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EP2566628B2 - Atomizer with a lattice mixer - Google Patents
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EP2566628B2 - Atomizer with a lattice mixer - Google Patents

Atomizer with a lattice mixer Download PDF

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Publication number
EP2566628B2
EP2566628B2 EP11719471.2A EP11719471A EP2566628B2 EP 2566628 B2 EP2566628 B2 EP 2566628B2 EP 11719471 A EP11719471 A EP 11719471A EP 2566628 B2 EP2566628 B2 EP 2566628B2
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EP
European Patent Office
Prior art keywords
mixer
atomizer
paint
mixing elements
mixers
Prior art date
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Application number
EP11719471.2A
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German (de)
French (fr)
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EP2566628B1 (en
EP2566628A1 (en
Inventor
Bernhard Seiz
Frank Herre
Michael Baumann
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Duerr Systems AG
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Duerr Systems AG
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Application filed by Duerr Systems AG filed Critical Duerr Systems AG
Priority to PL11719471T priority Critical patent/PL2566628T5/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/04Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge
    • B05B7/0408Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge with arrangements for mixing two or more liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B3/00Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements
    • B05B3/02Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements
    • B05B3/10Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements discharging over substantially the whole periphery of the rotating member
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/421Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions by moving the components in a convoluted or labyrinthine path
    • B01F25/423Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions by moving the components in a convoluted or labyrinthine path by means of elements placed in the receptacle for moving or guiding the components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/431Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
    • B01F25/4316Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor the baffles being flat pieces of material, e.g. intermeshing, fixed to the wall or fixed on a central rod
    • B01F25/43161Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor the baffles being flat pieces of material, e.g. intermeshing, fixed to the wall or fixed on a central rod composed of consecutive sections of flat pieces of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B12/00Arrangements for controlling delivery; Arrangements for controlling the spray area
    • B05B12/14Arrangements for controlling delivery; Arrangements for controlling the spray area for supplying a selected one of a plurality of liquids or other fluent materials or several in selected proportions to a spray apparatus, e.g. to a single spray outlet
    • B05B12/1418Arrangements for controlling delivery; Arrangements for controlling the spray area for supplying a selected one of a plurality of liquids or other fluent materials or several in selected proportions to a spray apparatus, e.g. to a single spray outlet for supplying several liquids or other fluent materials in selected proportions to a single spray outlet

