JP2747757B2 - Cylindrical parts with ceramic sleeves - Google Patents
Cylindrical parts with ceramic sleevesInfo
- Publication number
- JP2747757B2 JP2747757B2 JP4202826A JP20282692A JP2747757B2 JP 2747757 B2 JP2747757 B2 JP 2747757B2 JP 4202826 A JP4202826 A JP 4202826A JP 20282692 A JP20282692 A JP 20282692A JP 2747757 B2 JP2747757 B2 JP 2747757B2
- Authority
- JP
- Japan
- Prior art keywords
- cylinder
- ceramic
- cylindrical
- sleeve
- outer cylinder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Ceramic Products (AREA)
- Laminated Bodies (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は円筒部品内面が耐摩耗
性、耐食性等を要求されるようなシリンダ、例えばプラ
スチック、セラミックス、フェライトまたは希土類磁石
等の成形に用いられる射出・押出成形機に装着されるシ
リンダのような円筒部品の改良に関するものであり、特
に金属材料からなる外筒内にセラミックス材料からなる
円筒を嵌着してなる円筒シリンダで使用時に加熱・冷却
される用途におけるセラミックス複合部品の改良に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is applied to a cylinder in which the inner surface of a cylindrical part is required to have wear resistance, corrosion resistance, etc., for example, an injection / extrusion molding machine used for molding plastic, ceramics, ferrite or rare earth magnets. The present invention relates to the improvement of cylindrical parts such as cylinders, particularly ceramic composite parts in applications where a cylindrical cylinder made of a ceramic material is fitted into an outer cylinder made of a metallic material and heated and cooled during use. Regarding improvement.
【0002】[0002]
【従来の技術】例えばプラスチック成形機等に用いられ
る円筒状シリンダの内面は、前記シリンダに内装される
スクリューがシリンダ内を摺動・回転する際に、成形さ
れる樹脂または樹脂に加えられる硬質添加剤・ガラス繊
維などの強化材等による摩耗や腐食を生じるうえ、シリ
ンダ成分が成形材料中へ混入するという問題がある。こ
のような問題点に対し、円筒状シリンダ内面に耐摩耗性
・耐食性・耐熱(耐熱衝撃)性に優れているセラミック
スからなるライナーを装着したシリンダが検討されてい
る。この場合、セラミックスは金属材料に比較し、極め
て優れた耐摩耗性・耐食性を有するものの、反面極めて
脆いという欠点を有しているため、前記のように、プラ
スチック成形機等のシリンダ内面に適用するにあたっ
て、成形時の成形内圧、スクリューとの接触等により該
セラミックスが破損するのを防止する目的として、例え
ば特開昭64−53825号公報に開示があるように、
焼き嵌め等によって外周部を炭素鋼等で補強した複合構
造部品が用いられている。2. Description of the Related Art For example, the inner surface of a cylindrical cylinder used in a plastic molding machine or the like is formed of a resin or a hard additive added to the resin when a screw provided in the cylinder slides and rotates in the cylinder. In addition to abrasion and corrosion caused by reinforcing agents such as agents and glass fibers, there is a problem that cylinder components are mixed into the molding material. In response to such problems, a cylinder in which a liner made of ceramics having excellent wear resistance, corrosion resistance, and heat resistance (thermal shock resistance) is mounted on the inner surface of a cylindrical cylinder is being studied. In this case, ceramics have extremely excellent wear resistance and corrosion resistance as compared with metal materials, but have the disadvantage that they are extremely brittle, but as described above, they are applied to the inner surface of a cylinder of a plastic molding machine or the like. For the purpose of preventing the ceramic from being damaged by molding internal pressure during molding, contact with a screw, etc., for example, as disclosed in JP-A-64-53825,
A composite structural part whose outer peripheral portion is reinforced with carbon steel or the like by shrink fitting or the like is used.
