EP0234299B2 - Starter bar head for a steel band casting machine - Google Patents
Starter bar head for a steel band casting machine Download PDFInfo
- Publication number
- EP0234299B2 EP0234299B2 EP87101021A EP87101021A EP0234299B2 EP 0234299 B2 EP0234299 B2 EP 0234299B2 EP 87101021 A EP87101021 A EP 87101021A EP 87101021 A EP87101021 A EP 87101021A EP 0234299 B2 EP0234299 B2 EP 0234299B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- connecting element
- chill mould
- mold
- connector
- strip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005266 casting Methods 0.000 title claims abstract description 8
- 229910000831 Steel Inorganic materials 0.000 title claims description 17
- 239000010959 steel Substances 0.000 title claims description 17
- 239000007858 starting material Substances 0.000 title 1
- 238000007789 sealing Methods 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims 1
- 239000002184 metal Substances 0.000 abstract description 3
- 238000001816 cooling Methods 0.000 description 5
- 229910001208 Crucible steel Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/10—Supplying or treating molten metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/08—Accessories for starting the casting procedure
- B22D11/081—Starter bars
- B22D11/083—Starter bar head; Means for connecting or detaching starter bars and ingots
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/08—Accessories for starting the casting procedure
Definitions
- the invention relates to a starting head for a Steel strip caster, one with a top lower part that can be inserted into the mold a sealing paint made of refractory material is covered and protrusions reaching into the mold space are provided.
- US-A 3,262,161 is a start-up line known for slab formats, two in its head Rows of connecting bolts side by side are attached by anchor pins. On the surface the start-up line is a flexible, heat-resistant Painted considerably on the edges protrudes from the head and when inserted into the mold in a space on all sides is pressed in and seals it. The painting is through on the head of the start-up line held a metal plate. The between plate and The gap remaining in the mold walls is heat-resistant Material filled and can be with scrap covered on the walls.
- the object of the invention is to create a Starting head for steel strip casting molds with one outside the mold quickly, easily and precisely secure seal to be attached, being without Using refrigerated scrap is a faster resilient Connection to cast tape formed becomes.
- the steel strip casting mold with all-round Distance filling connecting element with upper projections while saving Sealing material and difficult manual work inside a narrow mold space without using Refrigerated scrap a quick and firm sprue connection to the first flowing liquid steel educated. It was surprisingly found that through the cold surfaces of the connector a stronger cooling effect is achieved than due to the low mass of the due to its air inclusion first of all isolating cooling scrap.
- the connecting element with the matching flat gasket and steel plate to the casting format connected in one operation to the lower part one exact centering is guaranteed by the screws. Due to the steel plate, the seal is when inserted into the Mold held securely and protected when poured on. The connecting element leads to a through its large cooling volume rapid cooling and thus an immediately resilient connection between the start head and the cast belt. Another The advantage is that only the outermost edge of the seal comes into contact with the melt, so that a multiple use is possible.
- Form in the illustrated steel strip casting mold two opposite broad side walls 1, 2 and two between parallel side areas of the Broad side walls 1, 2 arranged narrow side walls 3, 4 the molding space. For cooling, they are Broad side walls 1, 2 and the narrow side walls 3, 4 provided with channels 5.
- the broad side walls 1, 2 form an extended pouring area in the middle 6 into which a pouring tube 7 projects.
