EP1777337A1 - Procédé pour la teinture de fibres de polyamide - Google Patents
Procédé pour la teinture de fibres de polyamide Download PDFInfo
- Publication number
- EP1777337A1 EP1777337A1 EP05021866A EP05021866A EP1777337A1 EP 1777337 A1 EP1777337 A1 EP 1777337A1 EP 05021866 A EP05021866 A EP 05021866A EP 05021866 A EP05021866 A EP 05021866A EP 1777337 A1 EP1777337 A1 EP 1777337A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- active substance
- dye
- liquor ratio
- foam
- dyeing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 19
- 238000004043 dyeing Methods 0.000 title claims abstract description 15
- 239000004952 Polyamide Substances 0.000 title claims abstract description 13
- 229920002647 polyamide Polymers 0.000 title claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 239000013543 active substance Substances 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 8
- 150000001450 anions Chemical class 0.000 claims abstract description 4
- 239000002657 fibrous material Substances 0.000 claims abstract description 4
- 239000000975 dye Substances 0.000 claims description 29
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 claims description 2
- 235000020661 alpha-linolenic acid Nutrition 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 235000020778 linoleic acid Nutrition 0.000 claims description 2
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 claims description 2
- 229960004488 linolenic acid Drugs 0.000 claims description 2
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 claims description 2
- 150000002888 oleic acid derivatives Chemical class 0.000 claims description 2
- -1 unsaturated fatty acid amine Chemical class 0.000 abstract description 6
- 125000003342 alkenyl group Chemical group 0.000 abstract description 3
- 235000021122 unsaturated fatty acids Nutrition 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 description 13
- 239000000243 solution Substances 0.000 description 12
- 239000006260 foam Substances 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 10
- 238000012360 testing method Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 230000005012 migration Effects 0.000 description 4
- 238000013508 migration Methods 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- GUOIYUMEFRMHGR-UHFFFAOYSA-N 4-ethyl-2-(5-methylhexyl)octanamide Chemical compound CCCCC(CC)CC(C(N)=O)CCCCC(C)C GUOIYUMEFRMHGR-UHFFFAOYSA-N 0.000 description 2
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- 150000001767 cationic compounds Chemical class 0.000 description 2
- 238000013016 damping Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 230000002572 peristaltic effect Effects 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- RJZLMBIYRSBCDQ-UHFFFAOYSA-N 6-amino-5-[[2-[ethyl(phenyl)sulfamoyl]phenyl]diazenyl]-4-hydroxynaphthalene-2-sulfonic acid Chemical compound CCN(C1=CC=CC=C1)S(=O)(=O)C1=CC=CC=C1N=NC1=C(N)C=CC2=C1C(O)=CC(=C2)S(O)(=O)=O RJZLMBIYRSBCDQ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000002891 organic anions Chemical class 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- FTYDFSDLKHVWLD-UHFFFAOYSA-M sodium;3-[[4-[(4-ethoxyphenyl)diazenyl]naphthalen-1-yl]diazenyl]benzenesulfonate Chemical compound [Na+].C1=CC(OCC)=CC=C1N=NC(C1=CC=CC=C11)=CC=C1N=NC1=CC=CC(S([O-])(=O)=O)=C1 FTYDFSDLKHVWLD-UHFFFAOYSA-M 0.000 description 1
- NTOOJLUHUFUGQI-UHFFFAOYSA-M sodium;4-(4-acetamidoanilino)-1-amino-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].C1=CC(NC(=O)C)=CC=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O NTOOJLUHUFUGQI-UHFFFAOYSA-M 0.000 description 1
- DBSJKTVELUTRJM-UHFFFAOYSA-M sodium;4-[[5-methoxy-4-[(4-methoxyphenyl)diazenyl]-2-methylphenyl]diazenyl]benzenesulfonate Chemical compound [Na+].C1=CC(OC)=CC=C1N=NC1=CC(C)=C(N=NC=2C=CC(=CC=2)S([O-])(=O)=O)C=C1OC DBSJKTVELUTRJM-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/607—Nitrogen-containing polyethers or their quaternary derivatives
- D06P1/6076—Nitrogen-containing polyethers or their quaternary derivatives addition products of amines and alkylene oxides or oxiranes
Definitions
- the subject of this invention is a process for dyeing natural and synthetic polyamides or polyamide-containing materials by means of a leveling agent, which leads to uniform dyeings.
