JP2597980B2 - Manufacturing method of hot rolled steel - Google Patents
Manufacturing method of hot rolled steelInfo
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- JP2597980B2 JP2597980B2 JP14394985A JP14394985A JP2597980B2 JP 2597980 B2 JP2597980 B2 JP 2597980B2 JP 14394985 A JP14394985 A JP 14394985A JP 14394985 A JP14394985 A JP 14394985A JP 2597980 B2 JP2597980 B2 JP 2597980B2
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- recrystallization
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Description
【発明の詳細な説明】 (発明の属する技術分野) 本発明は熱間圧延によって鋼材を製造する方法に関す
るものである。Description: TECHNICAL FIELD The present invention relates to a method for producing a steel product by hot rolling.
(従来の技術) 従来熱間圧延によって、鋼材を製造する場合には、熱
間圧延の全領域でAr3以上の鋼材温度を維持して圧延す
ることにより、圧延の安定化と同時に材質の安定化をは
かっていた。通常の圧延スケジュールでは、圧延中に鋼
材温度がAr3以以下になった場合にはフェライトの加工
組織が生成され、材質を著しく劣化させる。例として、
第1図に強度−延性バランス、第2図に穴拡げ性につい
て、実機圧延材の結果を示した。(Prior art) Conventionally, when a steel material is manufactured by hot rolling, the steel material is maintained at a temperature of Ar 3 or higher in the entire hot rolling area, thereby stabilizing the rolling and material stability at the same time. Was going on. In a normal rolling schedule, when the steel material temperature becomes equal to or lower than Ar 3 during rolling, a processed structure of ferrite is generated, and the material is significantly deteriorated. As an example,
FIG. 1 shows the results of the strength-ductility balance, and FIG.
第1図中;Ar3以上の温度を維持した圧延を示し、
−1は通常の高強度鋼板、−2は2相鋼板、;圧延
中にAr3以下の温度となった圧延の加工組織を示す。
(C;0.16%,Mn;1.22%) 第2図中;Ar3以上の温度を維持した圧延、;圧延
中にAr3以下の温度となった圧延を示す。(C;0.16%,M
n;1.22%) このような材質の劣化を防ぐために、従来からAr3以
上で圧延を終了する圧延方法がとられてきたが、その際
に用いられているAr3は、主に成分で決定され、(13)
式(三好ら鉄と鋼、vol.51 No.11,2006)、(14)式
(関根ら第86,87回西山記念技術講座「新制御圧延技
術」p.150)等によって計算されていた。FIG. 1 shows rolling while maintaining the temperature of Ar 3 or more;
-1 indicates a normal high-strength steel sheet, -2 indicates a two-phase steel sheet, and indicates a work structure of rolling at a temperature of Ar 3 or less during rolling.
(C; 0.16%, Mn; 1.22%) FIG. 2 shows rolling while maintaining a temperature of Ar 3 or higher; and rolling at a temperature of Ar 3 or lower during rolling. (C; 0.16%, M
n; 1.22%) In order to prevent such deterioration of the material, a rolling method of terminating the rolling with Ar 3 or more has been conventionally used, but the Ar 3 used at that time is mainly determined by the component. (13)
Equations (Miyoshi et al., Iron and Steel, vol.51 No.11, 2006), (14) Equations (Sekine et al., 86th and 87th Nishiyama Memorial Technical Lecture "New Controlled Rolling Technology" p.150) .
Ar3=750.8−26.6×[C]+17.6×[Si]−11.6× [Mn]−22.9×[Cu]−23.0×[Ni]+24.1 ×[Cr]+22.5×[Mo]−39.7×[V]−5.7× [Ti]+31.9×[Zr]+232.6×[Nb]−169.4 ×[Al]−894.7×[B] …(13) Ar3=868−396×[C]+24.6×[Si]−68.1×[Mn] −36.1×[Ni]−20.7×[Cu]−24.8×[Cr]…(14) ([ ]内は各成分の重量%) (発明が解決しようとする課題) しかし、これらの式の中には、加工によるAr3の上昇
が考慮されておらず、実際の熱間圧延において、正確に
歩留りよく材質を出すには不十分である。従って、実際
には経験的な安全代を見込んで、より高温で圧延されて
いるのが現状である。 Ar 3 = 750.8-26.6 × [C] + 17.6 × [Si] -11.6 × [Mn] -22.9 × [Cu] -23.0 × [Ni] +24.1 × [Cr] + 22.5 × [Mo] - 39.7 × [V] -5.7 × [ Ti] + 31.9 × [Zr] + 232.6 × [Nb] -169.4 × [Al] -894.7 × [B] ... (13) Ar 3 = 868-396 × [C ] + 24.6 x [Si]-68.1 x [Mn]-36.1 x [Ni]-20.7 x [Cu]-24.8 x [Cr] ... (14) (Weights in [] indicate weight percent of each component) Problems to be solved) However, these formulas do not take into account the increase in Ar 3 due to working, and it is insufficient to accurately produce a material with good yield in actual hot rolling. Therefore, in reality, rolling is performed at a higher temperature in consideration of empirical safety costs.
一方、加工による変態点の上昇については、田中ら
(鉄と鋼、vol.64 No.3,1353)や、大内ら(鉄と鋼、vo
l.67 No.1,143)の報告があり、表1,2に成分、第3図、
第4図、第5図に、そこで述べられている結果を示し
た。On the other hand, regarding the rise of the transformation point due to processing, Tanaka et al. (Iron and steel, vol.64 No.3, 1353) and Ouchi et al. (Iron and steel, vo
l.67 No.1,143), and Tables 1 and 2 show the components, Fig. 3,
FIGS. 4 and 5 show the results described therein.
しかし、現在まで、定式化がなされていないばかりで
なく、実機熱間圧延で、材質決定に重要な意味を持つ歪
み速度の効果が考慮されておらず、さらに圧延後の時間
の効果も考慮されていない。 However, to date, not only has not been formulated, in the actual hot rolling, the effect of the strain rate, which is important in determining the material, is not considered, and the effect of time after rolling is also considered. Not.
従って、熱間圧延において、正確に、歩留りよく、材
質を出すには不十分である。第3図はAr3の歪による上
昇、第4図はSi−Mn鋼の歪によるAr3上昇、第5図はNb
鋼の歪によるAr3上昇を示す。Therefore, in hot rolling, it is insufficient to produce a material accurately and with good yield. FIG. 3 shows the rise due to the strain of Ar 3 , FIG. 4 shows the rise of Ar 3 due to the strain of the Si—Mn steel, and FIG.