【0003】[0003]
【発明が解決しようとする課題】しかし、前記の事前に
焼き嵌め等を施して外筒の金属でセラミックスを保持さ
せた構造のセラミックス複合シリンダをプラスチック成
形機等に用いる場合、成形(使用)温度が200℃〜4
00℃にもなるため、金属材料からなる外筒とセラミッ
クス材料からなる内筒との間の熱膨張率の違いにより、
軸方向の伸びの差を生じ両者の接触面の摩擦力により内
筒に軸方向の引張り応力が作用し円周方向のクラックを
発生するという問題点がある。また、内筒に作用させる
圧縮応力は、成形機用シリンダとして使用状態で発生す
る内圧に対する圧縮応力と、加熱時の外筒と内筒の熱膨
張率の違いによる圧縮応力の減少分を確保する必要があ
り、非常に大きな焼き嵌め代を付加することになる。こ
のため、セラミックス複合シリンダの加熱・冷却を繰り
返すと両者の接触面で焼き付きが発生する場合がある。
この焼き付きが発生すると軸方向の伝達力は極端に大き
くなるため、円周方向のクラック発生に至るという問題
になる。However, when a ceramic composite cylinder having a structure in which ceramics are held by metal of the outer cylinder by performing shrink fitting or the like in advance as described above is used for a plastic molding machine or the like, the molding (use) temperature is increased. Is 200 ℃ ~ 4
Because of the temperature rise to 00 ° C, the difference in the coefficient of thermal expansion between the outer cylinder made of a metal material and the inner cylinder made of a ceramic material,
There is a problem that a difference in elongation in the axial direction is caused, and a tensile force in the axial direction acts on the inner cylinder due to the frictional force between the contact surfaces of the two to generate cracks in the circumferential direction. Further, the compressive stress applied to the inner cylinder secures a compressive stress with respect to the internal pressure generated in a state of use as a molding machine cylinder and a decrease in the compressive stress due to a difference in thermal expansion coefficient between the outer cylinder and the inner cylinder during heating. Need to add a very large shrink fit. For this reason, when heating and cooling of the ceramic composite cylinder are repeated, seizure may occur on the contact surface between them.
When this seizure occurs, the transmission force in the axial direction becomes extremely large, which causes a problem that cracks occur in the circumferential direction.
【0004】そのためこれを防止する方法として、従
来、加熱・冷却による影響を小さくする方法の一つとし
て、金属材料からなる外筒材の選択にあたってその熱膨
張率をセラミックス材料よりなる内筒材の熱膨張率に近
づけることがなされており、例えば、実開昭61−47
043号公報に開示があるように、コバール(主成分2
8〜29%Ni−17〜18%Co−Fe系合金)、ア
ンバー(主成分36〜52%Ni−Fe系合金)等が、
また実開平4−450号公報にはTi系合金、例えばT
i−6Al−4V合金といった低熱膨張合金が適用され
ている。しかし、この方法で適用できるセラミックスと
同等の低熱膨張率の金属材料は、いずれも素材入手が困
難で高価な材料となると同時に、炭素鋼等と比較すると
加工性が悪く、一般的に工業用途には適さないものであ
る。[0004] Therefore, as a method for preventing this, conventionally, as one of the methods for reducing the influence of heating and cooling, when selecting an outer cylinder made of a metal material, the coefficient of thermal expansion of the outer cylinder made of a ceramic material is reduced. The coefficient of thermal expansion has been approached.
No. 043, Kovar (main component 2)
8-29% Ni-17-18% Co-Fe alloy), Amber (36-52% Ni-Fe alloy).
Japanese Utility Model Laid-Open No. 4-450 discloses a Ti-based alloy such as T
A low thermal expansion alloy such as an i-6Al-4V alloy is applied. However, any metal material having a low coefficient of thermal expansion equivalent to ceramics that can be applied by this method is difficult to obtain and is expensive, and at the same time, has poor workability compared to carbon steel, etc., and is generally used for industrial applications. Is not suitable.