Definitions

  • the invention relates to an atomizer, in particular a rotary atomizer, for applying a coating composition consisting of several components.
  • rotary atomizers are usually used as the application device, some of which can also apply multi-component paints which consist of several coating agent components, such as, for example, a base paint and a hardener. It is important here that the various components of the multi-component lacquer are mixed as well as possible in the atomizer.
  • the conventional rotary atomizers have static spiral mixers, which are also referred to as Kenics ® mixers. These spiral mixers have numerous spiral-shaped mixing elements that direct the coating agent flow radially outwards and then lead it back to the center.
  • two separate spiral mixers are used, the first spiral mixer being arranged in the color tube of the rotary atomizer, while the second spiral mixer is located outside the color tube in the connection block of the rotary atomizer.
  • a disadvantage of this conventional design is the fact that a relatively long overall length of the mixer is required, so that large losses of paint or detergent occur during a color change or during rinsing processes.
  • the object of the invention is therefore to create a correspondingly improved atomizer with a structurally integrated mixer.
  • the invention encompasses the general technical teaching of using another type of mixer, namely a so-called lattice mixer, which has numerous mixing elements which are arranged in a lattice-like arrangement.
  • Grid mixers of this type are made, for example US 2004/0114461 A1 is known, so that the content of this document of the present description with regard to the structure and operation of a grid mixer is fully attributable.
  • a common feature of the new mixer according to the invention with the conventional spiral mixer is that it is a static mixer in both cases. This means that the mixer itself has no moving parts, since the mixing is brought about by the flow movement of the coating agent components to be mixed with one another.
  • the grid mixer differs from the conventional spiral mixer in the arrangement and design of the individual mixing elements.
  • the conventionally used spiral mixer has spiral-shaped mixing elements which divert the flow of coating agent in a spiral, the mixing elements adjacent in the flow direction each having opposite deflection directions, as a result of which the mixing is effected.
  • the lattice mixer used according to the invention preferably has elongated, straight, sharp-edged and rod-shaped mixing elements which are made of plastic and each have an essentially rectangular cross section. These mixing elements therefore each cause turbulence, which leads to effective mixing of the coating agent components to be mixed with one another.
  • the individual mixing elements are arranged in a grid-like manner.
  • a plurality of rod-shaped mixing elements are arranged together in one plane and thus form a lattice, a plurality of such lattices consisting of a plurality of mixing elements being interleaved.
  • the individual mixing elements preferably have a certain angle of attack relative to the flow direction. This means that the individual mixing elements are not aligned parallel to the direction of flow, since this would only lead to a low mixing effect.
  • the angle of attack of the mixing elements with respect to the direction of flow is preferably greater than 20 °, 30 ° or 40 ° and / or less than 70 °, 60 ° or 50 °. In the preferred embodiment, the angle of attack is essentially the same for all mixing elements. However, there is alternatively also the possibility that the mixing elements have different angles of attack.
  • the mixer has several sections, which are arranged one behind the other in the direction of flow are and are flowed through in succession.
  • the different sections can differ, for example, in the orientation of the mixing elements.
  • the angle of attack of the mixing elements can fluctuate relative to the flow direction between the sections.
  • the mixer has a total of more than 5, 6, 7, 8, 9, 10 or even more than 11 different sections.
  • the immediately adjacent sections of the mixer are each designed differently, for example with regard to the angle of attack or the orientation and design of the mixing elements, the section after the next but one again having the same structure.
  • the mixer is preferably elongated in the direction of flow and has an essentially cylindrical cross section, the mixer preferably being arranged completely inside the atomizer.
  • the mixer preferably has a length in the flow direction that is less than 10 cm, 8 cm or even 6 cm. This advantageously enables the mixer to be arranged completely in the paint tube of the atomizer.
  • the overall length of the mixer is therefore preferably less than the overall length of the paint tube of the atomizer.
  • the atomizer according to the invention like the conventional atomizers, has a controllable main needle valve which either releases or blocks the flow of coating agent.
  • the main needle valve When the main needle valve is closed, the atomizer does not apply any coating agent, so that the valve position of the main needle valve determines whether the atomizer applies the coating agent or not.
  • the mixer is arranged upstream of the main needle valve so that the ready mixed coating agent is present on the main needle valve. It is advantageous here if the mixer is moved as far upstream as possible to the main needle valve in order to minimize the distance between the downstream end of the mixer and the main needle valve. This is advantageous because it reduces the amount of paint or solvent used when changing colors or rinsing.
  • the line length between the downstream end of the mixer and the main needle valve is therefore preferably shorter than 10 cm, 6 cm, 5 cm, 4 cm, 3 cm, 2 cm or even shorter than 1 cm.
  • the atomizer according to the invention like the conventional atomizers - has a hollow paint tube in order to supply the coating agent to be applied.
  • the advantages of the grating mixer according to the invention offer the possibility that the mixer is arranged completely in the paint tube, so that under certain circumstances an additional mixer in the connection block of the atomizer can be dispensed with, which was necessary in the conventional atomizer described at the beginning.
  • the paint tube can also form the casing of the usually cylindrical mixer, so that an additional mixing pipe for the casing of the mixer can be dispensed with.
  • the diameter of the mixer essentially corresponds to the diameter of the paint tube in one exemplary embodiment, so that the mixer completely fills the cross section of the paint tube.
  • several mixers are arranged side by side in the paint tube of the atomizer, which will be described in detail below.
  • each of the two paint systems having several components, in particular a base paint and a hardener.
  • a mixer is assigned to each of the two coating systems in order to mix the components of the coating system with one another.
  • the mixers for the different paint systems are arranged together in the paint tube, the mixers for the different paint systems preferably being located next to one another with respect to the direction of flow. Each mixer for the different paint systems then fills only part of the cross-section of the paint tube.
  • the various mixers are then preferably encased by a mixing tube in order to separate the various mixers from one another.
  • mixers for the different color systems can have different mixing properties that are adapted to the properties of the respective color system in order to achieve the best possible mixing result.
  • the mixers for the different paint systems are not arranged together in the paint tube.
  • the mixer for the one paint system can be arranged in the paint tube, while the mixer for the other paint system is located outside the paint tube, for example in a valve or connection block of the atomizer upstream of the paint tube.
  • the atomizer according to the invention has several mixers, which can also be very useful in general for optimizing the mixing result.
  • Figure 1 shows a rotary atomizer 1, which can be used, for example, for painting motor vehicle body components, the rotary atomizer 1 being constructed largely conventionally, so that a detailed description of the structure and operation of the rotary atomizer 1 can be dispensed with.
  • the rotary atomizer 1 has a paint tube 2 which is fastened to a connection block 3, the paint tube 2 being aligned coaxially with the axis of rotation of a bell cup shaft 4 in order to supply the coating agent to be applied.
  • a grating mixer 5 is arranged in the paint tube 2 in order to mix the various components (e.g. master varnish and hardener) of the coating composition with one another.
  • the lattice mixer 5 has numerous elongated, rod-shaped, sharp-edged mixing elements 6 which are arranged in a lattice-like manner, with the mixing elements 6 generating turbulence in the paint tube 2, which leads to thorough mixing.
  • the grid mixer consists of a total of twelve sections 7, 8, which are arranged one behind the other in the direction of flow and flow through one after the other.
  • the different sections 7, 8 of the lattice mixer 5 differ in the orientation of the individual mixing elements 6, as shown in the perspective view in FIG Figure 2 can be seen.
  • Figure 3 shows a schematic diagram to illustrate the structure of a rotary atomizer 9 according to the invention, which is suitable for the application of two different paint systems, the first paint system consisting of a first base paint SL1 and a first hardener H1, while the second paint system consists of a second base paint SL2 and a second hardener H2.
  • the rotary atomizer has two main needle valves 10, 11 and one grating mixer 12, 13 each, the two grating mixers 12, 13 being arranged together next to one another in a paint tube 14 of the rotary atomizer 9.
  • the lattice mixer 12 mixes the first base paint SL1 with the first hardener H1, while the other lattice mixer 13 mixes the second base paint SL2 with the second hardener H2.
  • the two grid mixers 12, 13 correspond in structure and function to the grid mixer 5 according to FIGS Figures 1 and 2nd .
  • the rotary atomizer 9 also has a connection block 15 with integrated valves in this exemplary embodiment.
  • the two grid mixers 12, 13 are arranged at a very short distance 1 ⁇ 5 cm upstream of the associated main needle valves 10, 11. This is advantageous because the line section to be rinsed between the lattice mixers 12, 13 and the associated main needle valves 10, 11 thus has a small volume, so that the detergent losses and the paint losses are correspondingly small.
  • Figure 4 shows a modification of the embodiment according to Figure 3 , so that to avoid repetition reference is made to the above description, the same reference numerals being used for corresponding details.
  • a special feature of this exemplary embodiment is the arrangement of the two grid mixers 12, 13.
  • the grid mixer 12 in this exemplary embodiment is also located within the paint tube 14, whereas the other grid mixer 13 is integrated in the connection block 15.

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  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nozzles (AREA)

Description

Die Erfindung betrifft einen Zerstäuber, insbesondere einen Rotationszerstäuber, zur Applikation eines aus mehreren Komponenten bestehenden Beschichtungsmittels.The invention relates to an atomizer, in particular a rotary atomizer, for applying a coating composition consisting of several components.

