow stream may be recycled to any suitable point within the flotation circuit. In some embodiments of the invention, the thickener overflow stream may be partly or wholly recycled to the bank comprising at least one cleaner flotation cell. The recycling of at least part of the thickener overflow stream to the bank comprising at least one cleaner flotation cell may help to improve dilution cleaning in the bank comprising at least one cleaner flotation cell. In some embodiments of the invention wherein the thickener overflow stream is partly or wholly recycled to the bank comprising at least one cleaner flotation cell, water may be added to the thickener overflow stream.

In a preferred embodiment of the present invention, the flotation cells are naturally aspirated cells, such as, but not limited to, Jameson cells.

In another preferred embodiment of the present invention, the flotation cells are colunm cells, such as, but not limited to, those produced by manufacturers such as CESL and MinnovEX.

Brief Description of the Drawings.

An embodiment of the invention will be described with reference to the following drawings in which:.

Figure 1 illustrates an example of a possible oil sands flotation circuit flowsheet, with rougher, cleaner and scavenger flotation stages according to an embodiment of the present invention.

Best Mode In the embodiment of the invention shown in Figure 1 there is illustrated an oil sands flotation circuit 10 in which a fresh feed stream 11 is fed directly to the feed inlet of a rougher flotation cell 12. In the embodiment of the invention illustrated, the rougher flotation cell 12 is a Jameson cell.

The rougher flotation cell 12 produces a rougher concentrate stream 13 which is fed to the inlet of a cleaner flotation cell 14. In the embodiment of the invention illustrated, the cleaner flotation cell 14 is a Jameson cell. The cleaner flotation cell produces a cleaner concentrate stream 15 which represents the final flotation product of the circuit 10.

The rougher tailings stream 16 may either be partially or wholly recycled 17 to the feed inlet of the rougher flotation cell 12 or may be pumped to a tailings sump 18, 5 from where at least a portion of the stream is pumped to the feed inlet of a scavenger flotation cell 19. In the embodiment of the invention illustrated, the scavenger flotation cell 19 is a Jameson cell.

The scavenger concentrate stream 20 is pumped to a cleaner feed sump 21, where it is combined with the rougher concentrate stream 13 to form the feed stream to the cleaner flotation cell 14.

The scavenger tailings stream 22 is fed to the tailings sump 18, from where it may be wholly or partially recycled 23 to the feed inlet of the scavenger flotation cell 19.
Likewise, the cleaner tailings stream 24 may be partially or wholly recycled to the feed inlet of the cleaner flotation cell 14. Alternatively, the tailings streams from all flotation cells may be partially or wholly combined in the tailings sump 18, from where the combined tailings stream 25 is pumped to a thickener 26 for dewatering.

The thickened slurry that forms the thickener underflow stream 27 is discharged to a tailings storage area (not shown).

In the embodiment of the invention illustrated in Fig 1, the thickener overflow stream 28 may be partially or wholly recycled to the feed inlet of the cleaner flotation cell 14.
The flotation circuit illustrated in Fig 1 provides a number of advantages over existing oil sands flotation circuits. The inclusion of cleaner and scavenger flotation stages in the circuit provides significant increases in the recovery of bitumen, while at the same time increasing the quality of the bitumen concentrate by reducing the amount of sand collected in the flotation process. By reducing the amount of sand collected, significant savings can be made in the downstream processing steps, as the need for further treatment of the concentrate to remove sand may be reduced or removed altogether.

Furthermore, the use of Jameson cells in the flotation circuit provides clear advantages over prior art oil sands flotation circuits.

Jameson cells require significantly less maintenance than conventional mechanical flotation cells, thereby reducing the cost of ongoing maintenance and loss of production due to maintenance shutdowns. In addition, Jameson cells do not require the use of blowers or compressors (unlike with mechanical cells or columns), again saving on maintenance as well as operating costs.

