EP2888382B2 - Aluminium alloy strip which is resistant to intercrystalline corrosion and method for producing same - Google Patents
Aluminium alloy strip which is resistant to intercrystalline corrosion and method for producing same Download PDFInfo
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- EP2888382B2 EP2888382B2 EP13756051.2A EP13756051A EP2888382B2 EP 2888382 B2 EP2888382 B2 EP 2888382B2 EP 13756051 A EP13756051 A EP 13756051A EP 2888382 B2 EP2888382 B2 EP 2888382B2
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- aluminium alloy
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
Definitions
- the invention relates to an aluminum alloy strip consisting of an aluminum alloy of type AA 5xxx, which, in addition to Al and unavoidable impurities, has a Mg content of at least 4% by weight.
- the invention relates to a method for producing the aluminum alloy strip according to the invention and to a component produced from an aluminum alloy strip according to the invention.
- Aluminum-magnesium (AlMg) alloys of type AA 5xxx are used in the form of sheets, plates or strips for the construction of welded or joined structures in shipbuilding, automobile construction and aircraft construction. They are characterized in particular by their high strength, which increases with increasing magnesium content.
- Aluminium alloy strips of type AA5182 with a Mg content of at least 4 wt.% are also known from the paper Semi-Solid Processing of Alloys and Composites by Kang et al. and from the paper Comparison of recrystallization textures in cold-rolled DC and CC AA 5182 aluminum alloys by Liu et al., as well as from the US 2003/0150587 A1
- the paper Hot-Tear Susceptibility of Aluminum Wrought Alloys and the Effect of Grain Refining by Lin et al. concerns round bars made of its AA5182 alloy.
- the DE 102 31 437 A1 relates to corrosion-resistant aluminium alloy sheets, whereby sufficient resistance to intergranular corrosion is achieved by the addition of Zn in a content of more than 0.4 wt.%.
- AlMg alloys of type AA 5xxx with Mg contents of more than 3%, especially more than 4%, are increasingly prone to intergranular corrosion when exposed to elevated temperatures.
- ⁇ -Al 5 Mg 3 phases precipitate along the grain boundaries, which are referred to as ⁇ particles and can be selectively dissolved in the presence of a corrosive medium.
- the aluminum alloy of type AA 5182 Al 4.5% Mg 0.4% Mn
- a corrosive medium for example water in the form of moisture, is to be expected.
- Susceptibility to intergranular corrosion is usually tested in a standard test according to ASTM G67, in which the samples are exposed to nitric acid and the mass loss due to the release of ⁇ -particles is measured.
- ASTM G67 the mass loss for materials that are not resistant to intergranular corrosion is more than 15 mg/cm 2 .
- the present invention is based on the object of proposing an aluminum alloy strip made of an AlMg alloy which, despite high strengths and a Mg content of more than 4% by weight, is resistant to intergranular corrosion, in particular even after forming and subsequent exposure to heat.
- a manufacturing process is to be specified with which aluminum strips resistant to intergranular corrosion can be produced.
- components of a motor vehicle that are resistant to intergranular corrosion for example body components or body attachments such as doors, hoods and tailgates or other structural parts, but also component parts made of an aluminum alloy of type AA 5xxx, are to be proposed.
- Remainder Al and unavoidable impurities individually maximum 0.05 wt.%, in total maximum 0.15 wt.%, wherein the aluminium alloy strip is cold rolled and annealed and the aluminium alloy strip has a yield strength Rp0.2 of more than 120 MPa and a tensile strength Rm of more than 260 MPa.
- An aluminum alloy strip with a recrystallized structure can be provided by hot strips or annealed cold strips.
- Extensive studies have shown that there is a relationship between grain size, magnesium content and resistance to intergranular corrosion. Since the grain size of a material is always in the form of a distribution, all information provided on grain size refers to the average grain size. The average grain size can be determined according to ASTM E1382. With a sufficiently large grain size, i.e. if the grain size is greater than or equal to the lower limit of the grain size according to the invention in relation to the Mg content of the aluminum alloy strip, resistance to intergranular corrosion can be achieved so that the mass loss in the ASTM G67 test drops to below 15 mg/cm 2.
- Corresponding aluminum strips can therefore be described as resistant to intergranular corrosion. This was demonstrated for the above-mentioned aluminum strips in the undeformed state after a simulated cathodic dip-painting cycle and after a simulated cathodic dip-painting cycle including a subsequent operating load of a maximum of 500 hours at 80°C. The resistance to intergranular corrosion was also demonstrated for the above-mentioned strips when the material is stretched by 15% before the cathodic dip-painting cycle and the operating load in order to simulate the formation into a component. As a result, the aluminum alloy strip according to the invention provides high strengths and yield points due to its relatively high Mg content and is also resistant to intergranular corrosion. It is therefore very suitable for use in heat-stressed areas in automotive construction.
- the remainder Al and unavoidable impurities individually maximum 0.05 wt.%, in total maximum 0.15 wt.%.
- Mg 4.45 wt.% to 4.8 wt.%
- the maximum grain size is 50 ⁇ m, since the process reliability decreases when producing aluminum strips with grain sizes of more than 50 ⁇ m from an aluminum alloy of type AA 5xxx with a Mg content of at least 4% by weight.
- a maximum grain size of 50 ⁇ m can be achieved with process stability.
- the process stability for producing structures with controlled grain size increases with decreasing grain size.
- the production of an aluminum alloy strip with a maximum grain size of 45 ⁇ m, preferably a maximum of 40 ⁇ m, is therefore associated with increasing process stability.
- the aluminum alloy strip according to the invention has a thickness of 0.5 mm - 5 mm and is therefore ideally suited for most applications, for example in automobile construction.
- the aluminum alloy strip according to the invention is cold rolled and then soft annealed. Recrystallizing soft annealing usually takes place at temperatures of 300°C - 500°C and makes it possible to eliminate the hardening introduced during the rolling process and to ensure good formability of the aluminum alloy strip. In addition, cold rolled, soft annealed and therefore recrystallized strips can be used to provide lower final thicknesses than recrystallized hot strips.
- the aluminum alloy strip according to the invention has a yield strength R p0.2 of more than 120 MPa and a tensile strength R m of more than 260 MPa.
- the aluminum alloy strip according to the invention which is resistant to intergranular corrosion, thus also exceeds the strength properties of an aluminum alloy of type AA5182 required by DIN485-2.
- the elongation values with a uniform elongation A g of at least 19% and an elongation at break A 80mm of at least 22% also far exceed the values required by DIN485-2.
- the process steps listed result in a grain size after annealing that satisfies the dependency on the Mg content listed above, due to the low degree of rolling during cold rolling of the aluminum alloy strip to the final thickness.
- the degree of rolling to the final thickness is used to set the hardening of the strip before annealing, which determines the resulting grain size.
- the degree of rolling before annealing i.e. the degree of rolling of the final thickness during cold rolling
- the degree of rolling before annealing is limited to less than 40%, preferably a maximum of 30%, particularly preferably a maximum of 25%.
- an additional cold rolling step takes place after an intermediate annealing at 300°C - 500°C.
- the aluminum alloy strip which has been strongly hardened by cold rolling, is recrystallized and converted back into a formable state.
- the subsequent cold rolling step with a degree of rolling of less than 40%, preferably a maximum of 30%, particularly preferably a maximum of 25%, means that, in conjunction with the Mg content of the aluminum alloy used, the grain size can be adjusted to the required ratio.
- a degree of rolling of less than 40% preferably a maximum of 30%, particularly preferably a maximum of 25%
- the soft annealing and/or the intermediate annealings take place in a batch furnace, in particular a chamber furnace, or a continuous furnace. Both furnaces provide a sufficiently coarse grain structure, which ensures resistance to intergranular corrosion. Batch furnaces are usually not as expensive to operate and purchase as continuous furnaces.
- the above-mentioned object is achieved by a component for a motor vehicle which consists at least partially of an aluminum alloy strip according to the invention.
- the component is usually subjected to painting, preferably cathodic dip painting. Nevertheless, there are also possible uses for unpainted components made from the aluminum alloy strip according to the invention.
- the aluminum alloy strip has excellent properties in terms of strength, forming properties and resistance to intergranular corrosion, so that the heat load during painting, a baking process that typically takes 20 minutes at around 185°C, has little influence on the resistance of the component to intergranular corrosion.
