JP2732855B2 - Electrostatic camera with voice information input function - Google Patents

Description

Description: TECHNICAL FIELD The present invention relates to an electrostatic camera using a charge holding medium,
In particular, the present invention relates to an electrostatic camera having an audio information input function capable of simultaneously recording audio information together with still image information.

[Conventional technology]

Conventionally, silver halide photography has been used for photographing and storing still images, and records, cassette tapes, and the like have been used for recording audio information. For recording image information and audio information, video tapes, compact discs, optical discs and the like are used.

[Problems to be solved by the invention]

By the way, silver halide photography is excellent as a means for preserving still images, but it requires a development process to form a silver halide image, and in image reproduction, it involves complicated processes such as hard copy and soft copy (CRT output). Optical, electrical, or chemical treatments are required. Records, cassette tapes, etc. are very simple means for recording audio, but they cannot record image information due to the small memory capacity. However, image information obtained by using an optical semiconductor is extracted and recorded as an electric signal. Line-sequential scanning is required, and the resolution depends on the number of scanning lines. It deteriorates remarkably compared to the analog recording, and is essentially the same for compact discs and optical discs. The problems built into these technologies are that if the image recording is of high quality and high resolution, the processing steps are complicated, and if the steps are simple, there is a lack of storage function or a basic deterioration of image quality.

The present invention is intended to solve the above problems, and has high quality, high resolution, simple processing steps, long-term storage, and recording of audio information together with high-quality images. An object of the present invention is to provide an electrostatic camera having a voice information input function.

[Means for solving the problem]

FIG. 1 is a view for explaining a recording method in the electrostatic image recording / reproducing method of the present invention, wherein 1 is a photosensitive member, 3 is a charge holding medium, 5 is a photoconductive layer support, and 7 is a photosensitive member. Electrode, 9
Denotes a photoconductive layer, 11 denotes an insulating layer, 13 denotes a charge holding medium electrode, 15 denotes an insulating layer support, and 17 denotes a power supply.

FIG. 1 shows an embodiment in which exposure is performed from the photoreceptor 1 side. First, a transparent photoreceptor electrode 7 made of ITO having a thickness of 1000 mm is formed on a photoconductive layer support 5 made of 1 mm thick glass. The photoconductor 1 is formed by forming a photoconductive layer 9 of about 10 μm thereon. The charge holding medium 3 is arranged on the photoconductor 1 with a gap of about 10 μm. The charge holding medium 3 is placed on an insulating layer support 15 made of glass having a thickness of 1 mm.
An Al electrode 13 having a thickness of 0 mm is formed by evaporation, and
In this case, an insulating layer 11 having a thickness of 0 μm is formed.

First, as shown in FIG.
The charge holding medium 3 is set through a gap of about 10 μm,
As shown in FIG. 1 (b), a voltage is applied between the electrodes 7 and 13 by the power supply 17. In a dark place, since the photoconductive layer 9 is a high-resistance body, no change occurs between the electrodes. When light is incident from the photoreceptor 1 side, the photoconductive layer 9 in the portion where the light is incident shows conductivity, and a discharge occurs between the photoconductive layer 9 and the insulating layer 11.
The electric charge is accumulated.

When the exposure is completed, a voltage is applied as shown in FIG.
Turn off, and then take out the charge holding medium 3 as shown in FIG. 1 (d) to complete the formation of the electrostatic latent image.

The photoconductor 1 and the charge holding medium 3 may be of a contact type instead of a non-contact type as described above. In the case of the contact type, a positive or negative charge is applied to the exposed portion of the photoconductive layer 9 from the photoconductor electrode 7 side. Charges are injected, and the charges are drawn by the electrode 13 on the charge holding medium 3 side, pass through the photoconductive layer 9, and stop moving when reaching the surface of the insulating layer 11. Is done. Then, when the photoconductor 1 and the charge holding medium 3 are separated, the insulating layer
11 are separated while keeping the charge.

When this recording method is a planar analog recording, high resolution can be obtained in the same manner as the silver halide photography, and an insulating layer to be formed is formed.
Although the surface charge on 11 is exposed to the air environment, the air has a good insulating performance, so it is stored for a long time without discharging regardless of the light place and the dark place.

The charge storage period on the insulating layer 11 is determined by the properties of the insulator, and is affected by the charge trapping characteristics of the insulator in addition to the insulating properties of air. In the above description, charges are described as surface charges.Injected charges may simply accumulate on the surface, and microscopically penetrate into the vicinity of the insulator surface, and electrons or electrons enter the structure of the substance. Since the holes may be trapped, long-term storage is performed. Further, the surface of the insulating layer 11 may be covered with an insulating film or the like and stored in order to prevent physical damage to the charge holding medium or discharge when the humidity is high.

Hereinafter, constituent materials of the photoreceptor and the charge holding medium used in the present invention will be described.

The material and thickness of the photoconductive layer support 5 are not particularly limited as long as the photoconductive layer support 5 has a certain strength capable of supporting the photoreceptor. For example, a flexible plastic film, metal foil, paper, or the like may be used. Alternatively, a rigid body such as a glass, a plastic sheet, or a metal plate (which can also serve as an electrode) is used. However, when used in a device that records information by irradiating light from the photoconductor side, it is naturally necessary to have the property of transmitting that light.For example, when using natural light as incident light and using it in a camera that enters from the photoconductor side Has a thickness of 1m
A transparent glass plate of about m or a plastic film or sheet is used.

The photoreceptor electrode 7 is formed on the photoconductive layer support 5 except when a metal is used for the photoconductive layer support 5, and the material thereof is as long as the specific resistance value is 10 ⁶ Ω · cm or less. There is no limitation, and an inorganic metal conductive film, an inorganic metal oxide conductive film, or the like can be used.
Such a photoconductor electrode 7 is formed on the photoconductive layer support 5 by vapor deposition, sputtering, CVD, coating, plating, dipping, electrolytic polymerization, or the like. The thickness of the electrode must be changed depending on the electrical characteristics of the material constituting the photoreceptor electrode 7 and the applied voltage when recording information. For example, in the case of aluminum, the thickness is about 100 to 3000 °. This photoconductor electrode 7 is also similar to the photoconductive layer support 5,
When the information light needs to be incident, the above-mentioned optical characteristics are required, and for example, the information light is a visible light (400 to 700 nm).
A transparent electrode such as ITO (In ₂ O ₃ —SnO ₂ ), SnO ₂ , or the like, which is formed by sputtering, vapor deposition, or coating a fine powder thereof by ink with a binder, Au, A
Translucent electrode made of l, Ag, Ni, Cr, etc. by evaporation or sputtering, tetracyanoquinodimethane (TCNQ),
An organic transparent electrode or the like with a coating of polyacetylene or the like is used.

When the information light is infrared (700 nm or more) light, the above electrode material can be used. In some cases, a colored visible light absorbing electrode can also be used to cut off visible light.

Further, when the information light is ultraviolet light (400 nm or less), the above-mentioned electrode materials can be basically used, but those in which the electrode substrate material absorbs ultraviolet light (organic polymer materials, soda glass, etc.) are not preferable. A material that transmits ultraviolet light, such as quartz glass, is preferable.

The photoconductive layer 9 is a conductive layer in which photocarriers (electrons and holes) are generated in the irradiated portion when light is irradiated, and the carriers can move in a layer width. In particular, an electric field exists. In this case, the effect is remarkable. The material is composed of an inorganic photoconductive material, an organic photoconductive material, an organic-inorganic hybrid type photoconductive material, or the like.

Hereinafter, a method for forming the photoconductive material and the photoconductive layer will be described.

(A) Inorganic Photoreceptor (Photoconductor) Examples of inorganic photoreceptor materials include amorphous silicon, amorphous selenium, cadmium sulfide, and zinc oxide.

