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EP0455990B2 - Nappe non tissée lien fondu fortifiée chaleur stable et procédé de sa fabrication - Google Patents
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EP0455990B2 - Nappe non tissée lien fondu fortifiée chaleur stable et procédé de sa fabrication - Google Patents

Nappe non tissée lien fondu fortifiée chaleur stable et procédé de sa fabrication Download PDF

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Publication number
EP0455990B2
EP0455990B2 EP91105398A EP91105398A EP0455990B2 EP 0455990 B2 EP0455990 B2 EP 0455990B2 EP 91105398 A EP91105398 A EP 91105398A EP 91105398 A EP91105398 A EP 91105398A EP 0455990 B2 EP0455990 B2 EP 0455990B2
Authority
EP
European Patent Office
Prior art keywords
filaments
binder
load
carrying
melting point
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP91105398A
Other languages
German (de)
English (en)
Other versions
EP0455990B1 (fr
EP0455990A1 (fr
Inventor
Günther Dr. Vock
Michael Schöps
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johns Manville
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Hoechst AG filed Critical Hoechst AG
Publication of EP0455990A1 publication Critical patent/EP0455990A1/fr
Application granted granted Critical
Publication of EP0455990B1 publication Critical patent/EP0455990B1/fr
Publication of EP0455990B2 publication Critical patent/EP0455990B2/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/14Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
    • D04H3/153Mixed yarns or filaments
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/009Condensation or reaction polymers
    • D04H3/011Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/14Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • DTEXTILES; PAPER
    • D05SEWING; EMBROIDERING; TUFTING
    • D05CEMBROIDERING; TUFTING
    • D05C17/00Embroidered or tufted products; Base fabrics specially adapted for embroidered work; Inserts for producing surface irregularities in embroidered products
    • D05C17/02Tufted products
    • D05C17/023Tufted products characterised by the base fabric
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/92Fire or heat protection feature
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2929Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/681Spun-bonded nonwoven fabric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/697Containing at least two chemically different strand or fiber materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/699Including particulate material other than strand or fiber material

