Deprecated: The each() function is deprecated. This message will be suppressed on further calls in /home/zhenxiangba/zhenxiangba.com/public_html/phproxy-improved-master/index.php on line 456
JP2697553B2 - Titanium carbonitride cermet cutting tool with excellent toughness - Google Patents
[go: Go Back, main page]

JP2697553B2 - Titanium carbonitride cermet cutting tool with excellent toughness - Google Patents

Titanium carbonitride cermet cutting tool with excellent toughness

Info

Publication number
JP2697553B2
JP2697553B2 JP5110979A JP11097993A JP2697553B2 JP 2697553 B2 JP2697553 B2 JP 2697553B2 JP 5110979 A JP5110979 A JP 5110979A JP 11097993 A JP11097993 A JP 11097993A JP 2697553 B2 JP2697553 B2 JP 2697553B2
Authority
JP
Japan
Prior art keywords
cutting
phase
cutting tool
phase structure
ticn
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP5110979A
Other languages
Japanese (ja)
Other versions
JPH06299281A (en
Inventor
清弘 照内
勝彦 矢野
二郎 小谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP5110979A priority Critical patent/JP2697553B2/en
Publication of JPH06299281A publication Critical patent/JPH06299281A/en
Application granted granted Critical
Publication of JP2697553B2 publication Critical patent/JP2697553B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Landscapes

  • Cutting Tools, Boring Holders, And Turrets (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】この発明は、すぐれた靭性を有
し、かつ耐摩耗性にもすぐれているので、例えば鋼の連
続切削は勿論のこと、特に断続切削に用いた場合に、切
刃に欠損やチッピング(微小欠け)などの発生なく、す
ぐれた切削性能を長期に亘って発揮する炭窒化チタン
(以下、TiCNで示す)系サーメット製切削工具に関
すものである。
BACKGROUND OF THE INVENTION The present invention has excellent toughness and excellent wear resistance, so that it can be used not only in continuous cutting of steel but also in intermittent cutting. The present invention relates to a titanium cermet (hereinafter, referred to as TiCN) cermet-based cutting tool that exhibits excellent cutting performance over a long period of time without occurrence of chipping or chipping (micro chipping).

【0002】[0002]

【従来の技術】従来、一般に、各種技術論文や、例えば
特開昭50−86512公報などに記載されるように、
容量%で(以下、単に%は容量%を意味する)、Coお
よび/またはNiを主成分とする金属結合相:5〜30
%、単一相構造を有するTiCNからなる硬質分散相、
および同じく単一相構造を有し、かつTiと、Ta,N
b,Zr,W、およびMoのうちの1種以上との複合炭
窒化物固溶体[以下、(Ti,M)CNで示す]からな
る硬質分散相:実質的に残り、の組成を有するTiCN
系サーメットで構成された切削工具が知られており、こ
れが例えば鋼などの連続切削に用いられていることも知
られている。
2. Description of the Related Art Conventionally, generally, as described in various technical papers and, for example, Japanese Patent Application Laid-Open No. 50-86512,
By volume% (hereinafter, simply “%” means volume%), a metal binding phase containing Co and / or Ni as a main component: 5 to 30
%, A hard dispersed phase composed of TiCN having a single phase structure,
And also having a single phase structure, and Ti, Ta, N
a hard dispersed phase composed of a complex carbonitride solid solution with one or more of b, Zr, W, and Mo [hereinafter, referred to as (Ti, M) CN]: TiCN substantially having the composition of
A cutting tool composed of a system cermet is known, and it is also known that the cutting tool is used for continuous cutting of, for example, steel.