(A) Amorphous silicon photoreceptor As an amorphous silicon photoreceptor, hydrogenated amorphous silicon (a-Si: H) fluorinated amorphous silicon (a-Si: F) ・ Those not doped with impurities, ・ B, Al , Ga, In, Tl, etc. are made P-type (hole transport type) by doping; and P, Ag, Sb, Bi, etc. are made N-type (electron transport type) by doping.

As a method of forming the photoreceptor layer, a silane gas and an impurity gas are introduced into a low vacuum together with a hydrogen gas (10 ^{-2 to 1} Torr).
r), a film is formed by pre-stacking on an electrode substrate heated or not heated by glow discharge, or a thermochemical reaction is formed on a heated electrode substrate, or a solid material is formed by vapor deposition and sputtering. Used as a film, a single layer or a laminate. The film thickness is 1 to 50 μm.

Further, a charge injection preventing layer can be provided on the surface of the photoreceptor electrode 7 in order to prevent charge from being injected from the transparent electrode 7 and being exposed as if it were not exposed. As the charge injection preventing layer, an a-SiN layer, a-SiC layer is formed on one or both of the electrode substrate and the uppermost layer (surface layer) of the photoreceptor by glow discharge, vapor deposition, sputtering or the like.
It is preferable to provide an insulating layer such as a layer, a SiO ₂ layer, and an Al ₂ O ₃ layer. If the insulating layer is too thick, no current will flow when exposed, so it must be at least 1000 ° or less, and preferably about 400-500 ° in consideration of ease of fabrication.

Further, as the charge injection preventing layer, it is preferable to provide a charge transporting layer having a charge transporting ability of a polarity opposite to the rigidity of the electrode substrate on the electrode substrate by utilizing a rectifying effect. Is positive, an electron transport layer is provided. For example, a-Si: H in which boron is doped in Si
(N ⁺ ) enhances the hole transporting property, provides a rectifying effect, and functions as a charge injection preventing layer.

The (b) amorphous selenium photoreceptor amorphous selenium photosensitive member, there is amorphous selenium (a-Se) amorphous selenium tellurium (a-Se-Te) amorphous arsenic selenium compound (a-As ₂ Se ₃₎ amorphous arsenic selenium compound + Te .

This photoreceptor is prepared by vapor deposition and sputtering, and a SiO ₂ , Al ₂ O ₃ , SiC, SiN layer as a charge injection blocking layer is provided on the electrode substrate by vapor deposition, sputtering, glow discharge or the like. Further, the above-mentioned may be combined to form a laminated photoreceptor. The thickness of the photoconductor layer is the same as that of the amorphous silicon photoconductor.

(C) Cadmium sulfide (CdS) This photoreceptor is prepared by coating, vapor deposition, and sputtering. In the case of vapor deposition, solid particles of CdS are placed on a tungsten board and vapor-deposited by resistance heating, or EB
(Electron beam) This is performed by vapor deposition. In the case of sputtering, deposition is performed on a substrate in argon plasma using a CdS target. In this case, CdS is usually deposited in an amorphous state, but a crystalline alignment film (oriented in the film thickness direction) can be obtained by selecting sputtering conditions.
You can also get In the case of coating, CdS particles (particle diameter: 1 to 100 μm) may be dispersed in a binder, and a solvent may be added to coat on a substrate. .

(D) Zinc oxide (ZnO) This photoreceptor is manufactured by a coating method or a CVD method. As the coating method, ZnS particles (particle size 1 to 100
μm) is dispersed in a binder, a solvent is added, and coating is performed on a substrate. In the CVD method, an organic metal such as diethyl zinc or dimethyl zinc and oxygen gas are mixed in a low vacuum (10 ^{-2 to 1} Torr), and a chemical reaction is performed on a heated electrode substrate (150 to 400 ° C.) to oxidize. Deposited as a zinc film. Also in this case, a film oriented in the film thickness direction can be obtained.

(B) Organic Photoreceptor The organic photoreceptor includes a single-layer type photoreceptor and a function-separated type photoreceptor.

(A) Single-layer photoconductor The single-layer photoconductor is composed of a mixture of a charge generating substance and a charge transport substance.

<Charge-generating substance type> It is a substance that absorbs light and easily generates an electric charge.For example, azo pigments, disazo pigments, trisazo pigments, phthalocyanine pigments, perylene pigments, pyrylium dyes,
Cyanine dyes and methine dyes are used.

<Charge transporting substance system> A substance having a good ionized charge transporting property, for example, hydrazone type, pyrazoline type, polyvinyl carbazole type, carbazole type, stilbene type, anthracene type,
There are naphthalene type, tridiphenylmethane type, azine type, amine type, aromatic amine type and the like.

Further, a charge transfer complex may be formed by forming a complex between the charge generation material and the charge transport material.

Normally, a photoreceptor has photosensitivity determined by the light absorption characteristics of a charge generating substance. However, when a charge generating substance and a charge transporting substance are mixed to form a complex, the light absorption properties change. For example, polyvinyl carbazole (PVK) is an ultraviolet light. Only in the region, trinitrofluorenone (TNF) only feels around 400 nm wavelength, while the PVK-TNF complex feels up to 650 nm wavelength region.

The thickness of such a single-layer type photoreceptor is preferably 10 to 50 μm.

(B) Function-separated type photoreceptor Although the charge generating material easily absorbs light, it has the property of trapping light, and the charge transporting material has good charge transporting properties.
Light absorption characteristics are not good. Therefore, the two are separated so as to sufficiently exhibit their respective characteristics, and the charge generation layer and the charge transport layer are stacked.

<Charge Generating Layer> Examples of the material for forming the charge generating layer include azo-based materials,
There are disazo type, trisazo type, phthalocyanine type, acid xansen dye type, cyanine type, styryl dye type, pyrylium dye type, perylene type, methine type, a-Se, a-Si, azulenium salt type, squarium salt type and the like.

<Charge transport layer> Examples of the material forming the charge transport layer include hydrazone, pyrazoline, PVK, carbazole, oxazole, triazole, aromatic amine, amine, triphenylmethane, and polycyclic aromatic compounds. Group compounds.

As a method for producing a function-separated type photoreceptor, a charge generating substance is first dissolved in a solvent and applied on an electrode, and then the charge transport layer is dissolved in a solvent and applied to the charge transport layer.
It is preferable that the thickness of the charge transport layer be 0.1 to 10 μm and the thickness of the charge transport layer be 10 to 50 μm.

In addition, in any case of the single-layer type photoreceptor and the function separation type photoreceptor, as a binder, a silicone resin, a styrene-butadiene copolymer resin, an epoxy resin, an acrylic resin,
Saturated or unsaturated polyester resin, polycarbonate resin, polyvinyl acetal resin, phenol resin, polymethyl methacrylate (PMMA) resin, melamine resin,
0.1 to 10 parts of a polyimide resin or the like is added to 1 part of each of the charge generating material and the charge transport material so that the resin can be easily attached. As a coating method, a dipping method, an evaporation method, a sputtering method, or the like can be used.

 Next, the charge injection preventing layer will be described in detail.

The charge injection preventing layer is provided on at least one of the two surfaces of the photoconductive layer 9 or on both surfaces, when a voltage is applied to the photoconductive layer 9 when a voltage is applied (charge injection from the electrode), that is, when the photoconductive layer 9 is not exposed. It can be provided to prevent a phenomenon in which charges move in the photosensitive layer as if exposed as if exposed.