Furthermore, the Jameson cell produces significantly improved contact between bitumen particles and air bubbles due to the high intensity mixing conditions in the downcomer. The high intensity agitation of the particles results in an increased probability of the particles coming into contact with the air bubbles compared to mechanical cells or flotation columns, that rely on long residence times for the collision to take place. This not only decreases the residence time of the flotation circuit, but also eliminates the requirements for large, energy-intensive mixing tanks prior to the flotation circuit required when using mechanical flotation cells.
Additionally, due to the decreased residence time in the circuit, a flotation circuit utilizing Jameson cells requires fewer cells than for an equivalent sized circuit using mechanical flotation cells. This in turn reduces the footprint and associated infrastructure required for the flotation circuit.

Throughout the specification and the claims (if present), unless the context requires otherwise, the term "comprise", or variations such as "comprises" or "comprising", will be understood to apply the inclusion of the stated integer or group of integers but not the exclusion of any other integer or group of integers.

Throughout the specification and claims (if present), unless the context requires otherwise, the term "substantially" or "about" will be understood to not be limited to the value for the range qualified by the terms.
Any embodiment of the invention is meant to be illustrative only and is not meant to be limiting to the invention. Therefore, it should be appreciated that various other changes and modifications can be made to any embodiment described without departing from the spirit and scope of the invention.

Claims (15)

1. An oil sands flotation circuit wherein a feed stream is fed to a bank comprising at least one rougher flotation cell producing a rougher concentrate stream and a rougher tailings stream, said rougher concentrate stream being fed to a bank comprising at least one cleaner flotation cell producing a cleaner concentrate stream and a cleaner tailings stream, and wherein the cleaner concentrate stream comprises the final flotation product of the flotation circuit.
2. An oil sands flotation circuit according to claim 1 wherein the cleaner tailings stream is at least partly recycled to said bank comprising at least one rougher flotation cell.
3. An oil sands flotation circuit according to claim 1 or claim 2 wherein the rougher tailings stream is discharged to a tailings storage area.
4. An oil sands flotation circuit according to claim 3 wherein the rougher tailings stream is at least partly dewatered prior to being discharged to a tailings storage area.
5. An oil sands flotation circuit according to any one of claims 1-4 wherein said rougher tailings stream is partly or wholly fed to a bank comprising at least one scavenger flotation cell producing a scavenger concentrate stream and a scavenger tailings stream.
6. An oil sands flotation circuit according to claim 5 wherein the scavenger concentrate stream is at least partly recycled to either said bank comprising at least one rougher flotation cell or said bank comprising at least one cleaner flotation cell.
7. An oil sands flotation circuit according to claims 5 or 6 wherein the scavenger tailings stream is discharged to a tailings storage area.
8. An oil sands flotation circuit according to claim 7 wherein the scavenger tailings stream is at least partly dewatered prior to being discharged to a tailings storage area
9. An oil sands flotation circuit according to any one of claims 5-8 wherein the cleaner tailings stream is at least partly combined with the scavenger tailings stream, and this combined tailings stream is discharged to a tailings storage area.
10. An oil sands flotation circuit according to claim 9 wherein the combined tailings stream is at least partly dewatered prior to being discharged to a tailings storage area.
11. An oil sands flotation circuit according to claim 5, wherein the scavenger tailings stream is at least partly recycled to the bank comprising at least one scavenger flotation cell.
12. An oil sands flotation circuit according to any one of claims 4, 8 or 10 wherein dewatering is carried out in a thickener.
13. An oil sands flotation circuit according to claim 12 wherein a thickener overflow stream is at least partly recycled to said bank comprising at least one cleaner flotation cell.
14. An oil sands flotation circuit according to any one of the preceding claims wherein the flotation cells are Jameson cells.
15. An oil sands flotation circuit according to any one of claims 1-13 wherein the flotation cells are column cells.
CA2685084A 2007-05-29 2008-05-16 Oil sands flotation Expired - Fee Related CA2685084C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
AU2007902865A AU2007902865A0 (en) 2007-05-29 Oil Sands Flotation
AU2007902865 2007-05-29
PCT/AU2008/000689 WO2008144801A1 (en) 2007-05-29 2008-05-16 Oil sands flotation