5 shows an increase in Ar 3 due to steel strain.
これらの問題を解決するために本発明者らは、特願昭
59−39983号において加工時の歪速度、加工後の時間を
考慮したAr3の予測方法を示した。しかし、特願昭59−3
9983号においては、加工後の組織変化、すなわち再結晶
による細粒化とそれに伴う歪の解放が考慮されておら
ず、初期粒径が異なることにより加工後の粒径変化と歪
の解放過程が異なる事実が取り込まれていない。従っ
て、加工前の粒径が大きく変化した場合に精度よいAr3
の推定ができない欠点を持つ。特に、連続熱延の場合に
は各パスで大きく粒径が変化するので上記の効果は重要
となる。In order to solve these problems, the present inventors have disclosed a Japanese Patent Application No.
In No. 59-39983, a method for predicting Ar 3 in consideration of the strain rate during processing and the time after processing was described. However, Japanese Patent Application No. 59-3
No. 9983 does not consider the structural change after processing, that is, fine graining by recrystallization and the release of strain accompanying it, and the change in grain size after processing and the release process of strain due to the difference in initial grain size are not considered. Different facts are not captured. Therefore, when the particle size before processing changes greatly, accurate Ar 3
There is a drawback that cannot be estimated. In particular, in the case of continuous hot rolling, the above-mentioned effect is important because the particle size changes greatly in each pass.
本発明は今後圧延条件が高圧下、高速圧延も含めて広
い範囲にわたる際に、上記の従来知見がもたらす問題点
を解消することを目的として行われたもので、特に先願
の特願昭59−39983号で考慮していない加工後の組織変
化、すなわち再結晶による細粒化とそれに伴う歪の回復
を考慮し、変態のための潜伏期の消費率を考慮すること
により、Ar3の予測を精度をさらに高め、これにより更
に熱間圧延における省エネルギー、鋼材の材質の安定化
を進めるものである。The present invention has been made in order to solve the problems caused by the above-mentioned conventional knowledge when the rolling conditions are wide range including high pressure and high speed rolling in the future. tissue changes after processing is not considered in Patent -39983, i.e. taking into account the recovery of the strain and accompanying grain refining by recrystallization, by taking into account the consumption rate of the incubation period for the transformation, the prediction of the Ar 3 Accuracy is further improved, thereby further saving energy in hot rolling and stabilizing the material of steel.
(課題を解決するための手段) 本発明は上記した問題点を解決するために (1)熱間でC−Mn系鋼材を加工し材質を調整する際
に、予め定めた関係式にもとづいて、 各パスにおいて加えられる歪εが、動的再結晶がおこ
る限界歪εCより大きい場合は、動的再結晶、静的再結
晶、未再結晶の3グループに分かれ、歪εがεC以下の
場合は、静的再結晶、未再結晶の2グループに分かれる
として、動的再結晶、静的再結晶、未再結晶のそれぞれ
の粒径dD,dS,dN及び占積率fD,fS,fNを求め、 次パスまでの時間を短い時間Δtに細分化し、Δtの
間での静的再結晶占積率fSの増加を求めた後、動的再結
晶粒の粒成長後の粒径及び静的再結晶粒の粒成長後の粒
径を求めてΔt経過後の平均粒径dを求め、動的再結晶
粒の残留歪と未再結晶の残留歪の合計の熱的な回復を求
めることによりΔt経過後の平均残留歪Δεを求め、 この平均粒径、平均残留歪状態での潜伏期の消費率を
計算し、 次のΔtに対し〜を次パスまでくり返し、 次パス直前の平均粒径と平均残留歪とを次パスの初期
条件として次パスの歪をこの平均残留歪に加えた歪を実
効歪とし、 〜の工程を熱間加工パス回数だけくり返し、 各Δtでの潜伏期の消費率が1になるか否かを判定
し、最終パス加工以前に潜伏期の消費率が1を越す場合
にはこの時の温度を変態点Ar3と予測し、 〜をくり返し、鋼材温度を熱間加工の全領域で変
態点Ar3以上に維持するように全体の加工温度を調節し
加工すること を特徴とする熱延鋼材の製造方法。(Means for Solving the Problems) In order to solve the above-mentioned problems, the present invention provides: (1) When working a C-Mn-based steel material by hot working and adjusting the material, based on a predetermined relational expression. , strain epsilon applied in each pass is greater than the limit strain epsilon C caused dynamic recrystallization, dynamic recrystallization, static recrystallization, divided into three groups of non-recrystallized, strain epsilon is epsilon C or less Is divided into two groups, static recrystallization and non-recrystallization, the respective particle diameters d D , d S , d N of dynamic recrystallization, static recrystallization and non-recrystallization and the space factor f D, f S, seeking f N, subdivided into shorter Delta] t the time until the next pass, after obtaining the increase in static recrystallization space factor f S between Delta] t, the dynamic recrystallization grains The grain size after the grain growth and the grain size after the grain growth of the static recrystallized grains are determined, and the average grain size d after elapse of Δt is determined. Calculate the average residual strain Δε after elapse of Δt by calculating the thermal recovery of this, calculate the average particle diameter, the consumption rate of the incubation period in the average residual strain state, and repeat the following for the next Δt until the next pass The average grain size and the average residual strain immediately before the next pass are set as initial conditions of the next pass, and the strain obtained by adding the strain of the next pass to the average residual strain is defined as the effective strain. It is determined whether the consumption rate of the incubation period at each Δt becomes 1 or not. If the consumption rate of the incubation period exceeds 1 before the final pass machining, the temperature at this time is predicted as the transformation point Ar 3, and A method for producing a hot-rolled steel material, comprising repeatedly adjusting the entire processing temperature so as to maintain the temperature of the steel material at the transformation point Ar 3 or higher in all regions of the hot working.