The charge injection preventing layer includes two types, a layer using a so-called tunneling effect and a layer using a rectifying effect. First, in the case of utilizing the so-called tunneling effect, the current does not flow to the photoconductive layer or the insulating layer surface by the voltage injection preventing layer only by applying a voltage, but when light is injected, it corresponds to the incident portion. In the charge injection preventing layer, a high electric field is applied due to the presence of one of the charges (electrons or holes) generated in the photoconductive layer, causing a tunnel effect and causing a current to flow through the charge injection preventing layer. . Such a charge injection prevention layer is formed of a single layer of an inorganic insulating film, an organic insulating polymer film, an insulating monomolecular film, or the like, or is formed by laminating them. As the inorganic insulating film, for example, As ₂ O _{3, B 2 O 3, Bi} 2 O 3, CdS, CaO, CeO 2, Cr 2 O 3, CoO,
GeO ₂ , HfO ₂ , Fe ₂ O ₃ , La ₂ O ₃ , MgO, MnO ₂ , Nd ₂ O, Nb ₂ O ₅ ,
_{PbO, Sb 2 O 3, SiO} 2, SeO 2, Ta 2 O 5, TiO 2, WO 3, V 2 O 5, Y 2
_{O 5, Y 2 O 3,} ZrO 2, BaTiO 3, Al 2 O 3, Bi 2 TiO 5, CaO-SrO,
_{CaO-Y 2 O 3, Cr} -SiO, LiTaO 3, PbTiO 3, PbZrO 3, ZrO 2 -
Co, ZrO ₂ -SiO ₂ , AlN, BN, NbN, Si ₃ N ₄ , TaN, TiN, V
Glow discharge, deposition, N, ZrN, SiC, TiC, WC, Al ₄ C ₃ etc.
It is formed by sputtering or the like. The thickness of this layer is determined for each material used in consideration of the insulating property for preventing charge injection and the tunnel effect. Next, as the charge injection preventing layer utilizing the rectifying effect, a charge transporting layer having a charge transporting ability having a polarity opposite to the polarity of the electrode substrate is provided using the rectifying effect. That is, such a charge injection preventing layer is formed of an inorganic photoconductive layer, an organic photoconductive layer, and an organic-inorganic hybrid type photoconductive layer, and has a thickness of about 0.1 to 10 μm. Specifically, when the electrode is negative, B, Al, Ga, amorphous silicon photoconductive layer doped with In, etc., amorphous selenium, or oxadiazole, pyrazoline, polyvinylcarbazole, stilbene, anthracene, naphthalene, tridiphenylmethane, Organic photoconductive layer formed by dispersing triphenylmethane, azine, amine, aromatic amine, etc. in a resin. If the electrode is positive, P, N, As,
Amorphous silicon photoconductive layer doped with Sb, Bi, etc.,
Glow discharge, vapor deposition, sputtering, C
It is formed by a method such as VD or coating.

Next, a charge holding medium material and a method for manufacturing the charge holding medium will be described.

The charge holding medium 3 is used together with the photoreceptor 1 to record information as a distribution of electrostatic charges on the surface of the insulating layer 11 constituting the charge holding medium 3 or inside thereof.
The charge holding medium itself is used as a recording medium. Therefore, the shape of the charge holding medium can take various shapes depending on the information to be recorded or the recording method. For example, when used for an electrostatic camera (filed on the same date by the same applicant), it takes the form of a general film (for single frame or continuous frame) or disk shape, and records digital information or analog information using a laser or the like. Takes a tape shape, a disk shape, or a card shape.

The insulating layer support 15 strongly supports the charge holding medium 3 as described above, but is basically made of the same material as the photoconductive layer support 5 and has the same light transmittance. May be required. Specifically, when the charge holding medium 3 takes the shape of a flexible film, tape, or disk, a flexible plastic film is used, and when strength is required, a rigid sheet, glass, or the like is used. An inorganic material or the like is used.

The charge storage medium electrode 13 may be basically the same as the photoreceptor electrode 7, and is formed on the insulating layer support 15 by the same forming method as the photoreceptor electrode 7 described above.

Since the insulating layer 11 records information on the surface or inside thereof as a distribution of static charges, high insulating properties are required to suppress the movement of charges, and the specific resistance is 10 ¹⁴ Ω ·
It is required to have insulation properties of not less than cm. Such an insulating layer 11 can be formed by dissolving a resin or rubber in a solvent and coating or dipping, or by vapor deposition or sputtering.

Here, as the resin and rubber, for example, polyethylene, polypropylene, vinyl resin, styrene resin, acrylic resin, nylon 66, nylon 6, polycarbonate, acetal homopolymer, fluororesin, cellulose resin, phenol resin, urea resin, and polystyrene resin ,
Epoxy resin, flexible epoxy resin, melamine resin, silicone resin, phenoxy resin, aromatic polyimide, PP
O, polysulfone, etc. or polyisoprene, polybutadiene, polychloroprene, isobutylene, ultra high nitrile, polyacryl rubber, chlorosulfonated polyethylene, ethylene / propylene rubber, fluorine rubber, silicon rubber, polysulfide synthetic rubber, urethane rubber, etc. A simple substance or a mixture of rubber is used.

Further, a layer is formed by attaching a silicon film, a polyester film, a polyimide film, a polyfluorinated film, a polyethylene film, a polypropylene film, a polyparabanic acid film, a polycarbonate film, a polyamide film or the like to the charge holding medium electrode 13 via an adhesive or the like. Even if the layer is formed by coating or dipping a thermoplastic resin, a thermosetting resin, an ultraviolet curable resin, an electron beam curable resin, a curing agent necessary for a rubber or the like, a solvent, etc. Good.

Further, as the insulating layer 11, a monomolecular film formed by a Langmuir-Blodget method or a monomolecular cumulative film can also be used.

In addition, a charge retention enhancing layer can be provided between the insulating layer 11 and the electrode surface or on the insulating layer 11. The charge retention enhancing layer refers to a layer into which electric charge is injected when a strong electric field (10 ⁴ V / cm or more) is applied, but which is not injected at a low electric field (10 ⁴ V / cm or less). As the charge retention enhancing layer, for example, SiO ₂ , Al ₂ O ₃ , SiC, SiN or the like can be used, and as the organic substance, for example, a polyethylene deposited film or a polyparaxylene deposited film can be used.

In order to more stably hold the electrostatic charge, the insulating layer 11
In addition, a substance having an electron-donating property (donor material) or a substance having an electron-accepting property (acceptor material) may be added. Donor materials include styrene, pyrene,
There are naphthalene-based, anthracene-based, pyridine-based, and azine-based compounds. Specifically, tetrathiofulvalene (TT
F), polyvinyl pyridine, polyvinyl naphthalene, polyvinyl anthracene, polyazine, polyvinyl pyrene, polystyrene and the like are used, and one kind or a mixture is used. As the acceptor material, there are a halogen compound, a cyan compound, a nitro compound and the like, and specifically, tetracyanoquinodimethane (TCNQ) trinitrofluorenone (TNF) and the like are used, and one kind or a mixture is used. The donor material and the acceptor material are used by adding about 0.001 to 10% to the resin or the like.

Further, in order to stably hold the charge, elemental element fine particles can be added to the charge holding medium. Elemental elements include the following elements in the periodic table: Group IA (alkali metal), Group IB (copper group), Group IIA (alkaline earth metal), Group IIB (zinc group), Group IIIA (aluminum group) ), IIIB (rare earth), IVB (titanium), VB (vanadium), VIB (chromium), VIB (manganese), VIII (iron) Group, platinum group) or IV group A (carbon group) as silicon, germanium, tin, lead, V
Antimony, bismuth, and VIA
As the group (oxygen group), sulfur, selenium, and tellurium are used in the form of fine powder. Metals among the above elemental elements can be used in the form of metal ions, fine powdery alloys, organic metals, and complexes. Further, the above element simple substance can be used in the form of an oxide, a phosphate, a sulfate, or a halide. These additives may be added to the charge holding medium such as the above-mentioned resins and rubbers in a very small amount, and may be added in an amount of about 0.01 to 10% by weight based on the charge holding medium. Insulating layer 11 is at least 1000 mm (0.1 μ
m) or more, and the thickness is preferably 100 μm or less from the viewpoint of flexibility.

