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GB2255178A - Optical gas detector - Google Patents
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GB2255178A - Optical gas detector - Google Patents

Optical gas detector Download PDF

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Publication number
GB2255178A
GB2255178A GB9114910A GB9114910A GB2255178A GB 2255178 A GB2255178 A GB 2255178A GB 9114910 A GB9114910 A GB 9114910A GB 9114910 A GB9114910 A GB 9114910A GB 2255178 A GB2255178 A GB 2255178A
Authority
GB
United Kingdom
Prior art keywords
light
filter
gas
detector
gas detector
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB9114910A
Other versions
GB9114910D0 (en
Inventor
Brian Arthur Goody
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens Plessey Controls Ltd
Original Assignee
Siemens Plessey Controls Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens Plessey Controls Ltd filed Critical Siemens Plessey Controls Ltd
Publication of GB9114910D0 publication Critical patent/GB9114910D0/en
Priority to EP19920303301 priority Critical patent/EP0510856A3/en
Priority to CA002066816A priority patent/CA2066816A1/en
Priority to US07/873,951 priority patent/US5268745A/en
Priority to JP4106879A priority patent/JPH06167448A/en
Publication of GB2255178A publication Critical patent/GB2255178A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J3/00Spectrometry; Spectrophotometry; Monochromators; Measuring colours
    • G01J3/28Investigating the spectrum
    • G01J3/42Absorption spectrometry; Double beam spectrometry; Flicker spectrometry; Reflection spectrometry
    • G01J3/433Modulation spectrometry; Derivative spectrometry
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J3/00Spectrometry; Spectrophotometry; Monochromators; Measuring colours
    • G01J3/12Generating the spectrum; Monochromators
    • G01J2003/1226Interference filters
    • G01J2003/1243Pivoting IF or other position variation
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J3/00Spectrometry; Spectrophotometry; Monochromators; Measuring colours
    • G01J3/28Investigating the spectrum
    • G01J3/42Absorption spectrometry; Double beam spectrometry; Flicker spectrometry; Reflection spectrometry
    • G01J3/433Modulation spectrometry; Derivative spectrometry
    • G01J2003/4332Modulation spectrometry; Derivative spectrometry frequency-modulated
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3504Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

A light radiation absorption gas detector for detecting the presence of a specified gas, comprising a light source 1, a region 6 containing a gas to be detected through which light from the source is passed, an interference filter 9a having a substantially flat face and a light radiation absorption peak at a wavelength which facilitates detection of the specified gas, a shaft to which the filter is by means of arms secured for rotation so that a perpendicular to the flat face of the filter is at an angle to the axis of the rotation, and light detector means 11 responsive to light from the source which has passed through the region and the filter, for detecting predetermined light amplitude variations, wherein light from the source is arranged to be projected towards the filter at an angle offset from the axis of shaft rotation whereby a filter pass band which includes the said wavelength is scanned consequent upon rotation of the filter, thereby to produce amplitude variations of light in the presence within the region of the specified gas, whereby detection of the specified gas by the detector means is facilitated. <IMAGE>