- Forming into a component which was simulated by stretching by 15% transverse to the original rolling direction, also has only a minor influence on the resistance to intergranular corrosion.
- the values for the mass loss according to ASTM G67 are less than 15 mg/cm 2 .
- operation in temperature-stressed areas which was simulated by a heat load of 200 or 500 hours at 80°C, only has a minor influence on the resistance to intergranular corrosion.
- the mass loss values according to ASTM G67 are less than 15 mg/cm 2 even after corresponding temperature stress.
- a component is particularly advantageous if it is designed as a body or body attachment part of a motor vehicle.
- Typical body parts are the fender or parts of the floor assembly, the roof, etc.
- Body attachment parts are generally doors and tailgates, etc. that are not firmly connected to the motor vehicle.
- Invisible body components or body attachment parts are preferably made from the aluminum alloy strip according to the invention. These are, for example, inner door parts or inner parts of tailgates, but also floor panels, etc.
- a typical heat load for such components of a motor vehicle, for example inner door parts is caused, for example, by sunlight during operation of a motor vehicle.
- body or body attachment parts of a motor vehicle are generally exposed to moisture, for example in the form of splash water or condensation, so that resistance to intergranular corrosion must be required.
- the body or body attachment parts according to the invention made from an aluminum alloy strip according to the present invention, meet these conditions and also ensure a weight advantage over the steel structures used to date.
- the grain size varied, for example, from 16 ⁇ m to 61 ⁇ m, the final rolling degree from 17% to 57%.
- the final annealing was carried out either in a chamber furnace (KO) or in a continuous strip furnace (BDLO).
- Fig. 1 shows the sequence of examples for the production of aluminum strips.
- the flow chart of Fig.1 shows schematically the various process steps of the manufacturing process of the aluminum alloy strip according to the invention.
- step 1 a rolling ingot made of an aluminum alloy of type AA 5xxx with a Mg content of at least 4 wt.% is cast, for example in DC continuous casting.
- the rolling ingot is then subjected to homogenization in process step 2, which can be carried out in one or more stages. During homogenization, temperatures of the rolling ingot of 480 to 550 °C are reached for at least 0.5 h.
- process step 3 the rolling ingot is then hot rolled, with typical temperatures of 280 °C to 500 °C being reached.
- the final thicknesses of the hot strip are, for example, 2 to 12 mm.
- the final hot strip thickness can be selected so that after hot rolling only a single cold rolling step 4 takes place, in which the hot strip is reduced in thickness with a rolling degree of less than 40%, preferably a maximum of 30%, particularly preferably a maximum of 25%.
- the aluminium alloy strip, cold rolled to final thickness, is then subjected to soft annealing.
- the soft annealing was carried out in a continuous furnace or in a chamber furnace in order to determine the dependence of the To test corrosion properties of the chamber or continuous furnace.
- the second method with an intermediate annealing was used.
- the hot strip is fed to a cold roller 4a, which has a rolling degree of more than 30% or more than 50%, so that the aluminum alloy strip preferably recrystallizes throughout during a subsequent intermediate annealing.
- the intermediate annealing was carried out either in a continuous furnace at 400 °C to 450 °C or in a chamber furnace at 330 °C to 380 °C.
- the intermediate annealing is in Fig. 1 with the process step 4b.
- process step 4c according to Fig. 1 the intermediately annealed aluminum alloy strip is finally fed to a cold rolling process to the final thickness, with the degree of rolling in process step 4c being less than 40%, preferably a maximum of 30%, particularly preferably a maximum of 25%.
- the aluminum alloy strip is then returned to the soft state by soft annealing, with the soft annealing being carried out either in a continuous furnace at 400 °C to 450 °C or in a chamber furnace at 330 °C to 380 °C.
- different aluminum alloys and different degrees of rolling after the intermediate annealing were set in addition to different ones.
- the values for the degree of rolling after the intermediate annealing are also shown in Table 1.
- the grain size of the annealed aluminum alloy strip was measured in each case.
- the aluminum alloy strips were also subjected to various heat treatments before the corrosion test.
- a first heat treatment consisted of storing the aluminum strips for 20 minutes at 185 °C to simulate the KTL cycle.
- the aluminum alloy strips were stored for an additional 200 hours or 500 hours at 80 °C and then subjected to the corrosion test. Since forming of aluminum alloy strips or sheets can also influence corrosion resistance, the aluminum alloy strips were stretched by around 15% in a further test, subjected to heat treatment or storage at an elevated temperature and then subjected to an intergranular corrosion test in accordance with ASTM G67, in which the mass loss was measured.
- examples 11 to 19 can all be classified as resistant to intergranular corrosion. This also applies to their use in motor vehicles with thermal stress and the presence of moisture or a corrosive medium.
- examples 12, 14, 16 and 17 showed the mechanical properties of an aluminum alloy strip of type AA 5182 required by DIN EN 485-2.
- Fig. 2 The diagram shows the measured grain sizes as a function of the Mg content in wt.%. In addition to the measuring points, the diagram also contains two curves A and B.
- the straight line A shows the grain sizes above which the aluminum alloy strip can be described as resistant to intergranular corrosion at a specific Mg content.
- Curve B shows the limit from which the aluminium alloy strips have a yield strength that is too low, less than 110 MPa, so that they cannot be considered alloy AA 5182 according to DIN EN485-2.
- Fig. 3 a typical component of a motor vehicle, shown schematically in the form of an inner door part.
- Inner door parts 6 are usually made of steel.
- the aluminum alloy strips produced show that the provision of high strengths with resistance to intergranular corrosion can also be achieved, provided that the grain size ratio in relation to the Mg content is adjusted according to the invention.
- the component according to the invention according to Fig. 3 is significantly lighter than a comparable component made of steel and is nevertheless resistant to intergranular corrosion.
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Description
Die Erfindung betrifft ein Aluminiumlegierungsband bestehend aus einer Aluminiumlegierung vom Typ AA 5xxx, welche neben Al und unvermeidbaren Verunreinigungen einen Mg-Gehalt von mindestens 4 Gew.-% aufweist. Daneben betrifft die Erfindung ein Verfahren zur Herstellung des erfindungsgemäßen Aluminiumlegierungsbandes sowie ein Bauteil hergestellt aus einem erfindungsgemäßen Aluminiumlegierungsband.The invention relates to an aluminum alloy strip consisting of an aluminum alloy of type AA 5xxx, which, in addition to Al and unavoidable impurities, has a Mg content of at least 4% by weight. In addition, the invention relates to a method for producing the aluminum alloy strip according to the invention and to a component produced from an aluminum alloy strip according to the invention.
Aluminiummagnesium-(AlMg-)legierungen vom Typ AA 5xxx werden in Form von Blechen oder Platten bzw. Bändern für die Konstruktion von geschweißten oder gefügten Strukturen im Schiffs-, Automobil- und Flugzeugbau verwendet. Sie zeichnen sich insbesondere durch eine hohe Festigkeit aus, welche mit zunehmendem Magnesiumgehalt steigt.Aluminum-magnesium (AlMg) alloys of type AA 5xxx are used in the form of sheets, plates or strips for the construction of welded or joined structures in shipbuilding, automobile construction and aircraft construction. They are characterized in particular by their high strength, which increases with increasing magnesium content.
Beispielsweise ist aus dem Aufsatz Development of twin-belt cast AA5XXX series aluminum alloy materials for automotive sheet applications von Zhao et al. ein Aluminiumband bestehend aus einer AA5182-Legierung mit einem Mg-Gehalt von 4,65 Gew.-%, welches sich für den Einsatz im Automobilbau eignet, bekannt.For example, from the article Development of twin-belt cast AA5XXX series aluminum alloy materials for automotive sheet applications by Zhao et al., an aluminum strip consisting of an AA5182 alloy with a Mg content of 4.65 wt.%, which is suitable for use in automotive construction, is known.