- Leveling agents are usually surface-active textile dyeing auxiliaries which have the task of well wetting the fiber / fiber mixture to be dyed, promoting the dye through of the fibers and preventing too rapid dyeing, which can lead to irregularity (blotchiness) in the dyeing process.
- Egalisierysmittel come u.a. Oleylsulfonates, fatty alcohol sulfonates, fatty acid condensation products, alkyl and alkylaryl polyglycol ethers and general surfactants in question.
- Inadequate levelness can be prevented by suitable staining techniques (inter alia, enhancing the diffusion of the solution within the tissue, pH control) and leveling agents.
- Leveling agents primarily reduce the rate of dyeing, increase the rate of migration of the dye within the fabric and improve the compatibility of the dyes.
- Leveling agents may also have other effects that do not directly affect the dye-fiber interactions, but still have a positive effect on the color. These include the improvement of the solubility or the dispersion stability of the dye.
- Leveling aids can exert several of the above effects simultaneously.
- Leveling agents can be classified into two groups, those that have an affinity for the fiber or that have an affinity for the dye.
- Leveling agents that have an affinity for the dyes form an addition compound with the dye whose stability is concentration dependent and usually decreases with increasing temperature.
- the dye distribution balance between the dye in solution and the dye in the fiber is shifted to the dye in solution.
- the increased dye concentration in the dye solution makes it possible to equalize areas of the tissue that have not been dyed the same way by the dye migration.
- Effective leveling agents have an affinity to the dye which is sufficient to reduce the rate of absorption or to accelerate the rate of migration. Differences in the absorption behavior of different dyes can be equalized so that the dyes in a dye mixture uniformly raise.
- Adjuvants having an affinity for dyes can also be used to level already colored materials. Aids with an affinity for fibers are grown on the fiber in competition with the dye. This competitive reaction reduces the rate of absorption and promotes migration rate.
- Important dye-affinity leveling agent types for polyamides are non-ionic surfactants, cationic compounds or ethoxylated compounds.
- Important fiber-based leveling agent types for polyamides are cationic compounds.
- EP-A-135 198 As a leveling agent for polyamides often ethoxylated amine compounds, some quaternized, are used, such as in EP-A-135 198 .
- the active substance is used as an aqueous solution, the concentration of the active substance being 15 to 35% by weight.
- the concentration of the active substance in the aqueous solution is 25 to 35% by weight and if 0.1 to 5% by weight of foam-damping substances are contained as further additives.
- the staining is usually carried out at a pH of 2 to 9, preferably from 3 to 8, in particular from 4 to 7.
- X - represents a common inorganic or organic anion such as halides (chloride, bromide, iodide), sulfate, sulfonate, methosulfate, ethylsulfate, hydroxide, phosphate, phosphonate or acetate. Preference is given to chloride.
- the present active substance is known (CAS No. 747377-35-1 and 133189-76-1) and can be prepared in a simple manner by alkoxylation of the corresponding fatty amine.
- the alkoxylation could also be done with propylene oxide instead of with ethylene oxide or ethylene oxide and propylene oxide, random or block alkoxylated, but show only ethoxylated amines give better results.
- the alkoxylate obtained could still be completely or partially sulfonated or sulfated, but here also show the non-sulfonated or non-sulfated species better activity.
- the active substance generally contains 15 to 30 ethylene oxide units (EO), preferably 17 to 19 EO.
- Particularly preferred as an active substance is an oleylamine with 17 to 19 EO, which was quaternized with 1 EO and contains chloride as the counterion.
- foam-suppressing substances such as biocides, optionally dispersing agents or wetting agents, such as sulfonated or sulfated alkyl, alkenyl or Arylpolyglykolether, sulfonated or sulfated alkyl, alkenyl or Arylaminpolyglykolether, and optionally defoamers based on silicone oil or mineral oil become.
