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JP2801462B2 - Superconducting magnetic sensor and method of manufacturing the same - Google Patents
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JP2801462B2 - Superconducting magnetic sensor and method of manufacturing the same - Google Patents

Superconducting magnetic sensor and method of manufacturing the same

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Publication number
JP2801462B2
JP2801462B2 JP4079587A JP7958792A JP2801462B2 JP 2801462 B2 JP2801462 B2 JP 2801462B2 JP 4079587 A JP4079587 A JP 4079587A JP 7958792 A JP7958792 A JP 7958792A JP 2801462 B2 JP2801462 B2 JP 2801462B2
Authority
JP
Japan
Prior art keywords
oxide superconducting
film
cylindrical member
substrates
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP4079587A
Other languages
Japanese (ja)
Other versions
JPH05281316A (en
Inventor
学 藤本
秀雄 野島
英隆 新宅
昌也 長田
正義 木場
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sharp Corp
Original Assignee
Sharp Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sharp Corp filed Critical Sharp Corp
Priority to JP4079587A priority Critical patent/JP2801462B2/en
Publication of JPH05281316A publication Critical patent/JPH05281316A/en
Application granted granted Critical
Publication of JP2801462B2 publication Critical patent/JP2801462B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Measuring Magnetic Variables (AREA)
  • Superconductor Devices And Manufacturing Methods Thereof (AREA)
  • Hall/Mr Elements (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】この発明は超電導磁気センサおよ
びその製造方法に関し、より詳しくは、結晶粒界を有
し、磁気抵抗効果を示す酸化物超電導膜によって構成し
た超電導磁気センサおよびその製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a superconducting magnetic sensor and a method of manufacturing the same, and more particularly, to a superconducting magnetic sensor formed of an oxide superconducting film having a crystal grain boundary and exhibiting a magnetoresistance effect, and a method of manufacturing the same. .

【0002】[0002]

【従来の技術】この種の超電導磁気センサとしては、本
出願人が先に提案したように、酸化物超電導膜(Y1Ba2
Cu37-x)を基板の片面にミアンダパターン状(つづら
折りの線状パターン)に形成したものがある(特願平2−
264682号に基づく優先権主張出願(特願平3−2
52509号))。この超電導磁気センサは、SQUID
(超電導量子干渉素子)に比して出力レベルが高く、簡単
な構成の信号処理システムでもって磁気を測定すること
ができる。その磁気検出感度(最小磁束分解能)は10-5
〜10-6ガウス(正確には、gauss/(Hz)1/2を単位とす
る。)であった。
2. Description of the Related Art As a superconducting magnetic sensor of this type, as previously proposed by the present applicant, an oxide superconducting film (Y 1 Ba 2
Cu 3 O 7-x ) is formed on one side of the substrate in a meander pattern (a zigzag linear pattern).
Priority Application based on No. 264682 (Japanese Patent Application No. 3-2)
52509)). This superconducting magnetic sensor is a SQUID
The output level is higher than that of the (superconducting quantum interference device), and the magnetism can be measured with a signal processing system having a simple configuration. Its magnetic detection sensitivity (minimum magnetic flux resolution) is 10 -5
(More precisely, gauss / (Hz) 1/2 and the unit.) 10-6 gauss was.

【0003】[0003]

【発明が解決しようとする課題】ところで、生体磁気、
特に心臓からの磁気を検出することは磁気センサの極め
て重要な用途であるが、生体磁気を検出しようとする場
合、10-7ガウスの磁気検出感度が必要とされる。この
ため、上記超電導磁気センサの磁気検出感度を高めるこ
とが要求されている。
By the way, biomagnetism,
In particular, detecting the magnetism from the heart is a very important application of the magnetic sensor, but when detecting biomagnetism, a magnetic detection sensitivity of 10 −7 gauss is required. Therefore, it is required to increase the magnetic detection sensitivity of the superconducting magnetic sensor.

【0004】そこで、この発明の目的は、高い磁気検出
感度を得ることができる超電導磁気センサおよびその製
造方法を提供することにある。
An object of the present invention is to provide a superconducting magnetic sensor capable of obtaining high magnetic detection sensitivity and a method for manufacturing the same.

【0005】[0005]

【課題を解決するための手段】上記目的を達成するた
め、この発明の超電導磁気センサは、互いに平行な複数
の基板面にそれぞれ線状に設けられ、磁気抵抗効果を示
す第1の酸化物超電導膜と、上記各基板面を貫通する円
筒状部材と、上記円筒状部材の表面を被覆し、上記各基
板面に設けられた第1の酸化物超電導膜を電気的に直列
に接続する第2の酸化物超電導膜を備えたことを特徴と
している。
In order to achieve the above object, a superconducting magnetic sensor according to the present invention is provided on a plurality of substrate surfaces parallel to each other in a linear manner and has a first oxide superconducting effect exhibiting a magnetoresistance effect. A film, a cylindrical member penetrating through the respective substrate surfaces, and a second member which covers the surface of the cylindrical member and electrically connects the first oxide superconducting films provided on the respective substrate surfaces in series. Characterized by having an oxide superconducting film of

【0006】また、上記第1の酸化物超電導膜は、複数
の基板の同一の向きの面にそれぞれ設けられ、上記円筒
状部材は周面を貫通する横穴を各基板の間に有し、この
横穴の端面を上記第2の酸化物超電導膜が被覆している
のが望ましい。
In addition, the first oxide superconducting film is provided on each of the plurality of substrates in the same direction, and the cylindrical member has a lateral hole penetrating the peripheral surface between the substrates. It is desirable that the end surface of the lateral hole be covered with the second oxide superconducting film.

【0007】また、上記第1の酸化物超電導膜は、2枚
の基板の互いに対向する面または互いに反対向きの面に
それぞれ設けられているのが望ましい。
It is preferable that the first oxide superconducting film is provided on the surface of the two substrates facing each other or on the surface facing each other.

【0008】また、上記第1の酸化物超電導膜は、1枚
の基板の両面にそれぞれ設けられているのが望ましい。
It is desirable that the first oxide superconducting film is provided on both surfaces of one substrate.

【0009】また、上記第1の酸化物超電導膜は、複数
の基板の両面にそれぞれ設けられ、上記円筒状部材は2
枚の基板の互いに対向する面を貫通する第1の円筒状部
材と、1枚の基板の両面を貫通する第2の円筒状部材と
を含み、上記第2の酸化物超電導膜は上記第1の円筒状
部材および第2の円筒状部材の表面をそれぞれ被覆して
いるのが望ましい。
Further, the first oxide superconducting film is provided on both surfaces of a plurality of substrates, respectively, and the cylindrical member is formed of two substrates.
A first cylindrical member penetrating through the opposing surfaces of the one substrate; and a second cylindrical member penetrating through both surfaces of the one substrate, wherein the second oxide superconducting film includes the first oxide member. It is desirable to cover the surfaces of the cylindrical member and the second cylindrical member, respectively.

【0010】さらに、上記第1の円筒状部材は上記各基
板を貫通して一本に連なっているのが望ましい。
Further, it is desirable that the first cylindrical member penetrates each of the substrates and is continuous.