The insulating layer 11 thus formed can be provided with a protective film on its surface in order to prevent damage or discharge of information charges on its surface. As the protective film, a rubber such as silicone rubber having adhesiveness, a resin such as polyterpene resin is formed into a film, and the film is adhered to the surface of the insulating layer 11, or a plastic film is formed using an adhesive such as silicone oil. It is good if the specific resistance is 10 ¹⁴ Ωcm or more, the film thickness is about 0.5 to 30 μm,
When the information of the insulating layer 11 needs to have high resolution, the thinner the protective film, the better. This protective layer may reproduce information from above the protective film at the time of reproducing information, or may reproduce the information of the insulating layer by peeling off the protective film.

As an electrostatic charge holding method, there is an electret that causes charge distribution and polarization inside an insulating medium, in addition to the so-called free charge holding method of accumulating surface charges as described above.

FIG. 2 is a diagram showing a method for retaining electrostatic charges using an optical electret, and the same numbers as those in FIG. 1 indicate the same contents. In the figure, reference numeral 19 denotes a transparent electrode.

As shown in FIG. 2 (a), an electrode 13 is formed on a support 15 such as a film, and ZnS, CdS, and ZnO are formed on the electrode plate in a thickness of 1 to 5 μm by vapor deposition sputtering, CVD, coating method, or the like. I do. Then, when a transparent electrode 19 is superposed on the surface of the photosensitive layer in a contact or non-contact manner, and exposed under a voltage applied state (FIG. 2 (b)), charges are generated by light in the exposed portion and polarized by an electric field. Is trapped at that position (FIG. 2 (c)). Thus, an electret corresponding to the exposure amount is obtained. In the case of the charge holding medium shown in FIG. 2, there is an advantage that a separate photoconductor is not required.

FIG. 3 is a diagram showing a method for retaining electrostatic charges using a thermal electret, and the same reference numerals as those in FIG. 1 denote the same contents.

Examples of the heat electret material include polyvinylidene fluoride (PVDF), poly (VDF / ethylene trifluoride), poly (VDF / ethylene tetrafluoride), polyvinyl fluoride, polyvinylidene chloride, polyacrylonitrile, and poly-α-. It is made of chloroacrylonitrile, poly (acrylonitrile / vinyl chloride), polyamide 11, polyamide 3, poly-m-phenylene isophthalamide, polycarbonate, poly (vinylidene cyanide vinyl acetate), PVDF / PZT composite, etc. A single layer of 1 to 50 μm is provided thereon, or two or more layers are laminated.

Then, before exposure, the medium is heated above the glass transition of the medium material by resistance heating or the like, and voltage application exposure is performed in that state (FIG. 3 (b)). At high temperatures, the mobility of ions is large, and in the exposed area, a high electric field is applied to the insulating layer,
Of the thermally activated ions, the negative charge collects on the positive electrode and the positive charge collects on the negative electrode to form a space charge, causing polarization. Thereafter, when the medium is cooled, the generated charges are trapped at the position even after the electric field is removed, and an electret corresponding to the exposure amount is generated (FIG. 3 (c)).

Next, as a method for inputting information to the insulating layer 11, there are a method using a high-resolution electrostatic camera and a recording method using a laser. First, the high-resolution electrostatic camera used in the present invention comprises a photoconductor 1 comprising a photoconductive layer 9 provided with a photoconductor electrode 7 on the front, instead of a photographic film used in a normal camera, A recording member is constituted by a charge holding medium comprising an insulating layer 11 having a charge holding medium electrode 13 provided on the rear surface thereof, and a voltage is applied to both electrodes so that the photoconductive layer becomes conductive according to incident light. An electrostatic latent image of an incident optical image is formed on a charge storage medium by accumulating electric charges on an insulating layer in accordance with the amount of incident light, and a mechanical shutter can be used. It can be used, and the electrostatic latent image can be held for a long period of time irrespective of a bright place or a dark place. Also, optical information is separated into R, G, and B light components by a prism, and a color filter that takes out as parallel light is used. One frame is formed by three sets of the R, G, and B separated charge holding media. By arranging the R, G, and B images on a plane to form one frame in one set, color photography can also be performed.

As a recording method using a laser, an argon laser (514.488 nm), a helium-neon laser (633 nm), a semiconductor laser (780 nm, 810 nm, etc.) are used as a light source.
A voltage is applied by bringing the photoreceptor and the charge holding medium into a planar shape and bringing the surfaces into close contact or facing each other at a certain interval. In this case, the photoconductor electrode may be set to the same polarity as the carrier of the photoconductor. In this state, laser exposure corresponding to the image signal, character signal, code signal, and line drawing signal is performed by scanning. Analog recording such as images is performed by modulating the laser light intensity, and digital recording such as characters, codes, and line drawings is performed by ON-OFF control of laser light. In the case where halftone dots are formed in an image, the halftone dots are formed by applying dot generator ON-OFF control to laser light.
Note that the spectral characteristics of the photoconductive layer in the photoreceptor need not be panchromatic, but may be any as long as they have sensitivity to the wavelength of the laser light source.

FIG. 4 is a diagram showing a configuration of an electrostatic camera having a voice information input function of the present invention. In the figure, 101 is a microphone, 102 is an amplifier, 103 is a laser, 104 is an acousto-optic modulator, and 105 is a polygon mirror. , 106 are power supplies.

The photoconductor 1 is connected between the charge holding medium 3 and the switch 107 by an O switch.
A predetermined voltage is applied from the power supply 106 by N / OFF. Then, surface exposure is performed with the image information light 100 in a state where a predetermined voltage is applied, so that the charge holding medium 3 is exposed.
Is formed with a latent image potential corresponding to the image. On the other hand, an electric signal corresponding to the sound is amplified by the amplifier 102 via the microphone 101, the laser light from the laser 103 is modulated by the acousto-optic modulator 104 according to the sound signal, and the polygon mirror 105 scans the photosensitive member 1 for scanning. To form a latent image potential corresponding to the audio signal on the charge holding medium 3. Thus, the charge holding medium 3
Will be recorded with audio information together with image information.
As a result, for example, when an image such as a landscape is recorded on a charge holding medium, the situation at the time of shooting can be recorded as audio, so that when reproduced, a reproduced image with the description at that time can be obtained. .

In the above description, scanning and exposure are performed by modulating light using a combination of an optical modulator and a polygon mirror. In addition, a combination of a CRT and a changing means such as a flying spot scanner (FSS) may be used. May be used to scan and expose through a photoreceptor with light from the bright spot on the surface of the cathode ray tube, or a charge holding medium close to the surface of a type of CRT having needle electrodes on the tube surface. May be arranged to face each other, and discharge recording is performed directly on the charge holding medium through the needle electrode irradiated with the scanning electron beam.

FIG. 5 is a diagram showing another embodiment of the present invention utilizing PCM modulation, and the same reference numerals as those in FIG. 4 indicate the same contents. In the case of FIG. 5, since the audio signal is converted into a digital signal by the PCM 120, it is possible to record high-quality audio information that is resistant to noise.

FIG. 6 is a view showing another embodiment of the present invention.
Is an A / D converter, 122 is a circulating memory, and 123 is a D / A converter.

In this embodiment, the audio signal is A / D converted and stored in the circulation memory 122, and the output of the circulation memory 122 is D / A converted and recorded. Circular memory 122
Has a storage capacity for storing voice information for a certain period of time and sequentially updates the stored contents, so that the voice information from a certain period before to the present is always stored. For example, if the storage capacity of the circulating memory is made to be able to record audio information for one minute,
Since the audio information can be recorded from 30 seconds before to 30 seconds later, it is possible to reproduce the scene at the time of shooting with a realistic feeling. For example, when shooting SL,
If you can capture the image of SL with the sound of shushuppo, shushuppo and shutter sound,
The reproduced image can be expected to recall the situation at the time of shooting.