- transverse grooves 14 of the lower part 8 are screws 15 held with their heads by the corresponding gaskets provided with flat holes 11, steel plate 12 and connecting element 9 are clamped by means of nuts 16. The screws 15 are used to solve the lower part 8 of connecting element connected to the cast steel strip 9 sideways from the transverse grooves 14 driven out.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Continuous Casting (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Coating With Molten Metal (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Fireproofing Substances (AREA)
- Braking Arrangements (AREA)
- Joining Of Building Structures In Genera (AREA)
- Moulds, Cores, Or Mandrels (AREA)
- Manufacturing Of Tubular Articles Or Embedded Moulded Articles (AREA)
- Preliminary Treatment Of Fibers (AREA)
Abstract
Description
Die Erfindung betrifft einen Anfahrkopf für eine Stahlbandgießanlage, wobei ein mit einer Oberseite teilweise in die Kokille einbringbares Unterteil mit einer abdichtenden Malte aus feuerfestem Material bedeckt ist und in den Kokillenraum reichende Vorsprünge vorgesehen sind.The invention relates to a starting head for a Steel strip caster, one with a top lower part that can be inserted into the mold a sealing paint made of refractory material is covered and protrusions reaching into the mold space are provided.
Durch die US-A 3 262 161 ist ein Anfahrstrang für Brammenformate bekannt, in dessen Kopf zwei Reihen von Verbindungsbolzen nebeneinander durch Ankerstifte befestigt sind. An der Oberfläche des Anfahrstranges befindet sich eine flexible, wärmebeständige Malte, die beträchtlich an den Rändern des Kopfes übersteht und beim Einschieben in die Kokille in einem allseitigen Zwischenraum hineingedrückt wird und diesen abdichtet. Die Malte wird auf dem Kopf des Anfahrstranges durch eine Metallplatte gehalten. Der zwischen Platte und den Kokillenwänden verbleibende Spalt ist mit wärmebeständigem Material gefüllt und kann mit Kühlschrott an den Wänden erhöht überdeckt werden.US-A 3,262,161 is a start-up line known for slab formats, two in its head Rows of connecting bolts side by side are attached by anchor pins. On the surface the start-up line is a flexible, heat-resistant Painted considerably on the edges protrudes from the head and when inserted into the mold in a space on all sides is pressed in and seals it. The painting is through on the head of the start-up line held a metal plate. The between plate and The gap remaining in the mold walls is heat-resistant Material filled and can be with scrap covered on the walls.
Die Verwendung von Kühlschrott verlängert die Vorbereitungszeit und führt zum Verkratzen der Kokillenwände und nachgeordneter Stützführungselemente. Darüber hinaus ist der bekannte aufwendige Anfahrkopf für Kokillen von Stahlbandgießanlagen wegen der formatbedingt schlechten Zugänglichkeit und Kontrollmöglichkeit nicht geeignet.The use of refrigerated scrap extends the Preparation time and leads to scratching the Mold walls and downstream support guide elements. In addition, the well-known start-up head for molds of steel strip caster because of the format-related poor accessibility and Control option not suitable.
Aufgabe der Erfindung ist die Schaffung eines Anfahrkopfes für Stahlbandgießkokillen mit einer außerhalb der Kokille schnell, einfach und exakt anzubringenden sicheren Abdichtung, wobei ohne Verwendung von Kühlschrott eine schneller belastbare Verbindung zu gegossenen Band gebildet wird.The object of the invention is to create a Starting head for steel strip casting molds with one outside the mold quickly, easily and precisely secure seal to be attached, being without Using refrigerated scrap is a faster resilient Connection to cast tape formed becomes.
Diese Aufgabe wird durch den Anfahrkopf nach
Anspruch 1 gelöst.This task is carried out by the
Bei einem derartigen Anfahrkopf wird durch das die Stahlbandgießkokille mit allseitigem Abstand ausfüllende Verbindungselement mit oberen Vorsprüngen bei Einsparung von Dichtmaterial und schwieriger Handarbeit innerhalb eines engen Formraumes ohne Verwendung von Kühlschrott eine schnelle und feste Angießverbindung zu dem zuerst einströmenden flüssigen Stahl gebildet. Überraschend wurde festgestellt, daß durch die kalten Oberflächen des Verbindungselements eine stärkere Kühlwirkung erzielt wird als durch die geringe Masse des aufgrund seines Lufteinschlusses zuerst isolierend wirkenden Kühlschrotts. With such a start-up head, the steel strip casting mold with all-round Distance filling connecting element with upper projections while saving Sealing material and difficult manual work inside a narrow mold space without using Refrigerated scrap a quick and firm sprue connection to the first flowing liquid steel educated. It was surprisingly found that through the cold surfaces of the connector a stronger cooling effect is achieved than due to the low mass of the due to its air inclusion first of all isolating cooling scrap.