(2)熱間でC−Mn系鋼材を加工し材質を調整する際
に、動的再結晶限界歪εCについては(1)式、動的再
結晶占積率fDについては(2)式、及び粒径dDについて
は(3)式、動的再結晶占積率fSについては(4)式、
及び粒径dSについては(5)式、また未再結晶占積率fN
については(6)式、及び粒径dNについては(7)式、
また動的再結晶粒の粒成長後の粒径▲d2 DG▼、静的再
結晶粒の粒成長後の粒径に▲d2 SG▼については(8)
(9)式、及びこれらの平均粒径については(10)
式、残留歪の熱的な回復後の平均残留歪Δεについては
(11)式を用い、パス間及び熱間加工終了後冷却開始ま
での時間を細分化した時間Δtでの潜伏期の消費率につ
いては(12)式を用いて、鋼材温度を熱間加工の全領域
でAr3以上に維持し加工することを特徴とする上記
(1)項に再の熱延鋼材の製造方法。(2) When hot working a C-Mn-based steel material to adjust the material, formula (1) is used for the dynamic recrystallization limit strain ε C and (2) is used for the dynamic recrystallization space factor f D. Equation (3) for the equation and the particle size d D , Equation (4) for the dynamic recrystallization space factor f S ,
Equation (5) for the particle size d S and the unrecrystallized space factor f N
For (6), and the particle diameter d N (7) below,
The grain size of the dynamically recrystallized grains after the grain growth {d 2 DG ▼} and the grain size of the static recrystallized grains after the grain growth are {d 2 SG }.
For the formula (9) and their average particle size,
Equation (11) is used to determine the average residual strain Δε after thermal recovery of the residual strain, and the equation (11) is used to determine the consumption rate of the incubation period at the time Δt obtained by subdividing the time between the pass and the end of hot working to the start of cooling. The method for producing a hot-rolled steel material according to the above item (1), wherein the steel material temperature is maintained at Ar 3 or more in the entire region of the hot working using the formula (12).
Tは圧延温度(K) Rは気体定数 A1は動的再結晶限界歪の統計的修正係数 Q1は動的再結晶限界歪に及ぼす温度の影響を表すエネル
ギー aは動的再結晶限界歪に及ぼす初期粒径の影響を表す指
数 m=A2・exp(Q2/T) εS=A3・〔1−exp(−d0/K)〕 K=A4・b・exp(−Q3/T) A2は動的再結晶占積率に及ぼす付加歪の影響を表す指数
mの統計的修正係数 Q2は動的再結晶占積率に及ぼす付加歪の影響を表す指数
mに及ぼす温度の影響を表すエネルギー A3は動的再結晶終了歪εSの統計的修正係数 A4は動的再結晶終了歪εSに及ぼす歪速度と温度の影響
を表すKの統計的修正係数 Q3は動的再結晶終了歪εSに及ぼす温度の影響を表すエ
ネルギー bは動的再結晶終了歪εSに及ぼす歪速度の影響を表す
指数 dD=A5・ZC,Z=exp(Q/RT) …(3) A5は動的再結晶粒径の統計的修正係数 cは動的再結晶粒径に及ぼすZener−Hollomon paramete
rの影響を表す指数 Qは動的再結晶の活性化エネルギー fS=(1−fD)・(1−exp{−(t/TS)S}) …
(4) tはパス間時間あるいは圧延後冷却開始までの時間(se
c) Sは静的再結晶占積率に及ぼす時間の影響を表す指数 TSは静的再結晶占積率に及ぼす歪と温度の影響を表す関
数 d0は圧延前粒径 A6は静的再結晶粒径の統計的修正係数 dは静的再結晶粒径に及ぼす初期粒径の影響を表す指数 eは静的再結晶粒径に及ぼす歪の影響を表す指数 fN=1−fD−fS …(6) dN=d0・exp(−ε/4) …(7) A7は動的再結晶粒成長の統計的修正係数 Q4は動的再結晶粒成長に及ぼす温度の影響を表すエネル
ギー fは動的再結晶粒成長に及ぼす時間の影響を表す指数 A8は静的再結晶粒成長の統計的修正係数 Q5は静的再結晶粒成長に及ぼす温度の影響を表すエネル
ギー gは静的再結晶粒成長に及ぼす時間の影響を表す指数 Δε=(fD・εC+fN・ε)・exp(−{t/Tk}h) …
(11) Tkは残留歪に及ぼす温度の影響を表す関数 hは残留歪に及ぼす時間の影響を表す指数 IP=Σ{Δt/exp(−B1lnKF+B2lnT+B3/T−B4)} …
(12) KF=Kf/d Kf=exp〔B5−B6・[C]−B7・[Mn]+B8 (T−273)−B9(T−273)2−ln(KD)+ ln(KK)〕 KD=B10/(B10・Δq/+B11ε2) KK=1+B12・ε Δq=1/2〔C3+C2C3(C1−C3)−1/2・F+ C2(C1−C3)1/2・E〕 μ=arc cos(C3/C1) C1=1/(1−P) C2=1 C3=1−P P=1−e−Δε B1はフェライト変態の潜伏期に及ぼす成分と粒径の効果
の係数 B2はフェライト変態の潜伏期に及ぼす温度の効果の係数 B3はフェライト変態の潜伏期に及ぼす温度の効果の係数 B4はフェライト変態の潜伏期の統計的修正定数 B5はフェライト変態の進行速度の統計的修正定数 B6はフェライト変態の進行速度に及ぼすCの効果を表す
係数 B7はフェライト変態の進行速度に及ぼすMnの効果を表す
係数 B8はフェライト変態の進行速度に及ぼす温度の効果を表
す係数 B9はフェライト変態の進行速度に及ぼす温度の効果を表
す係数 B10はフェライトの核生成サイトとしてのオーステナイ
ト粒界の偏平化の効果を表す係数 B11はフェライトの核生成サイトとしてのオーステナイ
ト粒内の変形帯の導入の効果を表す係数 B12はフェライトの核生成速度に及ぼす歪の効果を表す
係数 を手段とする。 T is the rolling temperature (K) R is the gas constant A 1 is the statistical correction coefficient of the dynamic recrystallization critical strain Q 1 is the energy representing the effect of temperature on the dynamic recrystallization critical strain a is the dynamic recrystallization critical strain Index showing the effect of initial particle size on the particle size m = A 2 · exp (Q 2 / T) ε S = A 3 · [1-exp (−d 0 / K)] K = A 4 · b · exp (−Q 3 / T) A 2 is dynamic The statistical correction factor Q 2 of the index m representing the effect of the additional strain on the recrystallization space factor is the energy A 3 representing the effect of the temperature on the index m representing the effect of the additional strain on the dynamic recrystallization space factor. statistical correction factor Q 3 are dynamic recrystallization completion strain of K statistical correction factor a 4 dynamic recrystallization ends strain epsilon S is representative of the influence of strain rate and temperature on the dynamic recrystallization ends strain epsilon S The energy b representing the effect of temperature on ε S is an index d D = A 5 · Z C , Z = exp (Q / RT) representing the effect of the strain rate on the dynamic recrystallization termination strain ε S. a 5 represents statistical correction factor c of the dynamic recrystallization grain size on the dynamic recrystallized grain size Zener's-Hollomon Paramete
The index Q representing the effect of r is the activation energy of dynamic recrystallization f S = (1−f D ) · (1−exp {− (t / T S ) S })
(4) t is the time between passes or the time until the start of cooling after rolling (se
c) S is an index representing the effect of time on the static recrystallization space factor T S is a function representing the effect of strain and temperature on the static recrystallization space factor d 0 is the grain size before rolling A 6 is a statistical correction coefficient of the static recrystallized grain size d is an index representing the effect of the initial grain size on the static recrystallized grain size e is the strain on the static recrystallized grain size index represents the impact f N = 1-f D -f S ... (6) d N = d 0 · exp (-ε / 4) ... (7) A 7 is a statistical correction factor for dynamic recrystallized grain growth Q 4 is energy representing the effect of temperature on dynamic recrystallized grain growth f is an index representing the effect of time on dynamic recrystallized grain growth A 8 is exponential statistical correction factor Q 5 static recrystallization grain growth energy g representing the effect of temperature on the static recrystallization grain growth which represents the effect of time on the static recrystallization grain growth Δε = (f D · ε C + f N · ε) · exp (- {t / T k} h) ...