In modernen Lackieranlagen zur Lackierung von Kraftfahrzeugkarosseriebauteilen werden als Applikationsgerät üblicherweise Rotationszerstäuber eingesetzt, die teilweise auch Mehrkomponentenlacke applizieren können, die aus mehreren Beschichtungsmittelkomponenten bestehen, wie beispielsweise einem Stammlack und einem Härter. Wichtig ist hierbei, dass die verschiedenen Komponenten des Mehrkomponentenlacks in dem Zerstäuber möglichst gut miteinander vermischt werden. Hierzu weisen die herkömmlichen Rotationszerstäuber statische Wendelmischer auf, die auch als Kenics®-Mischer bezeichnet werden. Diese Wendelmischer haben zahlreiche spiralförmige Mischelemente, die den Beschichtungsmittelstrom radial nach außen richten und dann wieder zur Mitte zurück führen. Üblicherweise werden hierbei zwei getrennte Wendelmischer eingesetzt, wobei der erste Wendelmischer in dem Farbrohr des Rotationszerstäubers angeordnet ist, während sich der zweite Wendelmischer außerhalb des Farbrohrs im Anschlussblock des Rotationszerstäubers befindet.In modern painting systems for painting motor vehicle body components, rotary atomizers are usually used as the application device, some of which can also apply multi-component paints which consist of several coating agent components, such as, for example, a base paint and a hardener. It is important here that the various components of the multi-component lacquer are mixed as well as possible in the atomizer. For this purpose, the conventional rotary atomizers have static spiral mixers, which are also referred to as Kenics ® mixers. These spiral mixers have numerous spiral-shaped mixing elements that direct the coating agent flow radially outwards and then lead it back to the center. Usually, two separate spiral mixers are used, the first spiral mixer being arranged in the color tube of the rotary atomizer, while the second spiral mixer is located outside the color tube in the connection block of the rotary atomizer.

Nachteilig an dieser herkömmlichen Bauweise ist die Tatsache, dass eine relativ große Baulänge des Mischers erforderlich ist, so dass bei einem Farbwechsel bzw. bei Spülvorgängen große Verluste an Lack bzw. Spülmittel auftreten.A disadvantage of this conventional design is the fact that a relatively long overall length of the mixer is required, so that large losses of paint or detergent occur during a color change or during rinsing processes.

Weiterhin offenbart DE 82 31 663 U1 ein Farbführungsrohr in einem Zerstäuber, wobei in dem Farbführungsrohr ein statischer Mischer angeordnet ist. Auch dieser bekannte Mischer erfordert jedoch eine relativ große Baulänge.Further disclosed DE 82 31 663 U1 a paint guide tube in an atomizer, a static mixer being arranged in the paint guide tube. However, this known mixer also requires a relatively large overall length.

Ferner ist zum Stand der Technik hinzuweisen auf DE 30 40 136 A1 und US 4 614 440 .Reference should also be made to the state of the art DE 30 40 136 A1 and US 4,614,440 .

Weiterhin offenbart US 2004/0114461 A1 einen sogenannten Gittermischer, wobei es sich um einen statischen Mischer handelt, der zum Mischen von hochviskosen Flüssigkeiten verwendet wird, beispielsweise in Spritzgussmaschinen. Bisher wurden derartige Gittermischer jedoch nicht in Zerstäubern eingesetzt, zumal man davon ausging, dass solche Gittermischer nur zum Mischen von hochviskosen Flüssigkeiten geeignet sind.Further disclosed US 2004/0114461 A1 a so-called lattice mixer, which is a static mixer that is used for mixing highly viscous liquids, for example in injection molding machines. So far, however, such lattice mixers have not been used in atomizers, especially since it was assumed that such lattice mixers are only suitable for mixing highly viscous liquids.

Ferner ist zum Stand der Technik hinzuweisen auf US 2006/0192033 A1 und WO 2008/136827 A1 .Reference should also be made to the state of the art US 2006/0192033 A1 and WO 2008/136827 A1 .

Schließlich offenbart FR 2 890 876 A1 einen Zerstäuber gemäß dem Oberbegriff des Hauptanspruchs. Nachteilig an diesem bekannten Zerstäuber mit einem Gittermischer ist jedoch die unbefriedigende Mischwirkung des Gittermischers.Finally revealed FR 2 890 876 A1 an atomizer according to the preamble of the main claim. A disadvantage of this known atomizer with a lattice mixer, however, is the unsatisfactory mixing effect of the lattice mixer.

Der Erfindung liegt deshalb die Aufgabe zugrunde, einen entsprechend verbesserten Zerstäuber mit einem baulich integrierten Mischer zu schaffen.The object of the invention is therefore to create a correspondingly improved atomizer with a structurally integrated mixer.

Diese Aufgabe wird durch einen erfindungsgemäßen Zerstäuber gemäß dem Hauptanspruch gelöst.This object is achieved by an atomizer according to the invention according to the main claim.

Die Erfindung umfasst die allgemeine technische Lehre, einen anderen Mischertyp zu verwenden, nämlich einen sogenannten Gittermischer, der zahlreiche Mischelemente aufweist, die gitterförmig ineinander verschränkt angeordnet sind. Derartige Gittermischer sind beispielsweise aus US 2004/0114461 A1 bekannt, so dass der Inhalt dieser Druckschrift der vorliegenden Beschreibung hinsichtlich des Aufbaus und der Funktionsweise eines Gittermischers in vollem Umfang zuzurechnen ist.The invention encompasses the general technical teaching of using another type of mixer, namely a so-called lattice mixer, which has numerous mixing elements which are arranged in a lattice-like arrangement. Grid mixers of this type are made, for example US 2004/0114461 A1 is known, so that the content of this document of the present description with regard to the structure and operation of a grid mixer is fully attributable.

Eine Gemeinsamkeit des erfindungsgemäßen neuen Mischers mit dem herkömmlichen Wendelmischer besteht darin, dass es sich in beiden Fällen um statische Mischer handelt. Dies bedeutet, dass der Mischer selbst keine beweglichen Teile aufweist, da die Mischung durch die Strömungsbewegung der miteinander zu mischenden Beschichtungsmittelkomponenten bewirkt wird.A common feature of the new mixer according to the invention with the conventional spiral mixer is that it is a static mixer in both cases. This means that the mixer itself has no moving parts, since the mixing is brought about by the flow movement of the coating agent components to be mixed with one another.

