JP2517862B2 - How to prevent salt solidification - Google Patents
How to prevent salt solidificationInfo
- Publication number
- JP2517862B2 JP2517862B2 JP4033296A JP3329692A JP2517862B2 JP 2517862 B2 JP2517862 B2 JP 2517862B2 JP 4033296 A JP4033296 A JP 4033296A JP 3329692 A JP3329692 A JP 3329692A JP 2517862 B2 JP2517862 B2 JP 2517862B2
- Authority
- JP
- Japan
- Prior art keywords
- salt
- caking
- inorganic compound
- weight
- finely divided
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000003839 salts Chemical class 0.000 title claims description 46
- 238000007711 solidification Methods 0.000 title claims description 7
- 230000008023 solidification Effects 0.000 title claims description 7
- 239000011833 salt mixture Substances 0.000 claims description 12
- 150000002484 inorganic compounds Chemical class 0.000 claims description 11
- 229910010272 inorganic material Inorganic materials 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- -1 alkaline earth metal carbonate Chemical class 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 238000007596 consolidation process Methods 0.000 claims description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 1
- 229910052814 silicon oxide Inorganic materials 0.000 claims 1
- 235000002639 sodium chloride Nutrition 0.000 description 41
- 239000003795 chemical substances by application Substances 0.000 description 13
- 239000002245 particle Substances 0.000 description 9
- 230000000903 blocking effect Effects 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 2
- 239000000404 calcium aluminium silicate Substances 0.000 description 2
- 235000012215 calcium aluminium silicate Nutrition 0.000 description 2
- WNCYAPRTYDMSFP-UHFFFAOYSA-N calcium aluminosilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O WNCYAPRTYDMSFP-UHFFFAOYSA-N 0.000 description 2
- 229940078583 calcium aluminosilicate Drugs 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 239000000429 sodium aluminium silicate Substances 0.000 description 2
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Landscapes
- Seasonings (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は食塩又は精製塩等が雰囲
気中の水分によって固結することを防止するための改良
方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an improved method for preventing salt or purified salt from being solidified by moisture in the atmosphere.
【０００２】[0002]
【従来の技術】食塩や精製塩等の不純物が少ない高純度
の塩は、食品工業等で大量に使用されているが、雰囲気
に暴露されていると雰囲気中の水分を吸収して固結し易
く、固結すると取扱に支障が生ずるばかりでなく作業能
率を低下させるという問題がある。そこで固結化の防止
のために炭酸マグネシウム、炭酸カルシウム等のアルカ
リ土類金属炭酸塩や、酸化アルミニウム、二酸化珪素等
の無機酸化物、或いはアルミノ珪酸ナトリウム、アルミ
ノ珪酸カルシウム等のアルミノ珪酸化合物などの水不溶
性の微粒化無機化合物を食塩や精製塩に添加混合する方
法が用いられている。2. Description of the Related Art High-purity salts containing few impurities such as salt and refined salts are used in large amounts in the food industry and the like, but when exposed to the atmosphere, they absorb water in the atmosphere and solidify. If it is easily solidified, there is a problem in that not only the handling will be hindered but also the work efficiency will be reduced. Therefore, in order to prevent solidification, such as alkaline earth metal carbonates such as magnesium carbonate and calcium carbonate, inorganic oxides such as aluminum oxide and silicon dioxide, or aluminosilicate compounds such as sodium aluminosilicate and calcium aluminosilicate. A method of adding a water-insoluble finely divided inorganic compound to common salt or purified salt and mixing it is used.
【０００３】ところが、このような水不溶性の微粒化無
機化合物を添加する場合は、食塩又は精製塩等に対する
添加量を０．２〜０．５重量％程度としないと有効に固
結化を防止することができない。しかも微粒化無機化合
物と食塩又は精製塩等との混合物は粒径が異なるために
偏析現象を起こしやすく、純度が低下するばかりでなく
水に溶解したときに濁りが大きくなるという問題もあっ
た。However, when such a water-insoluble finely divided inorganic compound is added, solidification is effectively prevented unless the addition amount to salt or purified salt is about 0.2 to 0.5% by weight. Can not do it. Moreover, since the mixture of the finely divided inorganic compound and salt or purified salt is different in particle size, segregation phenomenon is likely to occur, which not only lowers the purity but also increases turbidity when dissolved in water.