【0011】また、この発明の超電導磁気センサの製造
方法は、複数の基板の片面にそれぞれ所定の線状パター
ンの金属膜を設ける工程と、上記各基板の上記金属膜の
端部に相当する箇所に上記円筒状部材を貫通して上記各
基板を金属製の円筒状部材を介して一体に連結する工程
と、電気泳動法により、上記金属膜と円筒状部材の表面
にそれぞれ磁気抵抗効果を示す第1の酸化物超電導膜,
第2の酸化物超電導膜を同時に被着し、続いて、酸素を
含む雰囲気中で熱処理を行って、上記第1の酸化物超電
導膜,第2の酸化物超電導膜を焼結するとともに上記各
金属膜および円筒状部材の表面を絶縁膜に変化させる工
程を有することを特徴としている。
Further, according to a method of manufacturing a superconducting magnetic sensor of the present invention, a step of providing a metal film having a predetermined linear pattern on one surface of each of a plurality of substrates, and a step corresponding to an end of the metal film of each substrate A step of penetrating the cylindrical member and connecting the respective substrates integrally via a metal cylindrical member, and showing a magnetoresistive effect on the surfaces of the metal film and the cylindrical member by electrophoresis. A first oxide superconducting film,
A second oxide superconducting film is simultaneously deposited, followed by heat treatment in an atmosphere containing oxygen to sinter the first oxide superconducting film and the second oxide superconducting film, and The method is characterized by including a step of changing the surfaces of the metal film and the cylindrical member into an insulating film.

【0012】また、この発明の超電導磁気センサの製造
方法は、1枚の基板の両面に対称に所定の線状パターン
の金属膜を設ける工程と、上記各基板の上記金属膜の端
部に相当する箇所に金属製の円筒状部材を貫通して上記
基板と円筒状部材とを一体にする工程と、電気泳動法に
より、上記金属膜と円筒状部材の表面にそれぞれ磁気抵
抗効果を示す第1の酸化物超電導膜,第2の酸化物超電
導膜を同時に被着し、続いて、酸素を含む雰囲気中で熱
処理を行って、上記第1の酸化物超電導膜,第2の酸化
物超電導膜を焼結するとともに上記各金属膜および円筒
状部材の表面を絶縁膜に変化させる工程を有することを
特徴としている。
Further, a method of manufacturing a superconducting magnetic sensor according to the present invention includes the steps of providing a metal film of a predetermined linear pattern symmetrically on both surfaces of one substrate, and corresponding to an end of the metal film of each substrate. A step of penetrating a metal cylindrical member at a position to be integrated with the substrate and the cylindrical member, and a first method of forming a magnetoresistive effect on the surfaces of the metal film and the cylindrical member by electrophoresis. The oxide superconducting film and the second oxide superconducting film are simultaneously deposited, and then heat treatment is performed in an atmosphere containing oxygen to form the first oxide superconducting film and the second oxide superconducting film. The method is characterized by including a step of sintering and changing the surface of each of the metal films and the cylindrical member into an insulating film.

【0013】また、この発明の超電導磁気センサの製造
方法は、複数の基板の両面に、所定の線状パターンの金
属膜を各基板の両面で対称に設ける工程と、上記各基板
の上記金属膜の一方の端部に相当する箇所に1本の金属
製の第1の円筒状部材を貫通して各基板を一体に連結す
るとともに、上記各基板の上記金属膜の他方の端部に相
当する箇所に1枚の基板を貫通する金属製の第2の円筒
状部材を貫通する工程と、電気泳動法により、上記金属
膜の表面に磁気抵抗効果を示す第1の酸化物超電導膜を
被着すると同時に上記第1および第2の円筒状部材の表
面に磁気抵抗効果を示す第2の酸化物超電導膜を被着
し、続いて、酸素を含む雰囲気中で熱処理を行って、上
記第1の酸化物超電導膜,第2の酸化物超電導膜を焼結
するとともに上記各金属膜並びに第1および第2の円筒
状部材の表面を絶縁膜に変化させる工程と、上記第1の
円筒状部材の端面を被覆している第2の酸化物超電導膜
を除去する工程を有することを特徴としている。
Further, according to the method of manufacturing a superconducting magnetic sensor of the present invention, a metal film having a predetermined linear pattern is provided on both surfaces of a plurality of substrates symmetrically on both surfaces of each substrate; Each of the substrates is integrally connected by penetrating one metal first cylindrical member at a position corresponding to one end of the substrate, and corresponds to the other end of the metal film of each substrate. A step of penetrating a second cylindrical member made of metal penetrating one substrate at a position, and applying a first oxide superconducting film exhibiting a magnetoresistance effect to the surface of the metal film by electrophoresis At the same time, a second oxide superconducting film exhibiting a magnetoresistive effect is deposited on the surfaces of the first and second cylindrical members, and subsequently, a heat treatment is performed in an atmosphere containing oxygen. The oxide superconducting film and the second oxide superconducting film are sintered and A step of changing the surfaces of the metal film and the first and second cylindrical members to an insulating film; and a step of removing the second oxide superconducting film covering the end surface of the first cylindrical member. It is characterized by:

【0014】[0014]

【作用】この発明の超電導磁気センサでは、互いに平行
な基板面に設けられた第1の酸化物超電導膜が第2の酸
化物超電導膜を介して直列に接続されている。したがっ
て、磁界に対する発生抵抗が大きくなって、SN比(信
号ノイズ比)が大きくなり、磁気検出感度が高まる。な
お、第1の酸化物超電導膜は基板面に垂直な方向に積層
された状態となり、基板面に沿った向きには広がらない
ので、空間的分解能は殆んど低下しない。
In the superconducting magnetic sensor according to the present invention, the first oxide superconducting films provided on the mutually parallel substrate surfaces are connected in series via the second oxide superconducting film. Therefore, the generated resistance to the magnetic field increases, the SN ratio (signal noise ratio) increases, and the magnetic detection sensitivity increases. Note that the first oxide superconducting film is stacked in a direction perpendicular to the substrate surface and does not spread in the direction along the substrate surface, so that the spatial resolution hardly decreases.

【0015】また、上記第1の酸化物超電導膜が複数の
基板の同一の向きの面にそれぞれ設けられ、上記円筒状
部材が周面を貫通する横穴を各基板の間に有し、この横
穴の端面を上記第2の酸化物超電導膜が被覆している場
合、図1に例示するように、第1の酸化物超電導膜1,
1,…を電気的に直列に接続する接続経路C1が生ず
る。すなわち、円筒状部材12の基板10,10の間の
外周面と、横穴12tの端面と、円筒状部材12の内周
面と、隣の横穴12tの端面と、隣の基板10,10の間
の外周面とが上記第2の酸化物超電導膜2による接続経
路C1となる。したがって、第1の酸化物超電導膜1,
1…が簡単に直列接続される。
Further, the first oxide superconducting film is provided on each of the plurality of substrates in the same direction, and the cylindrical member has a lateral hole penetrating the peripheral surface between the substrates. When the second oxide superconducting film covers the end face of the first oxide superconducting film 1, as shown in FIG.
A connection path C1 for electrically connecting 1,... In series occurs. That is, the outer peripheral surface between the substrates 10 and 10 of the cylindrical member 12, the end surface of the lateral hole 12t, the inner peripheral surface of the cylindrical member 12, the end surface of the adjacent lateral hole 12t, and the adjacent substrates 10 and 10 Is a connection path C1 by the second oxide superconducting film 2. Therefore, the first oxide superconducting film 1,
Are easily connected in series.