Der Gittermischer unterscheidet sich dagegen von dem herkömmlichen Wendelmischer durch die Anordnung und Gestaltung der einzelnen Mischelemente. So weist der herkömmlicherweise verwendete Wendelmischer spiralförmige Mischelemente auf, die den Beschichtungsmittelstrom spiralförmig umleiten, wobei die in Strömungsrichtung benachbarten Mischelemente jeweils entgegengesetzte Umlenkrichtungen aufweisen, wodurch die Mischung bewirkt wird. Der erfindungsgemäß verwendete Gittermischer weist dagegen vorzugsweise langgestreckte, gerade, scharfkantige und stabförmige Mischelemente auf, die aus Kunststoff bestehen und jeweils einen im Wesentlichen rechteckigen Querschnitt aufweisen. Diese Mischelemente bewirken also jeweils Turbulenzen, die zu einer effektiven Durchmischung der miteinander zu mischenden Beschichtungsmittelkomponenten führen.The grid mixer, on the other hand, differs from the conventional spiral mixer in the arrangement and design of the individual mixing elements. For example, the conventionally used spiral mixer has spiral-shaped mixing elements which divert the flow of coating agent in a spiral, the mixing elements adjacent in the flow direction each having opposite deflection directions, as a result of which the mixing is effected. In contrast, the lattice mixer used according to the invention preferably has elongated, straight, sharp-edged and rod-shaped mixing elements which are made of plastic and each have an essentially rectangular cross section. These mixing elements therefore each cause turbulence, which leads to effective mixing of the coating agent components to be mixed with one another.

Die einzelnen Mischelemente sind hierbei gitterförmig ineinander verschränkt angeordnet. In dem bevorzugte Ausführungsbeispiel des erfindungsgemäßen Gittermischers sind jeweils mehrere stabförmige Mischelemente gemeinsam in einer Ebene angeordnet und bilden somit ein Gitter, wobei mehrere derartige Gitter aus mehreren Mischelementen ineinander verschränkt angeordnet sind.The individual mixing elements are arranged in a grid-like manner. In the preferred embodiment of the lattice mixer according to the invention, a plurality of rod-shaped mixing elements are arranged together in one plane and thus form a lattice, a plurality of such lattices consisting of a plurality of mixing elements being interleaved.

Weiterhin ist zu erwähnen, dass die einzelnen Mischelemente vorzugsweise einen bestimmten Anstellwinkel relativ zur Strömungsrichtung aufweisen. Dies bedeutet, dass die einzelnen Mischelemente nicht parallel zur Strömungsrichtung ausgerichtet sind, da dies nur zu einer geringen Mischwirkung führen würde. Vorzugsweise ist der Anstellwinkel der Mischelemente gegenüber der Strömungsrichtung größer als 20°, 30° oder 40° und/oder kleiner als 70°, 60° oder 50°. In dem bevorzugten Ausführungsbeispiel ist der Anstellwinkel bei allen Mischelementen im Wesentlichen gleich. Es besteht jedoch alternativ auch die Möglichkeit, dass die Mischelemente unterschiedliche Anstellwinkel aufweisen.It should also be mentioned that the individual mixing elements preferably have a certain angle of attack relative to the flow direction. This means that the individual mixing elements are not aligned parallel to the direction of flow, since this would only lead to a low mixing effect. The angle of attack of the mixing elements with respect to the direction of flow is preferably greater than 20 °, 30 ° or 40 ° and / or less than 70 °, 60 ° or 50 °. In the preferred embodiment, the angle of attack is essentially the same for all mixing elements. However, there is alternatively also the possibility that the mixing elements have different angles of attack.

Hierbei weist der Mischer mehrere Abschnitte auf, die in Strömungsrichtung hintereinander angeordnet sind und nacheinander durchströmt werden. Die verschiedenen Abschnitte können sich beispielsweise durch die Ausrichtung der Mischelemente unterscheiden. So kann beispielsweise der Anstellwinkel der Mischelemente relativ zur Strömungsrichtung zwischen den Abschnitten schwanken. In dem bevorzugten Ausführungsbeispiel der Erfindung weist der Mischer insgesamt mehr als 5, 6, 7, 8, 9, 10 oder sogar mehr als 11 verschiedene Abschnitte auf. Hierbei besteht die Möglichkeit, dass die unmittelbar benachbarten Abschnitte des Mischers jeweils unterschiedlich ausgestaltet sind, beispielsweise hinsichtlich des Anstellwinkels oder der Ausrichtung und Gestaltung der Mischelemente, wobei der jeweils übernächste Abschnitt des Mischers wieder den gleichen Aufbau aufweist.Here, the mixer has several sections, which are arranged one behind the other in the direction of flow are and are flowed through in succession. The different sections can differ, for example, in the orientation of the mixing elements. For example, the angle of attack of the mixing elements can fluctuate relative to the flow direction between the sections. In the preferred embodiment of the invention, the mixer has a total of more than 5, 6, 7, 8, 9, 10 or even more than 11 different sections. There is the possibility here that the immediately adjacent sections of the mixer are each designed differently, for example with regard to the angle of attack or the orientation and design of the mixing elements, the section after the next but one again having the same structure.

Weiterhin ist zu erwähnen, dass der Mischer vorzugsweise in Strömungsrichtung langgestreckt ist und einen im Wesentlichen zylindrischen Querschnitt aufweist, wobei der Mischer vorzugsweise vollständig innerhalb des Zerstäubers angeordnet ist.It should also be mentioned that the mixer is preferably elongated in the direction of flow and has an essentially cylindrical cross section, the mixer preferably being arranged completely inside the atomizer.

Wichtig ist ferner, dass der Mischer vorzugsweise eine Baulänge in Strömungsrichtung aufweist, die kleiner ist als 10cm, 8cm oder sogar 6cm. Dies ermöglicht es vorteilhaft, dass der Mischer vollständig in dem Farbrohr des Zerstäubers angeordnet ist. Die Baulänge des Mischers ist also vorzugsweise kleiner als die Baulänge des Farbrohrs des Zerstäubers.It is also important that the mixer preferably has a length in the flow direction that is less than 10 cm, 8 cm or even 6 cm. This advantageously enables the mixer to be arranged completely in the paint tube of the atomizer. The overall length of the mixer is therefore preferably less than the overall length of the paint tube of the atomizer.