Bei dem neuen Anfahrkopf wird das Verbindungselement mit der zum Gießformat passenden Flachdichtung und der Stahlplatte in einem Arbeitsgang mit dem Unterteil verbunden, wobei eine exakte Zentrierung durch die Schrauben gewährleistet ist. Durch die Stahlplatte ist die Dichtung beim Einführen in die Kokille sicher gehalten und beim Angießen geschützt. Das Verbindungselement führt durch sein großes Kühlvolumen zu einer schnellen Abkühlung und damit zu einer sofort belastbaren Verbindung zwischen Anfahrkopf und gegossenem Band. Ein weiterer Vorteil besteht darin, daß nur der äußerste Rand der Dichtung mit der Schmelze in Kontakt kommt, so daß eine mehrfache Benutzung möglich ist.With the new start head, the connecting element with the matching flat gasket and steel plate to the casting format connected in one operation to the lower part, one exact centering is guaranteed by the screws. Due to the steel plate, the seal is when inserted into the Mold held securely and protected when poured on. The connecting element leads to a through its large cooling volume rapid cooling and thus an immediately resilient connection between the start head and the cast belt. Another The advantage is that only the outermost edge of the seal comes into contact with the melt, so that a multiple use is possible.
Es wurde festgestellt, daß der flüssige Stahl bereits in dem Spalt zwischen Verbindungselement und Kokillenwand erstarrt und nur in geringem Maße bis zur Dichtung fließt. It was found that the molten steel was already in the The gap between the connecting element and the mold wall solidifies and only flows to a small extent to the seal.
Weitere Ausgestaltungen der Erfindung ergeben
sich aus den Ansprüchen 2 und 3.Further configurations of the invention result
themselves from
In der Zeichnung ist ein Ausführungsbeispiel der Erfindung dargestellt. Es zeigen
- Fig. 1
- den Querschnitt einer Stahlbandgießkokille mit eingeschobenem Anfahrkopf und
- Fig. 2
- eine Innenansicht in Richtung einer Breitseitenwand mit davorstehendem Anfahrkopf.
- Fig. 1
- the cross section of a steel strip casting mold with inserted start-up head and
- Fig. 2
- an interior view in the direction of a broad side wall with the starting head protruding.
Bei der dargestellten Stahlbandgießkokille bilden
zwei gegenüberliegende Breitseitenwände 1, 2
und zwei zwischen parallelen Seitenbereichen der
Breitseitenwände 1, 2 angeordnete Schmalseitenwände
3, 4 den Formraum. Zur Kühlung sind die
Breitseitenwände 1, 2 und die Schmalseitenwände
3, 4 mit Kanälen 5 versehen. Die Breitseitenwände
1, 2 formen zu ihrer Mitte einen erweiterten Eingießbereich
6 in den ein Gießrohr 7 hineinragt.Form in the illustrated steel strip casting mold
two opposite
Zum Verschließen der Kokille und als Auszugsverbindung
befindet sich im unteren Teil der Kokille
ein aus einem Unterteil 8 und einem Verbindungselement
9 bestehender Anfahrkopf. Der mit
einem Auszugselement 10 verbundene Unterteil 8
des Anfahrkopfes füllt die Kokille mit geringem
Spiel aus. Auf der ebenen Oberfläche des Unterteils
8 liegt eine Flachdichtung 11, die durch eine
dem Format des Unterteils 8 entsprechende Stahlplatte
12 gehalten ist. Die als Keramikfasermatte
ausgebildete Flachdichtung 11 weist einen geringen