Aluminiumlegierungsbänder vom Typ AA5182 mit einem Mg-Gehalt von mindestens 4 Gew.-% sind ebenfalls aus dem Aufsatz Semi-Solid Processing of Alloys and Composites von Kang et al. und aus dem Aufsatz Comparison of recrystallization textures in cold-rolled DC and CC AA 5182 aluminum alloys von Liu et al., sowie aus der
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AlMg-Legierungen vom Typ AA 5xxx mit Mg-Gehalten von mehr als 3 %, insbesondere mehr als 4 % neigen zunehmend zur interkristallinen Korrosion, wenn sie erhöhten Temperaturen ausgesetzt sind. Bei Temperaturen von 70 - 200°C scheiden sich β-Al5Mg3 Phasen entlang der Korngrenzen aus, welche als β-Partikel bezeichnet werden und in Anwesenheit eines korrosiven Mediums selektiv aufgelöst werden können. Dies hat zur Folge, dass insbesondere die sehr gute Festigkeitseigenschaften sowie eine sehr gute Umformbarkeit aufweisende Aluminiumlegierung vom Typ AA 5182 (Al 4,5 % Mg 0,4 % Mn) nicht in wärmebelasteten Bereichen eingesetzt wird, sofern mit der Anwesenheit eines korrosiven Mediums, beispielsweise Wasser in Form von Feuchtigkeit, gerechnet werden muss. Dies betrifft insbesondere die Bauteile eines Kraftfahrzeugs, welche üblicherweise einer kathodischen Tauch-Lackierung (KTL) unterzogen und anschließend in einem Einbrennvorgang getrocknet werden, da bereits durch diesen Einbrennvorgang bei üblichen Aluminiumlegierungsbändern eine Sensibilisierung bezüglich interkristalliner Korrosion hervorgerufen werden kann. Darüber hinaus muss für den Einsatz im Automobilbereich die Umformung bei der Herstellung eines Bauteils sowie die anschließende Betriebsbelastung des Bauteils berücksichtigt werden.AlMg alloys of type AA 5xxx with Mg contents of more than 3%, especially more than 4%, are increasingly prone to intergranular corrosion when exposed to elevated temperatures. At temperatures of 70 - 200°C, β-Al 5 Mg 3 phases precipitate along the grain boundaries, which are referred to as β particles and can be selectively dissolved in the presence of a corrosive medium. This means that the aluminum alloy of type AA 5182 (Al 4.5% Mg 0.4% Mn), which has very good strength properties and very good formability, is not used in heat-stressed areas if the presence of a corrosive medium, for example water in the form of moisture, is to be expected. This particularly applies to the components of a motor vehicle, which are usually subjected to cathodic dip painting (KTL) and then dried in a baking process, since this baking process alone can cause sensitization to intergranular corrosion in conventional aluminum alloy strips. In addition, for use in the automotive sector, the deformation during the manufacture of a component and the subsequent operating load of the component must be taken into account.
Die Anfälligkeit gegen interkristalline Korrosion wird üblicherweise in einem Standardtest gemäß ASTM G67 geprüft, bei welchem die Proben einer Salpetersäure ausgesetzt werden und der Massenverlust aufgrund der Auslösung von β-Partikeln gemessen wird. Gemäß ASTM G67 beträgt der Massenverlust bei Werkstoffen, welche nicht resistent gegen interkristalline Korrosion sind, mehr als 15 mg/cm2.Susceptibility to intergranular corrosion is usually tested in a standard test according to ASTM G67, in which the samples are exposed to nitric acid and the mass loss due to the release of β-particles is measured. According to ASTM G67, the mass loss for materials that are not resistant to intergranular corrosion is more than 15 mg/cm 2 .
Entsprechende Werkstoffe und Aluminiumbänder sind daher nicht geeignet, in wärmebelasteten Bereichen eingesetzt zu werden.Corresponding materials and aluminum strips are therefore not suitable for use in heat-stressed areas.
Hiervon ausgehend liegt der vorliegenden Erfindung die Aufgabe zugrunde, ein Aluminiumlegierungsband aus einer AlMg-Legierung vorzuschlagen, welches trotz hoher Festigkeiten und Mg-Gehalt von mehr als 4 Gew.-%, insbesondere auch nach einer Umformung und einer anschließenden Temperaturbeaufschlagung beständig gegen interkristalline Korrosion ist. Darüber hinaus soll ein Herstellverfahren angegeben werden, mit welchem gegen interkristalline Korrosion beständige Aluminiumbänder hergestellt werden können. Schließlich sollen gegen interkristalline Korrosion beständige Bauteile eines Kraftfahrzeugs, beispielsweise Karosseriebauteile oder Karosserieanbauteile, wie Türen, Hauben und Heckklappen oder andere Strukturteile aber auch Komponententeile aus einer Aluminiumlegierung vom Typ AA 5xxx vorgeschlagen werden.Based on this, the present invention is based on the object of proposing an aluminum alloy strip made of an AlMg alloy which, despite high strengths and a Mg content of more than 4% by weight, is resistant to intergranular corrosion, in particular even after forming and subsequent exposure to heat. In addition, a manufacturing process is to be specified with which aluminum strips resistant to intergranular corrosion can be produced. Finally, components of a motor vehicle that are resistant to intergranular corrosion, for example body components or body attachments such as doors, hoods and tailgates or other structural parts, but also component parts made of an aluminum alloy of type AA 5xxx, are to be proposed.
Gemäß einer ersten Lehre der vorliegenden Erfindung wird die oben aufgezeigte Aufgabe durch ein Aluminiumlegierungsband gelöst, das ein rekristallisiertes Gefüge hat, wobei die Korngröße (KG) des Gefüges in µm folgende Abhängigkeit vom Mg-Gehalt (c_Mg) in Gew.-% erfüllt:
- Si ≤ 0,2 %,
- Fe ≤ 0,35 %,
- 0,04 % ≤ Cu ≤ 0,08 %,
- 0,2 % ≤ Mn ≤ 0,5 %,
- 4,35 % ≤ Mg ≤ 4,8 %,
- Cr ≤ 0,1 %,
- Zn ≤ 0,25 %,
- Ti ≤ 0,1 %,
- Si ≤ 0.2%,
- Fe ≤ 0.35%,
- 0.04% ≤ Cu ≤ 0.08%,
- 0.2% ≤ Mn ≤ 0.5%,
- 4.35% ≤ Mg ≤ 4.8%,
- Cr ≤ 0.1%,
- Zn ≤ 0.25 %,
- Ti ≤ 0.1%,
Rest Al und unvermeidbare Verunreinigungen einzeln maximal 0,05 Gew.-%, in Summe maximal 0,15 Gew.-%, wobei das Aluminiumlegierungsband kalt gewalzt und weich geglüht ist und das Aluminiumlegierungsband eine Streckgrenze Rp0,2 von mehr als 120 MPa und eine Zugfestigkeit Rm von mehr als 260 MPa aufweist.Remainder Al and unavoidable impurities individually maximum 0.05 wt.%, in total maximum 0.15 wt.%, wherein the aluminium alloy strip is cold rolled and annealed and the aluminium alloy strip has a yield strength Rp0.2 of more than 120 MPa and a tensile strength Rm of more than 260 MPa.
Bei einem Cu-Gehalt von 0,04 Gew.-% bis 0,08 Gew.-% wird erreicht, dass Kupfer an einer Festigkeitssteigerung beteiligt ist, aber dennoch die Korrosionsbeständigkeit nicht zu stark herabsetzt. Zusätzlich kann durch die Beschränkung des Mg-Bereiches auf 4,35 Gew.-% bis 4,8 Gew.-% eine sehr gute Festigkeit bei moderater Korngröße erzielt werden. Mithin kann auch eine Beständigkeit gegen interkristalline Korrosion besonders prozesssicher erreicht werden, da die notwendigen Korngrößen des Gefüges im Verfahren sicher erreicht werden können.With a Cu content of 0.04 wt.% to 0.08 wt.%, copper contributes to an increase in strength, but does not reduce corrosion resistance too much. In addition, by limiting the Mg range to 4.35 wt.% to 4.8 wt.%, very good strength can be achieved with a moderate grain size. Resistance to intergranular corrosion can therefore also be achieved with particularly reliable processing, since the necessary grain sizes of the structure can be reliably achieved in the process.