Definitions

  • the invention relates to a thermally stable enamel-bonded spunbond made of load-bearing Filaments and serving as enamel binders Binder filaments in which the difference of Melting points of load-bearing and binding filaments is less than 30 ° C.
  • DE-C-14 35 114 is a nonwoven fabric known that contains crimped fibers or threads and that by means of a thermoplastic binder or thermoplastic binding fibers Heating is solidified.
  • the melting point of the binding fibers should be at least 20 ° C below the Melting point of the supporting filaments. Due to the proportion of crimped fibers in This nonwoven fabric is very drapable, i.e. he creases like a woven fabric; but it is as highly resilient and dimensionally stable reinforcement material and not usable as a tufted carrier.
  • Highly resilient spunbonded nonwovens bonded with melt binders are known, for example, from DE-PS 22 40 437 and DE-A-36 42 089. These previously known spunbonded nonwovens, in which both the supporting filaments and the binder filaments can consist of polyesters, serve in particular as reinforcing and carrier materials in the manufacture of needled felt and tufting.
  • filaments of a relatively coarse individual titer of more than 8 dtex are used.
  • the proportion of binder filaments is 10 to 30%, preferably between 15 and 25%.
  • individual titres of 5 or 12 dtex are given in the examples; the proportion of binder filaments is between 10 and 50%. preferably between 15 and 30%.
  • the weight per unit area is stated to be greater than 120 g / m 2 .
  • DE-PS 22 40 437 emphasizes that a relatively large distance between the Melting point of the supporting filaments and the the binder filaments must be observed, the minimum Must be 30 ° C. This is to ensure that when the nonwoven solidifies, a thermal damage to the supporting filaments is excluded.
  • This instruction is in a more recent publication, DE-OS 36 42 089 further tightened: there the difference of Melting points of load bearing and binder filaments even be at least 90 ° C. That's why there are polyolefin filaments as binder filaments prefers.
  • melt-bonded spunbonded nonwoven made of supporting polyester filaments and binder filaments is known, the melting point of the latter binder filaments being 10 ° C. below the melting point of the supporting polyester filaments.
  • the disclosed melt-bond-strengthened spunbonded fabrics have a weight per unit area of 50 to 100 g / m 2 .
  • the present invention now relates to a melt-bond-bonded nonwoven fabric with high strength and high dimensional stability, which is thermally highly resilient, ie which has an extremely advantageous high processing and use temperature.
  • the melt-bond-strengthened spunbonded web consists of load-bearing filaments and binder filaments serving as melt binders, and is characterized in that the melting point of the binder filaments is less than 30 ° C., preferably less than 20 ° C., below the melting point of the load-bearing filaments, with the exception of such spunbonded webs whose basis weight is between 50 and 100 g / m 2 .
  • the supporting filaments and binder filaments are preferably made of polyester.
  • the basis weight of the spunbonded nonwovens according to the invention is generally in the range between 50 and 500 g / m 2 , preferably between 50 and 250 g / m 2 , but can of course also be selected to be lower or higher for special applications, with the result that such spunbonded nonwovens are excluded from their basis weight is between 50 and 100 g / m 2 .
  • the individual titer of the supporting filaments and binder filaments is preferably in the range between 1 and 20 dtex and the proportion of the binder filaments is preferably between 5 and 25 percent by weight.
  • Spunbonded fabrics according to the invention are preferred in which the individual titer of the binder filaments is smaller than that of the supporting filaments.
  • Those spunbonded webs according to the invention in which the melting point of the binder filaments is 10 to 20 ° C. below the melting point of the supporting filaments are particularly preferred.
  • the spunbonded fabrics according to the invention consist of load-bearing filaments made of polyethylene terephthalate, during the melt binder from a polymer exists, whose melting point is the above Difference to the melting point of the supporting filaments having.
  • the binder filaments preferably consist from an isophthalic acid modified Polyester with a correspondingly slightly lowered Melting point.
  • the proportion of binder filaments in the total weight of the spunbonded nonwovens according to the invention is chosen to be as low as possible within the range given above and is adapted to the intended use of the nonwovens. Lower binder proportions further improve the thermal and mechanical properties, while higher binder proportions result in particularly delamination-resistant nonwovens.
  • the weight per unit area of the nonwovens according to the invention and the individual titer of the filaments are chosen within the ranges specified above depending on the area of use. For example, a basis weight of up to 500 g / m 2 and a single titer of up to 20 dtex are expediently chosen for a tufting carrier.
  • the supporting filaments and binder filaments consist of flame-retardant modified polyesters.
  • a further preferred embodiment of the nonwovens according to the invention has a layer structure of supporting filaments and binder filaments, it being particularly advantageous if the two outer layers do not contain any binder filaments.
  • spunbonded nonwovens according to the invention are preferred, the binder filaments of which contain an antistatic, in particular carbon black.
  • a further special embodiment of the nonwovens according to the invention does not contain separate binder filaments but bicomponent filaments in a core-shell or side-by-side arrangement, which are made up of the two polymers for the load-bearing and the binding filaments in the desired ratio.
  • the spun-bonded nonwoven formed according to the invention is free from resinous binders and is therefore inherently flame-retardant.
  • the low flammability can be further improved by suitable selection of flame-retardant modified raw materials for the supporting filaments and the binder filaments.
  • These flame-retardant spunbonded fabrics can then also be used in rooms at risk of fire, e.g. B. as a carrier material for curtains, wallpaper, blinds, or as components for seat covers in vehicles or aircraft.
  • Particularly voluminous spunbonded fabrics according to the invention are also preferred, such as those using a rel. small proportion of binder filaments and sieve drum fixation can be obtained. These then also have a loose, fibrous surface structure, which significantly increases the adhesion of coating materials, PVC or bitumen. Such voluminous spunbonded nonwovens with a fiber-rich surface are also suitable for the production of filter fabrics.
  • the addition of antistatic agents, in the simplest case of soot, in the melting cylinder also permits the use of the spun-bonded nonwoven according to the invention in potentially explosive zones or as a filter medium for clean rooms.
  • the dyeability of the melt binder can be adapted to that of the supporting filaments by modifying the melt binder raw material; on the other hand, different dyeability can also be used to create interesting color effects.
  • the spunbonded nonwoven according to the invention is produced in a manner known per se by depositing load-bearing filaments and binder filaments on a moving screen base to form a tangled nonwoven, and is characterized in that binder filaments are deposited whose melting point is less than 30 ° C., preferably less than 20 ° C. , is below the melting point of the supporting filaments.
  • Load-bearing filaments and binder filaments which consist of polyester, are preferably deposited.
  • the amount of filaments deposited per m 2 is measured according to the criteria given above; as a rule, 50 to 500 g of filaments are deposited per m 2 .
  • Filament is preferably deposited using a rotating baffle plate and a downstream guide surface as described in DE-PS 27 13 241.
  • the filament is deposited by a plurality of rows of depositing elements, one behind the other in the direction of movement of the screen support, from which alternating load-bearing and binding filaments are deposited.
  • the polymers for the supporting filaments and the binder filaments are spun out and deposited as bicomponent filaments in the specified ratio.
  • the needles are not needled Filaments, just thermal pre-consolidation, as for example in DE-PS 33 22 936 is described, and an adjoining final thermal solidification, e.g. with smooth or profiled roller.
  • basis weights may result in needling a further improvement in the nonwoven properties to lead.
  • the thermal consolidation is particularly preferably carried out by hot air, for example in screen drum fixers, which can be followed by a pair of embossing rollers.
  • Particularly voluminous spunbonded nonwovens result from the lowest possible proportion of binder filaments and a sieve drum fixation.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nonwoven Fabrics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Artificial Filaments (AREA)
  • Multicomponent Fibers (AREA)
  • Reinforcement Elements For Buildings (AREA)