Der erfindungsgemäße Zerstäuber weist in dem bevorzugten Ausführungsbeispiel - wie auch die herkömmlichen Zerstäuber - ein steuerbares Hauptnadelventil auf, das den Beschichtungsmittelstrom wahlweise freigibt oder sperrt. Bei geschlossenem Hauptnadelventil appliziert der Zerstäuber also kein Beschichtungsmittel, so dass die Ventilstellung des Hauptnadelventils bestimmt, ob der Zerstäuber das Beschichtungsmittel appliziert oder nicht. Der Mischer ist hierbei stromaufwärts vor dem Hauptnadelventil angeordnet, so dass an dem Hauptnadelventil das fertig gemischte Beschichtungsmittel ansteht. Hierbei ist es vorteilhaft, wenn der Mischer möglichst weit stromaufwärts zu dem Hauptnadelventil hin verlagert wird, um den Abstand zwischen dem stromabwärts gelegenen Ende des Mischers und dem Hauptnadelventil zu minimieren. Dies ist vorteilhaft, weil dadurch der Lack- bzw. Lösemittelverbrauch bei einem Farbwechsel bzw. beim Spülen reduziert wird. Die Leitungslänge zwischen dem stromabwärts gelegenen Ende des Mischers und dem Hauptnadelventil ist deshalb vorzugsweise kürzer als 10cm, 6cm, 5cm, 4cm, 3cm, 2cm oder sogar kürzer als 1cm.In the preferred exemplary embodiment, the atomizer according to the invention, like the conventional atomizers, has a controllable main needle valve which either releases or blocks the flow of coating agent. When the main needle valve is closed, the atomizer does not apply any coating agent, so that the valve position of the main needle valve determines whether the atomizer applies the coating agent or not. The mixer is arranged upstream of the main needle valve so that the ready mixed coating agent is present on the main needle valve. It is advantageous here if the mixer is moved as far upstream as possible to the main needle valve in order to minimize the distance between the downstream end of the mixer and the main needle valve. This is advantageous because it reduces the amount of paint or solvent used when changing colors or rinsing. The line length between the downstream end of the mixer and the main needle valve is therefore preferably shorter than 10 cm, 6 cm, 5 cm, 4 cm, 3 cm, 2 cm or even shorter than 1 cm.

Es wurde bereits vorstehend erwähnt, dass der erfindungsgemäße Zerstäuber - wie auch die herkömmlichen Zerstäuber - ein hohles Farbrohr aufweist, um das zu applizierende Beschichtungsmittel zuzuführen. Die Vorteile des erfindungsgemäßen Gittermischers bieten hierbei die Möglichkeit, dass der Mischer vollständig in dem Farbrohr angeordnet ist, so dass unter Umständen auf einen zusätzlichen Mischer in dem Anschlussblock des Zerstäubers verzichtet werden kann, was bei dem eingangs beschriebenen herkömmlichen Zerstäuber erforderlich war. Hierbei ist zu erwähnen, dass das Farbrohr auch die Ummantelung des üblicherweise zylindrischen Mischers bilden kann, so dass auf ein zusätzliches Mischrohr zur Ummantelung des Mischers verzichtet werden kann. Ferner ist zu erwähnen, dass der Durchmesser des Mischers in einem Ausführungsbeispiel im Wesentlichen dem Durchmesser des Farbrohrs entspricht, so dass der Mischer den Querschnitt des Farbrohrs vollständig ausfüllt. Es besteht jedoch im Rahmen der Erfindung auch die Möglichkeit, dass in dem Farbrohr des Zerstäubers mehrere Mischer nebeneinander angeordnet sind, was noch detailliert beschrieben wird.It has already been mentioned above that the atomizer according to the invention - like the conventional atomizers - has a hollow paint tube in order to supply the coating agent to be applied. The advantages of the grating mixer according to the invention offer the possibility that the mixer is arranged completely in the paint tube, so that under certain circumstances an additional mixer in the connection block of the atomizer can be dispensed with, which was necessary in the conventional atomizer described at the beginning. It should be mentioned here that the paint tube can also form the casing of the usually cylindrical mixer, so that an additional mixing pipe for the casing of the mixer can be dispensed with. It should also be mentioned that the diameter of the mixer essentially corresponds to the diameter of the paint tube in one exemplary embodiment, so that the mixer completely fills the cross section of the paint tube. However, there is also the possibility within the scope of the invention that several mixers are arranged side by side in the paint tube of the atomizer, which will be described in detail below.

Dies ist beispielsweise dann sinnvoll, wenn der Zerstäuber zur Applizierung von verschiedenen Lacksystemen geeignet ist, wobei jedes der beiden Lacksysteme mehrere Komponenten aufweist, insbesondere einen Stammlack und einen Härter. Jedem der beiden Lacksysteme ist jeweils ein Mischer zugeordnet, um die Komponenten des Lacksystems miteinander zu mischen.This is useful, for example, if the atomizer is suitable for the application of different paint systems, each of the two paint systems having several components, in particular a base paint and a hardener. A mixer is assigned to each of the two coating systems in order to mix the components of the coating system with one another.

Hierbei besteht - wie bereits vorstehend kurz erwähnt - die Möglichkeit, dass die Mischer für die verschiedenen Lacksysteme gemeinsam in dem Farbrohr angeordnet sind, wobei sich die Mischer für die verschiedenen Lacksysteme bezüglich der Strömungsrichtung vorzugsweise nebeneinander befinden. Jeder Mischer für die verschiedenen Lacksysteme füllt hierbei dann nur einen Teil des Querschnitts des Farbrohrs auf. Darüber hinaus sind die verschiedenen Mischer dann vorzugsweise durch jeweils ein Mischrohr ummantelt, um die verschiedenen Mischer voneinander zu trennen.As already mentioned briefly above, there is the possibility here that the mixers for the different paint systems are arranged together in the paint tube, the mixers for the different paint systems preferably being located next to one another with respect to the direction of flow. Each mixer for the different paint systems then fills only part of the cross-section of the paint tube. In addition, the various mixers are then preferably encased by a mixing tube in order to separate the various mixers from one another.

