GB960786A - Production of synthetic polyester filaments - Google Patents
Production of synthetic polyester filamentsInfo
- Publication number
- GB960786A GB960786A GB3400862A GB3400862A GB960786A GB 960786 A GB960786 A GB 960786A GB 3400862 A GB3400862 A GB 3400862A GB 3400862 A GB3400862 A GB 3400862A GB 960786 A GB960786 A GB 960786A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- compound
- metal
- formula
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000728 polyester Polymers 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 5
- 239000002184 metal Substances 0.000 abstract 5
- 150000001875 compounds Chemical class 0.000 abstract 4
- OJVAMHKKJGICOG-UHFFFAOYSA-N 2,5-hexanedione Chemical compound CC(=O)CCC(C)=O OJVAMHKKJGICOG-UHFFFAOYSA-N 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 125000004429 atom Chemical group 0.000 abstract 2
- 239000013522 chelant Substances 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000002902 organometallic compounds Chemical class 0.000 abstract 2
- SMQUZDBALVYZAC-UHFFFAOYSA-N salicylaldehyde Chemical compound OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 abstract 2
- CVBUKMMMRLOKQR-UHFFFAOYSA-N 1-phenylbutane-1,3-dione Chemical compound CC(=O)CC(=O)C1=CC=CC=C1 CVBUKMMMRLOKQR-UHFFFAOYSA-N 0.000 abstract 1
- JGKFWCXVYCDKDU-UHFFFAOYSA-N 2,4-dioxo-4-phenylbutanoic acid Chemical compound OC(=O)C(=O)CC(=O)C1=CC=CC=C1 JGKFWCXVYCDKDU-UHFFFAOYSA-N 0.000 abstract 1
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical group [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 abstract 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical group [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Chemical group 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 abstract 1
- 239000006187 pill Substances 0.000 abstract 1
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract 1
- -1 polyethylene terephthalates Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 235000002906 tartaric acid Nutrition 0.000 abstract 1
- 239000011975 tartaric acid Substances 0.000 abstract 1
- 239000011135 tin Chemical group 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 239000010936 titanium Chemical group 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical group [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/681—Polyesters containing atoms other than carbon, hydrogen and oxygen containing elements not provided for by groups C08G63/682 - C08G63/698
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Polyesters, spinnable into fibres having a reduced tendency to pill (see Division B5), are made by polymerizing an ester of a dihydroxy compound and a dicarboxylic acid in the presence of an organic compound having the grouping <PICT:0960786/C3/1> in which M is antimony, chromium, iron, tin, titanium, vanadium or zirconium, the metalorganic compound being present in an amount of at least 0.1 mole per cent. based on the number of mols. of metal atom per 100 mols. of dicarboxylate radicals. Linkages from the metal atom through oxygen atom to the polyester chains are then treated. The metalorganic compound may be (a) an ester of formula M-(O-R)n where R is an organic radical and n is the valency of the metal; (b) a metal chelate derived e.g. from acetonylacetone, benzoylacetone, acetoacetic ester, salicylaldehyde, benzoyl pyruvic acid, o-hydroxyacetone or triethanolamine; (c) a salt of an organic acid, e.g. acetic, phenylacetic, lactic, salicyclic, citric, glycolic or tartaric acid; (d) an ester-chelate compound of formula (RO)m-M-(OCOR1)m1, where m and m1 are integers whose sum is equal to the valency of the metal and R and R1 are organic radicals; or (e) a compound of formula (R)m-M-(OCOR1)m1. The dicarboxylic acid is preferably terephthalic acid or a mixture thereof with up to 25 mole per cent. of adipic, sebacic, isophthalic, bibenzoic, hexahydroterephthalic diphenoxyethane-4, 41-dicarboxylic, p, p1-carbonyldibenzoic or p, p1-sulphonyldibenzoic acid. The dihydroxy compound may be a glycol of formula: <FORM:0960786/C3/1> where p and q are integers and Y is a cycloaliphatic group, an aromatic group, an oxy group or an arylenedioxy group. The polyesterification mixture may also include catalysts, delustrants (e.g. titanium dioxide) or colour inhibitors (e.g. phosphoric acid). Examples describe the manufacture of metal-modified polyethylene terephthalates. Specification 578,074 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13751661A | 1961-09-12 | 1961-09-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB960786A true GB960786A (en) | 1964-06-17 |
Family
ID=22477776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3400862A Expired GB960786A (en) | 1961-09-12 | 1962-09-05 | Production of synthetic polyester filaments |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE622339A (en) |
| DE (1) | DE1227610B (en) |
| FR (1) | FR1333440A (en) |
| GB (1) | GB960786A (en) |
| LU (1) | LU42322A1 (en) |
| NL (1) | NL282825A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3484410A (en) * | 1966-11-23 | 1969-12-16 | Allied Chem | Process for preparing polyesters with antimony catalysts |
| US3528946A (en) * | 1967-08-30 | 1970-09-15 | Fmc Corp | Acetylacetonates as polycondensation catalysts in transesterification method of preparing polyesters |
| CN121700698A (en) * | 2026-02-13 | 2026-03-20 | 如皋市顺源电力绳网带织造有限公司 | A method for producing a high-strength wire traction rope |
-
1962
- 1962-09-04 NL NL282825D patent/NL282825A/nl unknown
- 1962-09-05 GB GB3400862A patent/GB960786A/en not_active Expired
- 1962-09-07 LU LU42322D patent/LU42322A1/xx unknown
- 1962-09-11 BE BE622339D patent/BE622339A/xx unknown
- 1962-09-11 FR FR909163A patent/FR1333440A/en not_active Expired
- 1962-09-12 DE DE1962P0030164 patent/DE1227610B/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3484410A (en) * | 1966-11-23 | 1969-12-16 | Allied Chem | Process for preparing polyesters with antimony catalysts |
| US3528946A (en) * | 1967-08-30 | 1970-09-15 | Fmc Corp | Acetylacetonates as polycondensation catalysts in transesterification method of preparing polyesters |
| CN121700698A (en) * | 2026-02-13 | 2026-03-20 | 如皋市顺源电力绳网带织造有限公司 | A method for producing a high-strength wire traction rope |
Also Published As
| Publication number | Publication date |
|---|---|
| LU42322A1 (en) | 1962-11-07 |
| DE1227610B (en) | 1966-10-27 |
| NL282825A (en) | 1965-01-11 |
| BE622339A (en) | 1963-03-11 |
| FR1333440A (en) | 1963-07-26 |
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