(11) T k is a function representing the effect of temperature on the residual strain h is an index representing the effect of time on the residual strain IP = {Δt / exp (−B 1 lnKF + B 2 lnT + B 3 / T−B 4 )} …
(12) KF = Kf / d Kf = exp [B 5 -B 6 · [C] -B 7 · [Mn] + B 8 (T-273) -B 9 (T-273) 2 -ln (KD) + ln (KK)] KD = B 10 / (B 10 · Δq / + B 11 ε 2) KK = 1 + B 12 · ε Δq = 1/2 [C 3 + C 2 C 3 ( C 1 -C 3) -1/2・ F + C 2 (C 1 −C 3 ) 1/2・ E] μ = arc cos (C 3 / C 1 ) C 1 = 1 / (1-P) C 2 = 1 C 3 = 1-P P = 1-e -Δε B 1 is the component and grain size that affect the incubation period of ferrite transformation. Coefficient of diameter effect B 2 is coefficient of temperature effect on incubation period of ferrite transformation B 3 is coefficient of temperature effect on incubation period of ferrite transformation B 4 is statistical modification constant of incubation period of ferrite transformation B 5 is ferrite transformation B 6 is a coefficient representing the effect of C on the progress of ferrite transformation B 7 is a coefficient representing the effect of Mn on the progress of ferrite transformation B 8 is a coefficient representing the effect of Mn on the progress of ferrite transformation factor B 11 coefficients B 9 representing the effect of the temperature coefficient B 10 indicating the effect of temperature on the rate of progression of ferrite transformation is representative of the effect of flattening the austenite grain boundaries as a nucleation site for ferrite nucleation of ferrite Austeni as a site Coefficients representing the effects of the introduction of deformation zones in the grains B 12 is a means a coefficient indicating the effect of the distortion on the nucleation rate of the ferrite.
εCは、(1)式でT,d0を変えた実験をあらかじめ行
い、A1,Q1,aを最小2乗法で決定することにより求め
る。その他実験で決定する各種記号の値も、同様に種々
の実験をあらかじめ行い、各種係数を最小2乗法で決定
した式を求めておき、その式を使って求める。又、平均
γ粒径、残留歪及び潜伏期の消費率の計算は第6図に示
すフロー図に従って進めるものとする。ε C is obtained by conducting an experiment in which T and d 0 are changed in the equation (1) in advance, and determining A 1 , Q 1 and a by the least square method. In addition, the values of various symbols determined by experiments are also obtained in advance by performing various experiments in advance, obtaining equations in which various coefficients are determined by the least squares method, and using the equations. The calculation of the average γ particle size, the residual strain, and the consumption rate during the incubation period shall proceed in accordance with the flowchart shown in FIG.
上記の本発明の手段により、Ar3を予測するので、熱
間圧延全領域でこのAr3の予測精度が向上し、熱間圧延
の全影響因子の制御を最適化し、熱間圧延の省エネルギ
ー、鋼材材質の安定化を一層進める。By means of the above-mentioned means of the present invention, since Ar 3 is predicted, the prediction accuracy of this Ar 3 is improved in the entire hot rolling region, the control of all the influence factors of hot rolling is optimized, energy saving of hot rolling, Further promote the stabilization of steel materials.
熱延鋼板を製造するに当り、鋼材の材質を劣化させる
ことなく圧延するためには、仕上げ圧延を変態点(A
r3)以上で行う必要がある。しかし、Ar3は圧延条件と
冷却条件に依存するため厳密には、オーステナイトの再
結晶モデルとフェライトの変態モデルを連成して予測す
る必要があり、本発明はそれを可能にするものである。
本発明においてオーステナイトの再結晶モデルは(1)
(2)(3)(4)(5)(6)(7)(8)(9)
(10)(11)式であり、第6図に示したように、熱延条
件を基に動的再結晶、静的再結晶、未再結晶それぞれの
占積率と粒径を求め、動的再結晶と静的再結晶について
は粒成長後の粒径を求めた上で全体の平均粒径及び残留
歪を求める。このとき、動的再結晶に関しては加えられ
た歪εが、動的再結晶の臨界歪εCより大きい場合に生
じると判定する。平均粒径大び残留歪の変化を時々刻々
求めるため、次の圧延パスまでの間をΔtで細分化して
Δt毎に以上の計算を行い、次の圧延パスに達した時点
で平均粒径及び残粒歪を次の圧延パスでの初期条件と
し、この残留歪と新たにこの圧延パスで加えられる歪と
の合計の歪を実効歪として上記と計算を繰り返す。ま
た、フェライトの変態モデルは(12)式であり、この式
により潜伏期の消費率を求めることができる。(12)式
からわかるように平均γ粒径d((10)式と残留歪Δε
((11)式)に強く依存しており、上記オーステナイト
再結晶モデルからこれらを求めることができる。よっ
て、この2因子によって両モデルは連成させることがで
きる。実際には、第6図に示すようにΔt毎にオーステ
ナイト再結晶モデルにより平均γ粒径と残留歪を求めた
後、(12)式を用いてΔt間にこの条件での潜伏期のう
ちのどれだけを消費したかを求める。この潜伏期の消費
率をΔt毎に求めておき、その総合計が1以上になると
フェライト変態が開始することを意味しているので、そ
の時点での温度を変態点Ar3とする。In order to roll a hot-rolled steel sheet without deteriorating the quality of the steel material, finish rolling must be performed at the transformation point (A
r 3 ) It is necessary to do above. However, since Ar 3 depends on rolling conditions and cooling conditions, strictly speaking, it is necessary to couple and predict an austenite recrystallization model and a ferrite transformation model, and the present invention makes it possible. .