【0005】一方、金属材料よりなる外筒に空隙を設け
て冷却し、外筒の温度をセラミックス材料よりなる内筒
の温度より低く保つことで同等の効果を得ることが考え
られるが、両者は焼き嵌めにより密着しているため、セ
ラミックス内筒の温度も下がる結果となり、成形材料毎
の混練や成形のための適切な温度保持が困難となり、混
練不足や成形不良を生じる結果となる。本発明は上記問
題点、課題を解決するためのもので、内層がセラミック
スから構成されるとともに外層部分が金属製である円筒
部品で、加熱・冷却される場合でもクラック等の発生を
防止することのできる健全なセラミックス内装円筒部品
を提供することを目的とするものである。On the other hand, it is conceivable that the same effect can be obtained by providing a gap in the outer cylinder made of a metal material and cooling it to keep the temperature of the outer cylinder lower than the temperature of the inner cylinder made of the ceramic material. Because of the close contact by shrink fitting, the temperature of the ceramic inner cylinder also decreases, and it becomes difficult to knead each molding material and maintain an appropriate temperature for molding, resulting in insufficient kneading and molding failure. The present invention has been made to solve the above problems and problems, and is a cylindrical part in which an inner layer is made of ceramics and an outer layer part is made of metal, which prevents cracks and the like even when heated and cooled. It is an object of the present invention to provide a ceramic interior cylindrical part that can be manufactured.
【0006】[0006]
【課題を解決するための手段】本発明は、金属製円筒ス
リーブの内側にセラミックス材料により円筒状に形成し
た内筒を焼き嵌め保持する複合円筒部品において、金属
製円筒スリーブの内面全長に硬質クロムメッキした後、
金属製円筒スリーブとセラミックス材料による内筒の間
の全長に潤滑材を配したことを特徴とするセラミックス
スリーブを内装した円筒部品にある。 SUMMARY OF THE INVENTION The present invention relates to a metal cylindrical sleeve.
A cylindrical shape made of ceramic material inside the leave
The composite cylindrical part that shrink-fits and holds the inner cylinder
After hard chrome plating the entire length of the inner surface of the cylindrical sleeve,
Between a metal cylindrical sleeve and a ceramic material inner cylinder
Characterized by lubricating material all over the length of the ceramic
It is in a cylindrical part with a sleeve inside.
【0007】[0007]
【作用】金属材料からなる外筒とセラミックスからなる
内筒間に配した潤滑材は、両者の接触面の摩擦力を軽減
しセラミックスに発生する引張り応力を下げると同時
に、焼き付きを防止する上でも大きな効果を発揮するの
である。[Function] The lubricating agent disposed between the outer cylinder made of metal material and the inner cylinder made of ceramic reduces the frictional force between the contact surfaces of the two, lowers the tensile stress generated in the ceramic, and also prevents seizure. It has a great effect.
【0008】[0008]
【実施例】以下、実施例により本発明を具体的に説明す
る。図1はこの発明の実施例を示す断面図である。図1
(a),(b)において内筒2はサイアロンセラミック
スにより中空円筒状に形成する。次に1は外筒であり、
内筒2に最適な圧縮応力を与えられるような寸法・形状
とした中空円筒状に形成し、内筒2を焼き嵌めにより嵌
着する。尚、加熱雰囲気での潤滑状態をより健全に維持
するために、事前に外筒内面に硬質クロムメッキ3を施
して使用した。このメッキ層に軟質層、例えば銅メッキ
層を用いると潤滑性が低下する結果となり好ましくな
い。焼き嵌めに際し、外筒1の加熱前に外筒1の内周面
および内筒2の外周面それぞれにBN(ボロンナイトラ
イド)粉末をスプレー状に噴霧し、表面に潤滑層4を形
成させた後施工する。シリンダ材料として使用する場合
の焼き嵌め率は、成形機使用温度、使用圧力に耐え得る
圧縮応力を付加するに必要な締め代を採用して実施す
る。また、セラミックスは衝撃に対して脆い欠点がある
ので、成形機用シリンダとして使用する場合において
は、摺動・回転するスクリューの接触により最も衝撃を
受け易い両端部の内面角部に面取りを施したものとし
た。The present invention will be described below in detail with reference to examples. FIG. 1 is a sectional view showing an embodiment of the present invention. FIG.
