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DE1923812B2 - Storage material - Google Patents
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DE1923812B2 - Storage material - Google Patents

Storage material

Info

Publication number
DE1923812B2
DE1923812B2 DE1923812A DE1923812A DE1923812B2 DE 1923812 B2 DE1923812 B2 DE 1923812B2 DE 1923812 A DE1923812 A DE 1923812A DE 1923812 A DE1923812 A DE 1923812A DE 1923812 B2 DE1923812 B2 DE 1923812B2
Authority
DE
Germany
Prior art keywords
volume
cadmium
copper
storage material
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE1923812A
Other languages
German (de)
Other versions
DE1923812A1 (en
DE1923812C3 (en
Inventor
George Christopher Chorleywood Herfordshire Pratt (Grossbritannien)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Federal Mogul Engineering Ltd
Original Assignee
Glacier Metal Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB2239868A external-priority patent/GB1271141A/en
Application filed by Glacier Metal Co Ltd filed Critical Glacier Metal Co Ltd
Publication of DE1923812A1 publication Critical patent/DE1923812A1/en
Publication of DE1923812B2 publication Critical patent/DE1923812B2/en
Application granted granted Critical
Publication of DE1923812C3 publication Critical patent/DE1923812C3/en
Expired legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02Parts of sliding-contact bearings
    • F16C33/04Brasses; Bushes; Linings
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0094Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with organic materials as the main non-metallic constituent, e.g. resin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Sliding-Contact Bearings (AREA)
  • Powder Metallurgy (AREA)

Description

Gegenstand einer älteren Anmeldung (P 14 94 079) ist ein Lagermaterial auf der Basis von Polytetrafluoräthylen enthaltend maximal 60Vol.-% Füllstoffe in Form von Blei und/oder Bleioxid sowie Kupfer, Kupferlegierung oder Kupferoxid, wobei der Anteil an Blei-Füllstoff 5 bis 40 VoL-% und der Anteil an Kupfer-Füllstoff 50 bis 1 Vol.-% betragen soll. Nachteilig an einem solchen Lagermaterial ist, daß es bei dessen Verarbeitung durch Sintern zu Explosionen infolge einer Wechselwirkung zwischen dem Kunststoff und dem Bleioxid kommen kann.The subject of an earlier application (P 14 94 079) is a bearing material based on polytetrafluoroethylene Contains a maximum of 60% by volume fillers in the form of lead and / or lead oxide as well as copper, copper alloy or copper oxide, the proportion of lead filler 5 to 40% by volume and the proportion of copper filler 50 to Should be 1% by volume. The disadvantage of such a storage material is that it is processed by Sintering can lead to explosions as a result of an interaction between the plastic and the lead oxide can.

Aus der DT-AS 1065 182 ist ein Lagermaterial auf der Basis eines Metallskeletts bekannt. In der Gleitfläche dieses Lagermaterials befindet sich das Metall des Metallskeletts, Polytetrafluoräthylen und ein Zusatzmetall wie Cadmium. Das Metallskelett ist Sinterbronze, gesinderte Eisenfasern oder ein Metallgewebe. Das Metallskelett ist das stützende Element in dem Lagermaterial, welches den größten Teil der Last aufnimmt Das in die Poren des Metallskeletts imprägnierte Polytetrafluoräthylen steuert zu den Gieiteigenschaften bei. Bei der Herstellung dieses bekannten Lagermaterials findet sich gegebenenfalls über dem Metallskelett eine dünne Schicht aus Polytetrafluoräthylen und Füllstoffen, die jedoch während des Einlaufens vollständig abgetragen werden muß, so daß in der Oberfläche des Lagers das Skelett freigelegt istFrom DT-AS 1065 182 a bearing material based on a metal skeleton is known. In the sliding surface This storage material contains the metal of the metal skeleton, polytetrafluoroethylene and an additional metal like cadmium. The metal skeleton is sintered bronze, sintered iron fibers or a metal mesh. That Metal skeleton is the supporting element in the bearing material that carries most of the load The polytetrafluoroethylene impregnated into the pores of the metal skeleton controls the Sliding properties. In the manufacture of this known bearing material, there may be found Over the metal skeleton a thin layer of polytetrafluoroethylene and fillers, which, however, during of running in must be completely removed, so that the skeleton is in the surface of the bearing is exposed

Gegenstand der Erfindung ist nun ein Lagermaterial auf der Basis von Polytetrafluoräthylen, enthaltend 1 bis 10 VoL-% Kupfer, Kupferlegierung oder Kupferoxid als Füllstoff, welches zusätzlich Wismut, Cadmium oder Cadmiumoxid als Füllstoff enthält wobei die Menge der gesamten Füllstoffe 40VoL-% nicht übersteigen soll. Bevorzugt beträgt der Anteil an zusätzlichem Füllstoff Wismut Cadmium oder Cadmiumoxid 10 bis 20 Vol.-%.The invention now relates to a bearing material based on polytetrafluoroethylene containing 1 to 10% by volume of copper, copper alloy or copper oxide as filler, which also contains bismuth, cadmium or Contains cadmium oxide as a filler, whereby the amount of the total fillers should not exceed 40% by volume. The proportion of additional filler is preferably Bismuth cadmium or cadmium oxide 10 to 20% by volume.