Ferner ist zu erwähnen, dass die Mischer für die verschiedenen Farbsysteme unterschiedliche Mischeigenschaften aufweisen können, die an die Eigenschaften des jeweiligen Farbsystems angepasst sind, um ein möglichst optimales Mischergebnis zu erzielen.It should also be mentioned that the mixers for the different color systems can have different mixing properties that are adapted to the properties of the respective color system in order to achieve the best possible mixing result.

Alternativ besteht auch die Möglichkeit, dass die Mischer für die verschiedenen Lacksysteme nicht gemeinsam in dem Farbrohr angeordnet sind. So kann der Mischer für das eine Lacksystem in dem Farbrohr angeordnet sein, während sich der Mischer für das andere Farbsystem außerhalb des Farbrohrs befindet, beispielsweise in einem Ventil- oder Anschlussblock des Zerstäubers stromaufwärts vor dem Farbrohr.Alternatively, there is also the possibility that the mixers for the different paint systems are not arranged together in the paint tube. For example, the mixer for the one paint system can be arranged in the paint tube, while the mixer for the other paint system is located outside the paint tube, for example in a valve or connection block of the atomizer upstream of the paint tube.

Allgemein ist zu erwähnen, dass der erfindungsgemäße Zerstäuber mehrere Mischer aufweist, was auch ganz allgemein zur Optimierung des Mischergebnisses sinnvoll sein kann.In general, it should be mentioned that the atomizer according to the invention has several mixers, which can also be very useful in general for optimizing the mixing result.

(gestrichen)(painted)

Andere vorteilhafte Weiterbildungen der Erfindung sind in den Unteransprüchen gekennzeichnet oder werden nachstehend zusammen mit der Beschreibung der bevorzugten Ausführungsbeispiele der Erfindung anhand der Figuren näher erläutert. Es zeigen:

  • Figur 1: eine schematisierte Querschnittszeichnung eines nicht erfindungsgemäßen Rotationszerstäubers mit einem integrierten Gittermischer,
  • Figur 2: eine Perspektivansicht des Gittermischers aus dem Rotationszerstäuber gemäß Figur 1,
  • Figur 3: ein vereinfachtes Diagramm zur Verdeutlichung des Aufbaus eines Rotationszerstäubers zur Applikation von zwei verschiedenen Lacksystemen, wobei in das Farbrohr des Rotationszerstäubers zwei Mischer integriert sind,
  • Figur 4: eine erfindungsgemäße Abwandlung von Figur 3, wobei der eine Mischer in dem Farbrohr angeordnet ist, während sich der andere Mischer in dem Ventilblock befindet.
Other advantageous developments of the invention are characterized in the subclaims or are explained in more detail below together with the description of the preferred exemplary embodiments of the invention with reference to the figures. Show it:
  • Figure 1 : a schematic cross-sectional drawing of a rotary atomizer not according to the invention with an integrated lattice mixer,
  • Figure 2 : a perspective view of the lattice mixer from the rotary atomizer according to Figure 1 ,
  • Figure 3 : a simplified diagram to illustrate the structure of a rotary atomizer for the application of two different coating systems, two mixers being integrated in the paint tube of the rotary atomizer,
  • Figure 4 : a modification of Figure 3 , wherein one mixer is arranged in the paint tube, while the other mixer is in the valve block.

Figur 1 zeigt einen Rotationszerstäuber 1, der beispielsweise zur Lackierung von Kraftfahrzeugkarosseriebauteilen eingesetzt werden kann, wobei der Rotationszerstäuber 1 weitgehend herkömmlich aufgebaut ist, so dass auf eine detaillierte Beschreibung des Aufbaus und der Funktionsweise des Rotationszerstäubers 1 verzichtet werden kann. Für die Beschreibung der Erfindung ist lediglich wichtig, dass der Rotationszerstäuber 1 ein Farbrohr 2 aufweist, das an einem Anschlussblock 3 befestigt ist, wobei das Farbrohr 2 koaxial zur Drehachse einer Glockentellerwelle 4 ausgerichtet ist, um das zu applizierende Beschichtungsmittel zuzuführen. Figure 1 shows a rotary atomizer 1, which can be used, for example, for painting motor vehicle body components, the rotary atomizer 1 being constructed largely conventionally, so that a detailed description of the structure and operation of the rotary atomizer 1 can be dispensed with. For the description of the invention it is only important that the rotary atomizer 1 has a paint tube 2 which is fastened to a connection block 3, the paint tube 2 being aligned coaxially with the axis of rotation of a bell cup shaft 4 in order to supply the coating agent to be applied.

In dem Farbrohr 2 ist ein Gittermischer 5 angeordnet, um die verschiedenen Komponenten (z.B. Stammlack und Härter) des Beschichtungsmittels miteinander zu vermischen.A grating mixer 5 is arranged in the paint tube 2 in order to mix the various components (e.g. master varnish and hardener) of the coating composition with one another.

Der Gittermischer 5 weist zahlreiche langgestreckte, stabförmige, scharfkantige Mischelemente 6 auf, die gitterförmig ineinander verschränkt angeordnet sind, wobei die Mischelemente 6 in dem Farbrohr 2 Turbulenzen erzeugen, was zu einer guten Durchmischung führt.The lattice mixer 5 has numerous elongated, rod-shaped, sharp-edged mixing elements 6 which are arranged in a lattice-like manner, with the mixing elements 6 generating turbulence in the paint tube 2, which leads to thorough mixing.