Überstand gegenüber der Kokillenöffnung auf,
so daß innerhalb der Kokille eine allseitig dichtende
Anlage gewährleistet ist.To close the mold and as a pull-out connection
is in the lower part of the mold
one of a
Auf der Stahlplatte 12 ist das Verbindungselement
9 aufgesetzt, das einen allseitigen Abstand a
zu den Kokillenwänden 1, 2, 3, 4 hat und an seiner
Oberseite mit pilzartigen Vorsprüngen 13 versehen
ist. In Quernuten 14 des Unterteils 8 sind Schrauben
15 mit ihren Köpfen gehalten, durch die mit
entsprechenden Bohrungen versehenen Flachdichtungen
11, Stahlplatte 12 und Verbindungselement
9 mittels Muttern 16 verspannt sind. Die Schrauben
15 werden zur Lösung des Unterteils 8 vom mit
dem gegossenen Stahlband verbundenen Verbindungselement
9 seitwärts aus den Quernuten 14
herausgetrieben.On the
Claims (3)
- Starting head for a steel strip casting plant, wherein a lower part (8), which is partly introducible by an upper side into the chill mould and which fills up the chill mould with a small play, is covered by a sealing mat (11) of fireproof material, wherein the sealing mat is held, with a small projection all round relative to the chill mould opening, by a steel plate (12), which corresponds with the format of the lower part (8), and projections (13) reaching into the chill mould chamber are provided, characterised in that the projections (13) are disposed at a connecting element (9) which is detachably clamped on the lower part (8) and which is placed on the steel plate (12), that the connecting element (9) fills up the chill mould by a spacing (a) at all sides and that the connecting element (9) consists of a base plate with upper mushroom-shaped projections.
- Starting head according to claim 1, characterised in that the spacing a of the connecting element (9) relative to the chill mould walls (1, 2, 3, 4) amounts to about 5 to 15 millimetres.
- Starting head according to claim 1, characterised in that the connecting element (9) is connected with the lower part (8) by screws (15), the heads of which are held in transverse grooves (14) in the lower part (8).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT87101021T ATE75172T1 (en) | 1986-02-03 | 1987-01-26 | STARTING HEAD FOR A STEEL STRIP CASTING PLANT. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19863603190 DE3603190A1 (en) | 1986-02-03 | 1986-02-03 | START-UP HEAD FOR A STEEL TAPE CASTING SYSTEM |
| DE3603190 | 1986-02-03 |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| EP0234299A2 EP0234299A2 (en) | 1987-09-02 |
| EP0234299A3 EP0234299A3 (en) | 1989-03-01 |
| EP0234299B1 EP0234299B1 (en) | 1992-04-22 |
| EP0234299B2 true EP0234299B2 (en) | 1999-07-28 |
Family
ID=6293220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP87101021A Expired - Lifetime EP0234299B2 (en) | 1986-02-03 | 1987-01-26 | Starter bar head for a steel band casting machine |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US4719960A (en) |
| EP (1) | EP0234299B2 (en) |
| JP (1) | JPH06102260B2 (en) |
| KR (1) | KR960002405B1 (en) |
| CN (1) | CN1007325B (en) |
| AT (1) | ATE75172T1 (en) |
| BR (1) | BR8700462A (en) |
| CA (1) | CA1281529C (en) |
| DD (1) | DD253387A5 (en) |
| DE (2) | DE3603190A1 (en) |