Zum Unterschied von dem obigen bekannten Lager ίο handelt es sich bei dem erfindungsgemäßen Lagermaterial um ein reines Kunststofflager, welches kein Metallskelett besitzt In der Gleitfläche aus dem erfindungsgemäßen Lagermaterial liegt Polytetrafluoräthylen vor, in dem sich gleichmäßig eingebettet die beiden Arten von Füllstoffen befinden. Das erfindungsgemäße Lagermaterial ist eine homogene gefüllte Kunststoffmasse, deren Zusammensetzung über die gesamte Materialstärke gleich ist Mach obigem Stand der Technik befindet sich jedoch das Cadmium zur Imprägnierung des Metallskeletts nur innerhalb der Porenräume des Metallskeletts in Kunststoff verteiltIn contrast to the above known bearing ίο it is the bearing material according to the invention around a pure plastic bearing, which has no metal skeleton In the sliding surface from the Storage material according to the invention is polytetrafluoroethylene, in which the evenly embedded two types of fillers are located. The storage material according to the invention is a homogeneously filled one Plastic compound, the composition of which is the same across the entire material thickness, as stated above In technology, however, the cadmium for impregnating the metal skeleton is only located within the Pore spaces of the metal skeleton distributed in plastic

Es war sehr überraschend, daß man ein Material, welches nach dem Stand der Technik beim Einlaufen entfernt werden muß, um zu dem eigentlichen Lagerwerkstoff zu gelangen, selbst als qualitativ hochwertiges Lagermaterial anwenden kann, denn nach Ansicht dieses Standes der Technik benötigte man zur Lastaufnahme das MetallskelettIt was very surprising to find a material which, according to the prior art, has to be removed when running in to get to the actual To arrive bearing material, even as high quality bearing material can apply, because after According to this state of the art, the metal skeleton was required to take up the load

Das erfindungsgemäße Lagermateria) eignet sich besonders für Lager mit Stützschalen, insbesondere aus Stahl.The storage material according to the invention is particularly suitable for bearings with support shells, in particular from Stole.

Die Erfindung ist an folgenden Beispielen näher erläutert:The invention is explained in more detail using the following examples:

B e i s ρ i e 1 1B e i s ρ i e 1 1

30 Vol.-% Wismut, 10 Vol.-% Kupferoxid, 60 Vol. % Polytetrafluoräthylen.30% by volume bismuth, 10% by volume copper oxide, 60% by volume Polytetrafluoroethylene.

Beispiel 2Example 2

25Vol.-% Cadmiumoxid, 5Vol.-% Bronze (89% Kupfer und 11 % Zinn), 70 Vol.-% Polytetrafluoräthylen.25% by volume cadmium oxide, 5% by volume bronze (89% Copper and 11% tin), 70% by volume polytetrafluoroethylene.

Beispiel 3Example 3

15Vol.-% Cadmium, 15Vol.-°/o Kupfer, 70Vol.-% Polytetrafluoräthylen.15% by volume cadmium, 15% by volume copper, 70% by volume Polytetrafluoroethylene.

Claims (2)

Patentansprüche:Patent claims: 1. Lagermaterial auf der Basis von Polytetrafluorethylen enthaltend 1 bis lOVoL-% Kupfer, eine Kupferlegierung oder ein Kupferoxid als Füllstoff, gekennzeichnet durch einen zusätzlichen Gehalt an Wismut, Cadmium oder Cadmiumoxid als Füllstoffe, wobei die Menge der gesamten Füllstoffe 40 VoL-% nicht übersteigt1. Storage material based on polytetrafluoroethylene containing 1 to 10% copper, a Copper alloy or a copper oxide as a filler, characterized by an additional Content of bismuth, cadmium or cadmium oxide as fillers, the amount of the total fillers Does not exceed 40% by volume 2. Lagermaterial nach Anspruch 1, dadurch gekennzeichnet, daß der Anteil an Wismut, Cadmium oder Cadmiumoxid 10 bis 20 VoL-% beträgt2. Storage material according to claim 1, characterized in that that the proportion of bismuth, cadmium or cadmium oxide is 10 to 20% by volume
DE1923812A 1961-01-09 1969-05-09 Storage material Expired DE1923812C3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEG0031335 1961-01-09
GB2239868A GB1271141A (en) 1968-05-10 1968-05-10 Plain bearing material

Publications (3)

Publication Number Publication Date
DE1923812A1 DE1923812A1 (en) 1969-12-04
DE1923812B2 true DE1923812B2 (en) 1978-06-08
DE1923812C3 DE1923812C3 (en) 1979-02-01

Family

ID=25978318

Family Applications (2)

Application Number Title Priority Date Filing Date
DE19611494079 Withdrawn DE1494079A1 (en) 1961-01-09 1961-01-09 Bearing material for plain bearings
DE1923812A Expired DE1923812C3 (en) 1961-01-09 1969-05-09 Storage material

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE19611494079 Withdrawn DE1494079A1 (en) 1961-01-09 1961-01-09 Bearing material for plain bearings

Country Status (1)

Country Link
DE (2) DE1494079A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2052513C2 (en) * 1970-10-26 1984-05-24 Ed. Scharwächter GmbH & Co KG, 5630 Remscheid Motor vehicle door hinge pin - has calibrating pins on end led through eye-hole with partially pliable filling
DE2100164C2 (en) * 1971-01-04 1987-02-19 Ed. Scharwächter GmbH & Co KG, 5630 Remscheid Hinge pin bearing on a hinge with maintenance-free hinge pin
DE50200928D1 (en) * 2002-04-15 2004-10-07 Grieder Ruenenberg Lab Additive to improve the bioenergetic properties of inorganic or organic substances, especially mineral building materials

Also Published As

Publication number Publication date
DE1923812A1 (en) 1969-12-04
DE1923812C3 (en) 1979-02-01
DE1494079A1 (en) 1969-02-13
DE1494079B2 (en) 1970-09-10

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
EHJ Ceased/non-payment of the annual fee