In the present invention, the recrystallization model of austenite is (1)
(2) (3) (4) (5) (6) (7) (8) (9)
(10) Equation (11) is used. As shown in FIG. 6, the space factor and particle size of each of the dynamic recrystallization, static recrystallization, and non-recrystallization are obtained based on the hot rolling conditions, and For the recrystallization and the static recrystallization, the average particle size and the residual strain of the whole are obtained after the particle size after the grain growth is obtained. At this time, it is determined that dynamic recrystallization occurs when the applied strain ε is larger than the critical strain ε C of dynamic recrystallization. In order to obtain the change in the average grain size and the residual strain every moment, the interval up to the next rolling pass is subdivided by Δt, and the above calculation is performed for each Δt. When the next rolling pass is reached, the average grain size and The above calculation is repeated with the residual strain set as the initial condition in the next rolling pass, and the total strain of the residual strain and the strain newly added in this rolling pass as the effective strain. Further, the transformation model of ferrite is equation (12), and the consumption rate during the incubation period can be obtained from this equation. As can be seen from the equation (12), the average γ particle size d (the equation (10) and the residual strain Δε)
(Equation (11)), which can be determined from the austenite recrystallization model. Therefore, both models can be coupled by these two factors. Actually, as shown in FIG. 6, after obtaining the average γ grain size and the residual strain by the austenite recrystallization model for each Δt, using equation (12), any one of the incubation periods under this condition between Δt is determined. Just ask what you consumed. The consumption rate in the incubation period is determined for each Δt, and it means that ferrite transformation starts when the total sum becomes 1 or more. Therefore, the temperature at that time is defined as a transformation point Ar 3 .
このようにして両モデルを連成させて仕上げ圧延の例
えば7パス中の温度履歴(実測や計算などで求める)に
そって変態点を予測する。仕上げ最終パス以前に変態が
開始する場合には、変態したフェライトを加工すること
になり、材質は劣化する。In this way, the two models are coupled to predict the transformation point along the temperature history (determined by actual measurement, calculation, or the like) during, for example, seven passes of the finish rolling. If the transformation starts before the final finishing pass, the transformed ferrite will be processed and the material will deteriorate.
よって、各種シミュレーションを行い、仕上げ最終パ
ス以降に変態が開始するような圧延条件を求め、実際に
圧延条件として指定することにより材質劣化のない良好
な材質を有する鋼材を製造することができる。Therefore, various simulations are performed to determine the rolling conditions under which the transformation starts after the final finishing pass, and by actually specifying the rolling conditions, it is possible to manufacture a steel material having a good material without any material deterioration.
ここで、材質とは具体的には伸びやr値であり、実際
の圧延においては仕上げ最終パス以前に変態が開始しな
いような圧延条件がとれるように、仕上げ圧延入側の温
度を設定する。ただし、鋼板の端部においては温度低下
が大きくそのような圧延条件がとれない場合があるの
で、加熱装置を用いて加熱する。Here, the material is specifically elongation or r-value, and the temperature on the entry side of the finish rolling is set so that in actual rolling, rolling conditions are set so that transformation does not start before the final finishing pass. However, since the temperature of the end of the steel sheet is so large that such rolling conditions cannot be obtained in some cases, the steel sheet is heated using a heating device.
(実施例) 表3には各成分系について従来法及び比較例(特願昭
59−39983号)及び本発明法により予測したAr3変態点と
その時に観察される組織の形態について示した。実験に
は2パス加工テストにより行い、2パス加工後は700℃
まで30℃/秒で冷却した後に水焼き入れした。(Examples) Table 3 shows a conventional method and a comparative example (Japanese Patent Application No.
59-39983) and the Ar 3 transformation point predicted by the method of the present invention and the morphology observed at that time. The experiment was performed by a two-pass processing test, and after the two-pass processing, 700 ° C
After cooling at a rate of 30 ° C./sec, water quenching was performed.
本発明法は従来法に比べて実際の組織状態をよく予測
できることがわかる。また、特願昭59−39983号(比較
法)では初期粒径が細粒で歪が小さい時の予測が十分で
なく、本発明法によりさらに精度よく予測可能となって
いることがわかる。例えば、No.10において従来法と比
較法ではAr3が第2パスの加工温度より低くなり、変形
フェライトは生じないと予測されるのに対し、本発明法
ではAr3が第2パスの加工温度より高くなり、変形フェ
ライトが生じると予測され、実際の組織では変形フェラ
イトが生じており、本発明法の予測が正しい。この場
合、変形フェライトを生じさせないためには加工温度を
上げる必要がある。それを示したのがNo.11であり、No.
10に対して加工温度を10℃上げることにより、本発明法
では変形フェライトが生じなくなることが予測され、実
際の組織もそうなっている。よって、本発明法を用いる
ことにより変形フェライトを生じさせないための温度履
歴を精度良く求めることが可能である。It can be seen that the method of the present invention can predict the actual tissue state better than the conventional method. Further, in Japanese Patent Application No. 59-39983 (comparison method), it is found that the prediction when the initial particle size is fine and the strain is small is not sufficient, and the prediction according to the present invention enables more accurate prediction. For example, the Ar 3 is lower than the processing temperature of the second pass is the conventional method and comparison method in No.10, whereas the predicted deformation ferrite does not occur, the processing is Ar 3 of the second pass in the present invention method It is predicted that the temperature will be higher than the temperature, and deformed ferrite is generated. In the actual structure, deformed ferrite is generated, and the prediction of the present invention is correct. In this case, it is necessary to raise the processing temperature in order not to generate deformed ferrite. No. 11 showed that, and No. 11
By raising the processing temperature by 10 ° C. with respect to 10, it is predicted that deformed ferrite will not be generated in the method of the present invention, and the actual structure is also the same. Therefore, by using the method of the present invention, it is possible to accurately obtain a temperature history for preventing generation of deformed ferrite.