【0016】また、上記第1の酸化物超電導膜が2枚の
基板の互いに対向する面にそれぞれ設けられている場合
は、図2に例示するように、第1の酸化物超電導膜10
1,151を電気的に直列に接続する接続経路C2が生
ずる。すなわち、円筒状部材112の外周面のうち2枚
の基板110,110の間の部分が第2の酸化物超電導
膜102による接続経路C2となる。したがって、第1
の酸化物超電導膜101,151が簡単に接続される。
また、上記第1の酸化物超電導膜101,101が2枚
の基板110,110の互いに反対向きの面にそれぞれ
設けられている場合は、図3に例示するように、それぞ
れ円筒状部材112の外周面のうち基板110,110
の外側の部分、円筒状部材112の端面および内周面が
第2の酸化物超電導膜102による接続経路C3とな
る。したがって、第1の酸化物超電導膜101,151
が簡単に直列接続される。
In the case where the first oxide superconducting film is provided on the surfaces of two substrates facing each other, as shown in FIG. 2, the first oxide superconducting film 10
A connection path C2 that electrically connects 1,151 in series is generated. That is, the portion between the two substrates 110 and 110 on the outer peripheral surface of the cylindrical member 112 becomes the connection path C2 by the second oxide superconducting film 102. Therefore, the first
Oxide superconducting films 101 and 151 are easily connected.
In the case where the first oxide superconducting films 101, 101 are provided on opposite surfaces of the two substrates 110, 110, respectively, as illustrated in FIG. Substrates 110, 110 of the outer peripheral surface
, The end surface and the inner peripheral surface of the cylindrical member 112 form a connection path C3 by the second oxide superconducting film 102. Therefore, the first oxide superconducting films 101 and 151
Are easily connected in series.

【0017】また、上記第1の酸化物超電導膜が1枚の
基板の両面にそれぞれ設けられている場合、図4に例示
するように、第1の酸化物超電導膜201,251を電
気的に直列に接続する接続経路C4が生ずる。すなわ
ち、円筒状部材212の外周面のうち基板210の外側
の部分と、円筒状部材212の端面と、内周面とが第2
の酸化物超電導膜202による接続経路C4となる。し
たがって、第1の酸化物超電導膜201,251が簡単
に直列接続される。
When the first oxide superconducting film is provided on both surfaces of one substrate, the first oxide superconducting films 201 and 251 are electrically connected as shown in FIG. A connection path C4 connected in series is generated. That is, a portion of the outer peripheral surface of the cylindrical member 212 outside the substrate 210, the end surface of the cylindrical member 212, and the inner peripheral surface are the second.
Of the oxide superconducting film 202. Therefore, the first oxide superconducting films 201 and 251 are easily connected in series.

【0018】また、上記第1の酸化物超電導膜は、複数
の基板の両面にそれぞれ設けられ、上記円筒状部材は2
枚の基板の互いに対向する面を貫通する第1の円筒状部
材と、1枚の基板の両面を貫通する第2の円筒状部材と
を含み、上記第2の酸化物超電導膜は上記第1の円筒状
部材および第2の円筒状部材の表面をそれぞれ被覆して
いる場合、図5に例示するように、第1の酸化物超電導
膜301,351,301,351,…を電気的に直列に接
続する接続経路C5が生ずる。すなわち、第1の円筒状
部材312を被覆する第2の酸化物超電導膜302は2
枚の基板310,310の互いに対向する面に設けられ
た第1の酸化物超電導膜351,301を電気的に直列
に接続する一方、第2の円筒状部材392を被覆する第
2の酸化物超電導膜382は1枚の基板310の両面に
設けられた第1の酸化物超電導膜311,351を電気
的に直列に接続する。したがって、複数の基板310,
310,…の両面に設けられた第1の酸化物超電導膜3
11,351,…がすべて直列に接続され、この結果、磁
気検出感度が顕著に高まる。なお、この場合、第1の円
筒状部材の内周面を通る経路は用いない(遮断する)。
Further, the first oxide superconducting film is provided on both surfaces of a plurality of substrates, respectively, and the cylindrical member is formed of two or more substrates.
A first cylindrical member penetrating through the opposing surfaces of the one substrate; and a second cylindrical member penetrating through both surfaces of the one substrate, wherein the second oxide superconducting film includes the first oxide member. When the surfaces of the cylindrical member and the second cylindrical member are respectively coated, as shown in FIG. 5, the first oxide superconducting films 301, 351, 301, 351,. A connection path C5 that connects to is generated. That is, the second oxide superconducting film 302 covering the first cylindrical member 312 has a thickness of 2
The first oxide superconducting films 351 and 301 provided on the surfaces of the substrates 310 and 310 facing each other are electrically connected in series, while the second oxide covering the second cylindrical member 392. The superconducting film 382 electrically connects the first oxide superconducting films 311 and 351 provided on both surfaces of one substrate 310 in series. Therefore, the plurality of substrates 310,
, The first oxide superconducting film 3 provided on both surfaces of
Are all connected in series, and as a result, the magnetic detection sensitivity is significantly increased. In this case, a path passing through the inner peripheral surface of the first cylindrical member is not used (blocked).

【0019】また、上記第1の円筒状部材が上記各基板
を貫通して一本に連なっている場合、各基板を一度に連
結できるので作製工程が簡単になる。しかも、連結後の
機械的強度が高まる。
Further, when the first cylindrical member penetrates each of the substrates and is continuous, each substrate can be connected at a time, thereby simplifying the manufacturing process. Moreover, the mechanical strength after connection is increased.

【0020】[0020]

【実施例】以下、この発明の超電導磁気センサおよびそ
の製造方法を実施例により詳細に説明する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The superconducting magnetic sensor according to the present invention and a method for manufacturing the same will be described in detail below with reference to embodiments.

【0021】図6(a)は第1実施例の超電導磁気センサ
を斜め上方から見たところ、同図(b)は真横から見たと
ころをそれぞれ示している。この超電導磁気センサは、
互いに平行に配された4枚のYSZ(イットリウム安定
化ジルコニウム)基板10と、これらの基板10を2枚
ずつ貫通して一体に連結する3本の円筒状部材12を備
えている。各基板10の同一の向きの面(片面)にそれぞ
れミアンダパターン(つづら折り)状の第1の酸化物超電
導膜(Y1Ba2Cu37-x膜)1が設けられている。各第1
の酸化物超電導膜1の端部1a,1bは所定寸法の矩形状
になっており、上記円筒状部材12は各2枚の基板毎に
第1の酸化物超電導膜1の端部1a,1bに相当する箇所
を交互に貫通している。円筒状部材12には周面を貫通
する横穴12tが基板10の間に設けられている。円筒
状部材12の表面、すなわち外周面,端面,内周面および
上記横穴12tの端面は、第2の酸化物超電導膜(Y1Ba
2Cu37-x膜)2によって被覆されている。したがっ
て、図1によって説明したように、各基板面の第1の酸
化物超電導膜1は第2の酸化物超電導膜2によって電気
的に直列に接続されている。
FIG. 6A shows the superconducting magnetic sensor of the first embodiment viewed obliquely from above, and FIG. 6B shows the superconducting magnetic sensor viewed from right beside. This superconducting magnetic sensor
It comprises four YSZ (yttrium-stabilized zirconium) substrates 10 arranged in parallel with each other, and three cylindrical members 12 penetrating these substrates 10 by two and integrally connecting them. A first oxide superconducting film (Y 1 Ba 2 Cu 3 O 7 -x film) 1 having a meandering pattern (square folding) is provided on a surface (one surface) in the same direction of each substrate 10. Each first
The end portions 1a and 1b of the oxide superconducting film 1 are rectangular in a predetermined size, and the cylindrical member 12 is provided with the end portions 1a and 1b of the first oxide superconducting film 1 for every two substrates. Are alternately penetrated. The cylindrical member 12 is provided with a lateral hole 12 t penetrating the peripheral surface between the substrates 10. The surface of the cylindrical member 12, that is, the outer peripheral surface, the end surface, the inner peripheral surface, and the end surface of the lateral hole 12t are formed on the second oxide superconducting film (Y 1 Ba).
2 Cu 3 O 7-x film) 2. Therefore, as described with reference to FIG. 1, the first oxide superconducting film 1 on each substrate surface is electrically connected in series by the second oxide superconducting film 2.