Claims (18)

  1. Nappe non tissée consolidée par des liants à bas points de fusion, constituée de filaments porteurs et de filaments liants servant de liants à bas point de fusion, caractérisée en ce que le point de fusion des filaments liants est de moins de 30°C inférieur au point de fusion des filaments porteurs, en excluant de telles nappes non tissées, dont la masse surfacique est comprise entre 50 et 100 g/m2.
  2. Nappe non tissée selon la revendication 1, caractérisée en ce que les filaments porteurs et les filaments liants sont en polyester.
  3. Nappe non tissée selon au moins l'une des revendications précédentes, caractérisée en ce que le titre unitaire des filaments porteurs et des filaments liants est compris entre 1 et 20 dtex.
  4. Nappe non tissée selon au moins l'une des revendications précédentes, caractérisée en ce que la quantité des filaments liants est comprise entre 5 et 25 % en poids.
  5. Nappe non tissée selon au moins l'une des revendications précédentes, caractérisée en ce que le titre unitaire des filaments liants est inférieur à celui des filaments porteurs.
  6. Nappe non tissée selon au moins l'une des revendications précédentes, caractérisée en ce que les filaments porteurs sont en poly(téréphtalate d'éthylène).
  7. Nappe non tissée selon au moins l'une des revendications précédentes, caractérisée en ce que le point de fusion des filaments liants est de moins de 20°C inférieur au point de fusion des filaments porteurs.
  8. Nappe non tissée selon au moins l'une des revendications précédentes, caractérisée en ce que le point de fusion des filaments liants est de 10 à 20°C inférieur au point de fusion des filaments porteurs.
  9. Nappe non tissée selon au moins l'une des revendications précédentes, caractérisée en ce que les filaments liants sont constitués d'un polyester modifié par l'acide isophtalique avec un point de fusion correspondant abaissé.
  10. Nappe non tissée selon au moins l'une des revendications précédentes, caractérisée en ce que les filaments porteurs et les filaments liants sont constitués de polyesters rendus ignifuges.
  11. Nappe non tissée selon au moins l'une des revendications précédentes, caractérisée en ce que les filaments liants contiennent un antistatique, en particulier le noir de carbone.
  12. Nappe non tissée selon au moins l'une des revendications précédentes, caractérisée en ce qu'elle présente une structure stratifiée de filaments porteurs et de filaments liants.
  13. Nappe non tissée selon la revendication 12, caractérisé en ce que les deux couches extérieures ne contiennent pas de filaments liants.
  14. Procédé de fabrication de nappes non tissées selon la revedication 1, par dépose de filaments porteurs et de filaments liants pour donner une nappe enchevêtrée, d'après une méthode connue en soi, caractérisé en ce qu'on dépose des filaments liants dont le point de fusion est de moins de 30°C inférieur au point de fusion des filaments porteurs.
  15. Procédé selon la revendication 14, caractérisé en ce que la dépose des filaments s'effectue par utilisation d'une chicane tournante, suivie d'un déflecteur.
  16. Procédé selon au moins l'une des revendications précédentes, caractérisé en ce que la dépose des filaments s'effectue par des organes de dépose, disposés les uns derrière les autres en plusieurs rangées, dans le sens du mouvement de transport de la nappe.
  17. Procédé selon au moins l'une des revendications précédentes, caractérisé en ce que les polymères destinés aux filaments porteurs et aux filaments liants sont filés et déposés selon le rapport pondéral indiqué, sous forme de filaments à deux composant.
  18. Procédé selon au moins l'une des revendications précédentes, caractérisé en ce que la consolidation de la nappe s'effectue par un traitement thermique à une température comprise entre le point de fusion des filaments porteurs et celui des filaments liants.
EP91105398A 1990-04-09 1991-04-05 Nappe non tissée lien fondu fortifiée chaleur stable et procédé de sa fabrication Expired - Lifetime EP0455990B2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4011479 1990-04-09
DE4011479A DE4011479A1 (de) 1990-04-09 1990-04-09 Thermisch stabiles, schmelzbinderverfestigtes spinnvlies