Der Gittermischer besteht hierbei aus insgesamt zwölf Abschnitten 7, 8, die in Strömungsrichtung hintereinander angeordnet sind, und nacheinander durchströmt werden. Die verschiedenen Abschnitte 7, 8 des Gittermischers 5 unterscheiden sich hierbei durch die Ausrichtung der einzelnen Mischelemente 6, wie aus der Perspektivdarstellung in Figur 2 ersichtlich ist.The grid mixer consists of a total of twelve sections 7, 8, which are arranged one behind the other in the direction of flow and flow through one after the other. The different sections 7, 8 of the lattice mixer 5 differ in the orientation of the individual mixing elements 6, as shown in the perspective view in FIG Figure 2 can be seen.

Figur 3 zeigt ein schematisches Diagramm zur Verdeutlichung des Aufbaus eines erfindungsgemäßen Rotationszerstäubers 9, der zur Applikation von zwei verschiedenen Lacksystemen geeignet ist, wobei das erste Lacksystem aus einem ersten Stammlack SL1 und einem ersten Härter H1 besteht, während das zweite Lacksystem aus einem zweiten Stammlack SL2 und einem zweiten Härter H2 besteht. Figure 3 shows a schematic diagram to illustrate the structure of a rotary atomizer 9 according to the invention, which is suitable for the application of two different paint systems, the first paint system consisting of a first base paint SL1 and a first hardener H1, while the second paint system consists of a second base paint SL2 and a second hardener H2.

Zur Applikation der verschiedenen Lacksysteme weist der Rotationszerstäuber zwei Hauptnadelventile 10, 11 sowie jeweils einen Gittermischer 12, 13 auf, wobei die beiden Gittermischer 12, 13 gemeinsam nebeneinander in einem Farbrohr 14 des Rotationszerstäubers 9 angeordnet sind. Der Gittermischer 12 mischt hierbei den ersten Stammlack SL1 mit dem ersten Härter H1, während der andere Gittermischer 13 den zweiten Stammlack SL2 mit dem zweiten Härter H2 mischt.To apply the various coating systems, the rotary atomizer has two main needle valves 10, 11 and one grating mixer 12, 13 each, the two grating mixers 12, 13 being arranged together next to one another in a paint tube 14 of the rotary atomizer 9. The lattice mixer 12 mixes the first base paint SL1 with the first hardener H1, while the other lattice mixer 13 mixes the second base paint SL2 with the second hardener H2.

Die beiden Gittermischer 12, 13 entsprechen hierbei in Aufbau und Funktion dem Gittermischer 5 gemäß den Figuren 1 und 2.The two grid mixers 12, 13 correspond in structure and function to the grid mixer 5 according to FIGS Figures 1 and 2nd .

Darüber hinaus weist der Rotationszerstäuber 9 auch in diesem Ausführungsbeispiel einen Anschlussblock 15 mit integrierten Ventilen auf.In addition, the rotary atomizer 9 also has a connection block 15 with integrated valves in this exemplary embodiment.

Aus der Zeichnung ist weiterhin ersichtlich, dass die beiden Gittermischer 12, 13 in einem sehr kurzen Abstand 1<5cm stromaufwärts vor den zugehörigen Hauptnadelventilen 10, 11 angeordnet sind. Dies ist vorteilhaft, weil der zu spülende Leitungsabschnitt zwischen den Gittermischern 12, 13 und den zugehörigen Hauptnadelventilen 10, 11 dadurch ein geringes Volumen aufweist, so dass auch die Spülmittelverluste bzw. die Lackverluste entsprechend klein sind.It can also be seen from the drawing that the two grid mixers 12, 13 are arranged at a very short distance 1 <5 cm upstream of the associated main needle valves 10, 11. This is advantageous because the line section to be rinsed between the lattice mixers 12, 13 and the associated main needle valves 10, 11 thus has a small volume, so that the detergent losses and the paint losses are correspondingly small.

Figur 4 zeigt eine Abwandlung des Ausführungsbeispiels gemäß Figur 3, so dass zur Vermeidung von Wiederholungen auf die vorstehende Beschreibung verwiesen wird, wobei für entsprechende Einzelheiten dieselben Bezugszeichen verwendet werden. Figure 4 shows a modification of the embodiment according to Figure 3 , so that to avoid repetition reference is made to the above description, the same reference numerals being used for corresponding details.

Eine Besonderheit dieses Ausführungsbeispiels besteht in der Anordnung der beiden Gittermischer 12, 13. So befindet sich der Gittermischer 12 in diesem Ausführungsbeispiel ebenfalls innerhalb des Farbrohrs 14, wohingegen der andere Gittermischer 13 in den Anschlussblock 15 integriert ist.A special feature of this exemplary embodiment is the arrangement of the two grid mixers 12, 13. Thus, the grid mixer 12 in this exemplary embodiment is also located within the paint tube 14, whereas the other grid mixer 13 is integrated in the connection block 15.

Die Erfindung ist nicht auf die vorstehend beschriebenen bevorzugten Ausführungsbeispiele beschränkt. Vielmehr ist eine Vielzahl von Varianten und Abwandlungen möglich, die ebenfalls von dem Erfindungsgedanken Gebrauch machen und deshalb in den Schutzbereich fallen. Weiterhin ist zu erwähnen, dass die Erfindung auch Schutz beansprucht für den Gegenstand der Unteransprüche unabhängig von den Merkmalen der vorangehenden Ansprüche.The invention is not restricted to the preferred exemplary embodiments described above. Rather, a large number of variants and modifications are possible which also make use of the inventive idea and therefore fall within the scope of protection. It should also be mentioned that the invention also claims protection for the subject matter of the subclaims regardless of the features of the preceding claims.