 Hereinafter, an image potential reading method will be described.

FIG. 7 is a diagram showing an example of a potential reading method according to the present invention, and the same numbers as those in FIG. 1 indicate the same contents. In the figure, 21 is a potential reading unit, 23 is a detection electrode, 25 is a guard electrode, 27 is a capacitor, and 29 is a voltmeter.

When the potential reading unit 21 faces the charge storage surface of the charge holding medium 3, an electric field generated by charges stored on the insulating layer 11 of the charge holding medium 3 acts on the detection electrode 23, and the charge is held on the detection electrode surface. An induced charge equal to the charge on the medium results. A capacitor 27 with an equal amount of charge of the opposite polarity to this induced charge
Is charged, a potential difference occurs between the electrodes of the capacitor in accordance with the accumulated charge. By reading this value with the voltmeter 29, the potential of the charge holding member can be obtained. The electrostatic latent image can be output as an electric signal by scanning the surface of the charge holding medium with the potential reading unit 21. When the detection electrode 23 alone is used, an electric field (line of electric force) due to electric charges in a wider range than the detection electrode facing portion of the charge storage medium acts to lower the resolution. Therefore, the grounded guard electrode 25 is arranged around the detection electrode. You may do so. As a result, the lines of electric force are directed in the direction perpendicular to the surface, so that the lines of electric force only act on the portion facing the detection electrode 23, and the potential of the portion substantially equal to the detection electrode area is read. be able to. The accuracy and resolution of potential reading vary greatly depending on the shape and size of the detection electrode and guard electrode, and the distance between the detection electrode and the guard electrode. Therefore, it is necessary to design the optimum conditions in accordance with the required performance.

FIG. 8 is a view showing another example of the potential reading method. The case of FIG. 7 except that a detection electrode and a guard electrode are provided on the insulating protective film 31 and the potential is detected via the insulating holding film. Is the same as

According to this method, since the detection can be performed by contacting the charge holding medium, the distance from the detection electrode can be made constant.

FIG. 9 is a view showing another example of the potential reading method, in which the needle-like electrode 33 is brought into direct contact with the charge holding medium to detect the potential at the site, and the detection area can be reduced. Resolution can be obtained. If a plurality of needle electrodes are provided for detection, the reading speed can be improved.

The above is a DC amplification type that detects a DC signal in a contact or non-contact manner. Next, an example of an AC amplification type will be described.

FIG. 10 is a diagram showing a potential reading method of a vibrating electrode type.
Is a detection electrode, 24 is an amplifier, and 26 is a meter.

The detection electrode 22 vibrates and is driven so that the distance with respect to the charged surface of the charge holding medium 3 changes with time, and as a result, the potential at the detection electrode 22 corresponds to the electrostatic potential of the charged surface. It changes over time with amplitude. This temporal potential change is extracted as a voltage change across the impedance Z,
The AC component is amplified by the amplifier 24 through the capacitor C and read by the meter 26, whereby the electrostatic potential of the charged surface can be measured.

FIG. 11 shows an example of a rotary detector, in which 28 is a rotary blade.

Conductive rotating blades 28 are provided between the electrode 22 and the charged surface of the charge holding medium 3, and are driven to rotate by driving means (not shown). As a result, the detection electrode 22 and the charge holding medium 3
Is periodically and electrically shielded. Therefore, the detection electrode 22 detects a periodically varying potential signal having an amplitude corresponding to the electrostatic potential of the charged surface, and the AC component is amplified by the amplifier 24 and read.

FIG. 12 shows an example of a vibration capacitance type detector, in which 28 is a drive circuit, and 30 is a vibrating reed.

The driving circuit 28 vibrates the vibrating reed 30 of one electrode forming the capacitor to change the capacitance of the capacitor. As a result, the DC potential signal detected by the detection electrode 22 is modulated, and the AC component is amplified and detected. This detector can convert a direct current into an alternating current and measure the potential with high sensitivity and high stability.

FIG. 13 is a diagram showing another example of a potential reading method, in which a CT method (computed tomographic imaging method) is used by using an elongated detection electrode.
Is used to perform potential detection.

When the detection electrodes 35 are arranged to face each other across the charge storage surface, the obtained data is a value obtained by linear integration along the detection electrodes, that is, data corresponding to projection data in CT. Therefore, necessary data is collected by scanning this detection electrode so as to cover the entire surface as indicated by the arrow in FIG. 13 (b), and further changing the angle θ to collect necessary data. By performing arithmetic processing using the CT algorithm, the potential distribution state on the charge holding member can be obtained.

If a plurality of detection electrodes are arranged as shown in FIG. 14, the data collection speed can be increased, and the processing speed as a whole can be improved.

FIG. 15 shows an example of a current collecting detector, in which 32 is a grounded metal cylinder, 34 is an insulator, and 36 is a current collector.

The current collector 36 contains a radioactive substance, from which alpha rays are emitted. Therefore, air is ionized in the metal cylinder to form positive and negative ion pairs. In the natural state, these ions disappear by recombination and diffusion, and maintain an equilibrium state.However, when an electric field is present, the ions statistically proceed in the direction of the electric field while repeatedly colliding with air molecules due to thermal motion. It plays the role of carrying charges.

In other words, it can be considered that the air is made conductive by the ions, and that an equivalent electric resistance path exists between the surrounding objects including the current collector 36.

Therefore, the charged surface of the charge holding medium 3 and the ground metal cylinder 32,
When the resistance between the charged body and the current collector 36 and the resistance between the current collector 36 and the ground metal cylinder 32 are R ₀ , R ₁ , and R ₂ , respectively, and when the potential of the charged body is V ₁ , the potential V _{2 of the current} collector 36 is obtained. Becomes V ₂ = R ₂ V ₁ (R ₁ + R ₂ ) in the steady state. As a result, the potential of the charge holding medium 3 can be obtained by reading the potential of the current collector 36.

FIG. 16 is a view showing an example of an electron beam type potential reader, wherein 37 is an electron gun, 38 is an electron beam, 39 is a first dynode, and 40 is a secondary electron multiplier.

Electrons emitted from the electron gun 37 are deflected by an electrostatic deflection device or an electromagnetic deflection device (not shown) to scan the charged surface. A part of the scanning electron beam is combined with the charge on the charged surface to cause a charging current to flow, and accordingly, the potential on the charged surface drops to an equilibrium potential. The remaining modulated electron beam returns to the direction of the electron gun 37, collides with the first diode 39, and its secondary electrons are amplified by the secondary electron multiplier 40 and taken out from its anode as a signal output. Reflected electrons or secondary electrons are used as the returning electron beam.

In the case of the electron beam type, a uniform charge is formed on the medium after scanning, but a current corresponding to a latent image is detected during scanning. When the latent image is negatively charged, the charge accumulated by the electrons is small and the charge current is small in a portion with a large amount of charge (exposed portion), but the maximum charge current flows in a portion where no charge is present, for example. In the case of a positive charge, the reverse is the case, and a negative type is obtained.

FIG. 17 is a diagram showing another example of the potential reading method,
Developing the charge holding medium 3 on which the electrostatic latent image is formed with toner,
Scanning by irradiating the colored surface with a light beam,
The reflected light is converted into an electric signal by the photoelectric converter 61, and high resolution can be achieved by reducing the diameter of the light beam, and the electrostatic potential can be easily detected optically. it can.

FIG. 18 is a diagram showing another example of the potential reading method,
R, formed by a fine color filter as described below,
An example is shown in which the G and B separated images are developed with toner, the colored surface is irradiated with a light beam, and the Y, M and C signals are obtained from the reflected light. In the figure, 63 is a scanning signal generator, 65 is a laser, 67 is a reflecting mirror, 69 is a half mirror, 71 is a photoelectric converter,
73, 75 and 77 are gate circuits.