Description

IMPROVEMENTS IN OR RELATING TO OPTICAL GAS DETECTORS This invention relates to gas detectors and more especially it relates to light radiation absorption gas detectors for detecting the presence of a specified gas or gases.
Such gas detectors make use of the fact that gases absorb more light at some wavelengths than others, each gas having its own unique absorption peak or peaks.
Such detectors are well known and comprise an interference filter which is chosen to pass light in a pass band including a wavelength corresponding to an absorption peak for a gas to be detected and having the characteristic that the pass band is dependent upon the angle at which light is incident on the filter.
Thus by changing the angle of incidence, the said pass band, or part thereof, can be scanned correspondingly as the angle is changed, such that detection of an absorption peak indicative of the presence of a particular gas as facilitated.
Interference filters comprise a film or films of predetermined thickness carried on a transparent substrate, the thickness of the film or films being chosen to afford a required filter characteristic. The construction and manufacture of such filters is well known and will therefore not be further described herein.
In order to change the angle of incidence to produce a required scanning function, it is known to mount the filter on an oscillating shaft. This known arrangement is inefficient due to the need for repeated reversal of shaft direction, with consequent changing inertial forces, which is obviously wasteful of energy. Moreover, the amplitude of the oscillatory motion may tend to vary with temperature and thus temperature stability of the gas detector is adversely affected.
It is an object of the present invention to provide a light radiation absorption gas detector in which the aforementioned disadvantages are obviated at least in part.
According to the present invention a light radiation absorption gas detector for detecting the presence of a specified gas, comprises a light source, a region containing a gas to be detected through which light from the source is passed, an interference filter having a substantially flat face and a light radiation absorption peak at a wavelength which facilitates detection of the specified gas, a shaft to which the filter is secured for rotation so that a perpendicular to the flat face of the filter is at an angle to the axis of the rotation and light detector means responsive to light from the source which has passed through the region and the filter, for detecting predetermined light amplitude variations, wherein light from the source is arranged to be projected towards the filter at an angle offset from the axis of shaft rotation whereby a filter pass band which includes the said wavelength is scanned consequent upon rotation of the filter, thereby to produce amplitude variations of light in the presence within the region of the specified gas, whereby detection of the specified gas by the detector means is facilitated.
By arranging that the filter is secured to the shaft so that a perpendicular to its flat face is arranged at an angle to the axis of rotation, and by further arranging that light is projected towards the filter at an angle offset from the shaft axis, it will be apparent that light from the source will strike the filter at an angle which changes with shaft rotation whereby a scanning function of the filter pass band is effected.
By using an arrangement according to the present invention, the shaft may be rotated at a substantially constant angular velocity whereby changing inertial forces (as produced by oscillatory systems) with their attendant disadvantages, are not present.
One embodiment of invention will now be described by way of example with reference to the accompanying drawings in which: Figure 1 is a generally schematic block diagram of a light absorption gas detector, Figure 2 is a somewhat schematic perspective view of a known filter arrangement for use with the system shown in Figure 1, Figure 3 is a somewhat schematic perspective view of a filter arrangement for use in a gas detector as shown in Figure 1 and according to one embodiment of the present invention, Figure 4 is a somewhat schematic perspective view of an alternative filter arrangement for use in a gas detector as shown in Figure 1 and according to an alternative embodiment of the present invention wherein parts corresponding to those shown in Figure 3 bear the same numerical designations, and Figure 5 is a graph showing a typical gas absorption curve.
Referring now to Figure 1, a light absorption gas detector comprises a light source 1 which in the present example is a filament lamp. Light from the source is directed towards an optical chopper 2 having blades 3 which are rotated by means of a motor 4. Light from the chopper 2 is passed via a lens 5 through a gas sensing region 6.
Due to operation of the chopper 2, light in the region 6 comprises pulses as shown in waveform A. The light pulses are fed through an optical system comprising lenses 7 and 8 to produce a narrow beam of parallel light pulses as shown in waveform B, which corresponds substantially with waveform A. Light from the lens 8 is fed through a filter assembly 9 which comprises an interference filter 9a having a pass band including a wavelength which corresponds to the absorption wavelength of a gas to be detected.
The operation and construction of the filter assembly will hereinafter be described in more detail with reference to Figures 2, 3 4 and 5. Light from the filter 9a is fed through a lens 10 to a photo detector arrangement 11, which includes a light detector element and a signal processor.