【０００４】[0004]
【発明が解決しようとする課題】そこで本発明では、食
塩や精製塩等の純度を低下させることなく固結化を防止
することを目的とした。すなわち本発明は、水不溶性の
微粒化無機化合物の添加量を大幅に低減してしかも効果
的に固結化を防止する方法を提供しようとするものであ
る。SUMMARY OF THE INVENTION Therefore, the present invention has an object to prevent solidification without lowering the purity of salt or purified salt. That is, the present invention intends to provide a method of significantly reducing the addition amount of a water-insoluble atomized inorganic compound and effectively preventing solidification.
【０００５】[0005]
【課題を解決するための手段】本発明の塩の固結防止方
法は、塩に水不溶性の微粒化無機化合物を添加して固結
を防止するに当たり、１重量％以下の該無機化合物を添
加した５０μｍ以下の微粒化塩混合物を、塩に対して
０．２〜１０重量％の割合で添加することを特徴とす
る。The method for preventing caking of a salt according to the present invention comprises adding 1% by weight or less of the inorganic compound to prevent caking by adding a water-insoluble atomized inorganic compound to the salt. The micronized salt mixture having a particle size of 50 μm or less is added at a ratio of 0.2 to 10% by weight with respect to the salt.
【０００６】本発明の塩の固結防止方法に用いられる固
結防止用の水不溶性の微粒化無機化合物は、従来からこ
の目的に使用されているものでよく、炭酸マグネシウ
ム、炭酸カルシウム等のアルカリ土類金属炭酸塩や、酸
化アルミニウム、二酸化珪素等の無機酸化物、或いはア
ルミノ珪酸ナトリウム、アルミノ珪酸カルシウム等のア
ルミノ珪酸化合物などを挙げることができる。The water-insoluble finely divided inorganic compound for preventing caking used in the method for preventing caking of salts according to the present invention may be one conventionally used for this purpose, such as an alkali such as magnesium carbonate or calcium carbonate. Examples thereof include earth metal carbonates, inorganic oxides such as aluminum oxide and silicon dioxide, and aluminosilicate compounds such as sodium aluminosilicate and calcium aluminosilicate.
【０００７】[0007]
【作用】本発明の塩の固結防止方法によれば、食塩や精
製塩等の塩に対して水不溶性の微粒化無機化合物すなわ
ち固結防止剤を均一に混合させることが可能となり、従
って固結防止剤の使用量を大幅に減らすことができ、純
度の低下を最小限に止めることができる。According to the salt caking prevention method of the present invention, it is possible to uniformly mix a water-insoluble finely divided inorganic compound, that is, a caking inhibitor, with a salt such as salt or purified salt. The amount of the anti-caking agent used can be greatly reduced, and the decrease in purity can be minimized.
【０００８】[0008]
【実施例】（第１実施例）市販の精製塩を平均粒径３２
μｍとなるよう粉砕して微粒化塩とした。この微粒化塩
に、固結防止剤ａとしての平均粒径２μｍの微粒二酸化
珪素（富士デヴィソン製、サイロページ７２０）を１重
量％となるよう添加して、緊密な塩混合物Ａを調製し
た。また、同様にして微粒化塩に、固結防止剤ｂとして
の平均粒径０．０１２μｍの微粒二酸化珪素（日本アエ
ロジル、２００ＣＦ）または固結防止剤ｃとしての平均
粒径３〜５μｍの微粒炭酸カルシウム（徳山ソーダ、食
添用）をそれぞれ１重量％となるよう添加して、塩混合
物Ｂまたは塩混合物Ｃを調製した。Example (First Example) A commercially available purified salt was used to obtain an average particle size of 32.