【0003】[0003]

【発明が解決しようとする課題】一方、近年の切削加工
のFA化はめざましく、かつ省力化に対する要求も強
く、これに伴ない、連続切削および断続切削のいずれに
も実用可能な切削工具が望まれる傾向にあるが、上記の
従来TiCN系サーメット製切削工具においては、連続
切削ではすぐれた耐摩耗性を示すものの、断続切削では
靭性不足が原因で切刃に欠損やチッピングが発生し易
く、短時間で使用寿命に至るのが現状である。
On the other hand, in recent years, the use of FA in cutting has been remarkable, and there has been a strong demand for labor saving. Accordingly, a cutting tool which can be used for both continuous cutting and interrupted cutting is desired. In the conventional TiCN-based cermet cutting tools described above, although continuous cutting shows excellent wear resistance, intermittent cutting tends to cause chipping or chipping due to insufficient toughness, resulting in short cutting. At present, the service life is reached in hours.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者等は、
上述のような観点から、上記の従来TiCN系サーメッ
ト製切削工具に着目し、これの具備するすぐれた耐摩耗
性を損なうことなく、これにすぐれた靭性を付与すべく
研究を行なった結果、上記の従来TiCN系サーメット
製切削工具を構成するTiCN系サーメットに、いずれ
も有芯2重相構造および/または有芯3重相構造を有
し、かつ芯部がTiCNまたは(Ti,M)CNからな
る硬質分散相を5〜40%の割合で含有させると、この
結果のTiCN系サーメットで構成された切削工具は、
すぐれた靭性を具備するようになり、連続切削は勿論の
こと、断続切削においてもすぐれた耐摩耗性を発揮する
ようになるという研究結果を得たのである。
Means for Solving the Problems Accordingly, the present inventors have
From the above-mentioned viewpoint, focusing on the above-mentioned conventional TiCN-based cermet cutting tool, and without impairing the excellent wear resistance of the cutting tool, a study was conducted to impart excellent toughness to the cutting tool. Of the conventional TiCN-based cermet cutting tools, each of which has a cored double-phase structure and / or a cored triple-phase structure, and whose core is made of TiCN or (Ti, M) CN. When the hard disperse phase is contained at a ratio of 5 to 40%, the resulting cutting tool composed of the TiCN-based cermet becomes
Research results have shown that the steel has excellent toughness and exhibits excellent wear resistance not only in continuous cutting but also in interrupted cutting.

【0005】この発明は、上記の研究結果にもとづいて
なされたものであって、Coおよび/またはNiを主成
分とする金属結合相:5〜30%、いずれも有芯2重相
構造および/または有芯3重相構造を有し、かつ芯部が
TiCNまたは(Ti,M)CNからなる硬質分散相:
5〜40%、いずれも単一相構造を有する(Ti,M)
CNとTiCNからなる硬質分散相:実質的に残り、の
組成を有するTiCN系サーメットで構成してなる靭性
および耐摩耗性にすぐれたTiCN系サーメット製切削
工具に特徴を有するものである。
The present invention has been made based on the results of the above-mentioned research, and has a metal binding phase containing Co and / or Ni as a main component: 5 to 30%, each having a cored double phase structure and / or Alternatively, a hard dispersed phase having a cored triple phase structure and having a core portion of TiCN or (Ti, M) CN:
5 to 40%, each having a single phase structure (Ti, M)
Hard dispersed phase composed of CN and TiCN: This is characterized by a cutting tool made of a TiCN-based cermet having substantially the remaining composition and excellent in toughness and abrasion resistance composed of a TiCN-based cermet having the following composition.

【0006】なお、この発明の切削工具において、これ
を構成するTiCN系サーメットの金属結合相の割合を
5〜30%としたのは、その割合が5%未満では、所望
の強度を確保することができず、一方その割合が30%
を越えると耐摩耗性が急激に低下するようになるという
理由によるものであり、またいずれも有芯2重相構造お
よび/または有芯3重相構造を有する硬質分散相の割合
を5〜40%と定めたのは、その割合が5%未満では、
断続切削でも切刃に欠損やチッピングの発生がない所望
のすぐれた靭性を確保することができず、一方その割合
が40%を越えると、耐摩耗性が急激に低下するように
なるという理由にもとづくものである。
In the cutting tool of the present invention, the ratio of the metal binder phase of the TiCN-based cermet constituting the cutting tool is set to 5 to 30%. If the ratio is less than 5%, desired strength is secured. Is not possible, while the ratio is 30%
Is exceeded, the abrasion resistance rapidly decreases, and the ratio of the hard dispersed phase having a cored double phase structure and / or a cored triple phase structure is 5 to 40 in all cases. The percentage is defined as being less than 5%,
Even in intermittent cutting, it is not possible to secure the desired excellent toughness with no chipping or chipping on the cutting edge. On the other hand, if the ratio exceeds 40%, the wear resistance rapidly decreases. It is based on.