- the foam-suppressing substance used is preferably 2-ethylhexylisononanamide and, as a network component with an additional foam-damping effect, a C 12-15 -alcohol having 8 ethylene oxide units and 4 propylene oxide units.
- the foam volume is measured after a certain amount of liquid was poured from a certain height, namely the immediately formed foam volume and the volume after a minute of waiting.
- a 1000 ml measuring cylinder with an inner diameter of 60 mm and an inner height of 430 mm is used.
- the test liquid is allowed to flow out of a 2 1 separating funnel through a capillary of 70 mm length and 2 mm inner diameter from a height of 600 mm, measured from the exit of the capillary above the bottom of the measuring cylinder.
- 500 ml of the solution to be tested are introduced into the separating funnel and allowed to flow out into the graduated cylinder with the outflow rate of about 0.171 / min caused by the capillary.
- a stopwatch is started and the entire volume (volume of foam and solution) is read off the cylinder. After one minute, the reading is repeated.
- the test temperature is 20 to 25 ° C.
- the liquor is added to the dyeing machine, after stabilization of the flow then the textile material is added. It is heated at full power from room temperature to 98 ° C, 15 min. treated at 98 ° C, then cooled to 70 ° C and then 10 min. rinsed with cold water.
- composition of the composition according to the invention (hereinafter referred to as "P1"):
- Active substance quaternized oleylamine with 17 to 19 EO, quaternized with 1 EO, chloride as counterion
- 2-ethylhexylisononanamide 12 10 C 12-15 alcohol with 8 EO and 4 PO 0.90 demineralized water 79.0
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05021866A EP1777337A1 (fr) | 2005-10-07 | 2005-10-07 | Procédé pour la teinture de fibres de polyamide |
| KR1020087008349A KR20080058361A (ko) | 2005-10-07 | 2006-09-20 | 폴리아미드 섬유의 염색 |
| PCT/EP2006/066549 WO2007042379A1 (fr) | 2005-10-07 | 2006-09-20 | Coloration de fibres en polyamide |
| JP2008533966A JP2009511757A (ja) | 2005-10-07 | 2006-09-20 | ポリアミド繊維の染色 |
| BRPI0616957-0A BRPI0616957A2 (pt) | 2005-10-07 | 2006-09-20 | tingimento de fibras de poliamida |
| EP06793678A EP1943383A1 (fr) | 2005-10-07 | 2006-09-20 | Coloration de fibres en polyamide |
| CNA2006800371594A CN101283142A (zh) | 2005-10-07 | 2006-09-20 | 聚酰胺纤维的染色 |
| US12/083,177 US20090255064A1 (en) | 2005-10-07 | 2006-09-20 | Dyeing of Polyamide Fibers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05021866A EP1777337A1 (fr) | 2005-10-07 | 2005-10-07 | Procédé pour la teinture de fibres de polyamide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1777337A1 true EP1777337A1 (fr) | 2007-04-25 |
Family
ID=35998495
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP05021866A Withdrawn EP1777337A1 (fr) | 2005-10-07 | 2005-10-07 | Procédé pour la teinture de fibres de polyamide |
| EP06793678A Withdrawn EP1943383A1 (fr) | 2005-10-07 | 2006-09-20 | Coloration de fibres en polyamide |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06793678A Withdrawn EP1943383A1 (fr) | 2005-10-07 | 2006-09-20 | Coloration de fibres en polyamide |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20090255064A1 (fr) |
| EP (2) | EP1777337A1 (fr) |
| JP (1) | JP2009511757A (fr) |
| KR (1) | KR20080058361A (fr) |
| CN (1) | CN101283142A (fr) |
| BR (1) | BRPI0616957A2 (fr) |
| WO (1) | WO2007042379A1 (fr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103911889B (zh) * | 2013-12-13 | 2016-06-22 | 泉州市新宏化工贸易有限公司 | 一种纺织用复合匀染助剂及其制备方法 |