1A and 1B, the inner cylinder 2 is formed in a hollow cylindrical shape using sialon ceramics. Next, 1 is an outer cylinder,
The inner cylinder 2 is formed in a hollow cylindrical shape having a size and a shape capable of giving an optimal compressive stress, and the inner cylinder 2 is fitted by shrink fitting. In order to maintain the lubrication state in the heating atmosphere sounder, the inner surface of the outer cylinder was previously subjected to hard chrome plating 3 before use. If a soft layer, for example, a copper plating layer is used as the plating layer, the lubricating property is reduced, which is not preferable. At the time of shrink fitting, BN (boron nitride) powder was sprayed onto each of the inner peripheral surface of the outer cylinder 1 and the outer peripheral surface of the inner cylinder 2 before heating the outer cylinder 1 to form a lubricating layer 4 on the surface. After construction. The shrink-fitting ratio when used as a cylinder material is determined by using a tightening margin necessary to add a compressive stress that can withstand the operating temperature and operating pressure of the molding machine. In addition, since ceramics have the disadvantage of being brittle against impact, when used as a cylinder for molding machines, chamfering was applied to the inner corners of both ends where the impact was most likely to be impacted by the contact of the sliding and rotating screw. It was taken.
【0009】上記の構成による押出成形機用シリンダを
種々製作し加熱・冷却試験した結果を表1に示す。加熱
温度はアルミナで250℃、サイアロンで300℃と
し、少なくとも10回以上加熱・冷却の繰り返しを行っ
た。表1より明らかなように本発明品は、潤滑処理を施
さないで嵌着・製作した従来品のシリンダで発生してい
た円周方向のクラックの防止に大きな効果を発揮するこ
とが確認できた。Table 1 shows the results of heating and cooling tests of various types of extruder cylinders manufactured as described above. The heating temperature was 250 ° C. for alumina and 300 ° C. for Sialon, and heating and cooling were repeated at least 10 times or more. As is clear from Table 1, it was confirmed that the product of the present invention exerts a great effect in preventing circumferential cracks which occurred in the conventional cylinder fitted and manufactured without performing lubrication treatment. .
【0010】[0010]
【表1】 [Table 1]
【0011】更に、表1中のセラミックス内径φ90、
サイアロン製シリンダを図2に示す押出成形機に装着し
て、成形温度250℃〜300℃で成形試験した結果、
潤滑処置を施さないで嵌着・製作した場合のシリンダで
発生していた加熱時の円周方向のクラックを防止すると
ともに、特に高温で成形される場合において、加熱され
たセラミック内装シリンダ7へ常温のスクリュー8を挿
入する際にセラミックス内筒2に生じる温度勾配(熱衝
撃)等によるクラックの発生もないことを確認した。ま
た、セラミックス角部を面取りしたことにより、挿入・
回転するスクリュー8とセラミックス内面角部との衝突
を防止し、端面角部の欠け等も全く発生しないことを確
認した。このセラミックス内装円筒部品を、例えばプラ
スチック成形機用シリンダとして適用する場合には、角
部の欠け発生を防止するためセラミックス端面角部に
0.1〜1.0mmの面取りを施すことが望ましい。な
お図2に示す符号5はホッパー、6はホッパー口シリン
ダ、9はバンドヒーター、10はダイである。Further, the ceramic inner diameter φ90 in Table 1
As a result of mounting a Sialon cylinder on the extruder shown in FIG. 2 and performing a molding test at a molding temperature of 250 to 300 ° C.,
In addition to preventing circumferential cracks at the time of heating that occurred in the cylinder when fitted and manufactured without performing lubrication treatment, and particularly when molded at a high temperature, the cylinder is heated to the heated ceramic interior cylinder 7 at room temperature. It was confirmed that there was no crack due to a temperature gradient (thermal shock) generated in the ceramic inner cylinder 2 when the screw 8 was inserted. In addition, the chamfered corners of the ceramic insert and insert
Collision between the rotating screw 8 and the inner surface corner of the ceramic was prevented, and it was confirmed that chipping of the end surface corner did not occur at all. When this ceramic interior cylindrical part is applied, for example, as a cylinder for a plastic molding machine, it is desirable to chamfer 0.1 to 1.0 mm to the corner of the ceramic end face in order to prevent chipping of the corner. 2, reference numeral 5 denotes a hopper, 6 denotes a hopper opening cylinder, 9 denotes a band heater, and 10 denotes a die.
