GB2106307A - Mineral insulated electric cable - Google Patents
Mineral insulated electric cable Download PDFInfo
- Publication number
- GB2106307A GB2106307A GB08223322A GB8223322A GB2106307A GB 2106307 A GB2106307 A GB 2106307A GB 08223322 A GB08223322 A GB 08223322A GB 8223322 A GB8223322 A GB 8223322A GB 2106307 A GB2106307 A GB 2106307A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sheath
- liquid
- insulated electric
- mineral insulated
- magnesium oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 17
- 239000011707 mineral Substances 0.000 title claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 29
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 16
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 13
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 13
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 13
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 9
- 239000011810 insulating material Substances 0.000 claims abstract description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 21
- 239000004020 conductor Substances 0.000 claims description 20
- 239000000395 magnesium oxide Substances 0.000 claims description 20
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 19
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 238000003466 welding Methods 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 238000005452 bending Methods 0.000 claims description 2
- 230000035515 penetration Effects 0.000 abstract description 7
- 230000004888 barrier function Effects 0.000 abstract description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 238000000137 annealing Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 4
- 238000010791 quenching Methods 0.000 description 3
- 230000000171 quenching effect Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/28—Protection against damage caused by moisture, corrosion, chemical attack or weather
- H01B7/282—Preventing penetration of fluid, e.g. water or humidity, into conductor or cable
- H01B7/285—Preventing penetration of fluid, e.g. water or humidity, into conductor or cable by completely or partially filling interstices in the cable
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
- H10N10/01—Manufacture or treatment
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
- H10N10/10—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects
- H10N10/17—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects characterised by the structure or configuration of the cell or thermocouple forming the device
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/14—Extreme weather resilient electric power supply systems, e.g. strengthening power lines or underground power cables
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Insulated Conductors (AREA)
Abstract
In a mineral insulated electric cable the powdered insulating material 3 is impregnated with a quantity of a hydrophobic material, for example a silicone, which has been introduced into the powder in liquid form. The added hydrophobic material serves as a barrier against the ingress of moisture, and liquid dimethylpolysiloxane has been found particularly effective, the presence of even a small quantity of this preventing any significant degree of moisture penetration into the cable. <IMAGE>
Description
SPECIFICATION
Mineral insulated electric cables and like elements
This invention relates to mineral insulated electric cables and like elements, that is to say elements of the type comprising one or more electrical conductor wires enclosed within a tubular metal sheath, and insulated from the sheath by a filling of compacted powdered insulating material.
Such elements will hereinafter be referred to simplay as "mineral insulated electric cables" but this term is to be understood to include, in addition to wiring cables for the conduction of electric current for general pu rposes, elements of the construction described above which are designed to be employed for other purposes, for example sensing cables, heating cables, including sheathed wire electric heating elements, and thermocouple cables. The invention also includes within its scope the manufacture of such elements.
The powdered insulating material which is most commonly used is magnesium oxide either fused or calcined or as sea-washed magnesia, and although magnesium oxide has a high electrical breakdown strength when dry the presence of even a small amount of moisture can reduce this significantly.
Consequently the ingress of moisture is a major problem, particulary in the case of cables designed to operate at high voltages. In the case of wiring cables it is therefore recommended that the ends of lengths of cable in store be provided with temporary seals to reduce the moisture penetration. Nevertheless prior to forming a termination in a length of stored cable required for use it is invariably necessary to cut off an appreciable length, in some cases as much as 300 mm, from the ends of the cable in order to ensure that any damp powder, which would effect the insulating properties of the cable, is removed.
This is clearly wasteful. Moreover terminations, formed in both this and other forms of cable, need to provide effective seals to prevent any subsequent moisture penetration in use.
According, therfore, to the present invention in a mineral insulated electric cable the filling of powdered insulating material is impregnated with a quantity of a hydrophobic material which has been introduced into the powder in liquid form.
The liquid hydrophobic material is readily absorbed by the powder and even a small amount of the liquid has been found sufficient to reduce moisture penetration to a marked extent.
The hydrophobic material is preferably a liquid silicone and is preferably present in a proportion of 0.03% to 0.6% by weight with respect to the insulating material, for example approximately 0.11%.