【0007】[0007]

【実施例】つぎに、この発明の切削工具を実施例により
具体的に説明する。原料粉末として、いずれも0.5〜
2μmの範囲内の所定の平均粒径を有する(Ti,T
a)CN〔TiCN/TaC=70/30〕粉末、(T
i,Nb)CN〔TiCN/NbC=70/30〕粉
末、(Ti,Zr)CN〔TiCN/ZrC=80/2
0〕粉末、(Ti,W,Ta)CN〔TiCN/WC/
TaC=60/20/20〕粉末、(Ti,Ta,N
b)CN〔TiCN/TaC/NbC=60/20/2
0〕粉末、(W,Mo)C〔WC/Mo2 C=50/5
0〕粉末、(W,Mo,Ta,Nb,Zr)CN〔WC
/Mo2 C/TaCN/NbCN/ZrCN=20/2
0/20/20/20〕粉末、さらにTiCN粉末、N
bCN粉末、WC粉末、NbC粉末、Mo2 C粉末、C
o粉末、およびNi粉末を用意し、これら原料粉末を表
1に示される配合組成に配合し、ボールミルにて72時
間湿式混合し、乾燥した後、1.5ton /cm2 の圧力で
圧粉体にプレス成形し、ついで、この圧粉体を、 (1) 常温から1100℃までの昇温過程を0.05
〜0.1torrの窒素雰囲気とし、1100℃から142
0〜1600℃の範囲内の所定の焼結温度までの昇温過
程、前記焼結温度に1時間の保持過程、および焼結温度
保持終了から常温までの冷却過程を40〜300torrの
窒素雰囲気とした条件(以下、窒素焼結条件という)、 (2) 0.05〜0.1torrの真空中、1420〜1
500℃の範囲内の所定温度に1時間保持後冷却の条件
(以下、真空焼結条件という)、以上(1)または
(2)の条件で焼結することにより、いずれもSNMG
432の規格に即したスローアウェイチップ形状をもっ
た本発明TiCN系サーメット製切削工具(以下、本発
明切削工具という)1〜5および従来TiCN系サーメ
ット製切削工具(以下、従来切削工具という)1,2を
それぞれ製造した。
Next, the cutting tool of the present invention will be described in detail with reference to examples. As raw material powder, all 0.5 ~
It has a predetermined average particle size in the range of 2 μm (Ti, T
a) CN [TiCN / TaC = 70/30] powder, (T
i, Nb) CN [TiCN / NbC = 70/30] powder, (Ti, Zr) CN [TiCN / ZrC = 80/2
0] powder, (Ti, W, Ta) CN [TiCN / WC /
TaC = 60/20/20] powder, (Ti, Ta, N
b) CN [TiCN / TaC / NbC = 60/20/2
0] powder, (W, Mo) C [WC / Mo 2 C = 50/ 5
0] powder, (W, Mo, Ta, Nb, Zr) CN [WC
/ Mo 2 C / TaCN / NbCN / ZrCN = 20/2
0/20/20/20] powder, further TiCN powder, N
bCN powder, WC powder, NbC powder, Mo 2 C powder, C
O powder and Ni powder were prepared, and these raw material powders were blended in the composition shown in Table 1, wet-mixed in a ball mill for 72 hours, dried, and then compacted at a pressure of 1.5 ton / cm 2. Then, the green compact was subjected to (1) a process of raising the temperature from room temperature to 1100 ° C. for 0.05 hour.
~ 0.1 torr nitrogen atmosphere, from 1100 ° C to 142
The process of raising the temperature to a predetermined sintering temperature in the range of 0 to 1600 ° C., the process of maintaining the sintering temperature for 1 hour, and the process of cooling from the end of the sintering temperature maintenance to the normal temperature are performed in a nitrogen atmosphere of 40 to 300 torr. (Hereinafter referred to as nitrogen sintering conditions), (2) in a vacuum of 0.05 to 0.1 torr,
After holding at a predetermined temperature in the range of 500 ° C. for 1 hour and then cooling under the conditions of cooling (hereinafter, referred to as vacuum sintering conditions), and sintering under the above conditions (1) or (2), all of them are SNMG.
Cutting tools made of TiCN-based cermet of the present invention (hereinafter, referred to as cutting tools of the present invention) 1 to 5 and conventional cutting tools of TiCN-based cermet (hereinafter, referred to as conventional cutting tools) 1 having a throw-away insert shape conforming to the standard of 432 , 2 were produced.

