GB217936A - Manufacture of dyestuffs containing sulphur - Google Patents
Manufacture of dyestuffs containing sulphurInfo
- Publication number
- GB217936A GB217936A GB15169/24A GB1516924A GB217936A GB 217936 A GB217936 A GB 217936A GB 15169/24 A GB15169/24 A GB 15169/24A GB 1516924 A GB1516924 A GB 1516924A GB 217936 A GB217936 A GB 217936A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sulphur
- shades
- product
- red
- dyes cotton
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000005864 Sulphur Substances 0.000 title abstract 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000000975 dye Substances 0.000 abstract 8
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 abstract 8
- 229920000742 Cotton Polymers 0.000 abstract 6
- XDLNRRRJZOJTRW-UHFFFAOYSA-N thiohypochlorous acid Chemical compound ClS XDLNRRRJZOJTRW-UHFFFAOYSA-N 0.000 abstract 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- 230000004927 fusion Effects 0.000 abstract 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- 239000003513 alkali Substances 0.000 abstract 3
- GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical compound OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- -1 sulphur halide Chemical class 0.000 abstract 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- 229910021595 Copper(I) iodide Inorganic materials 0.000 abstract 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- LSXDOTMGLUJQCM-UHFFFAOYSA-M copper(i) iodide Chemical compound I[Cu] LSXDOTMGLUJQCM-UHFFFAOYSA-M 0.000 abstract 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- VDOSWXIDETXFET-UHFFFAOYSA-N Afloqualone Chemical compound CC1=CC=CC=C1N1C(=O)C2=CC(N)=CC=C2N=C1CF VDOSWXIDETXFET-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 229910021589 Copper(I) bromide Inorganic materials 0.000 abstract 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical group C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract 1
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical class C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 abstract 1
- MRQIXHXHHPWVIL-ISLYRVAYSA-N Sudan I Chemical compound OC1=CC=C2C=CC=CC2=C1\N=N\C1=CC=CC=C1 MRQIXHXHHPWVIL-ISLYRVAYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- NKNDPYCGAZPOFS-UHFFFAOYSA-M copper(i) bromide Chemical compound Br[Cu] NKNDPYCGAZPOFS-UHFFFAOYSA-M 0.000 abstract 1
- 238000004043 dyeing Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 abstract 1
- 235000011118 potassium hydroxide Nutrition 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- FWMUJAIKEJWSSY-UHFFFAOYSA-N sulfur dichloride Chemical compound ClSCl FWMUJAIKEJWSSY-UHFFFAOYSA-N 0.000 abstract 1
- XOSXWYQMOYSSKB-LDKJGXKFSA-L water blue Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC(C=C2)=CC=C2S([O-])(=O)=O)=C(\C=C2)/C=C/C\2=N\C(C=C2)=CC=C2S([O-])(=O)=O)=CC(S(O)(=O)=O)=C1N.[Na+].[Na+] XOSXWYQMOYSSKB-LDKJGXKFSA-L 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B49/00—Sulfur dyes
- C09B49/06—Sulfur dyes from azines, oxazines, thiazines or thiazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The compounds obtained by alkali fusion of p-diazines having as members an 8-sulpho-1 : 2-naphthalene ring and another ring system are treated with a sulphur halide or a material yielding a sulphur halide: the products differ in dyeing properties according to the temperature, solvent, and catalyst employed in the treatment with sulphur halide. The following examples are given:-(1) the compound obtained by caustic potash fusion of 1 : 2 : 11 : 21 - dinaphthazine-8 : 81-disulphonic acid is heated with sulphur monochloride at 80 DEG C.; the product, from a sodium sulphide bath, dyes cotton blue shades changed to fast orange by treatment with an oxidizing agent; when the sulphurizing is effected at 115 DEG C. the product dyes cotton in blue shades changed to brownish-red by the air or potassium bichromate and to a yellow-red shade by hydrogen peroxide: when the sulphur chloride acts at 115 DEG C. in presence of aluminium chloride the product dyes cotton in bordeaux shades changed to red by hydrogen peroxide: (2) the same parent material is heated with nitrobenzene, cuprous bromide, iodine, and sulphur monochloride at 140 DEG C.; part of the product dissolves in sodium sulphide solution, from which cotton is dyed in red shades, while the residue dissolves in hydrosulphite solution which then dyes cotton in tints which can be developed by means of chlorine water; (3) the same parent material is heated with nitrobenzene, cuprous iodide, and sulphur monochloride at 85-90 DEG C.; the product, from the hydrosulphite vat, dyes cotton in copper shades changed to orange by chlorine water; (4) a brown sulphide dyestuff is obtained from the compound made by alkali fusion of 8-sulpho-1 : 2-naphthophenazine by heating at 115 DEG C. with nitrobenzene and sulphur monochloride; (5) the compound made by alkali fusion of 8-sulpho-1 : 2-naphtho-31-aminophenazine is treated at ordinary temperature for one day with nitrobenzene, cuprous iodide, and sulphur monochloride; part of the product dyes cotton red-brown from a sulphide bath, while the residue dyes in black-brown shades from the hydrosulphite vat.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE217936X | 1923-06-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB217936A true GB217936A (en) | 1925-04-23 |
Family
ID=5831032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB15169/24A Expired GB217936A (en) | 1923-06-23 | 1924-06-23 | Manufacture of dyestuffs containing sulphur |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB217936A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6019800A (en) * | 1998-12-17 | 2000-02-01 | Clariant Finance (Bvi) Limited | Process and composition of sulfur dyes |
| US6537333B2 (en) | 1998-12-17 | 2003-03-25 | Clariant Finance (Bvi) Limited | Process and composition of sulfur dyes |
| US11371518B2 (en) * | 2020-08-06 | 2022-06-28 | Hoteck Inc. | Ceiling fan and fan set |
-
1924
- 1924-06-23 GB GB15169/24A patent/GB217936A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6019800A (en) * | 1998-12-17 | 2000-02-01 | Clariant Finance (Bvi) Limited | Process and composition of sulfur dyes |
| US6537333B2 (en) | 1998-12-17 | 2003-03-25 | Clariant Finance (Bvi) Limited | Process and composition of sulfur dyes |
| US11371518B2 (en) * | 2020-08-06 | 2022-06-28 | Hoteck Inc. | Ceiling fan and fan set |
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