| ES (1) | ES2030396T5 (en) |
| GR (1) | GR3004450T3 (en) |
| IN (1) | IN169621B (en) |
| MX (1) | MX166838B (en) |
| SU (1) | SU1554756A3 (en) |
| UA (1) | UA6337A1 (en) |
| ZA (1) | ZA87321B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102021213770A1 (en) | 2021-12-03 | 2023-06-07 | Sms Group Gmbh | Sealing system for a continuous casting plant |
| WO2024094846A1 (en) | 2022-11-04 | 2024-05-10 | Sms Group Gmbh | Sealing system for use with a dummy bar head of a continuous casting system and method for producing a metal product by means of continuous casting using the sealing system |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3742190A1 (en) * | 1987-12-12 | 1989-06-22 | Schloemann Siemag Ag | START-UP HEAD FOR A STEEL TAPE CASTING SYSTEM |
| DE3801932A1 (en) * | 1988-01-23 | 1989-08-03 | Schloemann Siemag Ag | METHOD FOR CASTING A STEEL STRIP IN A STEEL STRIP CASTING SYSTEM |
| DE3834410A1 (en) * | 1988-10-10 | 1990-04-12 | Schloemann Siemag Ag | START-UP DEVICE FOR A STEEL TAPE CASTING SYSTEM |
| DE4124014C2 (en) * | 1991-07-19 | 1999-03-11 | Schloemann Siemag Ag | Starting device for a steel strip caster |
| AT399834B (en) * | 1993-02-12 | 1995-07-25 | Voest Alpine Ind Anlagen | START-UP HEAD FOR A CONTINUOUS CASTING SYSTEM |
| US6315497B1 (en) | 1995-12-29 | 2001-11-13 | Shell Oil Company | Joint for applying current across a pipe-in-pipe system |
| AT411822B (en) * | 2002-09-12 | 2004-06-25 | Voest Alpine Ind Anlagen | METHOD AND DEVICE FOR STARTING A CASTING PROCESS |
| ES2400704T3 (en) * | 2008-05-23 | 2013-04-11 | Concast Ag | Cold bar head sealing system in a shell of a continuous casting installation for casting large format preliminary profiles |
| KR20130088841A (en) * | 2010-06-30 | 2013-08-08 | 지멘스 브이에이아이 메탈스 테크놀로지스 게엠베하 | Initial casting part, dummy bar head, and dummy bar for a continuous casting machine for casting preliminary profiles |
| CN102380590B (en) * | 2011-11-14 | 2013-06-26 | 振石集团东方特钢股份有限公司 | Method for pouring plate blank stainless steel |
| CN102836981B (en) * | 2012-08-17 | 2014-04-30 | 秦皇岛首秦金属材料有限公司 | Design method for adjustment of driving roller of thick slab continuous casting machine |
| JP2019166724A (en) | 2018-03-23 | 2019-10-03 | セイコーエプソン株式会社 | Recording method and inkjet recording device |
| CN115055655A (en) * | 2022-05-14 | 2022-09-16 | 江阴兴澄特种钢铁有限公司 | A pouring device and method for large-sized continuous casting round billets |
| CN115106487A (en) * | 2022-05-14 | 2022-09-27 | 江阴兴澄特种钢铁有限公司 | Method for placing cold material of ultra-large-specification continuous casting round billet seal dummy ingot |
| DE102023210885A1 (en) | 2022-11-04 | 2024-05-08 | Sms Group Gmbh | Sealing system for use with a cold strand head of a continuous casting plant and method for producing a metallic product by continuous casting using the sealing system |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE649902A (en) * | 1963-06-27 | |||
| US3338297A (en) * | 1964-03-06 | 1967-08-29 | United States Steel Corp | Apparatus for bending a casting having a liquid core |
| FR1586893A (en) * | 1968-07-17 | 1970-03-06 | ||
| US3653427A (en) * | 1969-08-12 | 1972-04-04 | Mitsubishi Heavy Ind Ltd | Dummy bar mechanism |