The liquid hydrophobic material should, of course, also have electrically insulating properties such that it does not have a deleterious effect on insulating properties of the powder filling.
It is believed that the hydrophobic material
forms a coating around the particles of powder
and thereby provides a barrier to subsequent
moisture penetration, and we have found liquid
dimethylpolysiloxane, for example that sold by
Dow Corning Limited as Silicone Fluid No. 17, to
be particularly efficient hydrophobic material
suitable for this purpose. Thus a cable having
filling with between 1 and 20 mls of such a liquid
added to each 5.0 kilograms of powdered
magnesium oxide shows no significant moisture
penetration even after many weeks storage,
without the need for any separate end seals.
Accordingly a cable in accordance with the
invention can be stored without temporary end
seals, and when required to be used to the end
does not require to be cut back further than is
necessary to physically form the required
termination, as there is no damp powder which
needs to be removed.
Moreover not only does the incorporation of
liquid dimethylpolysiloxane within the filling have
no detrimental effect on the electrical insulating
properties of the filling, it has, in fact, been found to improve the electrical breakdown strength of the filling, particularly at high voltages, due, it is
believed, to the exclusion of free moisture throughout the length of the cable.
The sheath may be continuously formed from a ductile metal strip by bending the strip into tubular form and welding the edges together, whilst simultaneously introducing dry filling material and the conductor wire or wires into the sheath tube so formed, the liquid hydrophobic material being also introduced at this stage separately from the powder insulation.
In such a case the or each said conductor wire may be guided into the sheath through a respective guide tube and the liquid hydrophobic material can also be introduced into the sheath through the guide tube or tubes, although a separate delivery tube could alternatively serve for such a purpose.
Conveniently the powder insulation is introduced into the sheath tube through a delivery tube having its outlet downstream of the weld to avoid contamination of the weld, the liquid hydrophobic material also being delivered into the sheath tube, either through the conductor wire guide tubes or a separate delivery tube, downstream of the weld.
Following the introduction of the conductor or conductors and the filling powder and liquid, the diameter of the sheath tube will usually be reduced by passing it through a series of reduction rollers or dies and annealing furnaces in known manner.
The use of a liquid hydrophobic material has the further advantage that, during subsequent reducing and annealing processes, it acts as a lubricant, and this results in a pronounced reduction in the degree of abrasion of the conductor wire or wires and of the inner surface of the sheath.
Consequently the pronounced adherence of the filling powder to the conductor wire or wires, as is commonly experienced with mineral insulated electric cables as manufactured hitherto, is virtually avoided, and any loose powder on the surfaces of the wire or wires or on the inner surface of the sheath tube can be removed without difficulty when forming a termination.
However other liquid aryl or alkylpolysiloxanes or mixtures thereof or any other suitable liquid hydrophobic, electrically insulating material might alternatively be used as an additive to the filling powder in a mineral insulated electric cable in accordance with the invention.
One mineral insulated electric cable and the manufacture thereof will now be described by way of example with reference to Figures 1 to 4 of the accompanying schematic drawing, in which
Figure 1 represents a transverse section through the cable,
Figure 2 illustrates diagrammatically an elevation of part of one form of apparatus for manufacturing the cable, and
Figures 3 and 4 represent plan sections on an enlarged scale through different regions of the apparatus illustrated in Figure 2.
Referring first to Figure 1, the cable comprises an outer sheath 1 formed from a copper strip bent into tubular form and argon arc welded along the abutting edges. The sheath tube 1 contains a plurality of conductor wires 2 (in the case two) separated from each other and from the sheath tube 1 by a filling of powdered fused magnesium oxide 3, the powder being compacted around the conductors, following the introduction of the powder and conductors into the formed sheath tube, by a series of reduction stages, each followed by an annealing and quenching stage in known manner.
In accordance with the invention the sheath 1 contains, in addition to the powdered magnesium oxide a quantity of a dimethylpolysiloxane which has been introduced into the sheath in liquid form so that it penetrates into the magnesium oxide powder 3 surrounding the conductor wires 2.