【0022】この超電導磁気センサは次のようにして作
製する。 まず、各YSZ基板10の片面に、銅の膜を真空蒸着
し、フォトリソグラフィを行って、線幅500μm,線長
251mmのミアンダパターン状の銅電極(第1の酸化物
超電導膜が被着されるべき電極)11と、この銅電極1
1に基板面内で離間して並ぶ線幅100μmの対向電極
(図10に示す)31とを形成する。なお、銅電極11,
対向電極31の端部11a,11b,31aを矩形状に形成
する。 次に、図1に示すように、各2枚の基板毎に銅電極1
1の端部11a,11bに相当する箇所に円筒状部材12
を交互に貫通して、各基板10を円筒状部材12を介し
て一体に連結する。 次に、電気泳動法により、上記銅電極11と円筒状部
材12の表面にそれぞれ第1の酸化物超電導膜1,第2
の酸化物超電導膜2を4枚の基板について同時に被着す
る。なお、このとき、図10に示すように、銅電極11
を負電位、対向電極31を正電位とする。続いて、酸素
を含む雰囲気中で900℃,3時間の熱処理を行って、
上記第1の酸化物超電導膜1,第2の酸化物超電導膜2
を焼結するとともに各銅電極11および円筒状部材12
の表面を絶縁膜に変化させる。 最後に、図6に示すように、両端の基板10の第1の
酸化物超電導膜の端部1a,1bに電流端子3i,電圧端子
3vを取り付ける。
This superconducting magnetic sensor is manufactured as follows. First, a copper film is vacuum-deposited on one surface of each YSZ substrate 10 and subjected to photolithography to form a meander-patterned copper electrode having a line width of 500 μm and a line length of 251 mm (the first oxide superconducting film is deposited). Electrode 11) and the copper electrode 1
1. Opposite electrodes with a line width of 100 μm that are spaced apart in the substrate plane
(Shown in FIG. 10). The copper electrode 11,
The ends 11a, 11b, 31a of the counter electrode 31 are formed in a rectangular shape. Next, as shown in FIG. 1, a copper electrode 1 was placed on each of the two substrates.
The cylindrical member 12 is provided at a position corresponding to the end portions 11a and 11b of the
Are alternately penetrated to integrally connect the substrates 10 via the cylindrical member 12. Next, the first oxide superconducting film 1 and the second oxide superconducting film 1 were respectively formed on the surfaces of the copper electrode 11 and the cylindrical member 12 by electrophoresis.
Of the oxide superconducting film 2 is simultaneously applied to four substrates. At this time, as shown in FIG.
Is a negative potential, and the counter electrode 31 is a positive potential. Subsequently, heat treatment is performed at 900 ° C. for 3 hours in an atmosphere containing oxygen,
The first oxide superconducting film 1 and the second oxide superconducting film 2
While sintering each copper electrode 11 and cylindrical member 12
Is turned into an insulating film. Finally, as shown in FIG. 6, current terminals 3i and voltage terminals 3v are attached to the ends 1a and 1b of the first oxide superconducting film of the substrate 10 at both ends.

【0023】この超電導磁気センサでは、複数(4枚)の
基板の第1の酸化物超電導膜1が電気的に直列に接続さ
れているので、磁界に対する発生抵抗が大きくなって、
SN比(信号ノイズ比)が大きくなる。したがって、従来
に比して、磁気検出感度を高めることができる。なお、
第1の酸化物超電導膜1は基板面に垂直な方向に積層さ
れた状態となり、基板面に沿った向きには広がらないの
で、空間的分解能は殆んど低下しない。
In this superconducting magnetic sensor, since the first oxide superconducting films 1 of a plurality of (four) substrates are electrically connected in series, the generated resistance to a magnetic field increases.
The SN ratio (signal noise ratio) increases. Therefore, the magnetic detection sensitivity can be increased as compared with the related art. In addition,
Since the first oxide superconducting film 1 is stacked in a direction perpendicular to the substrate surface and does not spread in the direction along the substrate surface, the spatial resolution hardly decreases.

【0024】実際に測定を行ったところ、上記超電導磁
気センサは、磁電変換率が500mV/gauss、ノイズレ
ベルが164nV/(Hz)1/2であり、磁気検出感度(最小
磁束分解能)が3.3×10-7gauss/(Hz)1/2となっ
た。これに対して、従来のもの(1枚の基板の片面だけ
にY1Ba2Cu37-x膜を設けたもの)は、磁電変換率が
125mV/gauss、ノイズレベルが82.0nV/(Hz)
1/2であり、磁気検出感度が6.6×10-7gauss/(Hz)
1/2であった。したがって、磁気検出感度を約0.50倍
に高めることができた。
When the measurement was actually performed, the superconducting magnetic sensor had a magnetoelectric conversion rate of 500 mV / gauss, a noise level of 164 nV / (Hz) 1/2 and a magnetic detection sensitivity (minimum magnetic flux resolution) of 3. It was 3 × 10 −7 gauss / (Hz) 1/2 . On the other hand, the conventional one (having a Y 1 Ba 2 Cu 3 O 7-x film on only one side of one substrate) has a magnetoelectric conversion rate of 125 mV / gauss and a noise level of 82.0 nV / (Hz)
1/2 and the magnetic detection sensitivity is 6.6 × 10 -7 gauss / (Hz)
It was 1/2 . Therefore, the magnetic detection sensitivity could be increased about 0.50 times.

【0025】図7は第2実施例の超電導磁気センサを示
している。この例では、同図(b)に示すように、YSZ
基板110,150の互いに対向する面にミアンダパタ
ーン状の第1の酸化物超電導膜(Y1Ba2Cu37-x膜)1
01,151が鏡面対称に設けられている。これらの基
板110,150を一体に連結する円筒状部材112の
表面は第2の酸化物超電導膜(Y1Ba2Cu37-x膜)10
2によって被覆されている。したがって、図2によって
説明したように、上記第1の酸化物超電導膜101,1
51は第2の酸化物超電導膜102によって電気的に直
列に接続されている。
FIG. 7 shows a superconducting magnetic sensor according to a second embodiment. In this example, as shown in FIG.
First oxide superconducting film (Y 1 Ba 2 Cu 3 O 7 -x film) 1 in a meander pattern is formed on surfaces of substrates 110 and 150 facing each other.
01 and 151 are provided in mirror symmetry. The surface of the cylindrical member 112 connecting these substrates 110 and 150 together is formed of a second oxide superconducting film (Y 1 Ba 2 Cu 3 O 7 -x film) 10.
2 coated. Therefore, as described with reference to FIG. 2, the first oxide superconducting film 101, 1
Reference numeral 51 is electrically connected in series by the second oxide superconducting film 102.