【0008】ついで、この結果得られた各種の切削工具
について、これの任意個所を透過型電子顕微鏡により観
察し、画像に現われたそれぞれの硬質分散相の中心部の
全金属成分に占めるTi含有量を測定すると共に、画像
解析装置を併用して、結合相と硬質分散相の割合、さら
に前記硬質分散相における個々の構成相の割合を測定
し、この測定結果をサーメット全体に占める割合で表
2,3に示した。また、上記の各種切削工具について、 被削材:SNCM439(硬さ:HB 270)の丸棒、 切削速度:200m/min.、 切込み:2.5mm、 送り:0.3mm/rev.、 切削時間:5分、 の条件での鋼の連続切削試験、並びに、 被削材:SNCM439(硬さ:HB 270)の長さ方
向等間隔3本縦溝入り丸棒、 切削速度:180m/min.、 切込み:2mm、 送り:0.3mm/rev.、 切削時間:20分、 の条件での鋼の断続切削試験を行ない、いずれの試験で
も切刃の逃げ面摩耗幅を測定した。これらの測定結果を
表4に示した。
Next, with respect to various cutting tools obtained as a result, an arbitrary portion of the cutting tools was observed with a transmission electron microscope, and the Ti content in the total metal component at the center of each hard dispersed phase appeared in the image. And the ratio of the binder phase and the hard dispersed phase, and also the ratio of the individual constituent phases in the hard dispersed phase, were measured using an image analyzer together. , 3. Further, the above-mentioned various cutting tools, work material: SNCM439 (Hardness: H B 270) round bar, Cutting speed: 200m / min. , Cut: 2.5 mm, Feed:. 0.3 mm / rev, Cutting time: continuous cutting test of steel in 5 minutes, conditions as well as work material: SNCM439 (Hardness: H B 270) the length of the Round bar with 3 longitudinal grooves at equal intervals in the direction, Cutting speed: 180m / min. An intermittent cutting test of steel was performed under the following conditions: cutting depth: 2 mm, feed: 0.3 mm / rev., Cutting time: 20 minutes. In each test, the flank wear width of the cutting edge was measured. Table 4 shows the results of these measurements.

【0009】[0009]

【表1】 [Table 1]

【0010】[0010]

【表2】 [Table 2]

【0011】[0011]

【表3】 [Table 3]

【0012】[0012]

【表4】 [Table 4]

【0013】[0013]

【発明の効果】表2〜4に示される結果から、本発明切
削工具1〜5は、いずれもこれを構成するTiCN系サ
ーメットが含有する有芯2重相構造および/または有芯
3重相構造を有し、かつ芯部がTiCNまたは(Ti,
M)CNからなる硬質分散相によって、耐摩耗性の低下
なく、すぐれた靭性を具備するようになり、連続切削お
よび断続切削のいずれでもすぐれた切削性能を発揮する
のに対して、硬質分散相として単一相構造のTiCNお
よび(Ti,M)CNしか含有しない従来切削工具1,
2においては、連続切削ではすぐれた耐摩耗性を示すも
のの断続切削では靭性不足が原因で切刃にチッピングが
発生し、比較的短時間で使用寿命に至ることが明らかで
ある。上述のように、この発明のTiCN系サーメット
製切削工具は、連続切削は勿論のこと、高靭性が要求さ
れる断続切削でも著しく長期に亘ってすぐれた切削性能
を発揮するので、切削加工のFA化および省力化に十分
満足に対応することができるものである。
From the results shown in Tables 2 to 4, all of the cutting tools 1 to 5 of the present invention have a cored double phase structure and / or a cored triple phase contained in the TiCN-based cermet constituting the cutting tools. It has a structure and the core is TiCN or (Ti,
M) The hard dispersed phase composed of CN provides excellent toughness without deterioration of wear resistance, and exhibits excellent cutting performance in both continuous cutting and interrupted cutting. Conventional cutting tool 1 containing only TiCN and (Ti, M) CN having a single phase structure as
In No. 2, it is apparent that chipping occurs in the cutting edge due to insufficient toughness in intermittent cutting, but shows a long service life in intermittent cutting, although excellent wear resistance is exhibited in continuous cutting. As described above, the TiCN-based cermet cutting tool of the present invention exhibits excellent cutting performance not only in continuous cutting but also in intermittent cutting in which high toughness is required for a remarkably long period of time. Therefore, it is possible to satisfactorily cope with energy saving and labor saving.