次に、C−Mn鋼について本発明者らによって得られた
各係数を示す。Next, each coefficient obtained by the present inventors for the C-Mn steel is shown.
A1=1.43×10-5 Q1=18800 a=0.22 A2=0.026 A3=2.25 A4=472 Q2=4600 Q3=2960 b=−0.0723 Q=72600−52200×Ceq(Ceq=C+Mn/6) A5=0.1204×Q−5254 c=−0.155 S=1/3 TS=9.11×10-15・ε−2.36・exp(67670/RT) A6=9.71 d=0.25 e=−0.5 A7=3900×Ceq−1.43 A8=3.68×108×Ceq−1.43 Q4=5380 Q5=20000 f=0.3 g=0.24 Tk=8.46×10-9・(43800/RT) h=2/3 B1=−1.6454 B2=20 B3=3.265×104 B4=173.89 B5=4.7766 B6=13.339 B7=1.1922 B8=0.02505 B9=3.5067×10-5 B10=2.24 (発明の効果) 以上説明した本発明は、従来の成分のみによるAr3予
測に対し、加工による効果を取り込んだ先願特願昭59−
39983号の方法を改善し、加工後の組織変化も取り込む
ことにより、精度のよいAr3の予測を可能にした。この
方法を用い、鋼材温度を熱間加工全領域に渡りAr3以上
に維持し加工するための製造条件の調節が精度よく行な
われる。A 1 = 1.43 × 10 −5 Q 1 = 18800 a = 0.22 A 2 = 0.026 A 3 = 2.25 A 4 = 472 Q 2 = 4600 Q 3 = 2960 b = −0.0723 Q = 72600−52200 × Ceq (Ceq = C + Mn / 6) A 5 = 0.1204 x Q-5254 c = -0.155 S = 1/3 T S = 9.11 x 10 -15 · ε- 2.36 · exp (67670 / RT) A 6 = 9.71 d = 0.25 e = -0.5 A 7 = 3900 × Ceq -1.43 A 8 = 3.68 × 10 8 × Ceq -1.43 Q 4 = 5380 Q 5 = 20000 f = 0.3 g = 0.24 Tk = 8.46 × 10 -9 · (43800 / RT) h = 2 / 3 B 1 = -1.6454 B 2 = 20 B 3 = 3.265 x 10 4 B 4 = 173.89 B 5 = 4.7766 B 6 = 13.339 B 7 = 1.1922 B 8 = 0.02505 B 9 = 3.5067 x 10 -5 B 10 = 2.24 (Effects of the Invention) The present invention described above incorporates the effects of processing into Ar 3 predictions based on only the conventional components, and incorporates the effects of prior processing in Japanese Patent Application No. 59-59.
By improving the method of 39983 and incorporating the structural change after processing, accurate prediction of Ar 3 was made possible. Using this method, the production conditions for working while maintaining the steel material temperature at Ar 3 or higher over the entire hot working area are precisely adjusted.
また、各成分、各圧延条件に従ってAr3を予測できる
ので、圧延条件が新しい領域に広がった場合にも、又成
分が変化した時にも圧延条件の最適化が可能となり、大
きな安全代が必要でなくなり、鋼材の材質の安定化が進
む。従って、本発明が熱間圧延の分野においてもたらす
効果は大きい。In addition, since Ar 3 can be predicted according to each component and each rolling condition, the rolling condition can be optimized even when the rolling condition spreads to a new region or when the component changes, and a large safety margin is required. And the stabilization of the steel material proceeds. Therefore, the present invention has a great effect in the field of hot rolling.
第1図は現場試作材の強度−延性バランスに及ぼす加工
組織の影響の図表、第2図は現場試作材の穴拡げ比に及
ぼす加工組織の影響の図表、第3図はAr3の歪による上
昇の図表、第4図はSi−Mn鋼の歪によるAr3の上昇の図
表、第5図はNb鋼の歪によるAr3の上昇の図表、第6図
は平均γ粒径、残留歪及び潜伏期の消費率の計算のフロ
ー図を示す。Strength of the first figure-site test materials - Chart of the effects of processing tissue on ductility balance, the table of FIG. 2 Effect of processed structure on the hole expansion ratio of the field test materials, according to FIG. 3 is a distortion of Ar 3 FIG. 4 is a chart of the rise of Ar 3 due to the strain of the Si-Mn steel, FIG. 5 is a chart of the rise of Ar 3 due to the strain of the Nb steel, and FIG. FIG. 4 shows a flow chart of calculating the consumption rate during the incubation period.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 河野 治 大分市大字西ノ洲1番地 新日本製鐵株 式会社大分製鐵所内 (72)発明者 江坂 一彬 大分市大字西ノ洲1番地 新日本製鐵株 式会社大分製鐵所内 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Osamu Kono Oita-shi, Nishi-no-Su, 1 Nippon Steel Corporation Inside Oita Works (72) Inventor Kazuaki Esaka 1, Oita-shi, Oita Nishi-no-Su, 1 Nippon Steel Corporation Oita Works
Claims (2)
る際に、予め定めた関係式にもとづいて、 各パスにおいて加えられる歪εが、動的再結晶がおこ
る限界歪εCより大きい場合は、動的再結晶、静的再結
晶、未再結晶の3グループに分かれ、歪εがεC以下の
場合は、静的再結晶、未再結晶の2グループに分かれる
として、動的再結晶、静的再結晶、未再結晶のそれぞれ
の粒径dD,dS,dN及び占積率fD,fS,fNを求め、 次パスまでの時間を短い時間Δtに細分化し、Δtの
間での静的再結晶占積率fSの増加を求めた後、動的再結
晶粒の粒成長後の粒径及び静的再結晶粒の粒成長後の粒
径を求めてΔt経過後の平均粒径dを求め、動的再結晶
粒の残留歪と未再結晶の残留歪の合計の熱的な回復を求
めることによりΔt経過後の平均残留歪Δεを求め、 この平均粒径、平均残留歪状態での潜伏期の消費率を
計算し、 次のΔtに対し〜を次パスまでくり返し、 次パス直前の平均粒径と平均残留歪とを次パスの初期
条件として次パスの歪をこの平均残留歪に加えた歪を実
効歪とし、 〜の工程を熱間加工パス回数だけくり返し、 各Δtでの潜伏期の消費率が1になるか否かを判定
し、最終パス加工以前に潜伏期の消費率が1を越す場合
にはこの時の温度を変態点Ar3と予測し、 〜をくり返し、鋼材温度を熱間加工の全領域で変
態点Ar3以上に維持するように全体の加工温度を調節し
加工すること を特徴とする熱延鋼材の製造方法。When a C-Mn-based steel material is hot-worked to adjust the material, the strain ε applied in each pass is determined by a predetermined relational expression to be a critical strain ε at which dynamic recrystallization occurs. as if C is greater than the dynamic recrystallization, static recrystallization, divided into three groups of non-recrystallized, if the strain epsilon is less epsilon C, divided into two groups of static recrystallization, non-recrystallized, The respective particle diameters d D , d S , d N and space factors f D , f S , f N of the dynamic recrystallization, static recrystallization, and non-recrystallization are obtained, and the time until the next pass is shortened by Δt particle size after subdivided, after obtaining the increase in static recrystallization space factor f S between Delta] t, the grain growth of dynamic re-particle diameter of the crystal grains of the grain after the growth and the static recrystallization grains To obtain an average