It was pulverized to have a particle size of μm to obtain a finely divided salt. A fine salt mixture A was prepared by adding 1% by weight of finely divided silicon dioxide having an average particle diameter of 2 μm (manufactured by Fuji Devison, Silopage 720) as an anti-caking agent a to this finely divided salt. Similarly, the finely divided salt is added to the finely divided salt, as the anti-caking agent b, the fine particle silicon dioxide having an average particle size of 0.012 μm (Nippon Aerosil, 200CF) or as the anti-caking agent c, the fine particle carbonic acid having an average particle size of 3 to 5 μm. Calcium (Tokuyama soda, food additive) was added to each to be 1% by weight to prepare a salt mixture B or a salt mixture C.
【０００９】市販の精製塩（平均粒径３１５μｍ、σ＝
９０μｍ）に対して塩混合物Ａ、塩混合物Ｂまたは塩混
合物Ｃをそれぞれ０．５％、１．０％および１０．０％
となるよう添加して本発明による試料塩を調製すると共
に、固結防止剤ａ、固結防止剤ｂ又は固結防止剤ｃをそ
れぞれ添加量として本発明による試料塩と同一である
０．００５％、０．０１％および０．１％となるよう添
加した比較用の試料塩を調製した。Commercially available purified salt (average particle size 315 μm, σ =
90 μm) salt mixture A, salt mixture B or salt mixture C 0.5%, 1.0% and 10.0%, respectively.
To prepare the sample salt according to the present invention, and the addition amount of the anti-caking agent a, the anti-caking agent b or the anti-caking agent c is 0.005 which is the same as that of the sample salt according to the present invention. %, 0.01% and 0.1% were added to prepare comparative sample salts.
【００１０】これらの試料塩各５００ｇをほぼ立方体形
の内容約５００mlのプラスチック容器に入れて蓋を被
せ、３５℃で９０％RHの環境に２．５日放置したのち２
５℃で５０％RHの環境に１日置くという強制環境中に２
週間並びに４週間暴露した。暴露後内容物を容器から抜
き出して２×２mmの網の上に落とし、網上に止まった塩
の重量を計量して次式によりブロッキング率を算出し
た。500 g of each of these sample salts was placed in a plastic container of approximately 500 ml cubic content, covered with a lid, and allowed to stand in an environment of 90% RH at 35 ° C. for 2.5 days.
2 in a forced environment where it is placed in an environment of 5% and 50% RH for 1 day
It was exposed for a week and 4 weeks. After the exposure, the content was taken out of the container and dropped on a 2 × 2 mm net, and the weight of the salt remaining on the net was measured, and the blocking rate was calculated by the following formula.
【数１】ブロッキング率(%) ＝ 固結塩重量(g) ／全重
量(g) ×１００[Equation 1] Blocking rate (%) = solid salt weight (g) / total weight (g) x 100
【００１１】また、ブロッキング率が高い値を示した試
料については、縦に２分割したのち径３０mm、高さ３０
mmの円柱形の試験片を削り出して、ＪＩＳ−Ｒ５２０１
に準じて圧縮破壊試験を行い、単位断面積当たりの破壊
荷重（kgf/cm2 ）を算出して固結強度とした。これらの
試験結果を固結防止処理をしないままの市販の精製塩に
ついてのブランク試験結果と共に表１に示した。Further, for the sample showing a high blocking rate, it was divided into two vertically and then the diameter was 30 mm and the height was 30 mm.
Milling out a cylindrical test piece of mm, JIS-R5201
The compressive fracture test was conducted in accordance with the above, and the fracture load per unit cross-sectional area (kgf / cm 2 ) was calculated as the consolidation strength. The results of these tests are shown in Table 1 together with the results of blank tests on the commercially available purified salt without the anti-caking treatment.