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭64−28340(JP,A) 特開 平1−116050(JP,A) ────────────────────────────────────────────────── ─── Continuation of the front page (56) References JP-A-64-28340 (JP, A) JP-A-1-116050 (JP, A)

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 容量%で、 Coおよび/またはNiを主成分とする金属結合相:5
〜30%、 有芯2重相構造および/または有芯3重相構造を有し、
かつ芯部が炭窒化チタンからなる硬質分散相:5〜40
%、 単一相構造を有し、かつTiと、Ta,Nb,Zr,
W、およびMoのうちの1種以上との複合炭窒化物固溶
体からなる硬質分散相、および同じく単一相構造を有す
る炭窒化チタンからなる硬質分散相:実質的に残り、 の組成を有する炭窒化チタン系サーメットで構成したこ
とを特徴とする靭性のすぐれた炭窒化チタン系サーメッ
ト製切削工具。
1. A metal binding phase mainly composed of Co and / or Ni: 5% by volume
~ 30%, having a cored double phase structure and / or a cored triple phase structure,
Hard dispersed phase whose core is made of titanium carbonitride: 5 to 40
%, Having a single phase structure, and Ti, Ta, Nb, Zr,
A hard dispersed phase composed of a complex carbonitride solid solution with one or more of W and Mo; and a hard dispersed phase composed of titanium carbonitride, also having a single-phase structure: a carbon having substantially the following composition: A cutting tool made of titanium carbonitride cermet with excellent toughness, characterized by being composed of titanium nitride cermet.
【請求項2】 容量%で、 Coおよび/またはNiを主成分とする金属結合相:5
〜30%、 有芯2重相構造および/または有芯3重相構造を有し、
かつ芯部が、Tiと、Ta,Nb,Zr,W、およびM
oのうちの1種以上との複合炭窒化物固溶体からなる硬
質分散相:5〜40%、 単一相構造を有し、かつTiと、Ta,Nb,Zr,
W、およびMoのうちの1種以上との複合炭窒化物固溶
体からなる硬質分散相、および同じく単一相構造を有す
る炭窒化チタンからなる硬質分散相:実質的に残り、 の組成を有する炭窒化チタン系サーメットで構成したこ
とを特徴とする靭性のすぐれた炭窒化チタン系サーメッ
ト製切削工具。
2. A metal binding phase comprising Co and / or Ni as a main component: 5% by volume.
~ 30%, having a cored double phase structure and / or a cored triple phase structure,
And the core is made of Ti, Ta, Nb, Zr, W, and M
a hard dispersed phase composed of a composite carbonitride solid solution with at least one of the following: o, having a single-phase structure, and having Ti, Ta, Nb, Zr,
A hard dispersed phase composed of a complex carbonitride solid solution with one or more of W and Mo; and a hard dispersed phase composed of titanium carbonitride, also having a single-phase structure: a carbon having substantially the following composition: A cutting tool made of titanium carbonitride cermet with excellent toughness, characterized by being composed of titanium nitride cermet.
JP5110979A 1993-04-14 1993-04-14 Titanium carbonitride cermet cutting tool with excellent toughness Expired - Lifetime JP2697553B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5110979A JP2697553B2 (en) 1993-04-14 1993-04-14 Titanium carbonitride cermet cutting tool with excellent toughness