particle diameter d after elapse of Δt, and to obtain a thermal recovery of a sum of residual strain of dynamic recrystallized grains and residual strain of non-recrystallized to obtain an average residual strain Δε after elapse of Δt. The average particle diameter and the consumption rate during the incubation period in the state of the average residual strain are calculated. The following is repeated for the next Δt until the next pass, and the average particle diameter and the average residual strain immediately before the next pass are determined by the initial conditions of the next pass. The strain obtained by adding the strain of the next pass to the average residual strain is defined as the effective strain, and the steps of are repeated by the number of hot working passes, and it is determined whether or not the consumption rate of the incubation period at each Δt becomes 1. If the consumption rate in the incubation period exceeds 1 before the final pass machining, the temperature at this time is predicted as the transformation point Ar 3, and the process is repeated to maintain the steel material temperature at the transformation point Ar 3 or more in the entire hot working region. A method for manufacturing a hot-rolled steel material, wherein the entire processing temperature is adjusted so as to perform processing.
る際に、動的再結晶限界歪εCについては(1)式、動
的再結晶占積率fDについては(2)式、及び粒径dDにつ
いては(3)式、動的再結晶占積率fSについては(4)
式、及び粒径dSについては(5)式、また未再結晶占積
率fNについては(6)式、及び粒径dNについては(7)
式、また動的再結晶粒の粒成長後の粒径▲d2 DG▼、静
的再結晶粒の粒成長後の粒径に▲d2 SG▼については
(8)(9)式、及びこれらの平均粒径については
(10)式、残留歪の熱的な回復後の平均残留歪Δεにつ
いては(11)式を用い、パス間及び熱間加工終了後冷却
開始までの時間を細分化した時間Δtでの潜伏期の消費
率については(12)式を用いて、鋼材温度を熱間加工の
全領域でAr3以上に維持し加工することを特徴とする特
許請求の範囲第1項に記載の熱延鋼材の製造方法。 Tは圧延温度(K) Rは気体定数 A1は動的再結晶限界歪の統計的修正係数 Q1は動的再結晶限界歪に及ぼす温度の影響を表すエネル
ギー aは動的再結晶限界歪に及ぼす初期粒径の影響を表す指
数 m=A2・exp(Q2/T) εS=A3・〔1−exp(−d0/K)〕 K=A4・b・exp(−Q3/T) A2は動的再結晶占積率に及ぼす付加歪の影響を表す指数
mの統計的修正係数 Q2は動的再結晶占積率に及ぼす付加歪の影響を表す指数
mに及ぼす温度の影響を表すエネルギー A3は動的再結晶終了歪εSの統計的修正係数 A4は動的再結晶終了歪εSに及ぼす歪速度と温度の影響
を表すKの統計的修正係数 Q3は動的再結晶終了歪εSに及ぼす温度の影響を表すエ
ネルギー bは動的再結晶終了歪εSに及ぼす歪速度の影響を表す
指数 dD=A5・ZC,Z=exp(Q/RT) …(3) A5は動的再結晶粒径の統計的修正係数 cは動的再結晶粒径に及ぼすZener−Hollomon paramete
rの影響を表す指数 Qは動的再結晶の活性化エネルギー fS=(1−fD)・(1−exp{−(t/TS)S}) …
(4) tはパス間時間あるいは圧延後冷却開始までの時間(se
c) Sは静的再結晶占積率に及ぼす時間の影響を表す指数 TSは静的再結晶占積率に及ぼす歪と温度の影響を表す関
数 d0は圧延前粒径 A6は静的再結晶粒径の統計的修正係数 dは静的再結晶粒径に及ぼす初期粒径の影響を表す指数 eは静的再結晶粒径に及ぼす歪の影響を表す指数 fN=1−fD−fS …(6) dN=d0・exp(−ε/4) …(7) A7は動的再結晶粒成長の統計的修正係数 Q4は動的再結晶粒成長に及ぼす温度の影響を表すエネル
ギー fは動的再結晶粒成長に及ぼす時間の影響を表す指数 A8は静的再結晶粒成長の統計的修正係数 Q5は静的再結晶粒成長に及ぼす温度の影響を表すエネル
ギー gは静的再結晶粒成長に及ぼす時間の影響を表す指数 Δε=(fD・εC+fN・ε)・exp(−{t/Tk}h) …
(11) Tkは残留歪に及ぼす温度の影響を表す関数 hは残留歪に及ぼす時間の影響を表す指数 IP=Σ{Δt/exp(−B1lnKF+B2lnT+B3/T−B4)} …
(12) KF=Kf/ Kf=exp〔B5−B6・[C]−B7・[Mn]+B8 (T−273)−B9(T−273)2−ln(KD)+ ln(KK)〕 KD=B10/(B10・Δq/+B11ε2) KK=1+B12・ε μ=arc cos(C3/C1) C1=1/(1−P) C2=1 C3=1−P P=1−e−Δε B1はフェライト変態の潜伏期に及ぼす成分と粒径の効果
の係数 B2はフェライト変態の潜伏期に及ぼす温度の効果の係数 B3はフェライト変態の潜伏期に及ぼす温度の効果の係数 B4はフェライト変態の潜伏期の統計的修正定数 B5はフェライト変態の進行速度の統計的修正定数 B6はフェライト変態の進行速度に及ぼすCの効果を表す
係数 B7はフェライト変態の進行速度に及ぼすMnの効果を表す
係数 B8はフェライト変態の進行速度に及ぼす温度の効果を表
す係数 B9はフェライト変態の進行速度に及ぼす温度の効果を表
す係数 B10はフェライトの核生成サイトとしてのオーステナイ
ト粒界の偏平化の効果を表す係数 B11はフェライトの核生成サイトとしてのオーステナイ
ト粒内の変形帯の導入の効果を表す係数 B12はフェライトの核生成速度に及ぼす歪の効果を表す
係数2. When hot working a C-Mn-based steel material to adjust the material, formula (1) is used for the dynamic recrystallization limit strain ε C and ( D ) is used for the dynamic recrystallization space factor f D. Equation (2) and equation (3) for the particle size d D , and equation (4) for the dynamic recrystallization space factor f S
Equation (5) for the equation and particle size d S , Equation (6) for the unrecrystallized space factor f N , and equation (7) for the particle size d N
Equations (8) and (9) are used to calculate the particle size of the dynamically recrystallized grains after the grain growth {d 2 DG ▼} and the grain size of the statically recrystallized grains after the grain growth {d 2 SG }. The formula (10) is used for these average particle diameters, and the formula (11) is used for the average residual strain Δε after thermal recovery of residual strain, and the time from pass to completion of hot working after completion of hot working is subdivided. The consumption rate of the incubation period at the determined time Δt is obtained by using equation (12) to maintain the temperature of the steel material at Ar 3 or higher in the entire region of hot working. The method for producing a hot-rolled steel material according to the above. T is the rolling temperature (K) R is the gas constant A 1 is the statistical correction coefficient of the dynamic recrystallization critical strain Q 1 is the energy representing the effect of temperature on the dynamic recrystallization critical strain a is the dynamic recrystallization critical strain Index showing the effect of initial particle size on the particle size m = A 2 · exp (Q 2 / T) ε S = A 3 · [1-exp (−d 0 / K)] K = A 4 · b · exp (−Q 3 / T) A 2 is dynamic The statistical correction