Ein Aluminiumlegierungsband mit einem rekristallisierten Gefüge kann durch Warmbänder oder weichgeglühte Kaltbänder bereitgestellt werden. Durch umfangreiche Untersuchungen wurde herausgefunden, dass ein Zusammenhang zwischen der Korngröße, dem Magnesiumgehalt und der Beständigkeit gegen interkristalline Korrosion besteht. Da die Korngröße eines Materials stets in Form einer Verteilung vorliegt, beziehen sich alle gemachten Angaben der Korngröße auf die mittlere Korngröße. Die mittlere Korngröße kann gemäß ASTM E1382 ermittelt werden. Bei ausreichend großer Korngröße, d.h. sofern die Korngröße größer oder gleich des erfindungsgemäßen unteren Grenzwertes der Korngröße in Bezug auf den Mg-Gehalt des Aluminiumlegierungsbandes ist, kann eine Beständigkeit gegen interkristalline Korrosion erreicht werden, so dass der Massenverlust beim ASTM G67 Test auf unter 15 mg/cm2 absinkt. Entsprechende Aluminiumbänder können daher als beständig gegen interkristalline Korrosion bezeichnet werden. Dies wurde für die oben genannten Aluminiumbänder im unverformten Zustand nach einem simulierten KTL-Zyklus sowie nach einem simulierten KTL-Zyklus inklusive einer anschließenden Betriebsbelastung mit maximal 500 Stunden bei 80°C nachgewiesen. Auch wurden für die oben genannten Bänder die Beständigkeit gegen interkristalline Korrosion nachgewiesen, wenn vor dem KTL-Zyklus und der Betriebsbelastung das Material mit 15 % gereckt wird, um die Umformung zu einem Bauteil zu simulieren. Im Ergebnis stellt das erfindungsgemäße Aluminiumlegierungsband aufgrund seines relativ hohen Mg-Gehaltes hohe Festigkeiten und Streckgrenzen zur Verfügung und ist gleichzeitig beständig gegen interkristalline Korrosion. Es ist daher sehr gut für den Einsatz in wärmebelasteten Bereichen im Automobilbau einsetzbar.An aluminum alloy strip with a recrystallized structure can be provided by hot strips or annealed cold strips. Extensive studies have shown that there is a relationship between grain size, magnesium content and resistance to intergranular corrosion. Since the grain size of a material is always in the form of a distribution, all information provided on grain size refers to the average grain size. The average grain size can be determined according to ASTM E1382. With a sufficiently large grain size, i.e. if the grain size is greater than or equal to the lower limit of the grain size according to the invention in relation to the Mg content of the aluminum alloy strip, resistance to intergranular corrosion can be achieved so that the mass loss in the ASTM G67 test drops to below 15 mg/cm 2. Corresponding aluminum strips can therefore be described as resistant to intergranular corrosion. This was demonstrated for the above-mentioned aluminum strips in the undeformed state after a simulated cathodic dip-painting cycle and after a simulated cathodic dip-painting cycle including a subsequent operating load of a maximum of 500 hours at 80°C. The resistance to intergranular corrosion was also demonstrated for the above-mentioned strips when the material is stretched by 15% before the cathodic dip-painting cycle and the operating load in order to simulate the formation into a component. As a result, the aluminum alloy strip according to the invention provides high strengths and yield points due to its relatively high Mg content and is also resistant to intergranular corrosion. It is therefore very suitable for use in heat-stressed areas in automotive construction.
Erfüllt die Korngröße gemäß einer nächsten Ausführungsform des erfindungsgemäßen Aluminiumlegierungsbandes zusätzlich die folgende Bedingung:
- mit KG in µm und c_Mg in Gew.-%,
- kann sichergestellt werden, dass die Streckgrenze Rp0,2 des Aluminiumlegierungsbandes größer als 110 MPa ist. Die Zugfestigkeit des Bandes liegt dabei üblicherweise oberhalb von 255 MPa.
- with KG in µm and c_Mg in wt.%,
- It can be ensured that the yield strength R p0.2 of the aluminum alloy strip is greater than 110 MPa. The tensile strength of the strip is usually above 255 MPa.
Eine weitere vorteilhafte Ausgestaltung des Aluminiumlegierungsbandes wird dadurch erreicht, dass die Aluminiumlegierung des Aluminiumlegierungsbandes folgende Zusammensetzung in Gew.-% aufweist:
- Si ≤ 0,2 %,
- Fe ≤ 0,35 %,
- 0,04 % ≤ Cu ≤ 0,08 %,
- 0,2 % ≤ Mn ≤ 0,5 %,
- 4,45 % ≤ Mg ≤ 4,8 %,
- Cr ≤ 0,1 %,
- Zn ≤ 0,25 %,
- Ti ≤ 0,1 %,
- Si ≤ 0.2%,
- Fe ≤ 0.35%,
- 0.04% ≤ Cu ≤ 0.08%,
- 0.2% ≤ Mn ≤ 0.5%,
- 4.45% ≤ Mg ≤ 4.8%,
- Cr ≤ 0.1%,
- Zn ≤ 0.25 %,
- Ti ≤ 0.1%,
Rest Al und unvermeidbare Verunreinigungen einzeln maximal 0,05 Gew.-%, in Summe maximal 0,15 Gew.-%. Durch die Beschränkung des Mg-Bereiches auf 4,45 Gew.-% bis 4,8 Gew.-% wird ebenfalls eine sehr gute Festigkeit bei moderater Korngröße erzielt werden.The remainder Al and unavoidable impurities individually maximum 0.05 wt.%, in total maximum 0.15 wt.%. By limiting the Mg range to 4.45 wt.% to 4.8 wt.%, a very good strength is also achieved. with moderate grain size.
Gemäß einer nächsten Ausgestaltung des erfindungsgemäßen Aluminiumlegierungsbandes liegt die Korngröße maximal bei 50 µm, da bei der Herstellung von Aluminiumbändern mit Korngrößen von mehr als 50 µm aus einer Aluminiumlegierung vom Typ AA 5xxx mit einem Mg-Gehalt von mindestens 4 Gew.-% die Prozesssicherheit absinkt. Eine Korngröße von maximal 50 µm kann dagegen prozessstabil erreicht werden. Die Prozessstabilität zur Erzeugung von Gefügen mit kontrollierter Korngröße nimmt mit sinkender Korngröße zu. Damit ist die Herstellung eines Aluminiumlegierungsbandes mit einer Korngröße von maximal 45 µm, bevorzugt maximal 40 µm mit steigender Prozessstabilität verbunden.According to a further embodiment of the aluminum alloy strip according to the invention, the maximum grain size is 50 µm, since the process reliability decreases when producing aluminum strips with grain sizes of more than 50 µm from an aluminum alloy of type AA 5xxx with a Mg content of at least 4% by weight. A maximum grain size of 50 µm, on the other hand, can be achieved with process stability. The process stability for producing structures with controlled grain size increases with decreasing grain size. The production of an aluminum alloy strip with a maximum grain size of 45 µm, preferably a maximum of 40 µm, is therefore associated with increasing process stability.
Gemäß einer nächsten Ausgestaltung des erfindungsgemäßen Aluminiumlegierungsbandes weist dieses eine Dicke von 0,5 mm - 5 mm auf und ist damit für die meisten Anwendungen, beispielsweise im Automobilbau, hervorragend geeignet.According to a further embodiment of the aluminum alloy strip according to the invention, it has a thickness of 0.5 mm - 5 mm and is therefore ideally suited for most applications, for example in automobile construction.
Das erfindungsgemäße Aluminiumlegierungsband ist kalt gewalzt und abschließend weich geglüht. Eine rekristallisierende Weichglühung findet üblicherweise bei Temperaturen von 300°C - 500°C statt und ermöglicht es, die im Walzvorgang eingebrachten Verfestigungen zu beseitigen und eine gute Umformbarkeit des Aluminiumlegierungsbandes zu gewährleisten. Darüber hinaus können mit kaltgewalzten, weich geglühten und daher rekristallisierten Bändern geringere Enddicken bereitgestellt werden als mit rekristallisierten Warmbändern.The aluminum alloy strip according to the invention is cold rolled and then soft annealed. Recrystallizing soft annealing usually takes place at temperatures of 300°C - 500°C and makes it possible to eliminate the hardening introduced during the rolling process and to ensure good formability of the aluminum alloy strip. In addition, cold rolled, soft annealed and therefore recrystallized strips can be used to provide lower final thicknesses than recrystallized hot strips.