【0026】この超電導磁気センサは次のようにして作
製する。 まず、同図(a)に示すように、YSZ基板110,15
0の片面に、第1実施例と同様に、銅電極111,16
1を形成する。なお、それぞれ対向電極(端部131a,
181aのみ示す)も同時に形成する。 次に、上記基板110,150を平行に対向させて、
銅電極111,161の端部111a,161aに相当する
箇所に円筒状部材112を貫通して、基板110,15
0を一体に連結する。 次に、同図(b)に示すように、電気泳動法により、上
記銅電極111,161と円筒状部材112の表面にそ
れぞれ第1の酸化物超電導膜101,151,第2の酸化
物超電導膜102を同時に被着する。続いて、酸素を含
む雰囲気中で900℃,3時間の熱処理を行って、上記
第1の酸化物超電導膜101,151,第2の酸化物超電
導膜102を焼結するとともに各銅電極111,161
および円筒状部材112の表面を絶縁膜に変化させる。 最後に、第1の酸化物超電導膜101,151の端部
101b,151bに電流端子103i,電圧端子103vを
それぞれ取り付ける。
This superconducting magnetic sensor is manufactured as follows. First, as shown in FIG.
0, copper electrodes 111 and 16 on one side as in the first embodiment.
Form one. In addition, each counter electrode (end 131a,
181a only) is formed at the same time. Next, the substrates 110 and 150 are opposed to each other in parallel,
The cylindrical members 112 are penetrated at locations corresponding to the end portions 111a, 161a of the copper electrodes 111, 161 to form the substrates 110, 161.
0 are connected together. Next, as shown in FIG. 2B, the first oxide superconducting films 101 and 151 and the second oxide superconducting film were respectively formed on the surfaces of the copper electrodes 111 and 161 and the cylindrical member 112 by electrophoresis. The film 102 is simultaneously applied. Subsequently, a heat treatment at 900 ° C. for 3 hours is performed in an atmosphere containing oxygen to sinter the first oxide superconducting films 101 and 151 and the second oxide superconducting film 102 and to form each copper electrode 111, 161
Then, the surface of the cylindrical member 112 is changed to an insulating film. Finally, current terminals 103i and voltage terminals 103v are attached to the ends 101b and 151b of the first oxide superconducting films 101 and 151, respectively.

【0027】この超電導磁気センサも、第1実施例と同
様に、従来(基板が1枚のもの)に比して磁気検出感度を
高めることができる。実際に測定を行ったところ、磁電
変換率が250mV/gauss、ノイズレベルが116nV
/(Hz)1/2であり、磁気検出感度(最小磁束分解能)を従
来の0.71倍に高めることができた。
As in the first embodiment, this superconducting magnetic sensor can also increase the magnetic detection sensitivity as compared with the related art (one substrate). When the measurement was actually performed, the magnetoelectric conversion rate was 250 mV / gauss, and the noise level was 116 nV.
/ (Hz) 1/2 , and the magnetic detection sensitivity (minimum magnetic flux resolution) could be increased to 0.71 times the conventional value.

【0028】なお、この例では、YSZ基板110,1
50の互いに対向する面に第1の酸化物超電導膜(Y1
a2Cu37-x膜)101,151を設けたが、YSZ基板
110,150の互いに反対向きの面に第1の酸化物超
電導膜を設けても良い。この場合も、図3によって説明
したように、各第1の酸化物超電導膜を直列に接続で
き、したがって、同様の磁気検出感度を得ることができ
る。
In this example, the YSZ substrates 110, 1
A first oxide superconducting film (Y 1 B)
Although the a 2 Cu 3 O 7-x films) 101 and 151 are provided, the first oxide superconducting films may be provided on the surfaces of the YSZ substrates 110 and 150 opposite to each other. Also in this case, as described with reference to FIG. 3, each first oxide superconducting film can be connected in series, and therefore, the same magnetic detection sensitivity can be obtained.

【0029】図8は第3実施例の超電導磁気センサを示
している(同図(a)は斜め上方から見たところ、同図(b),
(c)は基板の両面をそれぞれ示している。)。この例で
は、YSZ基板210の両面にミアンダパターン状の第
1の酸化物超電導膜(Y1Ba2Cu37-x膜)201,25
1が対称に設けられている。この基板210を貫通する
円筒状部材212の表面は第2の酸化物超電導膜(Y1
a2Cu37-x膜)202によって被覆されている。したが
って、図4によって説明したように、両面の第1の酸化
物超電導膜201,251は第2の酸化物超電導膜20
2によって電気的に直列に接続されている。
FIG. 8 shows a superconducting magnetic sensor according to the third embodiment (FIG. 8 (a) is an oblique view from above, and FIG.
(c) shows both surfaces of the substrate. ). In this example, meander-patterned first oxide superconducting films (Y 1 Ba 2 Cu 3 O 7 -x films) 201 and 25 are formed on both surfaces of a YSZ substrate 210.
1 are provided symmetrically. The surface of the cylindrical member 212 that penetrates the substrate 210 has a second oxide superconducting film (Y 1 B
a 2 Cu 3 O 7 -x film) 202. Therefore, as described with reference to FIG. 4, the first oxide superconducting films 201 and 251 on both surfaces are
2 electrically connected in series.

【0030】この超電導磁気センサは次のようにして作
製する。 まず、YSZ基板210の両面にミアンダパターン状
の銅電極211,261を形成する。なお、それぞれ対
向電極(端部231a,281aのみ示す)も同時に形成す
る。 次に、上記基板210の銅電極211,261の端部
211a,261aに相当する箇所に円筒状部材212を
貫通する。 次に、電気泳動法により、上記銅電極211,261
と円筒状部材212の表面にそれぞれ第1の酸化物超電
導膜201,251,第2の酸化物超電導膜202を同時
に被着する。このとき、図11に示すように、銅電極2
11を負電位、対向電極231を正電位とする。続い
て、酸素を含む雰囲気中で900℃,3時間の熱処理を
行って、上記第1の酸化物超電導膜201,251,第2
の酸化物超電導膜202を焼結するとともに各銅電極2
11,261および円筒状部材212の表面を絶縁膜に
変化させる。 最後に、図8(a)に示すように、第1の酸化物超電導
膜201,251の端部201b,251bに電流端子20
3i,電圧端子203vをそれぞれ取り付ける。
This superconducting magnetic sensor is manufactured as follows. First, copper electrodes 211 and 261 in a meander pattern are formed on both surfaces of the YSZ substrate 210. Note that counter electrodes (only the end portions 231a and 281a are shown) are formed at the same time. Next, the cylindrical member 212 is penetrated at a position corresponding to the end portions 211a and 261a of the copper electrodes 211 and 261 of the substrate 210. Next, the copper electrodes 211 and 261 were formed by electrophoresis.
Then, the first oxide superconducting films 201 and 251 and the second oxide superconducting film 202 are simultaneously deposited on the surface of the cylindrical member 212, respectively. At this time, as shown in FIG.
11 is a negative potential, and the counter electrode 231 is a positive potential. Subsequently, a heat treatment is performed at 900 ° C. for 3 hours in an atmosphere containing oxygen, so that the first oxide superconducting films 201 and 251 and the second
Sintering of the oxide superconducting film 202 of each
11, 261 and the surface of the cylindrical member 212 are changed into insulating films. Finally, as shown in FIG. 8A, the current terminals 20 are connected to the ends 201b and 251b of the first oxide superconducting films 201 and 251.
3i and the voltage terminal 203v are attached.