【0012】以上、本願発明について実施例をあげた
が、セラミックス内装円筒部品を構成する材料として
は、使用時の温度域が300℃位の低温域においては、
セラミックス製ライナーはアルミナ、炭化珪素、窒化珪
素、サイアロン等の耐摩耗性、耐食性、耐熱(耐熱衝
撃)性を有したセラミックス材料を用い、鋼製外筒は炭
素鋼、クロム・モリブデン鋼等の一般鋼材を用いる。特
に300℃を越える高温域で使用する場合、セラミック
ス製ライナーはより耐熱衝撃性の高い窒化珪素、サイア
ロンを適用することが望ましい。潤滑層を形成させるた
めに用いる材料としては、内外層の嵌合に必要な施工温
度、例えば焼き嵌めの施工温度ならびにシリンダとして
の使用温度で潤滑効果を保持できる潤滑材、例えばボロ
ンナイトライド、グラファイト、二硫化モリブデン等が
好ましい。また、この潤滑材を外筒と内筒の接触面に保
持する目的で、図3に示すように、金属材料外筒1の内
周面に深さ10μm程度の螺旋状溝11を一条もしくは
数条、更に両端面から潤滑材が流出しないよう端面近傍
に周状溝12を設けることが望ましい。Although the embodiments of the present invention have been described above, the material constituting the ceramic interior cylindrical part is as follows.
The ceramic liner is made of ceramic material such as alumina, silicon carbide, silicon nitride, and sialon, which has wear resistance, corrosion resistance, and heat resistance (thermal shock resistance). The steel outer cylinder is made of carbon steel, chromium-molybdenum steel, etc. Use steel. In particular, when the ceramic liner is used in a high temperature region exceeding 300 ° C., it is desirable to apply silicon nitride and sialon having higher thermal shock resistance. Materials used for forming the lubricating layer include lubricating materials capable of maintaining a lubricating effect at a working temperature required for fitting the inner and outer layers, such as a shrink fitting working temperature and a use temperature as a cylinder, for example, boron nitride, graphite, and the like. And molybdenum disulfide are preferred. As shown in FIG. 3, a spiral groove 11 having a depth of about 10 μm is formed on the inner peripheral surface of the metallic material outer cylinder 1 in order to hold the lubricant on the contact surface between the outer cylinder and the inner cylinder. It is desirable to provide a circumferential groove 12 near the end face, and also near the end face so that the lubricant does not flow out from both end faces.
【0013】[0013]
【発明の効果】セラミックス材料からなる内筒に作用す
る成形(加熱)時の軸方向の引張り応力を極めて小なる
値とすることができ、内筒に発生する円周方向のクラッ
クの発生を防止することができる。また、使用する外筒
材料も炭素鋼等の安価な材料を用いることが可能であ
る。この結果、セラミックス材料本来の耐摩耗性、耐食
性等の諸特性を充分に発揮させることができ、例えば押
出成形機用スリーブの耐久性、成形製品の品質安定化、
製品歩留まり等の向上に著しく貢献し得るとともに、炭
素鋼等の金属材料を使用して安価に製作し得る点でも大
きな効果がある。According to the present invention, the tensile stress in the axial direction at the time of forming (heating) acting on the inner cylinder made of a ceramic material can be made extremely small, and the occurrence of circumferential cracks generated in the inner cylinder can be prevented. can do. Also, an inexpensive material such as carbon steel can be used as the outer cylinder material. As a result, various properties such as wear resistance and corrosion resistance inherent in ceramic materials can be sufficiently exhibited, for example, durability of an extruder sleeve, stabilization of molded product quality,
It can significantly contribute to the improvement of product yield and the like, and has a great effect in that it can be manufactured at low cost by using a metal material such as carbon steel.
【図1】本発明の実施例を示す破断面図および角部拡大
断面図、FIG. 1 is an exploded sectional view and an enlarged sectional view of a corner showing an embodiment of the present invention;
【図2】実施例の試験に用いた押出成形機シリンダの断
面形状、FIG. 2 is a cross-sectional view of an extruder cylinder used in the test of the embodiment.
【図3】潤滑材保持のための金属材料性外筒の溝加工例
を示す。FIG. 3 shows an example of groove processing of a metal material outer cylinder for holding a lubricant.