Schließlich weist das erfindungsgemäße Aluminiumlegierungsband eine Streckgrenze Rp0,2 von mehr als 120 MPa und eine Zugfestigkeit Rm von mehr als 260 MPa auf. Damit übertrifft das gegen interkristalline Korrosion beständige, erfindungsgemäße Aluminiumlegierungsband auch die gemäß DIN485-2 geforderten Festigkeitseigenschaften einer Aluminiumlegierung vom Typ AA5182. Dabei übertreffen auch die Dehnungswerte mit einer Gleichmaßdehnung Ag von mindestens 19% sowie einer Bruchdehnung A80mm von mindestens 22% die in DIN485-2 geforderten Werte bei weitem.Finally, the aluminum alloy strip according to the invention has a yield strength R p0.2 of more than 120 MPa and a tensile strength R m of more than 260 MPa. The aluminum alloy strip according to the invention, which is resistant to intergranular corrosion, thus also exceeds the strength properties of an aluminum alloy of type AA5182 required by DIN485-2. The elongation values with a uniform elongation A g of at least 19% and an elongation at break A 80mm of at least 22% also far exceed the values required by DIN485-2.
Gemäß einer zweiten Lehre der vorliegenden Erfindung wird die oben aufgezeigte Aufgabe durch ein Verfahren zur Herstellung eines Aluminiumlegierungsbandes umfassend die folgenden Verfahrensschritte gelöst:
- Gießen eines Walzbarrens bestehend aus einer erfindungsgemäßen Aluminiumlegierungszusammensetzung,
- Homogenisieren des Walzbarrens bei 480 °C bis 550 °C für mindestens 0,5 h,
- Warmwalzen des Walzbarrens bei einer Temperatur von 280 °C bis 500 °C,
- Kaltwalzen des Aluminiumlegierungsbandes an Enddicke mit einem Abwalzgrad von weniger
als 40%, bevorzugt maximal 30 %, besonders bevorzugt maximal 25%, - Weichglühen des fertig gewalzten Aluminiumlegierungsbandes bei 300 °C bis 500 °C.
- Casting a rolling ingot consisting of an aluminum alloy composition according to the invention,
- Homogenizing the rolling ingot at 480 °C to 550 °C for at least 0.5 h,
- Hot rolling of the rolling ingot at a temperature of 280 °C to 500 °C,
- Cold rolling of the aluminium alloy strip to final thickness with a rolling degree of less than 40%, preferably a maximum of 30%, particularly preferably a maximum of 25%,
- Annealing of the finished rolled aluminium alloy strip at 300 °C to 500 °C.
Die aufgezählten Verfahrensschritte führen in Summe dazu, dass aufgrund des geringen Abwalzgrads beim Kaltwalzen des Aluminiumlegierungsbandes an Enddicke eine Korngröße nach dem Weichglühen zur Verfügung gestellt werden kann, welche die oben aufgeführte Abhängigkeit vom Mg-Gehalt erfüllt. Über den Abwalzgrad an Enddicke wird die Verfestigung des Bandes vor dem Weichglühen eingestellt, welche die resultierende Korngröße bestimmt. Mit geringer werdendem Abwalzgrad von weniger als 40 %, über maximal 30 % und maximal 25 % werden also unterschiedliche Korngröße eingestellt, welche auf die Legierungszusammensetzung abgestimmt werden können. Insofern kann ein Aluminiumlegierungsband hergestellt werden, welches gegen interkristalline Korrosion beständig ist.The process steps listed result in a grain size after annealing that satisfies the dependency on the Mg content listed above, due to the low degree of rolling during cold rolling of the aluminum alloy strip to the final thickness. The degree of rolling to the final thickness is used to set the hardening of the strip before annealing, which determines the resulting grain size. As the degree of rolling decreases from less than 40%, to a maximum of 30% and a maximum of 25%, different grain sizes are set, which can be adjusted to the alloy composition. In this respect, an aluminum alloy strip can be produced that is resistant to intergranular corrosion.
Gemäß einer weiteren Ausgestaltung des erfindungsgemäßen Verfahrens werden nach dem Warmwalzen alternativ die folgenden Verfahrensschritte durchgeführt:
- Kaltwalzen des warmgewalzten Aluminiumlegierungsbandes mit einem
Abwalzgrad von mindestens 30 %,vorzugsweise mindestens 50 %, - Zwischenglühen des Aluminiumlegierungsbandes bei 300 °C bis 500 °C,
- anschließendes Kaltwalzen an Enddicke mit einem Abwalzgrad von weniger
als 40%, bevorzugt maximal 30 %, besonders bevorzugt maximal 25%, - Weichglühen des fertig gewalzten Aluminiumlegierungsbandes bei 300 °C bis 500 °C.
- Cold rolling of the hot-rolled aluminium alloy strip with a rolling degree of at least 30%, preferably at least 50%,
- Intermediate annealing of the aluminium alloy strip at 300 °C to 500 °C,
- subsequent cold rolling to final thickness with a rolling degree of less than 40%, preferably a maximum of 30%, particularly preferably a maximum of 25%,
- Annealing of the finished rolled aluminium alloy strip at 300 °C to 500 °C.
Beiden zuvor aufgeführten Verfahren ist gemein, dass der Abwalzgrad vor dem Weichglühen, d.h. der Abwalzgrad an Enddicke beim Kaltwalzen auf von weniger als 40%, bevorzugt maximal 30 %, besonders bevorzugt maximal 25% beschränkt ist. In der zweiten Ausgestaltung des erfindungsgemäßen Verfahrens findet ein zusätzlicher Kaltwalzschritt nach einer Zwischenglühung bei 300°C - 500°C statt. Bei der Zwischenglühung wird das durch das Kaltwalzen stark verfestigte Aluminiumlegierungsband rekristallisiert und erneut in einen umformbaren Zustand überführt. Der anschließende Kaltwalzschritt mit einem Abwalzgrad von weniger als 40%, bevorzugt maximal 30 %, besonders bevorzugt maximal 25% führt dazu, dass in Verbindung mit den verwendeten Mg-Gehalten der Aluminiumlegierung die Korngröße entsprechend dem beanspruchten Verhältnis eingestellt werden kann. Im Ergebnis wird dann im weichgeglühten Zustand ein Band herstellbar, welches sowohl beständig gegen interkristalline Korrosion ist als auch die notwendigen Umform- bzw. Festigkeitseigenschaften aufweist.Both of the above-mentioned processes have in common that the degree of rolling before annealing, i.e. the degree of rolling of the final thickness during cold rolling, is limited to less than 40%, preferably a maximum of 30%, particularly preferably a maximum of 25%. In the second embodiment of the process according to the invention, an additional cold rolling step takes place after an intermediate annealing at 300°C - 500°C. During the intermediate annealing, the aluminum alloy strip, which has been strongly hardened by cold rolling, is recrystallized and converted back into a formable state. The subsequent cold rolling step with a degree of rolling of less than 40%, preferably a maximum of 30%, particularly preferably a maximum of 25%, means that, in conjunction with the Mg content of the aluminum alloy used, the grain size can be adjusted to the required ratio. As a result, in the annealed state A strip can be produced which is both resistant to intergranular corrosion and has the necessary forming and strength properties.
Gemäß einer nächsten Ausgestaltung des erfindungsgemäßen Verfahrens finden die Weichglühung und/oder die Zwischenglühungen in einem Batchofen, insbesondere einem Kammerofen, oder einem Durchlaufofen statt. Beide Öfen führen zur Bereitstellung eines ausreichend groben Korngefüges, welches die Beständigkeit gegen interkristalline Korrosion gewährleistet. Batchöfen sind in Betrieb und Anschaffung üblicherweise nicht so kostenintensiv wie Durchlauföfen.According to a further embodiment of the method according to the invention, the soft annealing and/or the intermediate annealings take place in a batch furnace, in particular a chamber furnace, or a continuous furnace. Both furnaces provide a sufficiently coarse grain structure, which ensures resistance to intergranular corrosion. Batch furnaces are usually not as expensive to operate and purchase as continuous furnaces.