| AT352924B (en) | 1978-03-25 | 1979-10-10 | Voest Ag | ACCESS LINE FOR CONTINUOUS CASTING PLANTS |
| CH659016A5 (en) | 1982-12-20 | 1986-12-31 | Concast Service Union Ag | METHOD AND DEVICE FOR SEALING A STARTING HEAD IN A CONTINUOUS CASTING COIL. |
| DE3306186C2 (en) * | 1983-02-23 | 1985-08-08 | Mannesmann AG, 4000 Düsseldorf | Method and device for casting in horizontal continuous casting |
| DE3400220A1 (en) * | 1984-01-05 | 1985-07-18 | SMS Schloemann-Siemag AG, 4000 Düsseldorf | CHOCOLATE FOR CONTINUOUSLY STEEL STRIP |
-
1986
- 1986-02-03 DE DE19863603190 patent/DE3603190A1/en not_active Withdrawn
-
1987
- 1987-01-13 IN IN15/MAS/87A patent/IN169621B/en unknown
- 1987-01-16 ZA ZA87321A patent/ZA87321B/en unknown
- 1987-01-26 ES ES87101021T patent/ES2030396T5/en not_active Expired - Lifetime
- 1987-01-26 AT AT87101021T patent/ATE75172T1/en not_active IP Right Cessation
- 1987-01-26 DE DE8787101021T patent/DE3778394D1/en not_active Expired - Lifetime
- 1987-01-26 EP EP87101021A patent/EP0234299B2/en not_active Expired - Lifetime
- 1987-01-28 DD DD87299514A patent/DD253387A5/en not_active IP Right Cessation
- 1987-01-30 MX MX005106A patent/MX166838B/en unknown
- 1987-02-02 BR BR8700462A patent/BR8700462A/en not_active IP Right Cessation
- 1987-02-02 UA UA4028883A patent/UA6337A1/en unknown
- 1987-02-02 KR KR1019870000812A patent/KR960002405B1/en not_active Expired - Lifetime
- 1987-02-02 JP JP62020628A patent/JPH06102260B2/en not_active Expired - Lifetime
- 1987-02-02 US US07/009,809 patent/US4719960A/en not_active Expired - Lifetime
- 1987-02-02 SU SU874028883A patent/SU1554756A3/en active
- 1987-02-03 CN CN87100519A patent/CN1007325B/en not_active Expired
- 1987-02-03 CA CA000528874A patent/CA1281529C/en not_active Expired - Lifetime
-
1992
- 1992-04-23 GR GR920400743T patent/GR3004450T3/el unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102021213770A1 (en) | 2021-12-03 | 2023-06-07 | Sms Group Gmbh | Sealing system for a continuous casting plant |
| WO2023099141A1 (en) | 2021-12-03 | 2023-06-08 | Sms Group Gmbh | Sealing system for a continuous casting plant |
| WO2024094846A1 (en) | 2022-11-04 | 2024-05-10 | Sms Group Gmbh | Sealing system for use with a dummy bar head of a continuous casting system and method for producing a metal product by means of continuous casting using the sealing system |
Also Published As
| Publication number | Publication date |
|---|---|
| GR3004450T3 (en) | 1993-03-31 |
| EP0234299A2 (en) | 1987-09-02 |
| EP0234299B1 (en) | 1992-04-22 |
| ES2030396T5 (en) | 2000-01-16 |
| JPH06102260B2 (en) | 1994-12-14 |
| DE3603190A1 (en) | 1987-08-06 |
| CN87100519A (en) | 1987-08-19 |
| ATE75172T1 (en) | 1992-05-15 |
| CN1007325B (en) | 1990-03-28 |
| ES2030396T3 (en) | 1992-11-01 |
| DD253387A5 (en) | 1988-01-20 |
| IN169621B (en) | 1991-11-23 |
| EP0234299A3 (en) | 1989-03-01 |
| BR8700462A (en) | 1987-12-08 |
| MX166838B (en) | 1993-02-09 |
| UA6337A1 (en) | 1994-12-29 |
| US4719960A (en) | 1988-01-19 |
| ZA87321B (en) | 1987-10-28 |
| DE3778394D1 (en) | 1992-05-27 |
| JPS63165051A (en) | 1988-07-08 |
| KR870007739A (en) | 1987-09-21 |
| CA1281529C (en) | 1991-03-19 |
| SU1554756A3 (en) | 1990-03-30 |
| KR960002405B1 (en) | 1996-02-17 |
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