Bezugszeichenliste:Reference symbol list:

11
RotationszerstäuberRotary atomizer
22nd
FarbrohrPaint tube
33rd
AnschlussblockTerminal block
44th
GlockentellerwelleBell plate shaft
55
GittermischerLattice mixer
66
MischelementeMixing elements
77
Abschnitt des GittermischersSection of the grid mixer
88th
Abschnitt des GittermischersSection of the grid mixer
99
RotationszerstäuberRotary atomizer
1010th
HauptnadelventilMain needle valve
1111
HauptnadelventilMain needle valve
1212
GittermischerLattice mixer
1313
GittermischerLattice mixer
1414
FarbrohrPaint tube
1515
AnschlussblockTerminal block
H1H1
Erster HärterFirst hardener
H2H2
Zweiter HärterSecond hardener
11
Leitungslänge zwischen Gittermischer und HauptnadelventilLine length between lattice mixer and main needle valve
SL1SL1
Erster StammlackFirst master paint
SL2SL2
Zweiter StammlackSecond base coat

Claims (9)

  1. An atomizer (1; 9), particularly a rotary atomizer, for the application of a coating agent consisting of several components, with
    a) a static mixer (5; 12, 13) which mixes the various components (SL1, H1, SL2, H2) of the coating agent with one another, wherein the mixer (5; 12, 13) has a plurality of fixed mixing elements (6) and is constructionally integrated into the atomizer (1; 9),
    b) wherein the mixer (5; 12, 13) is a lattice mixer, in which the mixing elements (6) are arranged intertwined in a lattice-like manner,
    c) wherein the mixer (5; 12, 13) comprises a plurality of sections (7, 8) which are arranged one behind the other in the direction of flow and through which the flow successively passes,
    characterized in that
    d) the mixing elements (6) in the adjacent sections (7, 8) of the mixer (5; 12, 13) in the direction of flow are aligned differently, so that the different section (7, 8) differ in the alignment of the mixing elements (6),
    e) the atomizer (1; 9) is suitable for application of at least two different paint systems, wherein each of the two paint systems has a plurality of components, particularly a base paint (SL1, SL2) and a hardener (H1, H2), and
    f) the atomizer (1; 9) for each of the two paint systems has a mixer (5; 12, 13) in each case, wherein the mixers (5; 12, 13) are constructionally integrated into the atomizer (1; 9).
  2. The atomizer (1; 9) according to Claim 1, characterized in that
    a) the individual mixing elements (6) have an essentially rectangular cross section in each case, and/or
    b) the individual mixing elements (6) are elongated in each case, and/or
    c) the individual mixing elements (6) are straight in each case, and/or
    d) the individual mixing elements (6) are sharp-edged in each case, and/or
    e) the individual mixing elements (6) are rod-shaped in each case, and/or
    f) the individual mixing elements (6) consist of plastic.
  3. The atomizer (1; 9) according to any one of the preceding claims, characterized in that
    a) the individual mixing elements (6) have a certain pitch angle relative to the direction of flow, and/or
    b) the pitch angle of the mixing elements (6) is greater than 20°, 30° or 40° and/or smaller than 70°, 60° or 50°, and/or
    c) the pitch angle for all mixing elements (6) is essentially the same.
  4. The atomizer (1; 9) according to any one of the preceding claims, characterized in that
    a) the number of sections of the mixer (5; 12, 13) is larger than 5, 6, 7, 8, 9, 10 or 11, and/or
    b) the mixer (5; 12, 13) is elongated in the direction of flow, and/or
    c) the mixer (5; 12, 13) is essentially cylindrical, and/or
    d) the mixer (5; 12, 13) has an overall length of less than 10cm, 8cm or 6cm, and/or
    e) the mixer (5; 12, 13) is arranged completely within the atomizer (1; 9).
  5. The atomizer (1; 9) according to any one of the preceding claims, characterized in that
    a) the atomizer (1; 9) has a controllable main needle valve (10, 11) which determines whether the atomizer (1; 9) applies the coating agent or not as a function of the valve position thereof, and
    b) the mixer (5; 12, 13) is arranged upstream of the main needle valve (10, 11), and
    c) a line length (1) lies between the end of the mixer (5; 12, 13) positioned downstream and the main needle valve (10, 11), which is shorter than 10cm, 6cm or 5cm.
  6. The atomizer (1; 9) according to any one of the preceding claims, characterized in that
    a) the atomizer (1; 9) has a hollow paint tube (14) in order to supply the coating agent, and
    b) the mixer (5; 12, 13) is arranged completely in the paint tube (14), and/or
    c) the mixing elements (6) are arranged without an additional mixing tube in the paint tube (14), and/or
    d) the diameter of the mixer (5; 12, 13) essentially corresponds to the diameter of the paint tube (14), so that the mixer (5; 12, 13) fills the cross section of the paint tube (14) completely.
  7. The atomizer (1; 9) according to Claim 6, characterized in that
    a) the mixers (5; 12, 13) for the various paint systems are arranged together in the paint tube (14), and/or
    b) the mixers (5; 12, 13) for the various paint systems are arranged adjacently with respect to the direction of flow, and/or
    c) the mixers (5; 12, 13) for the various paint systems in each case only fill part of the cross section of the paint tube (14), and/or
    d) the mixers (5; 12, 13) for the various paint systems in each case have a mixing tube in which the mixing elements (6) are arranged, wherein the mixing tubes separate the mixers (5; 12, 13) from one another, and/or
    e) the mixers (5; 12, 13) for the various paint systems have different mixing properties which are adapted to the properties of the respective paint system.
  8. The atomizer (1; 9) according to Claim 6, characterized in that the mixer (5; 12, 13) for one paint system is arranged in the paint tube (14), whilst the mixer (5; 12, 13) for the other paint system is located outside of the paint tube (14), for example in a valve block of the atomizer (1; 9) upstream of the paint tube (14).
  9. The atomizer (1; 9) according to one of the preceding claims, characterized in that a plurality of mixers (5; 12, 13) are arranged in the atomizer (1; 9).
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US9539594B2 (en) 2017-01-10
DE102010019771A1 (en) 2011-11-10
MX2012012740A (en) 2012-11-21
CN102883818B (en) 2016-01-06
PL2566628T5 (en) 2020-11-02
EP2566628B1 (en) 2017-09-06
US20150122915A1 (en) 2015-05-07
EP2566628A1 (en) 2013-03-13
CN102883818A (en) 2013-01-16
PL2566628T3 (en) 2018-02-28
ES2648137T5 (en) 2021-02-22
WO2011138028A1 (en) 2011-11-10
ES2648137T3 (en) 2017-12-28

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