Gemäß einer dritten Lehre der vorliegenden Erfindung wird die oben aufgezeigte Aufgabe durch ein Bauteil für ein Kraftfahrzeug gelöst, welches zumindest teilweise aus einem erfindungsgemäßen Aluminiumlegierungsband besteht. Das Bauteil wird üblicherweise einer Lackierung, vorzugsweise einer kathodischen Tauch-Lackierung unterzogen. Dennoch gibt es auch Einsatzmöglichkeiten von unlackierten Bauteilen hergestellt aus dem erfindungsgemäßen Aluminiumlegierungsband.According to a third teaching of the present invention, the above-mentioned object is achieved by a component for a motor vehicle which consists at least partially of an aluminum alloy strip according to the invention. The component is usually subjected to painting, preferably cathodic dip painting. Nevertheless, there are also possible uses for unpainted components made from the aluminum alloy strip according to the invention.
Wie bereits oben ausgeführt, weist das Aluminiumlegierungsband hervorragende Eigenschaften in Bezug auf die Festigkeit, Umformeigenschaften und Beständigkeit gegen interkristalline Korrosion auf, so dass insbesondere die Wärmebelastung bei einer Lackierung, einem Einbrennvorgang der typischerweise 20 Min. bei etwa 185°C dauert, nur wenig Einfluss auf die Beständigkeit des Bauteils gegen interkristalline Korrosion hat. Auch die Umformung zu einem Bauteil, welche mittels eines Reckens um 15% quer zur ursprünglichen Walzrichtung simulierte wurde, hat einen nur geringen Einfluss auf die Beständigkeit gegen interkristalline Korrosion. Auch nach 15% Recken betragen die Werte für den Massenverlust gemäß ASTM G67 weniger als 15 mg/cm2. Weiterhin hat auch der Betrieb in temperaturbelasteten Bereichen, welcher durch eine Wärmebelastung von 200 bzw. 500 Stunden bei 80°C simuliert wurde, nur einen geringen Einfluss auf die Beständigkeit gegen interkristalline Korrosion. Die Werte für den Massenverlust gemäß ASTM G67 betragen auch nach einer entsprechenden Temperaturbelastung weniger als 15mg/cm2.As already stated above, the aluminum alloy strip has excellent properties in terms of strength, forming properties and resistance to intergranular corrosion, so that the heat load during painting, a baking process that typically takes 20 minutes at around 185°C, has little influence on the resistance of the component to intergranular corrosion. Forming into a component, which was simulated by stretching by 15% transverse to the original rolling direction, also has only a minor influence on the resistance to intergranular corrosion. Even after 15% stretching, the values for the mass loss according to ASTM G67 are less than 15 mg/cm 2 . Furthermore, operation in temperature-stressed areas, which was simulated by a heat load of 200 or 500 hours at 80°C, only has a minor influence on the resistance to intergranular corrosion. The mass loss values according to ASTM G67 are less than 15 mg/cm 2 even after corresponding temperature stress.
Besonders vorteilhaft ist ein Bauteil, wenn dieses als Karosserie- oder ein Karosserieanbauteil eines Kraftfahrzeugs ausgebildet ist. Typische Karosserieteile sind der Kotflügel oder Teile der Bodengruppe, des Dachs etc. Als Karosserieanbauteile werden in der Regel Türen und Heckklappen etc. bezeichnet, welche nicht fest mit dem Kraftfahrzeug verbunden sind. Bevorzugt werden nicht sichtbare Karosseriebauteile oder Karosserieanbauteile aus dem erfindungsgemäßen Aluminiumlegierungsband hergestellt. Dies sind beispielsweise Türinnenteile oder Innenteile von Heccklappen aber auch Bodenbleche etc. Eine typische Wärmebelastung für solche Bauteile eines Kraftfahrzeugs beispielsweise von Türinnenteilen ist beispielsweise durch die Sonneneinstrahlung während des Betriebs eines Kraftfahrzeugs gegeben. Darüber hinaus sind Karosserie- oder Karosserieanbauteile eines Kraftfahrzeugs im Allgemeinen auch Feuchtigkeit, beispielsweise in Form von Spritzwasser oder Kondenswasser, ausgesetzt, so dass eine Beständigkeit gegen interkristalline Korrosion gefordert werden muss. Die erfindungsgemäßen Karosserie- oder Karosserieanbauteile, hergestellt aus einem Aluminiumlegierungsband gemäß der vorliegenden Erfindung, erfüllen diese Bedingungen und gewährleisten darüber hinaus einen Gewichtsvorteil gegenüber den bisher verwendeten Stahlkonstruktionen.A component is particularly advantageous if it is designed as a body or body attachment part of a motor vehicle. Typical body parts are the fender or parts of the floor assembly, the roof, etc. Body attachment parts are generally doors and tailgates, etc. that are not firmly connected to the motor vehicle. Invisible body components or body attachment parts are preferably made from the aluminum alloy strip according to the invention. These are, for example, inner door parts or inner parts of tailgates, but also floor panels, etc. A typical heat load for such components of a motor vehicle, for example inner door parts, is caused, for example, by sunlight during operation of a motor vehicle. In addition, body or body attachment parts of a motor vehicle are generally exposed to moisture, for example in the form of splash water or condensation, so that resistance to intergranular corrosion must be required. The body or body attachment parts according to the invention, made from an aluminum alloy strip according to the present invention, meet these conditions and also ensure a weight advantage over the steel structures used to date.
Im Weiteren soll die Erfindung nun anhand von Ausführungsbeispielen in Verbindung mit der Zeichnung näher erläutert werden. Die Zeichnung zeigt in
- Fig. 1
- ein schematisches Ablaufschema für ein Ausführungsbeispiele eines Herstellverfahrens,
- Fig. 2
- in einem Diagramm die Korngröße in Abhängigkeit vom Magnesiumgehalt der Ausführungsbeispiele und
- Fig. 3
- ein Bauteil für ein Kraftfahrzeug gemäß einem weiteren Ausführungsbeispiel.
- Fig. 1
- a schematic flow chart for an embodiment of a manufacturing process,
- Fig. 2
- in a diagram the grain size depending on the magnesium content of the embodiments and
- Fig. 3
- a component for a motor vehicle according to a further embodiment.
Anhand von umfangreichen Versuchen wurde untersucht, ob es einen Zusammenhang zwischen der Korngröße eines Aluminiumlegierungsbandes aus einer Aluminiumlegierung vom Typ AA 5xxx und dem Mg-Gehalt in Bezug auf die Beständigkeit gegen interkristalline Korrosion besteht. Hierzu wurden verschiedene Aluminiumlegierungen verwendet und unterschiedliche Verfahrensparameter angewendet. In Tabelle 1 sind die verschiedenen Legierungszusammensetzungen dargestellt, anhand deren der Zusammenhang zwischen Korngröße, Beständigkeit gegen interkristalline Korrosion und Streckgrenze untersucht wurde. Neben den Gehalten der Legierungselemente Si, Fe, Cu, Mn, Mg, Cr, Zn und Ti in Gew.-% enthalten die in Tabelle 1 genannten Aluminiumlegierungen als Rest Aluminium sowie Verunreinigungen einzeln maximal 0,05 Gew.-% und in Summe maximal 0,15 Gew.-%.Extensive tests were carried out to investigate whether there is a relationship between the grain size of an aluminum alloy strip made from an aluminum alloy of type AA 5xxx and the Mg content in relation to resistance to intergranular corrosion. For this purpose, various aluminum alloys were used and different process parameters applied. Table 1 shows the various alloy compositions used to investigate the relationship between grain size, resistance to intergranular corrosion and yield strength. In addition to the contents of the alloying elements Si, Fe, Cu, Mn, Mg, Cr, Zn and Ti in wt.%, the aluminum alloys listed in Table 1 contain aluminum as the remainder and impurities individually up to a maximum of 0.05 wt.% and in total up to a maximum of 0.15 wt.%.
Da insbesondere die Schlussweichglühung und der Endabwalzgrad Einfluss auf die Korngröße hat, sind diese bei den jeweiligen Versuchen variiert bzw. gemessen worden. Die Korngröße variierte beispielsweise von 16 µm bis 61 µm, der Endabwalzgrad von 17 % bis 57 %. Die Schlussweichglühung wurde entweder im Kammerofen (KO) oder im Banddurchlaufofen (BDLO) durchgeführt.