【0031】この超電導磁気センサも、上記各実施例と
同様に、従来(基板が1枚のもの)に比して磁気検出感度
を高めることができる。実際に測定を行ったところ、磁
電変換率が250mV/gauss、ノイズレベルが116n
V/(Hz)1/2であり、第2実施例と同様に、磁気検出感
度(最小磁束分解能)を従来の0.71倍に高めることが
できた。
This superconducting magnetic sensor can also increase the magnetic detection sensitivity as compared with the related art (one substrate), similarly to the above embodiments. When the measurement was actually performed, the magnetoelectric conversion rate was 250 mV / gauss, and the noise level was 116 n.
V / (Hz) 1/2 , and as in the second embodiment, the magnetic detection sensitivity (minimum magnetic flux resolution) could be increased to 0.71 times the conventional value.

【0032】図9は第4実施例の超電導磁気センサを示
している(同図(a)は斜め上方から見たところ、同図(b)
は真横から見たところをそれぞれ示している。)。この
超電導磁気センサはは、互いに平行に配された4枚のY
SZ基板310と、これら4枚の基板310を貫通して
一体に連結する1本の第1の円筒状部材312と、各1
枚の基板を貫通する4本の第2の円筒状部材392を備
えている。各基板310の両面にそれぞれミアンダパタ
ーン状の第1の酸化物超電導膜(Y1Ba2Cu37-x膜)3
01,351が対称に設けられている。同図(a)に示すよ
うに、各第1の酸化物超電導膜301の端部301a,3
01bはそれぞれ所定寸法の矩形状になっている(裏側の
第1の酸化物超電導膜351の端部351a,351bも
矩形状になっている)。上記第1の円筒状部材312は
第1の酸化物超電導膜301の一方の端部301aに相
当する箇所を貫通する一方、上記第2の円筒状部材39
2は第1の酸化物超電導膜301の他方の端部301b
に相当する箇所を貫通している。また、第1の円筒状部
材312と第2の円筒状部材392の表面は、いずれも
第2の酸化物超電導膜(Y1Ba2Cu37-x膜)302,3
82によって被覆されている。したがって、図5によっ
て説明したように、各基板310の両面の第1の酸化物
超電導膜301,351は第2の酸化物超電導膜302,
382によって電気的に直列に接続されている。
FIG. 9 shows a superconducting magnetic sensor according to the fourth embodiment (FIG. 9 (a) is an oblique view from above, and FIG. 9 (b)
Indicates the position viewed from the side. ). This superconducting magnetic sensor is composed of four Y
An SZ substrate 310, one first cylindrical member 312 penetrating the four substrates 310 and integrally connected thereto;
It is provided with four second cylindrical members 392 that penetrate through the two substrates. A first oxide superconducting film (Y 1 Ba 2 Cu 3 O 7 -x film) 3 having a meander pattern on both surfaces of each substrate 310.
01,351 are provided symmetrically. As shown in FIG. 3A, the end portions 301a, 301 of each first oxide superconducting film 301 are formed.
No. 01b has a rectangular shape with a predetermined dimension (the end portions 351a and 351b of the back-side first oxide superconducting film 351 also have a rectangular shape). The first cylindrical member 312 penetrates a portion corresponding to one end 301a of the first oxide superconducting film 301, while the second cylindrical member 39
2 is the other end 301b of the first oxide superconducting film 301
Penetrates a portion corresponding to. The surfaces of the first cylindrical member 312 and the second cylindrical member 392 are both formed of the second oxide superconducting film (Y 1 Ba 2 Cu 3 O 7 -x film) 302,3.
82. Therefore, as described with reference to FIG. 5, the first oxide superconducting films 301 and 351 on both surfaces of each substrate 310 are replaced with the second oxide superconducting films 302 and 351.
382 are electrically connected in series.

【0033】この超電導磁気センサは次のようにして作
製する。 まず、各YSZ基板310の両面にミアンダパターン
状の銅電極311,361を形成する。なお、それぞれ
対向電極(端部331aのみ示す)も同時に形成する。 次に、上記各基板310の銅電極311(および36
1)の一方の端部311aに相当する箇所に1本の第1の
円筒状部材312を貫通するとともに、銅電極311の
他方の端部311bに相当する箇所に4本の第2の円筒
状部材392を貫通する。 次に、電気泳動法により、上記銅電極311,361
と第1の円筒状部材312,第2の円筒状部材392の
表面に、それぞれ第1の酸化物超電導膜301,351,
第2の酸化物超電導膜302,382を同時に被着す
る。続いて、酸素を含む雰囲気中で900℃,3時間の
熱処理を行って、上記第1の酸化物超電導膜301,3
51,第2の酸化物超電導膜302,382を焼結すると
ともに各銅電極311,361および第1の円筒状部材
312,第2の円筒状部材392の表面を絶縁膜に変化
させる。 次に、上記第1の円筒状部材312の両端をリング状
に切断する。これにより、第1の円筒状部材の内周面を
上下方向に通る接続経路を遮断する。 最後に、同図(a)に示すように、上端の基板310の
第1の酸化物超電導膜301の端部301aと下端の基
板310の第1の酸化物超電導膜351の端部351a
とに、電流端子203i,電圧端子203vをそれぞれ取
り付ける。
This superconducting magnetic sensor is manufactured as follows. First, copper electrodes 311 and 361 in a meander pattern are formed on both surfaces of each YSZ substrate 310. Note that counter electrodes (only the end portion 331a is shown) are formed at the same time. Next, the copper electrodes 311 (and 36)
1) penetrates one first cylindrical member 312 at a position corresponding to one end 311a and four second cylindrical members at a position corresponding to the other end 311b of the copper electrode 311. It penetrates the member 392. Next, the copper electrodes 311 and 361 were formed by electrophoresis.
And the first oxide superconducting films 301, 351 and 351 on the surfaces of the first cylindrical member 312 and the second cylindrical member 392, respectively.
The second oxide superconducting films 302 and 382 are simultaneously deposited. Subsequently, a heat treatment is performed at 900 ° C. for 3 hours in an atmosphere containing oxygen to form the first oxide superconducting films 301 and 3.
51, sintering the second oxide superconducting films 302 and 382, and changing the surfaces of the copper electrodes 311 and 361 and the first cylindrical member 312 and the second cylindrical member 392 into insulating films. Next, both ends of the first cylindrical member 312 are cut into a ring shape. Thereby, the connection path that passes through the inner peripheral surface of the first cylindrical member in the vertical direction is blocked. Finally, as shown in FIG. 3A, an end 301a of the first oxide superconducting film 301 of the upper substrate 310 and an end 351a of the first oxide superconducting film 351 of the lower substrate 310.
Then, a current terminal 203i and a voltage terminal 203v are respectively attached.