【００１２】[0012]
【表１】 表 １ ─────────────────────────────────── 試験 塩混合物 固結防止剤 ブロッキング率 固結強度 番号 種類 量(%) 種類 量(%) (%) (kgf/cm2) 14日後 28日後 14日後 28日後 ─────────────────────────────────── 1 Ａ 0.5 ａ 0.005 100 100 0.29 1.02 2 Ａ 1.0 ａ 0.01 44 100 − 0.91 3 Ａ 10.0 ａ 0.1 2 0.6 − − 4 * ａ 0.005 100 100 0.99 2.40 5 * ａ 0.01 100 100 0.39 1.20 6 * ａ 0.1 4.1 0.7 − − 7 Ｂ 0.5 ｂ 0.005 0 100 − 1.46 8 Ｂ 1.0 ｂ 0.01 75 100 − 0.65 9 Ｂ 10.0 ｂ 0.1 0 0 − − 10 * ｂ 0.005 100 100 0.85 2.26 11 * ｂ 0.01 100 100 0.34 1.40 12 * ｂ 0.1 0 0 − − 13 Ｃ 0.5 ｃ 0.005 100 100 0.32 1.24 14 Ｃ 1.0 ｃ 0.01 85 100 0.15 0.41 15 Ｃ 10.0 ｃ 0.1 8 31 0.10 0.10 16 * ｃ 0.005 100 100 1.13 2.31 17 * ｃ 0.01 100 100 0.22 0.89 18 * ｃ 0.1 49 54 0.10 0.10 19 ** − − 100 100 0.79 3.31 ─────────────────────────────────── * ：比較例、 **：ブランク[Table 1] Table 1 ─────────────────────────────────── Test salt mixture Anti-caking agent Blocking rate Caking strength No.Type Amount (%) Type Amount (%) (%) (kgf / cm 2 ) 14 days 28 days 14 days 28 days ──────────────────── ───────────────── 1 A 0.5 a 0.005 100 100 0.29 1.02 2 A 1.0 a 0.01 44 100 − 0.91 3 A 10.0 a 0.1 2 0.6 − − 4 * a 0.005 100 100 0.99 2.40 5 * a 0.01 100 100 0.39 1.20 6 * a 0.1 4.1 0.7 − − 7 B 0.5 b 0.005 0 100 − 1.46 8 B 1.0 b 0.01 75 100 − 0.65 9 B 10.0 b 0.1 0 0 − − 10 * b 0.005 100 100 0.85 2.26 11 * b 0.01 100 100 0.34 1.40 12 * b 0.1 0 0 − − 13 C 0.5 c 0.005 100 100 0.32 1.24 14 C 1.0 c 0.01 85 100 0.15 0.41 15 C 10.0 c 0.1 8 31 0.10 0.10 16 * c 0.005 100 100 1.13 2.31 17 * c 0.01 100 100 0.22 0.89 18 * c 0.1 49 54 0.10 0.10 19 ** − − 10 0 100 0.79 3.31 ─────────────────────────────────── *: Comparative example, **: Blank
【００１３】（第２実施例）第１実施例で用いた市販の
精製塩の２０重量％水溶液に前記の固結防止剤ｂを０．
２重量％となるよう分散させ、回転ディスク型の噴霧乾
燥機を用いてディスク回転数３００００rpm 、入口空気
温度２５０℃で噴霧乾燥して平均粒径約１５μｍの固結
防止用の塩混合物Ｄを得た。(Second Example) The anti-caking agent b was added to a 20% by weight aqueous solution of the commercially available purified salt used in the first example.
The mixture was dispersed so as to be 2% by weight, and spray-dried using a rotary disk type spray dryer at a disk rotation speed of 30,000 rpm and an inlet air temperature of 250 ° C. to obtain an anti-caking salt mixture D having an average particle diameter of about 15 μm. It was
【００１４】第１実施例と同様にして市販の精製塩にこ
の塩混合物Ｄを１．０％となるよう添加して本発明によ
る試料塩を調製し、第１実施例と同様にして４週間の固
結試験を行った。その試験結果を、固結防止剤ｂを添加
量として同一レベルとなるように市販の精製塩に直接に
混合した比較用の試料塩についての試験結果と共に表２
に示した。In the same manner as in Example 1, the salt mixture D was added to a commercially available purified salt so as to be 1.0% to prepare a sample salt according to the present invention, and the same procedure as in Example 1 was carried out for 4 weeks. The solidification test was performed. The test results are shown in Table 2 together with the test results for the sample salt for comparison in which the anti-caking agent b was directly mixed with the commercially available purified salt so that the addition amount was the same level.
It was shown to.