In Schritt 1 wird ein Walzbarren aus einer Aluminiumlegierung vom Typ AA 5xxx mit einem Mg-Gehalt mit mindestens 4 Gew.-% gegossen, beispielsweise im DC-Strangguss. Anschließend wird der Walzbarren im Verfahrensschritt 2 einem Homogenisieren, welches ein- oder mehrstufig durchgeführt werden kann, unterzogen. Bei einem Homogenisieren werden Temperaturen des Walzbarrens vom 480 bis 550 °C für mindestens 0,5 h erreicht. Im Verfahrensschritt 3 wird dann der Walzbarren warmgewalzt, wobei typische Temperaturen von 280 °C bis 500 °C erreicht werden. Die Enddicken des Warmbandes betragen beispielsweise 2 bis 12 mm. Die Warmbandenddicke kann dabei so gewählt werden, dass nach dem Warmwalzen lediglich ein einziger Kaltwalzschritt 4 erfolgt, bei welchem das Warmband mit einem Abwalzgrad von weniger als 40%, bevorzugt maximal 30 %, besonders bevorzugt maximal 25% in seiner Dicke reduziert wird.In
Anschließend wird das an Enddicke kaltgewalzte Aluminiumlegierungsband einer Weichglühung unterzogen. Die Weichglühung wurde in einem Durchlaufofen oder in einem Kammerofen durchgeführt, um die Abhängigkeit der Korrosionseigenschaften vom Kammer- oder Durchlaufofen zu testen. Bei den in Tabelle 1 dargestellten Ausführungsbeispielen wurde der zweite Weg mit einer Zwischenglühung angewendet. Hierzu wird das Warmband nach dem Warmwalzen gemäß Verfahrensschritt 3 einem Kaltwalzen 4a zugeführt, welches einen Abwalzgrad von mehr als 30 % bzw. mehr als 50 % aufweist, so dass das Aluminiumlegierungsband bei einem nachfolgenden Zwischenglühen vorzugsweise durchgehend rekristallisiert. Die Zwischenglühung wurde bei den Ausführungsbeispielen entweder im Durchlaufofen bei 400 °C bis 450 °C oder im Kammerofen bei 330 °C bis 380 °C durchgeführt.The aluminium alloy strip, cold rolled to final thickness, is then subjected to soft annealing. The soft annealing was carried out in a continuous furnace or in a chamber furnace in order to determine the dependence of the To test corrosion properties of the chamber or continuous furnace. In the embodiments shown in Table 1, the second method with an intermediate annealing was used. For this, after hot rolling according to
Die Zwischenglühung ist in
An den entsprechend hergestellten Aluminiumlegierungsbändern wurden mechanische Kennwerte, insbesondere die Streckgrenze Rp0,2, Zugfestigkeit Rm, die Gleichmaßdehnung Ag und die Dehnung A80mm bestimmt. Darüber hinaus wurde die Korrosionsbeständigkeit gegen interkristalline Korrosion gemäß ASTM G67 gemessen, und zwar ohne zusätzliche Wärmebehandlung im Ausgangszustand (Ausgang 0h). Neben den gemäß EN 10002-1 bzw. ISO 6892 gemessenen mechanischen Kenngrößen der Aluminiumlegierungsbänder sind zudem die berechneten Korngrößen gemäß der unten dargelegten Formeln (1) für die Beständigkeit gegen interkristalline Korrosion und der Formel (2) zur Erzielung der notwendigen mechanischen Eigenschaften, insbesondere einer ausreichend großen Streckgrenze, in der Tabelle 2 als Spalte KG(IK) und als Spalte KG(Rp) dargestellt. Die Korngrößen wurden nach ASTM E1382 bestimmt und sind in µm angegeben.Mechanical parameters, in particular the yield strength R p0.2 , tensile strength R m , the uniform elongation A g and the elongation A 80mm , were determined on the aluminum alloy strips produced in this way. In addition, the corrosion resistance to intergranular corrosion was measured in accordance with ASTM G67, without additional heat treatment in the initial state (output 0h). In addition to the mechanical parameters of the aluminum alloy strips measured in accordance with EN 10002-1 and ISO 6892, the calculated grain sizes are shown in Table 2 as column KG(IK) and column KG(Rp) according to the formulas (1) set out below for resistance to intergranular corrosion and formula (2) for achieving the necessary mechanical properties, in particular a sufficiently high yield strength. The grain sizes were determined in accordance with ASTM E1382 and are given in µm.
Um den Einsatz im Kraftfahrzeug zu simulieren, wurden die Aluminiumlegierungsbänder vor dem Korrosionstest darüber hinaus unterschiedlichen Wärmebehandlungen unterzogen. Eine erste Wärmebehandlung bestand aus einer Lagerung der Aluminiumbänder für 20 Minuten bei 185 °C, um den KTL-Zyklus abzubilden. In einer weiteren Messreihe wurden die Aluminiumlegierungsbänder zusätzlich 200 Stunden bzw. 500 Stunden bei 80°C gelagert und anschließend dem Korrosionstest unterzogen. Da Umformungen von Aluminiumlegierungsbändern oder -blechen zusätzlich die Korrosionsbeständigkeit beeinflussen können, wurden die Aluminiumlegierungsbänder in einem weiteren Versuch um etwa 15 % gereckt, einer Wärmebehandlung bzw. einer Lagerung bei erhöhter Temperatur unterzogen und dann einem Test auf interkristalline Korrosion gemäß ASTM G67 unterzogen, bei welchem der Massenverlust gemessen wurde.In order to simulate use in motor vehicles, the aluminum alloy strips were also subjected to various heat treatments before the corrosion test. A first heat treatment consisted of storing the aluminum strips for 20 minutes at 185 °C to simulate the KTL cycle. In a further series of measurements, the aluminum alloy strips were stored for an additional 200 hours or 500 hours at 80 °C and then subjected to the corrosion test. Since forming of aluminum alloy strips or sheets can also influence corrosion resistance, the aluminum alloy strips were stretched by around 15% in a further test, subjected to heat treatment or storage at an elevated temperature and then subjected to an intergranular corrosion test in accordance with ASTM G67, in which the mass loss was measured.
Es zeigte sich, dass es einen engen Zusammenhang zwischen der Korngröße, dem Mg-Gehalt und der Beständigkeit gegen interkristalline Korrosion gibt. Die Ausführungsbeispiele 11 bis 19 sind alle als beständig gegen interkristalline Korrosion einzustufen. Dies gilt auch für deren Einsatz in Kraftfahrzeugen mit Wärmebelastung und der Anwesenheit von Feuchtigkeit bzw. eines korrosiven Mediums. Zusätzlich zeigten die Ausführungsbeispiele 12, 14, 16 und 17 die nach DIN EN 485-2 geforderten mechanischen Kennwerte eines Aluminiumlegierungsbandes vom Typ AA 5182.It was found that there is a close relationship between grain size, Mg content and resistance to intergranular corrosion. The examples 11 to 19 can all be classified as resistant to intergranular corrosion. This also applies to their use in motor vehicles with thermal stress and the presence of moisture or a corrosive medium. In addition, examples 12, 14, 16 and 17 showed the mechanical properties of an aluminum alloy strip of type AA 5182 required by DIN EN 485-2.
In
Die Kurve B hingegen zeigt die Grenze, ab welcher die Aluminiumlegierungsbänder eine zu niedrige Streckgrenze von weniger als 110 MPa aufweisen, so dass diese nicht als Legierung AA 5182 gemäß DIN EN485-2 anzusehen sind. Die Kurve B wird durch folgende Gleichung bestimmt:
Alle Ausführungsbeispiele rechts der Kurve B erfüllen damit die Anforderung einer Streckgrenze von mehr als 110 MPa.All examples to the right of curve B therefore meet the requirement of a yield strength of more than 110 MPa.
Schließlich zeigt
Claims (10)
- Aluminium alloy strip composed of an AA 5 xxx -type aluminium alloy, which apart from Al and inevitable impurities has an Mg content of at least 4 wt.%, characterised in that the aluminium alloy strip has a recrystallized microstructure, wherein the grain size (GS) of the microstructure satisfies the following dependency on the Mg content (c_Mg) in wt.%:and in that the aluminium alloy of the aluminium alloy strip has the following composition in wt.%:
Si ≤ 0.2%, Fe ≤ 0.35%, 0.04% ≤ Cu ≤ 0.08%, 0.2% ≤ Mn ≤ 0.5%. 4.35% ≤ Mg ≤ 4.8%, Cr ≤ 0.1%, Zn ≤ 0.25%, Ti ≤ 0.1%, the remainder being Al and inevitable impurities, amounting to a maximum of 0.05 wt.% individually and a maximum of 0.15 wt.% in total, whereas the aluminium alloy strip is cold rolled and soft annealed and the aluminium alloy strip has a yield point Rp0.2 of greater than 120 MPa and a tensile strength Rm of greater than 260 MPa. - Aluminium alloy strip according to any one of Claims 1 or 2, characterised in that the aluminium alloy of the aluminium alloy strip has 4.45% ≤ Mg ≤ 4.8%.