Publications (2)

Publication Number Publication Date
CA2685084A1 true CA2685084A1 (en) 2008-12-04
CA2685084C CA2685084C (en) 2014-12-02

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA2685084A Expired - Fee Related CA2685084C (en) 2007-05-29 2008-05-16 Oil sands flotation

Country Status (5)

Country Link
US (1) US20100230326A1 (en)
AU (1) AU2008255615B2 (en)
CA (1) CA2685084C (en)
RU (1) RU2452761C2 (en)
WO (1) WO2008144801A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9334175B2 (en) 2010-07-02 2016-05-10 1501367 Alberta Ltd. Method and apparatus for treatment of fluids
US11857893B2 (en) 2020-08-18 2024-01-02 1501367 Alberta Ltd. Fluid treatment separator and a system and method of treating fluid

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2689729C (en) * 2010-01-11 2017-01-03 1501367 Alberta Ltd. Fluid treatment system
CN106799309A (en) * 2017-01-22 2017-06-06 彝良驰宏矿业有限公司 A kind of method for floating of high efficiency zincblende
CN109622241A (en) * 2019-02-02 2019-04-16 郑州广益达资源新技术有限公司 Multistage mineral gravity flow floatation system and mineral floating method
CN119186838B (en) * 2024-11-27 2025-02-28 湖南轨道芷江庆湾矿业有限公司 A mineral processing equipment for mineral mining

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Publication number Priority date Publication date Assignee Title
US4425227A (en) * 1981-10-05 1984-01-10 Gnc Energy Corporation Ambient froth flotation process for the recovery of bitumen from tar sand
US4576708A (en) * 1984-08-06 1986-03-18 Cities Service Oil & Gas Corp. Beneficiation of shale kerogen and its conversion into shale oil
CA1252409A (en) * 1985-04-11 1989-04-11 Roger St.Amour Process to recover bitumen from mineral slimes resulting from tar sands processing
ATE105510T1 (en) * 1986-09-25 1994-05-15 Univ Newcastle Res Ass COLUMN FLOTATION METHOD AND APPARATUS.
US5316664A (en) * 1986-11-24 1994-05-31 Canadian Occidental Petroleum, Ltd. Process for recovery of hydrocarbons and rejection of sand
US5242580A (en) * 1990-11-13 1993-09-07 Esso Resources Canada Limited Recovery of hydrocarbons from hydrocarbon contaminated sludge
CA2123076C (en) * 1994-05-06 1998-11-17 William Lester Strand Oil sand extraction process
US5968349A (en) * 1998-11-16 1999-10-19 Bhp Minerals International Inc. Extraction of bitumen from bitumen froth and biotreatment of bitumen froth tailings generated from tar sands
CA2524110C (en) * 2005-10-21 2009-04-14 William L. Strand Bitumen recovery process for oil sand
CN101370592A (en) * 2005-12-06 2009-02-18 斯特拉塔技术有限公司 Improved flotation method
US8147682B2 (en) * 2006-10-31 2012-04-03 Syncrude Canada Ltd. Bitumen and thermal recovery from oil sand tailings

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9334175B2 (en) 2010-07-02 2016-05-10 1501367 Alberta Ltd. Method and apparatus for treatment of fluids
US11857893B2 (en) 2020-08-18 2024-01-02 1501367 Alberta Ltd. Fluid treatment separator and a system and method of treating fluid

Also Published As

Publication number Publication date
WO2008144801A1 (en) 2008-12-04
US20100230326A1 (en) 2010-09-16
AU2008255615A1 (en) 2008-12-04
CA2685084C (en) 2014-12-02
AU2008255615B2 (en) 2010-11-04
RU2009148803A (en) 2011-07-10
RU2452761C2 (en) 2012-06-10

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