【００１５】[0015]
【表２】 表 ２ ────────────────────────────── 試験 塩混合物 固結防止剤 ブロッキング率 固結強度 番号 種類 量(%) 種類 量(%) (%) (kgf/cm2) ────────────────────────────── 20 Ｄ 1.0 ｂ 0.01 80 0.21 21 * ｂ 0.01 95 0.47 ────────────────────────────── * ：比較例[Table 2] Table 2 ────────────────────────────── Test salt mixture Anti-caking agent Blocking rate Caking strength Number Type Amount (%) Type Amount (%) (%) (kgf / cm 2 ) ────────────────────────────── 20 D 1.0 b 0.01 80 0.21 21 * b 0.01 95 0.47 ────────────────────────────── *: Comparative example
【００１６】これらの結果を見ると、本発明の固結防止
方法は固結防止剤を単純に塩と混合する従来の方法に比
べて格段に優れた固結防止効果を示すことがわかる。From these results, it is understood that the anti-caking method of the present invention exhibits a significantly superior anti-caking effect as compared with the conventional method of simply mixing the anti-caking agent with a salt.
【００１７】[0017]
【発明の効果】本発明の方法を適用して製造された塩
は、固結防止剤の含有量が極めて少ないにかかわらず固
結を起こしがたく、純度が高くて溶解時の白濁などの問
題がないから、種々の用途に向けて広く利用できる効果
がある。EFFECTS OF THE INVENTION The salt produced by applying the method of the present invention is unlikely to cause caking even if the content of the anti-caking agent is extremely small, has a high purity, and causes problems such as cloudiness during dissolution. Therefore, there is an effect that it can be widely used for various purposes.
Claims (2)
して固結を防止するに当たり、１重量％以下の該無機化
合物を添加した５０μｍ以下の微粒化塩混合物を、塩に
対して０．２〜１０重量％の割合で添加することを特徴
とする塩の固結防止方法。1. When adding a water-insoluble atomized inorganic compound to a salt to prevent caking, a finely divided salt mixture of 50 μm or less containing 1% by weight or less of the inorganic compound is added to the salt in an amount of 0. A method for preventing salt solidification, which is characterized in that the salt is added in a proportion of 2 to 10% by weight.
アルミニウム酸化物、珪素酸化物、アルミノ珪酸化合物
から選ばれたものである請求項１記載の塩の固結防止方
法。2. The inorganic compound is an alkaline earth metal carbonate,
The method for preventing salt consolidation according to claim 1, which is selected from aluminum oxide, silicon oxide, and aluminosilicate compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4033296A JP2517862B2 (en) | 1992-02-20 | 1992-02-20 | How to prevent salt solidification |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4033296A JP2517862B2 (en) | 1992-02-20 | 1992-02-20 | How to prevent salt solidification |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05229815A JPH05229815A (en) | 1993-09-07 |
| JP2517862B2 true JP2517862B2 (en) | 1996-07-24 |
Family
ID=12382585
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4033296A Expired - Fee Related JP2517862B2 (en) | 1992-02-20 | 1992-02-20 | How to prevent salt solidification |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2517862B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101813494B1 (en) * | 2017-08-22 | 2017-12-29 | 정승원 | Anti-caking additive reducing silicon dioxide in food and powder-type food composition including the anti-caking additive |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4572613B2 (en) * | 2004-07-16 | 2010-11-04 | 堺化学工業株式会社 | Prevention of caking of magnesium nitrate |
| JP2008303123A (en) * | 2007-06-11 | 2008-12-18 | Ako Kasei Co Ltd | Method for maintaining crystal form of sodium chloride |
| US9504274B2 (en) | 2009-01-27 | 2016-11-29 | Frito-Lay North America, Inc. | Methods of flavor encapsulation and matrix-assisted concentration of aqueous foods and products produced therefrom |
| US20100189845A1 (en) * | 2009-01-27 | 2010-07-29 | Frito-Lay North America Inc. | Flavor Encapsulation and Method Thereof |
-
1992
- 1992-02-20 JP JP4033296A patent/JP2517862B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101813494B1 (en) * | 2017-08-22 | 2017-12-29 | 정승원 | Anti-caking additive reducing silicon dioxide in food and powder-type food composition including the anti-caking additive |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05229815A (en) | 1993-09-07 |
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