If a gas to be detected is present in the region 6, absorption occurs which results in a modulation being imposed on the waveform shown in Figure B (produced by movement of the filter element 9a as will hereinafter be explained), so as to produce a modulated waveform C.
Referring now to Figure 2, the filter in one known arrangement comprises an interference filter element 12 which is attached to a shaft 13. The shaft 13 is coupled to an electrical drive unit 14 which produces oscillatory angular movement of the shaft 13. The electrical drive unit 14 may be a galvanometer movement for example. Thus it will be appreciated that light projected towards the filter 12 in the direction of arrows 15 will be incident upon the filter at an angle which is varied as the shaft 13 oscillates. As the angle of incidence changes consequent upon oscillation of the shaft 13, a pass band including the wavelength of absorption of a gas to be detected is scanned. The filter is chosen to include an absorption wavelength of a gas to be detected and thus the filter 9 would be chosen in accordance with the type of gas to be detected.This known arrangement as shown in Figure 2 has several disadvantages as hereinbefore explained, which stem from the fact that the filter 12 and the shaft are oscillated.
In order to avoid these disadvantages, a filter arrangement as shown in Figure 3 may be used. The filter arrangement comprises a filter element 16 which is secured to a shaft 19 having an axis of rotation 17. The shaft 19 is driven by a motor 18 shown schematically. The filter element 16, which comprises a substantially flat circular disk, is secured to the shaft 19 so that a perpendicular y to its flat face 16a is set at an angle x with respect to the axis of rotation 17. Light incident on the filter element 16, which is projected from the lens 8 as shown in Figure 1, is arranged to be offset by an angle z with respect to the axis of rotation 17. Although in the arrangement of Figure 3 the filter element 16 is shown attached centrally to the shaft 19, in an alternative arrangement the filter element 16 may be supported at its circular peripheral edge by an angular rim or bezel 25 which is coupled to a pair of support arms 24 as shown in Figure 4 which are coupled to the shaft 19. With this arrangement it can be arranged that light projected through the filter element 16 is not obstructed by the shaft 19.
Preferably an even number of connecting arms 23 are used, (two are shown in Figure 4) symmetrically spaced around the bezel 25. This ensures that with two arms, any interruption of the beam by the arms 23 will be at twice the oscillation frequency and may hence be easily rejected by the electronics processing. This however is not an essential requirement if the chopper blade 2 shown in Figure 1 is arranged to be correctly phased with the filter rotation such that the connecting arms break the light beam when the chopper interrupts the light.
A further advantage is obtained by arranging that the speed of rotation of the chopper blade is an even multiple of the speed of rotation of the filter. This tends to cancel errors caused by irregularities in the chopper blades as they similarly effect both positive and negative parts of the detected signal.
It is important that the portion of the Filter through which the light passes is substantially unchanged during the filter's rotation and the apparatus of Figure 4 achieves this by using the central area of the Filter.
In operation of the gas detector, the filter element 16 is rotated at a substantially constant velocity by the motor 18 and it will be apparent that the angle of incidence of light rays 20 on the filter will vary as the element 16 rotates. If a gas is present in the region 6 as shown in Figure 1, light modulation will be produced as shown in waveform C consequent upon rotation of the filter element 16.
Referring to Figure 5, it will be appreciated that if a wavelength band between the points 21 and 22 on the horizontal axis of the curve is scanned, a light intensity variation will be produced which corresponds to the modulation as shown in waveform C, at a frequency which corresponds to the angular rotation rate of the shaft 19.
The filter will be chosen having regard to the gas to be detected and for the detection of methane for example, which has an absorption peak at 2.9 microns, a filter with a passband including 2.9 microns would be chosen and a wavelength band of between 2.8 microns to 2.9 microns would be scanned with the angles x and z being about 5 degrees and 30 degrees respectively. The detector arrangement 11 comprises a photo detector, (not shown), output signals from which are fed to a signal processor which serves for the identification of signal variations indicative of the presence of a specified gas.
It will be appreciated by those skilled in the art that any suitable form of detector arrangement 11 may be used and in order to facilitate detection of small signals, an output signal on a line 23 from the drive motor 18 may be provided which corresponds to the frequency of rotation whereby the detection of a corresponding modulation frequency as shown in the waveform C is facilitated.
Various modifications may be made to the arrangement described herein without departing from the scope of the invention and for example it will be appreciated that any suitable light source and filter may be used and for example an infra-red or an ultraviolet light source may be appropriate, together with a suitable filter, for the detection of some gases. It will also be appreciated that any means may be used to rotate the filter element 16 and that any suitable form of detection may be used to detect the resultant modulation of the signal produced in the presence of a gas in the region 6.