factor Q 2 of the index m representing the effect of the additional strain on the recrystallization space factor is the energy A 3 representing the effect of the temperature on the index m representing the effect of the additional strain on the dynamic recrystallization space factor. statistical correction factor Q 3 are dynamic recrystallization completion strain of K statistical correction factor a 4 dynamic recrystallization ends strain epsilon S is representative of the influence of strain rate and temperature on the dynamic recrystallization ends strain epsilon S The energy b representing the effect of temperature on ε S is an index d D = A 5 · Z C , Z = exp (Q / RT) representing the effect of the strain rate on the dynamic recrystallization termination strain ε S. a 5 represents statistical correction factor c of the dynamic recrystallization grain size on the dynamic recrystallized grain size Zener's-Hollomon Paramete
The index Q representing the effect of r is the activation energy of dynamic recrystallization f S = (1−f D ) · (1−exp {− (t / T S ) S })
(4) t is the time between passes or the time until the start of cooling after rolling (se
c) S is an index representing the effect of time on the static recrystallization space factor T S is a function representing the effect of strain and temperature on the static recrystallization space factor d 0 is the grain size before rolling A 6 is a statistical correction coefficient of the static recrystallized grain size d is an index representing the effect of the initial grain size on the static recrystallized grain size e is the strain on the static recrystallized grain size index represents the impact f N = 1-f D -f S ... (6) d N = d 0 · exp (-ε / 4) ... (7) A 7 is a statistical correction factor for dynamic recrystallized grain growth Q 4 is energy representing the effect of temperature on dynamic recrystallized grain growth f is an index representing the effect of time on dynamic recrystallized grain growth A 8 is exponential statistical correction factor Q 5 static recrystallization grain growth energy g representing the effect of temperature on the static recrystallization grain growth which represents the effect of time on the static recrystallization grain growth Δε = (f D · ε C + f N · ε) · exp (- {t / T k} h) ...
(11) T k is a function representing the effect of temperature on the residual strain h is an index representing the effect of time on the residual strain IP = {Δt / exp (−B 1 lnKF + B 2 lnT + B 3 / T−B 4 )} …
(12) KF = Kf / Kf = exp [B 5 -B 6 · [C] -B 7 · [Mn] + B 8 (T-273) -B 9 (T-273) 2 -ln (KD) + ln (KK)] KD = B 10 / (B 10 · Δq / + B 11 ε 2) KK = 1 + B 12 · ε μ = arc cos (C 3 / C 1 ) C 1 = 1 / (1-P) C 2 = 1 C 3 = 1-P P = 1-e -Δε B 1 is the component and grain size that affect the incubation period of ferrite transformation. Coefficient of diameter effect B 2 is coefficient of temperature effect on incubation period of ferrite transformation B 3 is coefficient of temperature effect on incubation period of ferrite transformation B 4 is statistical modification constant of incubation period of ferrite transformation B 5 is ferrite transformation B 6 is a coefficient representing the effect of C on the progress of ferrite transformation B 7 is a coefficient representing the effect of Mn on the progress of ferrite transformation B 8 is a coefficient representing the effect of Mn on the progress of ferrite transformation factor B 11 coefficients B 9 representing the effect of the temperature coefficient B 10 indicating the effect of temperature on the rate of progression of ferrite transformation is representative of the effect of flattening the austenite grain boundaries as a nucleation site for ferrite nucleation of ferrite Austeni as a site Factor Factor B 12 representing the effect of the introduction of deformation zones in the grains representing the effect of the distortion on the nucleation rate of the ferrite
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14394985A JP2597980B2 (en) | 1985-07-02 | 1985-07-02 | Manufacturing method of hot rolled steel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14394985A JP2597980B2 (en) | 1985-07-02 | 1985-07-02 | Manufacturing method of hot rolled steel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS624822A JPS624822A (en) | 1987-01-10 |
| JP2597980B2 true JP2597980B2 (en) | 1997-04-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14394985A Expired - Lifetime JP2597980B2 (en) | 1985-07-02 | 1985-07-02 | Manufacturing method of hot rolled steel |
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| Country | Link |
|---|---|
| JP (1) | JP2597980B2 (en) |
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1985
- 1985-07-02 JP JP14394985A patent/JP2597980B2/en not_active Expired - Lifetime
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| Publication number | Publication date |
|---|---|
| JPS624822A (en) | 1987-01-10 |
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