【0034】この超電導磁気センサも、上記各実施例と
同様に、従来(基板が1枚のもの)に比して磁気検出感度
を高めることができる。実際に測定を行ったところ、磁
電変換率が1000mV/gauss、ノイズレベルが232
nV/(Hz)1/2であり、磁気検出感度(最小磁束分解能)
を従来の0.35倍に高めることができた。
This superconducting magnetic sensor can also improve the magnetic detection sensitivity as compared with the conventional one (one substrate), as in the above embodiments. When the measurement was actually performed, the magnetoelectric conversion rate was 1000 mV / gauss, and the noise level was 232.
nV / (Hz) 1/2 , magnetic detection sensitivity (minimum magnetic flux resolution)
Was increased to 0.35 times the conventional value.

【0035】[0035]

【発明の効果】以上より明らかなように、この発明の超
電導磁気センサは、互いに平行な基板面に存する第1の
酸化物超電導膜を、円筒状部材の表面を被覆する第2の
酸化物超電導膜で直列に接続しているので、磁界に対す
る発生抵抗を大きくすることができる。したがって、磁
気検出感度を高めることができる。
As is apparent from the above description, the superconducting magnetic sensor of the present invention is characterized in that the first oxide superconducting film existing on the mutually parallel substrate surfaces is replaced by the second oxide superconducting film covering the surface of the cylindrical member. Since the films are connected in series, the resistance to a magnetic field can be increased. Therefore, the magnetic detection sensitivity can be increased.

【0036】また、この発明の超電導磁気センサの製造
方法によれば、高い磁気検出感度を有する超電導磁気セ
ンサを簡単な工程でもって作製することができる。
Further, according to the method for manufacturing a superconducting magnetic sensor of the present invention, a superconducting magnetic sensor having high magnetic detection sensitivity can be manufactured by simple steps.

【図面の簡単な説明】[Brief description of the drawings]

【図1】 この発明の超電導磁気センサを構成する第1
の酸化物超電導膜の接続経路を説明する図である。
FIG. 1 shows a first embodiment of a superconducting magnetic sensor according to the present invention.
FIG. 4 is a diagram illustrating a connection path of the oxide superconducting film of FIG.

【図2】 この発明の超電導磁気センサを構成する第1
の酸化物超電導膜の接続経路を説明する図である。
FIG. 2 shows a first embodiment of the superconducting magnetic sensor according to the present invention.
FIG. 4 is a diagram illustrating a connection path of the oxide superconducting film of FIG.

【図3】 この発明の超電導磁気センサを構成する第1
の酸化物超電導膜の接続経路を説明する図である。
FIG. 3 shows a first embodiment of the superconducting magnetic sensor according to the present invention.
FIG. 4 is a diagram illustrating a connection path of the oxide superconducting film of FIG.

【図4】 この発明の超電導磁気センサを構成する第1
の酸化物超電導膜の接続経路を説明する図である。
FIG. 4 shows a first embodiment of the superconducting magnetic sensor according to the present invention.
FIG. 4 is a diagram illustrating a connection path of the oxide superconducting film of FIG.

【図5】 この発明の超電導磁気センサを構成する第1
の酸化物超電導膜の接続経路を説明する図である。
FIG. 5 shows a first embodiment of the superconducting magnetic sensor according to the present invention.
FIG. 4 is a diagram illustrating a connection path of the oxide superconducting film of FIG.

【図6】 この発明の第1実施例の超電導磁気センサを
示す図である。
FIG. 6 is a diagram showing a superconducting magnetic sensor according to a first embodiment of the present invention.

【図7】 この発明の第2実施例の超電導磁気センサを
示す図である。
FIG. 7 is a diagram showing a superconducting magnetic sensor according to a second embodiment of the present invention.

【図8】 この発明の第3実施例の超電導磁気センサを
示す図である。
FIG. 8 is a diagram showing a superconducting magnetic sensor according to a third embodiment of the present invention.

【図9】 この発明の第4実施例の超電導磁気センサを
示す図である。
FIG. 9 is a diagram showing a superconducting magnetic sensor according to a fourth embodiment of the present invention.

【図10】 電気泳動法により酸化物超電導膜を被着す
る工程を説明する図である。
FIG. 10 illustrates a step of depositing an oxide superconducting film by an electrophoresis method.

【図11】 電気泳動法により酸化物超電導膜を被着す
る工程を説明する図である。
FIG. 11 illustrates a step of depositing an oxide superconducting film by an electrophoresis method.

【符号の説明】[Explanation of symbols]

1,101,151,201,251,301,351 第1
の酸化物超電導膜 2,102,202,302,382 第2の酸化物超電導
膜 10,110,210,310 YSZ基板 11,111,161,211,261,311,361 銅
電極 12,112,212 円筒状部材 312 第1の円筒状部材 392 第2の円筒状部材
1,101,151,201,251,301,351 1st
Oxide superconducting film of 2,102,202,302,382 Second oxide superconducting film 10,110,210,310 YSZ substrate 11,111,161,211,261,311,361 Copper electrode 12,112,212 Cylindrical member 312 First cylindrical member 392 Second cylindrical member

───────────────────────────────────────────────────── フロントページの続き (72)発明者 長田 昌也 大阪府大阪市阿倍野区長池町22番22号 シャープ株式会社内 (72)発明者 木場 正義 大阪府大阪市阿倍野区長池町22番22号 シャープ株式会社内 (56)参考文献 特開 平3−248070(JP,A) 特開 平2−114575(JP,A) 特開 平5−196714(JP,A) (58)調査した分野(Int.Cl.6,DB名) G01R 33/035 ZAA G01R 33/09 ZAA H01L 39/22 ZAA H01L 43/08 ZAA──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Masaya Nagata 22-22 Nagaikecho, Abeno-ku, Osaka-shi, Osaka Inside Sharp Corporation (72) Inventor Masayoshi Kiba 22-22 Nagaikecho, Abeno-ku, Osaka-shi, Osaka Sharp Corporation (56) References JP-A-3-248070 (JP, A) JP-A-2-114575 (JP, A) JP-A-5-196714 (JP, A) (58) Fields investigated (Int. Cl. 6 , DB name) G01R 33/035 ZAA G01R 33/09 ZAA H01L 39/22 ZAA H01L 43/08 ZAA