Claims (13)

1. A light radiation absorption gas detector for detecting the presence of a specified gas, comprising a light source, a region containing a gas to be detected through which light from the source is passed, an interference filter having a substantially flat face and a light radiation absorption peak at a wavelength which facilitates detection of the specified gas, a shaft to which the filter is secured for rotation so that a perpendicular to the flat face of the filter is at an angle to the axis of the rotation and light detector means responsive to light from the source which has passed through the region and the filter, for detecting predetermined light amplitude variations, wherein light from the source is arranged to be projected towards the filter at an angle offset from the axis of shaft rotation whereby a filter pass band which includes the said wavelength is scanned consequent upon rotation of the filter, thereby to produce amplitude variations of light in the presence within the region of the specified gas, whereby detection of the specified gas by the detector means is facilitated.
2. A gas detector as claimed in claim 1 wherein a light chopper or interrupter is interposed between the said source and the said detector means.
3. A gas detector as claimed in claim 2, wherein light from the source is directed via first lens means through the region, via second lens means from the region to the filter and via third lens means from the filter to the detector.
4. A gas detector as claimed in Claim 3, wherein the light chopper is interposed between the light source and the first lens means.
5. A gas detector as claimed in any of claims 2 to 4 wherein the filter is supported by arms which interrupt the beam as the shaft is rotated.
6. A gas detector as claimed in claim 5 wherein the arms are positioned so as to interrupt the beam synchronously with the chopper.
7. A gas detector as claimed in claim 5 or claim 6 wherein there are an even number of arms.
8. A gas detector as claimed in any of claims 2 to 7 wherein the chopper comprises rotary blades which interrupt the beam at an even multiple of the shaft rotation rate.
9. A gas detector as claimed in any preceding Claim, wherein the light detector means comprises an optical detector element effective to detect the light amplitude variations and a signal processor responsive to the said element for detecting electrical signal variations corresponding to the light amplitude variations produced in the presence within the region of the specified gas.
10. A gas detector as claimed in any preceding Claim, wherein the signal processor is arranged to detect electrical signal variations in the form of amplitude modulation.
11. A gas detector as claimed in any preceding Claim, wherein the shaft rotating means comprises a motor.
12. A gas detector as claimed in any of claims 5 to 11, wherein the said filter is generally circular and supported at its circular peripheral edge by means of the arms.
13. A gas detector as claimed in Claim 1 and substantially as hereinbefore described with reference to Figures 3, 4 and 5 of the accompanying drawings.
GB9114910A 1991-04-26 1991-07-10 Optical gas detector Withdrawn GB2255178A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP19920303301 EP0510856A3 (en) 1991-04-26 1992-04-14 Improvements in or relating to optical gas detectors
CA002066816A CA2066816A1 (en) 1991-04-26 1992-04-22 Optical gas detectors
US07/873,951 US5268745A (en) 1991-04-26 1992-04-24 Light radiation absorption gas detector
JP4106879A JPH06167448A (en) 1991-04-26 1992-04-24 Optical gas detector

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB919108978A GB9108978D0 (en) 1991-04-26 1991-04-26 Improvements in or relating to optical gas detectors

Publications (2)

Publication Number Publication Date
GB9114910D0 GB9114910D0 (en) 1991-08-28
GB2255178A true GB2255178A (en) 1992-10-28

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GB919108978A Pending GB9108978D0 (en) 1991-04-26 1991-04-26 Improvements in or relating to optical gas detectors
GB9114910A Withdrawn GB2255178A (en) 1991-04-26 1991-07-10 Optical gas detector

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Application Number Title Priority Date Filing Date
GB919108978A Pending GB9108978D0 (en) 1991-04-26 1991-04-26 Improvements in or relating to optical gas detectors

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130041611A1 (en) * 2010-04-19 2013-02-14 Lni Schmidlin Ag) (Lni Schmidlin) Method of and system for calibrating gas flow dilutors

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN120489448B (en) * 2025-07-18 2025-09-19 成都市城市安全与应急管理研究院 An intelligent monitoring device for chemical tank leakage based on multispectral imaging

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1583845A (en) * 1976-09-14 1981-02-04 Balzers Patent Beteilig Ag Determination of the ratio of amounts of two components of a mixture of substances
GB2163251A (en) * 1984-07-19 1986-02-19 Elektrisk Bureau As Infrared gas detector

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1583845A (en) * 1976-09-14 1981-02-04 Balzers Patent Beteilig Ag Determination of the ratio of amounts of two components of a mixture of substances
GB2163251A (en) * 1984-07-19 1986-02-19 Elektrisk Bureau As Infrared gas detector

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130041611A1 (en) * 2010-04-19 2013-02-14 Lni Schmidlin Ag) (Lni Schmidlin) Method of and system for calibrating gas flow dilutors
US9229456B2 (en) * 2010-04-19 2016-01-05 Lni Schmidlin Sa (Lni Schmidlin Ag) (Lni Schmidlin Ltd) Method of and system for calibrating gas flow dilutors

Also Published As

Publication number Publication date
GB9108978D0 (en) 1991-06-26
GB9114910D0 (en) 1991-08-28

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