| US9840807B2 (en) | 2015-03-10 | 2017-12-12 | Charles Francis Luzon | Process for dyeing textiles, dyeing and fortifying rubber, and coloring and revitalizing plastics |
| DE102018220624A1 (de) | 2018-11-29 | 2020-06-04 | B. Braun Melsungen Ag | Wässrige Zusammensetzung, insbesondere zur Behandlung von Schleimhaut und/oder Wunden |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH373012A (de) * | 1961-05-24 | 1963-07-31 | Geigy Ag J R | Verfahren zur Erzeugung echter Wollfärbungen mit Kupfer- oder Nickelphthalocyaninen |
| US3104931A (en) * | 1958-03-11 | 1963-09-24 | Ciba Geigy Corp | Process for dyeing wool |
| DE1469657A1 (de) * | 1963-10-04 | 1969-10-09 | Ciba Geigy | Verfahren zum Faerben von Wolle und zur Durchfuehrung des Verfahrens geeignete Praeparate |
| US3816529A (en) * | 1969-05-16 | 1974-06-11 | American Cyanamid Co | N-carbamoylethyl aromatic amine compounds |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH644977GA3 (fr) * | 1977-08-11 | 1984-09-14 | ||
| US4444563A (en) * | 1981-09-07 | 1984-04-24 | Ciba-Geigy Corporation | Dyeing assistant and use thereof in dyeing or printing synthetic polyamide fibre materials |
| DE3368956D1 (en) * | 1982-09-03 | 1987-02-12 | Ciba Geigy Ag | Dyeing auxiliary and its use in dyeing or printing synthetic polyamide fibres |
| FR2574791A1 (fr) * | 1984-12-14 | 1986-06-20 | Sandoz Sa | Sulfates d'amines grasses, leur preparation et leur utilisation comme produits auxiliaires |
| US4818248A (en) * | 1986-10-10 | 1989-04-04 | Ciba-Geigy Corporation | Process for dyeing natural or synthetic polyamide fibre materials with 1:1 metal complex dyes in presence of alkali metal fluordsilicate or amindnlum silicate |
| EP0442844B2 (fr) * | 1990-02-14 | 1998-01-21 | Ciba SC Holding AG | Procédé de teinture de la laine avec des colorants réactifs |
| JPH09188976A (ja) * | 1996-01-10 | 1997-07-22 | Taoka Chem Co Ltd | 染色助剤及びそれを用いるポリアミド系繊維構造物の染色法 |
-
2005
- 2005-10-07 EP EP05021866A patent/EP1777337A1/fr not_active Withdrawn
-
2006
- 2006-09-20 EP EP06793678A patent/EP1943383A1/fr not_active Withdrawn
- 2006-09-20 CN CNA2006800371594A patent/CN101283142A/zh active Pending
- 2006-09-20 BR BRPI0616957-0A patent/BRPI0616957A2/pt not_active IP Right Cessation
- 2006-09-20 US US12/083,177 patent/US20090255064A1/en not_active Abandoned
- 2006-09-20 WO PCT/EP2006/066549 patent/WO2007042379A1/fr not_active Ceased
- 2006-09-20 KR KR1020087008349A patent/KR20080058361A/ko not_active Withdrawn
- 2006-09-20 JP JP2008533966A patent/JP2009511757A/ja active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3104931A (en) * | 1958-03-11 | 1963-09-24 | Ciba Geigy Corp | Process for dyeing wool |
| CH373012A (de) * | 1961-05-24 | 1963-07-31 | Geigy Ag J R | Verfahren zur Erzeugung echter Wollfärbungen mit Kupfer- oder Nickelphthalocyaninen |
| DE1469657A1 (de) * | 1963-10-04 | 1969-10-09 | Ciba Geigy | Verfahren zum Faerben von Wolle und zur Durchfuehrung des Verfahrens geeignete Praeparate |
| US3816529A (en) * | 1969-05-16 | 1974-06-11 | American Cyanamid Co | N-carbamoylethyl aromatic amine compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20080058361A (ko) | 2008-06-25 |
| WO2007042379A1 (fr) | 2007-04-19 |
| JP2009511757A (ja) | 2009-03-19 |
| US20090255064A1 (en) | 2009-10-15 |
| EP1943383A1 (fr) | 2008-07-16 |
| BRPI0616957A2 (pt) | 2011-07-05 |
| CN101283142A (zh) | 2008-10-08 |
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