Claims (9)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 互いに平行な複数の基板面にそれぞれ線
状に設けられ、磁気抵抗効果を示す第1の酸化物超電導
膜と、 上記各基板面を貫通する円筒状部材と、 上記円筒状部材の表面を被覆し、上記各基板面に設けら
れた第1の酸化物超電導膜を電気的に直列に接続する第
2の酸化物超電導膜を備えたことを特徴とする超電導磁
気センサ。
A first oxide superconducting film linearly provided on a plurality of substrate surfaces parallel to each other and exhibiting a magnetoresistance effect; a cylindrical member penetrating the respective substrate surfaces; And a second oxide superconducting film for electrically connecting the first oxide superconducting films provided on the respective substrate surfaces in series with each other.
【請求項2】 請求項1に記載の超電導磁気センサにお
いて、 上記第1の酸化物超電導膜は、複数の基板の同一の向き
の面にそれぞれ設けられ、 上記円筒状部材は周面を貫通する横穴を各基板の間に有
し、この横穴の端面を上記第2の酸化物超電導膜が被覆
していることを特徴とする超電導磁気センサ。
2. The superconducting magnetic sensor according to claim 1, wherein the first oxide superconducting films are respectively provided on surfaces of a plurality of substrates in the same direction, and the cylindrical member penetrates a peripheral surface. A superconducting magnetic sensor, wherein a lateral hole is provided between the substrates, and an end face of the lateral hole is covered with the second oxide superconducting film.
【請求項3】 請求項1に記載の超電導磁気センサにお
いて、 上記第1の酸化物超電導膜は、2枚の基板の互いに対向
する面または互いに反対向きの面にそれぞれ設けられて
いることを特徴とする超電導磁気センサ。
3. The superconducting magnetic sensor according to claim 1, wherein the first oxide superconducting film is provided on surfaces of the two substrates facing each other or surfaces facing each other. Superconducting magnetic sensor.
【請求項4】 請求項1に記載の超電導磁気センサにお
いて、 上記第1の酸化物超電導膜は、1枚の基板の両面にそれ
ぞれ設けられていることを特徴とする超電導磁気セン
サ。
4. The superconducting magnetic sensor according to claim 1, wherein the first oxide superconducting film is provided on both surfaces of one substrate.
【請求項5】 請求項1に記載の超電導磁気センサにお
いて、 上記第1の酸化物超電導膜は、複数の基板の両面にそれ
ぞれ設けられ、 上記円筒状部材は2枚の基板の互いに対向する面を貫通
する第1の円筒状部材と、1枚の基板の両面を貫通する
第2の円筒状部材とを含み、 上記第2の酸化物超電導膜は上記第1の円筒状部材およ
び第2の円筒状部材の表面をそれぞれ被覆していること
を特徴とする超電導磁気センサ。
5. The superconducting magnetic sensor according to claim 1, wherein the first oxide superconducting film is provided on both surfaces of a plurality of substrates, respectively, and the cylindrical member is a surface of the two substrates facing each other. And a second cylindrical member that penetrates both surfaces of one substrate, wherein the second oxide superconducting film includes the first cylindrical member and the second cylindrical member. A superconducting magnetic sensor characterized by covering the surfaces of cylindrical members.
【請求項6】 請求項5に記載の超電導磁気センサにお
いて、 上記第1の円筒状部材は上記各基板を貫通して一本に連
なっていることを特徴とする超電導磁気センサ。
6. The superconducting magnetic sensor according to claim 5, wherein the first cylindrical member penetrates each of the substrates and is continuous.
【請求項7】 複数の基板の片面にそれぞれ所定の線状
パターンの金属膜を設ける工程と、 上記各基板の上記金属膜の端部に相当する箇所に金属製
の円筒状部材を貫通して上記各基板を上記円筒状部材を
介して一体に連結する工程と、 電気泳動法により、上記金属膜と円筒状部材の表面にそ
れぞれ磁気抵抗効果を示す第1の酸化物超電導膜,第2
の酸化物超電導膜を同時に被着し、続いて、酸素を含む
雰囲気中で熱処理を行って、上記第1の酸化物超電導
膜,第2の酸化物超電導膜を焼結するとともに上記各金
属膜および円筒状部材の表面を絶縁膜に変化させる工程
を有することを特徴とする超電導磁気センサの製造方
法。
7. A step of providing a metal film having a predetermined linear pattern on one surface of each of a plurality of substrates, and a process of penetrating a metal cylindrical member at a position corresponding to an end of the metal film on each of the substrates. A step of integrally connecting the respective substrates via the cylindrical member; and a first oxide superconducting film, which exhibits a magnetoresistive effect on the surfaces of the metal film and the cylindrical member, respectively, by electrophoresis.
Oxide superconducting films are simultaneously deposited, and then heat-treated in an atmosphere containing oxygen to sinter the first oxide superconducting film and the second oxide superconducting film, And a step of changing the surface of the cylindrical member into an insulating film.
【請求項8】 1枚の基板の両面に対称に所定の線状パ
ターンの金属膜を設ける工程と、 上記各基板の上記金属膜の端部に相当する箇所に金属製
の円筒状部材を貫通して上記基板と円筒状部材とを一体
にする工程と、 電気泳動法により、上記金属膜と円筒状部材の表面にそ
れぞれ磁気抵抗効果を示す第1の酸化物超電導膜,第2
の酸化物超電導膜を同時に被着し、続いて、酸素を含む
雰囲気中で熱処理を行って、上記第1の酸化物超電導
膜,第2の酸化物超電導膜を焼結するとともに上記各金
属膜および円筒状部材の表面を絶縁膜に変化させる工程
を有することを特徴とする超電導磁気センサの製造方
法。
8. A step of providing a metal film of a predetermined linear pattern symmetrically on both surfaces of one substrate, and penetrating a metal cylindrical member at a position corresponding to an end of the metal film on each of the substrates. Integrating the substrate and the cylindrical member by electrophoresis. The first oxide superconducting film and the second oxide superconductive film exhibiting a magnetoresistive effect on the surfaces of the metal film and the cylindrical member, respectively.
Oxide superconducting films are simultaneously deposited, and then heat-treated in an atmosphere containing oxygen to sinter the first oxide superconducting film and the second oxide superconducting film, And a step of changing the surface of the cylindrical member into an insulating film.
【請求項9】 複数の基板の両面に、所定の線状パター
ンの金属膜を各基板の両面で対称に設ける工程と、 上記各基板の上記金属膜の一方の端部に相当する箇所に
1本の金属製の第1の円筒状部材を貫通して各基板を一
体に連結するとともに、上記各基板の上記金属膜の他方
の端部に相当する箇所に1枚の基板を貫通する金属製の
第2の円筒状部材を貫通する工程と、 電気泳動法により、上記金属膜の表面に磁気抵抗効果を
示す第1の酸化物超電導膜を被着すると同時に上記第1
および第2の円筒状部材の表面に磁気抵抗効果を示す第
2の酸化物超電導膜を被着し、続いて、酸素を含む雰囲
気中で熱処理を行って、上記第1の酸化物超電導膜,第
2の酸化物超電導膜を焼結するとともに上記各金属膜並
びに第1および第2の円筒状部材の表面を絶縁膜に変化
させる工程と、 上記第1の円筒状部材の端面を被覆している第2の酸化
物超電導膜を除去する工程を有することを特徴とする超
電導磁気センサの製造方法。
9. A step of providing a metal film having a predetermined linear pattern symmetrically on both surfaces of a plurality of substrates on both surfaces of each substrate; and forming one metal film on each of the substrates at a position corresponding to one end of the metal film. The first metal-made cylindrical member of the present invention penetrates one substrate at a position corresponding to the other end of the metal film of each substrate while connecting the substrates integrally with each other. A first oxide superconducting film exhibiting a magnetoresistive effect on the surface of the metal film by electrophoresis,
And applying a second oxide superconducting film exhibiting a magnetoresistive effect to the surface of the second cylindrical member, and subsequently performing a heat treatment in an atmosphere containing oxygen to form the first oxide superconducting film, Sintering the second oxide superconducting film and changing the surface of each of the metal films and the first and second cylindrical members into an insulating film; and covering the end surface of the first cylindrical member. A method for manufacturing a superconducting magnetic sensor, comprising: removing a second oxide superconducting film.
JP4079587A 1992-04-01 1992-04-01 Superconducting magnetic sensor and method of manufacturing the same Expired - Fee Related JP2801462B2 (en)

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