The scanning light from the scanning signal generator 63 is used to scan the laser light from the laser 65 by applying the laser light from the laser 65 to the colored surface via the reflecting mirror 67 and the half mirror 69. The light reflected from the colored surface is made incident on the photoelectric converter 71 via the half mirror 69 to be converted into an electric signal. If the gate circuits 73, 75, and 77 are controlled to open and close in synchronization with the signal from the scanning signal generator 63, the gate circuits 73, 75, and 77 are controlled to open and close in synchronization with the pattern of the fine filter. , C can be obtained without Y, M, C signals.

In the case where the color image is divided into three planes as described later, the signals of Y, M, and C can be obtained in exactly the same manner. In this case, the Y, M, and C signals need not be colored. The same is true.

In the electrostatic potential detection method shown in FIGS. 17 and 18,
It is necessary that the toner image has a γ characteristic corresponding to the charge amount of the electrostatic latent image. Therefore, it is necessary that the toner image does not have a threshold value for an analog change of the charge amount. As long as the measures are taken, even if the γ characteristics do not match, γ may be corrected by electrical processing.

Next, a color filter used for forming a color image will be described.

FIG. 19 is a diagram showing a color separation optical system using a prism. In the figure, 31, 33, and 35 are prism blocks, 37, 39, and 41 are filters, and 43 and 45 are reflection mirrors.

The color separation optical system is composed of three prism blocks. Light information incident from the a surface of the prism block 31 is partially reflected and reflected on the b surface, further reflected on the a surface, and a B color light component is extracted from the filter 37. It is. The remaining light information enters the prism block 33, proceeds to the c-plane, and is partially reflected, and the G color light component passes from the filter 39 and the other goes straight to extract the R color light component from the filter 41. And
The G, B light components are reflected by the reflecting mirrors 43, 45, so that the R, G, B light can be extracted as parallel light.

By arranging such a filter 51 in front of the photoreceptor 1 as shown in FIG. 20 and photographing, the filter 51 shown in FIG.
1 set for 3 sets of charge-retaining medium that has been decomposed into R, G,
Frames can be formed or, as shown in FIG. 20 (c), R, G and B images can be arranged on one plane to form one frame in one set.

FIG. 21 is a diagram showing an example of a fine color filter.For example, a resist-coated film is exposed with a mask pattern to form an R, G, B stripe pattern, and formed by dyeing R, G, B respectively. 19, or a method in which the light separated by the method as shown in FIG. 19 is formed by recording the R, G, B interference fringes generated by passing the light through a narrow slit on a hologram recording medium, or photoconductive. A method in which an R, G, B stripe pattern based on an electrostatic latent image is formed by bringing a mask into close contact with the body to form an R, G, B stripe pattern. Is formed. One pixel is formed by a set of R, G, and B of the filter formed by such a method, and one pixel is made as fine as about 10 μm. By using this filter as the filter 51 in FIG. 20, a color electrostatic latent image can be formed. In this case, the filter may be arranged separately from the photoconductor, or may be formed integrally with the photoconductor.

FIG. 22 is a diagram showing an example in which a fine color filter and a Fresnel lens are combined, and R, G, B
The pattern can be recorded in a reduced size, and a thin and compact lens can be designed as compared with a normal lens.

Figure 23 shows the ND (Neutral Densitvy) filter and R, G,
FIG. 4 is a diagram showing an example of three-plane division using a B filter together, where incident light is divided into three by ND filters 81 and 83 and a reflection mirror 85;
R, G, and B light can be extracted as parallel light by passing through the R filter 87, the G filter 89, and the B filter 91, respectively.

[Action]

The present invention records image information as an electrostatic latent image by exposing with a voltage applied between a photoconductor and a charge holding medium, optically modulates light with audio information, and applies the modulated information light to the photoconductor. By irradiating the image information, audio information can be recorded together with the image information.In addition, the sound quality is improved by recording the PCM-modulated audio information. The sound before and after can be recorded, and the atmosphere at the time of recording can be understood.

 Hereinafter, examples will be described.

Example 1 Method for Producing a Charge Retaining Medium To a mixed solution having a composition of 10 g of methylphenylsilicone resin and 10 g of xylene-butanol 1: 1 solvent, 1% by weight of a curing agent (metal catalyst): trade name CR-15 (0.2 g), and the mixture was stirred well, and coated on a glass substrate on which Al was deposited at 1000 ° using a doctor blade 4 mil. Then 15
Drying was performed at 0 ° C. for 1 hour to obtain a charge holding medium (a) having a film thickness of 10 μm.

In addition, the above mixed solution was coated on a 100 μm polyester film on which Al was deposited at 1000 ° in the same manner, and then dried to obtain a film-shaped charge holding medium (b).

The above mixed solution was spin-coated on a 4-inch disk-shaped acrylic (1 mm thick) substrate on which Al was vapor-deposited at 1000 °
And dried at 50 ° C. for 3 hours to obtain a disk-shaped charge holding medium (c) having a thickness of 7 μm.

Further, 0.1 g of zinc stearate was further added to the above mixed solution, and the same coating and drying were performed to obtain a charge retaining medium (d) having a film thickness of 10 μm.

Example 2 A mixed solution having a composition of 10 g of a polyimide resin and 10 g of N-methylpyrrolidone was spin-coated (1000 rpm, 20 seconds) on a glass substrate on which Al was deposited at 1000 °. After pre-drying at 150 ° C for 30 minutes to dry the solvent,
It was heated at 350 ° C. for 2 hours for curing. A uniform coating having a thickness of 8 μm was formed.

Example 3 Method for producing single-layer organic photoreceptor (PVK-TNF) 10 g of poly-N-vinyl carbazole (Anan Kofu Co., Ltd.)
Manufactured), 2,4,7-trinitrofluorenone 10 g, polyester resin 2 g (binder: Byron 200 Toyobo Co., Ltd.)
A mixed solution having a composition of 90 g of tetrahydrofuran (THF) was prepared in a dark place, and a doctor blade was applied to a glass substrate (1 mm thick) on which In ₂ O ₃ -SnO ₂ was sputtered to a thickness of about 1000 mm. It was then applied and dried by ventilation at 60 ° C. for about 1 hour to obtain a photosensitive layer having a photoconductive layer having a thickness of about 10 μm. In order to dry completely, it was further dried naturally for one day before use.

Example 4 Method for Producing Amorphous Silicon aSi: H Inorganic Photoreceptor Substrate Cleaning Corning 7059 glass (23 × 16 × 0.9 t, optically polished) provided with a thin transparent electrode layer of SnO ₂ on one surface. In each of the trichloroethane, acetone and ethanol solutions, ultrasonic cleaning is performed for 10 minutes each in this order.

Preparation of Apparatus The cleaned substrate is placed in the anode 2 in the reaction chamber 204 shown in FIG.
After setting so that the heat conduction is sufficient on 06, the reaction chamber was evacuated by DP to a level of 10 ^-5 Torr, and the reaction vessel and gas pipe were baked out at 150 ° C. to 350 ° C. for about 1 hour. After baking out, cool the device.

a. Deposition of Si: H (n ⁺ ) Adjust the heater 208 so that the temperature of the glass substrate is 350 ℃,
Heated and premixed in tank 201 PH ₃ / SiH ₄ = 1
After controlling the number of rotations of the needle valve and the PMB so that the internal pressure of the reaction chamber 204 becomes 200 mTorr and the internal pressure becomes constant, a 40 W R f Power 202 (13.56 KHz) is passed through the matching box 203. ) To form a plasma between the cathode and the anode. The deposition is performed for 4 minutes, the supply of Rf is stopped, and the needle valve is closed.