- Aluminium alloy strip according to any one of Claims 1 to 3, characterised in that the grain size is a maximum of 50 µm, preferably a maximum of 40 µm.
- Aluminium alloy strip according to any one of Claims 1 to 4, characterised in that the aluminium alloy strip has a thickness of 0.5 mm to 5 mm.
- Method for producing an aluminium alloy strip according to any one of Claims 1 to 5 comprising the following process steps:- casting a rolling ingot;- homogenisation of the rolling ingot at 480°C to 550°C for at least 0.5 hours;- hot rolling of the rolling ingot at a temperature of 280°C to 500°C- cold rolling of the aluminium alloy strip to the final thickness with a degree of rolling of less than 40%, preferably a maximum of 30%, particularly preferably a maximum of 25%;- soft-annealing of the finished-rolled aluminium alloy strip at 300°C to 500°C..
- Method according to Claim 6, wherein after the hot rolling alternatively the following process steps are carried out:- cold rolling of the hot-rolled aluminium alloy strip with a degree of rolling of at least 30%, preferably at least 50%;- intermediate annealing of the aluminium alloy strip at between 300°C and 500°C;- subsequent cold rolling to the final thickness with a degree of rolling of less than 40%, preferably a maximum of 30%, particularly preferably a maximum of 25%;- soft annealing of the finish-rolled aluminium alloy strip at between 300°C and 500°C.
- Method according to Claim 6 or 7, characterised in that the intermediate annealing and/or the soft annealing is/are carried out in a batch furnace or a continuous furnace.
- Component for a motor vehicle at least partially composed of an aluminium alloy strip according to any one of Claims 1 to 5.
- Component according to Claim 9, characterised in that the component is a body part or a body accessory of a motor vehicle.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13756051.2A EP2888382B2 (en) | 2012-08-22 | 2013-08-22 | Aluminium alloy strip which is resistant to intercrystalline corrosion and method for producing same |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12181356 | 2012-08-22 | ||
| PCT/EP2013/067484 WO2014029853A1 (en) | 2012-08-22 | 2013-08-22 | Intergranular corrosion-resistant aluminum alloy strip, and method for the production thereof |
| EP13756051.2A EP2888382B2 (en) | 2012-08-22 | 2013-08-22 | Aluminium alloy strip which is resistant to intercrystalline corrosion and method for producing same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP2888382A1 EP2888382A1 (en) | 2015-07-01 |
| EP2888382B1 EP2888382B1 (en) | 2016-11-23 |
| EP2888382B2 true EP2888382B2 (en) | 2025-02-26 |
Family
ID=48782349
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP13756051.2A Active EP2888382B2 (en) | 2012-08-22 | 2013-08-22 | Aluminium alloy strip which is resistant to intercrystalline corrosion and method for producing same |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US10550456B2 (en) |
| EP (1) | EP2888382B2 (en) |
| JP (1) | JP6270844B2 (en) |
| KR (1) | KR101803520B1 (en) |
| CN (2) | CN110592441A (en) |
| CA (1) | CA2882691C (en) |
| ES (1) | ES2613857T3 (en) |
| PT (1) | PT2888382T (en) |
| RU (1) | RU2606664C2 (en) |
| WO (1) | WO2014029853A1 (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2569664T3 (en) | 2012-08-28 | 2016-05-12 | Hydro Aluminium Rolled Products Gmbh | Intercrystalline Corrosion Resistant Aluminum Alloy |
| CA2985067C (en) * | 2015-06-05 | 2020-11-10 | Novelis Inc. | High strength 5xxx aluminum alloys and methods of making the same |
| CA2990303C (en) | 2015-06-25 | 2019-12-17 | Hydro Aluminium Rolled Products Gmbh | High-strength and easily formable almg-strip, and method for producing the same |
| CA3018415C (en) * | 2016-04-19 | 2020-01-21 | Hydro Aluminium Rolled Products Gmbh | Aluminum composite material having a corrosion protection layer |
| EP3802901B1 (en) * | 2018-06-11 | 2023-01-04 | Novelis Koblenz GmbH | Method of manufacturing an al-mg-mn alloy plate product having an improved corrosion resistance |
| US12091720B2 (en) * | 2018-11-15 | 2024-09-17 | Theodor Stuth | Method for producing a raw wire from a first metal strip and at least one further metal strip by roll profiling |
| RU2722950C1 (en) * | 2020-02-07 | 2020-06-05 | Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" | Aluminum-based alloy and method of producing article therefrom |
| KR20230118949A (en) * | 2021-03-12 | 2023-08-14 | 노벨리스 인크. | High-strength 5XXX aluminum alloy variant and manufacturing method thereof |
| CN114480928A (en) * | 2022-01-28 | 2022-05-13 | 全良金属(苏州)有限公司 | High-strength aluminum plate for electronic product and manufacturing method thereof |
| CN116855802A (en) * | 2022-03-28 | 2023-10-10 | 宝山钢铁股份有限公司 | A high-performance 5083 aluminum alloy medium-thick plate for pressure vessels and its manufacturing method |
| CN115652152B (en) * | 2022-11-30 | 2023-03-17 | 中铝材料应用研究院有限公司 | 5XXX aluminum alloy capable of refining MIG (Metal-inert gas welding) weld grains and preparation method and application thereof |
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2013
- 2013-08-22 CA CA2882691A patent/CA2882691C/en not_active Expired - Fee Related
- 2013-08-22 KR KR1020157007193A patent/KR101803520B1/en not_active Ceased
- 2013-08-22 CN CN201910917217.1A patent/CN110592441A/en active Pending
- 2013-08-22 RU RU2015110064A patent/RU2606664C2/en not_active IP Right Cessation
- 2013-08-22 ES ES13756051.2T patent/ES2613857T3/en active Active
- 2013-08-22 WO PCT/EP2013/067484 patent/WO2014029853A1/en not_active Ceased
- 2013-08-22 CN CN201380044171.8A patent/CN104781430A/en active Pending
- 2013-08-22 PT PT137560512T patent/PT2888382T/en unknown
- 2013-08-22 EP EP13756051.2A patent/EP2888382B2/en active Active
- 2013-08-22 JP JP2015527925A patent/JP6270844B2/en active Active
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2015
- 2015-02-18 US US14/625,071 patent/US10550456B2/en active Active
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| US4151013A (en) † | 1975-10-22 | 1979-04-24 | Reynolds Metals Company | Aluminum-magnesium alloys sheet exhibiting improved properties for forming and method aspects of producing such sheet |
| US4186034A (en) † | 1978-07-05 | 1970-01-29 | Swiss Aluminium Ltd. | Method of manufacturing aluminum alloy sheets containing magnesium and zinc |
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Also Published As
| Publication number | Publication date |
|---|---|
| RU2606664C2 (en) | 2017-01-10 |
| KR101803520B1 (en) | 2017-11-30 |
| KR20150065678A (en) | 2015-06-15 |
| US20150159251A1 (en) | 2015-06-11 |
| PT2888382T (en) | 2017-02-10 |
| WO2014029853A1 (en) | 2014-02-27 |
| EP2888382B1 (en) | 2016-11-23 |
| RU2015110064A (en) | 2016-10-10 |
| EP2888382A1 (en) | 2015-07-01 |
| JP2016504483A (en) | 2016-02-12 |
| ES2613857T3 (en) | 2017-05-26 |
| JP6270844B2 (en) | 2018-01-31 |
| CN104781430A (en) | 2015-07-15 |
| CN110592441A (en) | 2019-12-20 |
| US20160273084A2 (en) | 2016-09-22 |
| CA2882691A1 (en) | 2014-02-27 |
| CA2882691C (en) | 2017-11-07 |
| US10550456B2 (en) | 2020-02-04 |
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