The liquid dimethylpolysiloxane is introduced into the sheath tube 1 in the ratio of 3.5 mls of liquid to 5.0 kilogram of the powdered magnesium oxide and it has been found that even this small proportion of liquid imparts a marked hydrophobic quality to the filling which resists the penetration of moisture, and prevents any significant deterioration of the insulating properties of the filling adjacent severed ends of the cable for long periods without the need to provide additional seals, either during storage or when forming subsequent terminations.
Consequently when forming a termination it is not necessary to cut back the end of the cable further than is necessary to physically from the termination.
The cable may be manufactured by a continuous process, and one such process is illustrated in Figures 2 to 4 of the drawings.
In such a process the cable sheath 1 is formed in a continuous manner from a thoroughly degreased copper strip 1 a by means of a tube forming machine (not shown) which bends the downwardly fed strip into tubular form, and an argon arc welding head 4 which welds the abutting edges of the strip. The formed sheath tube 1, with the conductor wires 2 and the magnesium oxide powder3 introduced into it, is fed vertically downwards to a reduction machine, which reduces the diameter of the tube and compacts the filling powder around the conductor wires. The reduced tube is then fed through an annealing furnace, and then through a water quenching tank in which the cable is turned in a catenary curve to continue travelling horizontally through further reduction machines, annealing furnaces and quenching tanks.The reduction machines and associated equipment have, however, been omitted from the drawing for simplicity.
The conductor wires 2, which are also thoroughly degreased before their introduction into the sheath tube 1 , are fed continuously downwards into the tube, as it is being formed, through a pair of vertical guide tubes 5 rigidily located in desired positions within a powder delivery tube 7 through which the magnesium oxide powder is fed. The powder is introduced into the delivery tube 7 from a hopper 8 which is kept replenished from a vibratory conveyor 9 supplied, in turn, from a powder reservoir.
The lower ends of the powder delivery tube 7 and of the guide tubes 5 terminate below the weld so that the magnesium oxide powder 3 is effectively fed into the already formed and welded tube, and is thereby prevented from contaminating the weld.
The guide tubes 5 are preferably disposed, as shown in Figure 4, on opposite sides of the plane containing the axis of the sheath tube 1 and the welding head 4, and a further tube 10, by which argon is introduced into the sheath tube to maintain an inert atmosphere in the weld area, extends downwards withing the powder delivery tube 7 adjacent the seam edges of the sheath tube 1, the lower end communicating with the weld area through an opening 11 in the wall of the delivery tube. The opening 11 is sealed around its edges to the argon delivery tube 10 to prevent escape of the magnesium oxide powder in the vicinity of the weld.
In accordance with the invention liquid dimethylpolysiloxane, for example Dow Corning
Silicone Fluid No. 17, is introduced into the filling powder by being fed at a controlled rate through small bore pipes 6 into the conductor guide tubes 5 from a reservoir (not shown) by means of an adjustable low output pump 8. In a particular example in which the diameter of the sheath tube 1, before reduction, is of the order of 20 mm, and has an initial rate of travel past the welding head 4 of about 2 metres a minute, with the magnesium oxide powder being fed into the delivery tube 7 at a rate of about 1.0 kilogram a minute, the dimethylpolysiloxane was introduced into the conductor wire guide tubes 5 at approximately 0.7 ml a minute, although this ratio is not critical.
Although a vertical cable forming process has been described, the invention is also applicable to mineral insulated cables formed by a so-called horizontal process, in which the strip, which is to form the sheath tube, and the conductor wires are fed horizontally past the welding position. In such a case the liquid dimethylpolysiloxane is conveniently introduced into the powder filling through a separate delivery tube.
Claims (11)
1. A mineral insulated electric cable having the filling of powdered insulating material impregnated with a quantity of hydrophobic material which has been introduced into the powder in liquid form.
2. A mineral insulated electric cable according to Claim 1 wherein the hydrophobic material comprises a liquid silicone.
3. A mineral insulated electric cable according to Claim 2 wherein the hydrophobic material comprises liquid dimethylpolysiloxane.
4. A mineral insulated electric cable according to Claim 3 wherein the filling of powdered insulating material consists of powdered magnesium oxide and in which there is between 0.03% and 0.6% by weight of liquid dimethylpolysiloxane with respect to the weight of the magnesium oxide.