As a result, about 0.2 μm
-A Si: H (n ⁺ ) film was deposited on the substrate.

a. Deposition of Si ・ H 100% SiH ₄ gas was flowed in the same manner as above to keep the internal pressure at 200 mTorr, and when the internal pressure became constant, Matchi
A 40 W Rf Power 202 (13.56 KHz) is supplied through the ng Box 203, and a plasma is formed and maintained for 70 minutes. When the deposition is completed, the supply of Rf is stopped, and the needle valve is closed. Heater20
After 8 Off, take out the board because it is cold.

As a result, a film of about 18.8 μm was deposited on the a.Si:H(n ⁺ ) film.

Thus, SnO ₂ / a · Si · H (n ⁺ ) blocking layer / a · S
A photoreceptor of i: H (non-dope) 20 μm could be produced.

Example 5 Method for Producing Amorphous Selenium-Tellurium Inorganic Photoreceptor An a-Se-Te thin film was formed by vapor deposition using metal particles in which selenium (Se) was mixed with tellurium (Te) at a ratio of 13% by weight. Was deposited on an ITO glass substrate by a resistance heating method at a degree of vacuum of 10 ⁻⁵ Torr. The film thickness was 1 μm. Further, while maintaining the degree of vacuum, vapor deposition of only Se was similarly performed by the resistance heating method to perform a-Se.
A 10 μm a-Se layer was laminated on the -Te layer.

Example 6 Method for Producing a Function-Separated Type Photoreceptor Method for Forming (Charge Generation Layer) A mixed solution having a composition of 0.4 g of chlorodian blue and 40 g of dichloroethane was placed in a 250 ml stainless steel container.
Further, 180 ml of glass beads No. 3 is added, and crushed for about 4 hours by a vibration mill (KED9-4, Yaskawa Electric Seisakusho) to obtain chlorocyan blue having a particle size of 5 μm. After filtering the glass beads, 0.4 g of polycarbonate and Iupilone E-2000 (Mitsubishi Gas Chemical) is added and stirred for about 4 hours. In this solution
₂ O ₃ -SnO ₂ to about 1000Å sputtered glass substrate (1mm
Thickness) using a doctor blade to a thickness of about 1 μm
Was obtained. Drying was performed at room temperature for one day.

(Formation method of charge transport layer)

A mixture having a composition of 0.1 g of 4-dibenzylamino-2-methylbenzaldehyde-1,1'-diphenylhydrazone, 0.1 g of polycarbonate (Iupilone E-2000) and 2.0 g of dichloroethane was charged with a doctor blade to the above-mentioned charge generating layer. Coating on top to obtain a charge transport layer of about 10 μm. Drying was performed at 60 ° C. for 2 hours.

[Example 7] (Method of forming charge generation layer) Butyral resin (Sekisui Chemical, SLEC) in 10 g of butyl acetate
0.25 g, azulhenium ClO ₄ salt having the following structural formula, 0.5 g, glass beads No., 133 g were mixed, stirred for 1 day with a touch mixer, well dispersed and then laminated on a glass plate with a doctor blade or applicator.
It was applied on O and dried at 60 ° C. for 2 hours or more. The film thickness after drying is 1 μm or less.

(Method of forming charge transport layer) In 9.5 g of tetrahydrofuran, 0.5 g of polycarbonate (Mitsubishi Gas Chemical, Iupilon E-2000) and a hydrazone derivative represented by the following structural formula (Anan fragrance, CTC191) Then, the mixture was mixed with 0.5 g and applied on the charge generating layer with a doctor blade, and dried at 60 ° C. for 2 hours or more. 10 μm thick
It was below.

[Example 8] (Method of forming charge generation layer) In 20 g of tetrahydrofuran, 0.5 g of butyral resin (Sekisui Chemical, SLEC), 0.25 g of titanyl phthalocyanine, 4.10
-0.25 g of dibromoanthranthrone, glass beads No. 1
Was stirred for 1 day with a touch mixer, and the mixture was well dispersed and applied to ITO laminated on a glass plate with a doctor blade or an applicator, and dried at 60 ° C. for 2 hours or more. The dried film had a thickness of 1 μm or less.

(Preparation method of charge transport layer) In 9.5 g of dichloroethane, 0.5 g of polycarbonate (Mitsubishi Gas Chemical, Iupilon E2000) and 0.5 g of the above hydrazone derivative (Anan fragrance, CTC191) were dissolved, and the above-mentioned charge generation layer was placed on the charge generation layer with a doctor blade. The coating was performed and dried at 60 ° C. for 2 hours or more. The film thickness was 10 μm or more.

[Example 9] ... Method of producing a function-separated type photoreceptor provided with a charge injection preventing layer (Method of forming charge injection preventing layer) Soluble polyamide (Toa Gosei Chemical, FS-175SV10) on ITO laminated on a glass plate 0.5 by spin coater
１1 μm coating, dried at 60 ° C. for 2 hours or more.

(Formation method of charge generation layer) Butyral resin (Sekisui Chemical, SLEC) in 10 g of butyl acetate
0.25 g, the above-mentioned azulhenium ClO ₄ salt 0.5 g, and glass beads No. 133 g were mixed, stirred for 1 day with a touch mixer, and dispersed well, and then applied onto the above-mentioned charge injection preventing layer with a doctor blade or an applicator. , 60 ℃, 2
Dried for more than an hour. The dried film had a thickness of 1 μm or less.

(Method of forming charge transport layer) In 9.5 g of tetrahydrofuran, 0.5 g of polycarbonate (Mitsubishi Gas Chemical, Iupilon E2000) and 0.5 g of the above-mentioned hydrazone derivative (Anan Perfume, CTC191) are dissolved, and the above-mentioned charge generation layer is placed on the charge generation layer with a doctor blade. It was applied and dried at 60 ° C. for 2 hours or more. The film thickness was 10 μm or less.

Example 10 (Method for Forming Charge Injection Prevention Layer) Soluble polyamide (Toa Gosei Chemical Co., FS-175SV10) was applied on ITO laminated on a glass plate by a spin coater for 0.5 minute.
１1 μm coating, dried at 60 ° C. for 2 hours or more.

(Method of forming charge generation layer) 20 g of tetrahydrofuran was added to 0.5 g of butyral resin (Sekisui Chemical, SLEC), 0.25 g of titanyl phthalocyanine, 4.10
-0.25 g of dibromoanthranthrone, glass beads No. 1
Was stirred with a touch mixer for 1 day, and the resulting mixture was well dispersed and applied to the charge injection preventing layer with a doctor blade or an applicator and dried at 60 ° C. for 2 hours or more. The dried film had a thickness of 1 μm or less.

(Method of forming charge transport layer) In 9.5 g of dichloroethane as a solvent, 0.5 g of polycarbonate (Mitsubishi Gas Chemical, Iupilon E2000) and 0.5 g of the above-mentioned hydrazone derivative (Anan fragrance, CTC191) are dissolved, and the above-mentioned charge generation is performed with a doctor blade. It was applied on the layer and dried at 60 ° C. for 2 hours or more. The film thickness was 10 μm or more.

Example 11 (Method of forming photoconductor electrode layer) Indium tin oxide (ITO, specific resistance 100
Ω · cm ² ) was deposited by a sputtering method.

 In addition, vapor deposition can be similarly performed by the EB method.

(Method of Forming Charge Injection Prevention Layer) On the photoreceptor electrode layer, silicon dioxide was deposited by a sputtering method.

The film thickness can be 100 to 3000 °, aluminum oxide may be used instead of silicon dioxide, and vapor deposition can be similarly performed by an EB method instead of a sputtering method.

(Method of forming charge generation layer) Selenium-tellurium (tellurium content: 13% by weight) was deposited on the charge injection preventing layer by resistance heating. The film thickness is 2
μm or less.

(Method of Forming Charge Transport Layer) Granular selenium was deposited on the charge generation layer by a resistance heating method. The film thickness is 10 μm or less.