Publications (3)

Publication Number Publication Date
EP0455990A1 EP0455990A1 (fr) 1991-11-13
EP0455990B1 EP0455990B1 (fr) 1995-10-25
EP0455990B2 true EP0455990B2 (fr) 1998-02-11

Family

ID=6404082

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91105398A Expired - Lifetime EP0455990B2 (fr) 1990-04-09 1991-04-05 Nappe non tissée lien fondu fortifiée chaleur stable et procédé de sa fabrication

Country Status (9)

Country Link
US (1) US5219647A (fr)
EP (1) EP0455990B2 (fr)
JP (1) JPH04222266A (fr)
KR (1) KR0149674B1 (fr)
AT (1) ATE129531T1 (fr)
CA (1) CA2039971A1 (fr)
DE (2) DE4011479A1 (fr)
IE (1) IE70594B1 (fr)
PT (1) PT97285B (fr)

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US5654066A (en) * 1995-06-09 1997-08-05 Pacione; Joseph R. Carpet and layered backing for dimensional stability and integrity
DE69927888T3 (de) 1998-08-19 2012-07-05 Johns Manville International, Inc. Filtermedium mit veränderter Filtrations- und Festigkeitscharakteristik
DE60329921D1 (de) * 2002-09-13 2009-12-17 Cerex Advanced Fabrics Inc Verfahren zur reduzierung von statischen ladungen in einem spunbondverfahren
CA2514015A1 (fr) * 2003-01-30 2004-08-12 Joseph Rocco Pacione Dalle de moquette, pose, procedes de fabrication et de pose associes
JP2007241887A (ja) * 2006-03-10 2007-09-20 Fujitsu Component Ltd キーボード
CN101889109B (zh) 2007-12-14 2012-08-29 可隆工业株式会社 用于空气过滤的无纺布及其制备方法
CN105593420B (zh) * 2013-10-02 2018-01-23 科德宝两合公司 具有高热稳定性的片材

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JPS62215057A (ja) * 1986-03-04 1987-09-21 チッソ株式会社 補強不織布
DE3642089A1 (de) * 1986-12-10 1988-06-23 Freudenberg Carl Fa Teppichtuftingtraeger aus spinnvliesstoff
JPH0775648B2 (ja) * 1987-05-19 1995-08-16 チッソ株式会社 円筒状フイルタ−

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JPH04222266A (ja) 1992-08-12
IE911164A1 (en) 1991-10-09
US5219647A (en) 1993-06-15
KR0149674B1 (ko) 1998-10-15
CA2039971A1 (fr) 1991-10-10
DE59106749D1 (de) 1995-11-30
PT97285A (pt) 1993-07-30
ATE129531T1 (de) 1995-11-15
KR910018619A (ko) 1991-11-30
IE70594B1 (en) 1996-12-11
DE4011479A1 (de) 1991-10-10
PT97285B (pt) 1999-04-30
EP0455990B1 (fr) 1995-10-25
EP0455990A1 (fr) 1991-11-13

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