1 外筒 2 内筒 3 硬質クロムメッキ 4 潤滑材層 5 ホッパー 6 ホッパー口シリンダ 7 セラミックス内装シリンダ 8 スクリュー 9 バンドヒーター 10 ダイ 11 潤滑材保持用螺旋状溝 12 潤滑材保持用周状溝 DESCRIPTION OF SYMBOLS 1 Outer cylinder 2 Inner cylinder 3 Hard chrome plating 4 Lubricant layer 5 Hopper 6 Hopper port cylinder 7 Ceramic interior cylinder 8 Screw 9 Band heater 10 Die 11 Spiral groove for holding lubricant 12 Peripheral groove for holding lubricant
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI B32B 9/00 B32B 9/00 Z 15/04 15/04 18/00 18/00 (72)発明者 吉浦 潤一 福岡県北九州市戸畑区大字中原46−59 新日本製鐵株式会社 機械・プラント事 業部内 (56)参考文献 特開 平4−16569(JP,A) 特開 昭61−111981(JP,A) 特開 昭59−33128(JP,A) 実開 昭62−148701(JP,U)────────────────────────────────────────────────── ─── Continued on the front page (51) Int.Cl. 6 Identification symbol FI B32B 9/00 B32B 9/00 Z 15/04 15/04 18/00 18/00 (72) Inventor Junichi Yoshiura Kitakyushu, Fukuoka Prefecture 46-59 Nakahara, Tobata-ku Nippon Steel Corporation Machinery & Plant Business Department (56) References JP-A-4-16569 (JP, A) JP-A-61-111981 (JP, A) JP-A-59 −33128 (JP, A) Actually open 62-148701 (JP, U)
Claims (1)
ス材料により円筒状に形成した内筒を焼き嵌め保持する
複合円筒部品において、金属製円筒スリーブの内面全長
に硬質クロムメッキした後、金属製円筒スリーブとセラ
ミックス材料による内筒の間の全長に潤滑材を配したこ
とを特徴とするセラミックススリーブを内装した円筒部
品。 1. A ceramic sleeve inside a metal cylindrical sleeve.
Shrink-fitting and holding the inner cylinder formed of a cylindrical material
For composite cylindrical parts, the total inner length of the metal cylindrical sleeve
After hard chrome plating on the metal cylinder sleeve and ceramic
Lubricants are distributed over the entire length between the inner cylinders of the mixed material.
Cylindrical part with ceramic sleeve inside
Goods.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4202826A JP2747757B2 (en) | 1992-07-30 | 1992-07-30 | Cylindrical parts with ceramic sleeves |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4202826A JP2747757B2 (en) | 1992-07-30 | 1992-07-30 | Cylindrical parts with ceramic sleeves |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0648854A JPH0648854A (en) | 1994-02-22 |
| JP2747757B2 true JP2747757B2 (en) | 1998-05-06 |
Family
ID=16463833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4202826A Expired - Fee Related JP2747757B2 (en) | 1992-07-30 | 1992-07-30 | Cylindrical parts with ceramic sleeves |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2747757B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101439023B1 (en) * | 2013-04-30 | 2014-09-05 | 웅진에너지 주식회사 | Exhausted Sleeve for Ingot grower |
| CN107244056A (en) * | 2017-08-16 | 2017-10-13 | 成都米特瑞新材料科技有限公司 | Beneficial to the extrusion mechanism uniformly heated |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3427193A1 (en) * | 1984-07-17 | 1986-02-06 | Rhosdy Dipl.-Chem. Dr. 5000 Köln Ismail | Strengthened preparation for varicose veins |
| JPS61111981A (en) * | 1984-11-05 | 1986-05-30 | 株式会社豊田中央研究所 | How to join ceramic parts and metal parts |
| JP3270893B2 (en) * | 1990-05-10 | 2002-04-02 | 日本特殊陶業株式会社 | Combined structure of ceramic and metal |
-
1992
- 1992-07-30 JP JP4202826A patent/JP2747757B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0648854A (en) | 1994-02-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 19980113 |
|
| LAPS | Cancellation because of no payment of annual fees |