[Example 12] ... Method for preparing thermal electret Vacuum evaporation (10 μm) on a 20 μm polyvinylidene fluoride film
^An electrostatic latent image is formed together with the photoconductive photoreceptor of the function-separated type photoreceptor by using a charge-retention medium that has been formed by depositing Al at 1000 ° C. by ^-6 Torr (resistance heating method).

First, a hot plate (3
× 3 cm) and heat the medium to 180 ° C. Immediately after heating, the photoreceptor was exposed to the charge holding medium by applying a voltage of -550 V between the electrodes (the photoreceptor electrode was made negative) with the surfaces facing each other with an air gap of 10 μm. Exposure was performed for 1 second from the back of the photoreceptor through a character pattern original at 10 lux using a halogen lamp as a light source.

Thereafter, the film was naturally cooled. As a result, a potential of -150 V was measured in the exposed portion (character portion), and no potential was measured in the unexposed portion. After a water drop was dropped on the film on which the charged pattern was formed and collected, the potential was measured. As a result, a potential of -150 V was measured in the exposed portion as before. On the other hand, a charge of -150 V was forcibly formed on the surface of the same charge holding medium by corona discharge, and a water drop was dropped and collected. As a result, the exposed portion which initially showed -150 V was 0 V and the charge was completely lost. Therefore, it was found that polarization was generated inside the polyvinylidene fluoride during electrification under heating, and the film was electretized.

Example 13 Method for Producing Optical Electret Al was laminated on a glass support having a thickness of 1.1 mm by a sputtering method of about 1000 ° to form a substrate, and zinc sulfide was deposited on the Al layer to a thickness of about 1.5 μm ( 10 ^-5 Torr, resistance heating). On this zinc sulfide layer surface, an ITO surface laminated on glass was provided with an air gap of 10 μm and opposed to each other.
With the voltage applied (to make the Al electrode side negative),
Exposure was performed from the substrate side. Exposure was performed in the same manner as in Example 11. As a result, a potential of +80 V is measured at the exposed portion,
No potential was measured in the unexposed area. In this case as well, a water droplet experiment similar to that of Example 11 was performed, but there was no change in the potential after the collection, and an electret in which charges were accumulated was formed inside.

Example 14 Single-Layer Organic Photoconductor (PVK-TNF) of Example 3, Example 1
(A) The charge holding medium and a glass substrate are used, and they are set on a camera with the electrode side facing out. At that time, in order to provide a gap between the photoconductor 1 and the charge holding medium 3,
As shown in FIG. 25, a 10 μm polyester film is disposed as a spacer 2 around the periphery other than the exposed surface.

The voltage is set with the photoconductor electrode side negative and the charge holding medium side positive.
700V is applied, and in that state, the optical shutter is released at an exposure f = 1.4 and a shutter speed of 1/60 second, or the exposure f
= 1.4, voltage is applied for 1/60 seconds with the shutter open,
The subject was photographed outdoors during the daytime.

After the exposure is turned off and the voltage is turned off, place the charge holding medium in a bright place,
Alternatively, it was taken out in a dark place, and a CRT image was formed by a micro area potential reading method, and an image was formed by a toner phenomenon.

Then, a 100 × 100 μm micro area surface potential measurement probe was scanned on the XY axis, potential data was processed in units of 100 μm, and an image was formed on a CRT by potential-luminance conversion. An analog potential latent image was formed on the charge holding medium from the highest exposed portion potential of 200 V to the unexposed portion 0 V, and the latent image could be visualized on a CRT with a resolution of 100 μm.

Then, the positive charge image was obtained by immersing the removed charge holding medium in the negatively charged wet toner (black) for 10 seconds. The resolution of the obtained toner image was a high resolution of 1 μm.

 The photographing of the color image was performed by the following method.

Prism-type three-plane splitting method As shown in FIG. 20, R, G, and B filters are arranged on three faces of a prism, and the above-described medium is set on each face, and f
The subject was photographed at a shutter speed of 1/30 sec. = 1.4.

Color CRT display method Each of the R, G, B latent images is scanned and read in the same manner, and a fluorescent color corresponding to the R, G, B latent image is formed on the CRT,
A color image was obtained by synthesizing the three-color separated image on a CRT.

Toner Development Method The charge-holding medium that has been separated and exposed is developed with C (cyan), M (magenta), and Y (yellow) toners negatively charged with respect to the R, G, and B latent images, respectively, to form toner images. Before the toner dries, plain paper is overlaid on the medium on which the cyan toner image is formed, and positive corona charging is performed on the paper. Thereafter, when peeling was performed, the toner image was transferred to plain paper. Further, when the positions of the images were matched by the same method and the magenta toner and the yellow toner were sequentially transferred and synthesized at the same location, a color image was formed on plain paper.

〔The invention's effect〕

As described above, according to the present invention, audio information can be recorded simultaneously with the recording of a still image. In particular, by recording the sound before and after the still image recording, the atmosphere at the time of recording can be understood so that the still image can be recorded. It is possible to give a sense of power, and it is possible to make the camera multifunctional.

[Brief description of the drawings]

FIG. 1 is a view for explaining a charge holding medium used in the present invention, FIG. 2 is a view for explaining the principle of an electrostatic latent image recording method using an optical electret, and FIG. FIG. 4 is a diagram for explaining the principle of the electrostatic latent image recording method used, FIG. 4 is a diagram showing a configuration of an electrostatic camera having a voice information input function of the present invention, and FIG. 5 is a book using PCM modulation. FIG. 6 is a diagram showing another embodiment of the present invention, FIG. 6 is a diagram showing another embodiment of the present invention in which sound is recorded for a fixed time, FIG.
8 and 9 are diagrams showing examples of a DC amplification type potential reading method, FIG. 10, FIG. 11, and FIG. 12 are diagrams showing examples of an AC amplification type potential reading method, FIG. FIG. 14 is a diagram showing an example of a potential reading method by a CT scanning method, FIG. 15 is a diagram showing an example of a current collecting type potential reading method, and FIG. 16 is a diagram showing an example of an electron beam type potential reading method 17 and 18 are diagrams for explaining a potential reading method using toner coloring, FIG. 19 is a diagram showing a configuration of a color separation optical system, and FIG. 20 is a diagram for forming a color electrostatic latent image. FIG. 21 is a diagram showing an example of a fine color filter, FIG. 22 is a diagram showing an example in which a fine color filter and a Fresnel lens are combined, FIG.
Figure 23 shows 3 using the ND filter and R, G, B filters together.
FIG. 24 is a view showing surface division, FIG. 24 is a view for explaining a method of manufacturing an a-Si: H photosensitive member, and FIG. 25 is a view for explaining an example of photographing by an electrostatic camera to which the present invention is applied. It is. 101 microphone, 102 amplifier, 103 laser, 104 acousto-optic modulator, 105 polygon mirror,
106 ... Power supply.

Claims (3)

(57) [Claims] A voltage is applied between a photoreceptor in which an electrode and a photoconductive layer are laminated on a substrate and a charge holding medium in which an electrode and an insulating layer having a specific resistance of 10 ¹⁴ Ω · cm or more are laminated on the substrate. An electrostatic camera that records image information as an electrostatic latent image by irradiating light to the photoreceptor with the voltage applied, and optically modulates laser light with audio information and irradiates the modulated laser light to the photoreceptor An electrostatic camera having an audio information input function for recording audio information together with image information. 2. Modulation of laser light by voice information is performed by PCM.
2. The electrostatic camera according to claim 1, wherein the electrostatic camera is provided with a voice information input function. 3. An audio signal is A / D converted and stored in a circulating memory having a predetermined capacity, and a laser beam is optically modulated by an audio information output read out from the circulating memory and D / A converted, and before and after exposure of image information recording. 2. The electrostatic camera having an audio information input function according to claim 1, wherein audio information is recorded for a predetermined time.