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5110979A JP2697553B2 (en) 1993-04-14 1993-04-14 Titanium carbonitride cermet cutting tool with excellent toughness

Publications (2)

Publication Number Publication Date
JPH06299281A JPH06299281A (en) 1994-10-25
JP2697553B2 true JP2697553B2 (en) 1998-01-14

Family

ID=14549328

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5110979A Expired - Lifetime JP2697553B2 (en) 1993-04-14 1993-04-14 Titanium carbonitride cermet cutting tool with excellent toughness

Country Status (1)

Country Link
JP (1) JP2697553B2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE519832C2 (en) * 1999-05-03 2003-04-15 Sandvik Ab Titanium-based carbonitride alloy with binder phase of cobalt for easy finishing
SE519834C2 (en) * 1999-05-03 2003-04-15 Sandvik Ab Titanium-based carbonitride alloy with binder phase of cobalt for tough machining
SE519830C2 (en) * 1999-05-03 2003-04-15 Sandvik Ab Titanium-based carbonitride alloy with binder phase of cobalt for finishing

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2710934B2 (en) * 1987-07-23 1998-02-10 日立金属株式会社 Cermet alloy
JPH01116050A (en) * 1987-10-27 1989-05-09 Hitachi Metals Ltd Cermet alloy

Also Published As

Publication number Publication date
JPH06299281A (en) 1994-10-25

Similar Documents

Publication Publication Date Title
JPH10219385A (en) Composite cermet cutting tool with excellent wear resistance
JP3198680B2 (en) Cutting tools made of Ti-based carbonitride-based cermet with excellent wear resistance
JP2616655B2 (en) Titanium carbonitride-based cermet cutting tool with excellent wear resistance
JP2697553B2 (en) Titanium carbonitride cermet cutting tool with excellent toughness
JP3430737B2 (en) Ti-based carbonitride cermet with high strength
JP3493587B2 (en) Titanium carbonitride-based cermet cutting tool with excellent wear resistance
JP3483162B2 (en) Titanium carbonitride cermet cutting tool with excellent toughness and wear resistance
JP3319246B2 (en) Cermet cutting tool with excellent fracture resistance
EP0775755B1 (en) Carbonitride-type cermet cutting tool having excellent wear resistance
JP2737676B2 (en) Nitrogen-containing sintered hard alloy
JPH0698540B2 (en) Method for manufacturing a cutting tool made of thermite with excellent wear resistance
JP3227751B2 (en) Cutting tool made of cermet based on Ti-based carbonitride with excellent oxidation resistance
JP2503770B2 (en) Tungsten carbide based cemented carbide for cutting tools
JPH07224346A (en) Titanium carbonitride cermet with excellent toughness
JP3227774B2 (en) Cutting tool made of cermet based on Ti-based carbonitride with excellent wear resistance
JP3319213B2 (en) Cermet cutting tool with excellent fracture resistance
JPH10298694A (en) Cermet cutting tool with excellent wear resistance
JP2560344B2 (en) Manufacturing method of cutting tools made of titanium carbonitride based cermet with excellent fracture resistance
JP3264064B2 (en) Cermet cutting tools for high speed milling
JP2653173B2 (en) Cutting tool made of tungsten carbide based cemented carbide with excellent fracture resistance
JPH10502A (en) Carbonitride cermet cutting tool with excellent wear resistance
JP3223626B2 (en) Tungsten carbide based cemented carbide cutting tool with excellent wear resistance
JP3374653B2 (en) Carbonitride cermet cutting tool with excellent wear resistance
JPH091405A (en) Cutting tool made of Ti-W carbonitride based cermet with excellent fracture resistance
JPH0530881B2 (en)

Legal Events

Date Code Title Description
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 19970819

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080919

Year of fee payment: 11

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080919

Year of fee payment: 11

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090919

Year of fee payment: 12

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090919

Year of fee payment: 12

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100919

Year of fee payment: 13

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100919

Year of fee payment: 13

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100919

Year of fee payment: 13

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100919

Year of fee payment: 13

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110919

Year of fee payment: 14

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120919

Year of fee payment: 15

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130919

Year of fee payment: 16

EXPY Cancellation because of completion of term