5. A mineral insulated electric cable according to Claim 4 having approximately 0.1 1% by weight of liquid dimethylpolysiloxane with respect to the weight of the magnesium oxide.
6.The manufacture of mineral insulated electric cable comprising the steps of continuously bending a ductile metal strip into tubular form and welding the edges together to form the sheath, and introducing into the formed sheath the conductor wire or wires, an filling of powdered magnesium oxide and a liquid silicone, and subsequently reducing the diameter of the formed sheath.
7. The manufacture according to Claim 6 wherein the liquid silicone consists of liquid dimethylpolysiloxane and is introduced into the sheath in the ratio of between 1.0 and 20.0 mls to each 5.0 kilograms of powdered magnesium oxide.
8. The manufacture according to Claim 7 wherein the liquid dimethylpolysiloxane is introduced into the sheath in the ratio of approximately 3.5 mls to each 5.0 kilograms of powdered magnesium oxide.
9. The manufacture according to any one of
Claims 6 to 8 wherein the or each conductor is guided into the sheath through a respective guide tube and the liquid silicone is also introduced into the sheath through a said guide tube.
10. The manufacture according to any of
Claims 6 to 9 wherein the powdered magnesium oxide is introduced into the sheath through a delivery tube having its outlet downstream of the weld, and the liquid silicone is also introduced into the sheath downstream of the weid.
11. The manufacture of a mineral insulated electric cable carried out substantially as hereinbefore described with reference to the accompanying drawing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB08223322A GB2106307B (en) | 1981-09-21 | 1982-08-13 | Mineral insulated electric cable |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8128424 | 1981-09-21 | ||
| GB08223322A GB2106307B (en) | 1981-09-21 | 1982-08-13 | Mineral insulated electric cable |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2106307A true GB2106307A (en) | 1983-04-07 |
| GB2106307B GB2106307B (en) | 1985-10-02 |
Family
ID=26280762
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB08223322A Expired GB2106307B (en) | 1981-09-21 | 1982-08-13 | Mineral insulated electric cable |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB2106307B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0283132A3 (en) * | 1987-03-18 | 1989-10-18 | Associated Electrical Industries Limited | Mineral insulated electric cables |
| GB2243483A (en) * | 1990-04-11 | 1991-10-30 | Bicc Plc | Mineral insulated cable manufacture |
| NL1000712C2 (en) * | 1995-06-30 | 1996-12-31 | Nooren Frans Bv | Use of a preparation for insulating sealing and coating purposes as well as a method for sealing manhole covers. |
| CN114709032A (en) * | 2022-04-25 | 2022-07-05 | 重庆科宝电缆股份有限公司 | Filling method of magnesium oxide drainage tube and magnesium oxide insulation fireproof cable |
-
1982
- 1982-08-13 GB GB08223322A patent/GB2106307B/en not_active Expired
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0283132A3 (en) * | 1987-03-18 | 1989-10-18 | Associated Electrical Industries Limited | Mineral insulated electric cables |
| GB2243483A (en) * | 1990-04-11 | 1991-10-30 | Bicc Plc | Mineral insulated cable manufacture |
| GB2243483B (en) * | 1990-04-11 | 1994-08-10 | Bicc Plc | Mineral insulated cable manufacture |
| NL1000712C2 (en) * | 1995-06-30 | 1996-12-31 | Nooren Frans Bv | Use of a preparation for insulating sealing and coating purposes as well as a method for sealing manhole covers. |
| EP0751198A1 (en) * | 1995-06-30 | 1997-01-02 | Frans Nooren B.V. | Use of a preparation for insulation/sealing and coating purposes and method for sealing manhole covers |
| US5898044A (en) * | 1995-06-30 | 1999-04-27 | Nooren; Franciscus Petrus | Use of a preparation for insulation/sealing and coating purposes and method for sealing manhole covers |
| CN114709032A (en) * | 2022-04-25 | 2022-07-05 | 重庆科宝电缆股份有限公司 | Filling method of magnesium oxide drainage tube and magnesium oxide insulation fireproof cable |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2106307B (en) | 1985-10-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 20010813 |