JP2801726B2 - Triallyl isocyanurate composition - Google Patents
Triallyl isocyanurate compositionInfo
- Publication number
- JP2801726B2 JP2801726B2 JP5585590A JP5585590A JP2801726B2 JP 2801726 B2 JP2801726 B2 JP 2801726B2 JP 5585590 A JP5585590 A JP 5585590A JP 5585590 A JP5585590 A JP 5585590A JP 2801726 B2 JP2801726 B2 JP 2801726B2
- Authority
- JP
- Japan
- Prior art keywords
- taic
- weight
- composition
- parts
- tac
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 title claims description 43
- 239000000203 mixture Substances 0.000 title claims description 38
- 239000007788 liquid Substances 0.000 claims description 13
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims description 2
- 238000002844 melting Methods 0.000 description 9
- 230000008018 melting Effects 0.000 description 9
- 238000000034 method Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- 239000005909 Kieselgur Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 3
- 239000004709 Chlorinated polyethylene Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 description 2
- 235000019792 magnesium silicate Nutrition 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- YIWGJFPJRAEKMK-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yl)-3-methyl-8-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carbonyl]-1,3,8-triazaspiro[4.5]decane-2,4-dione Chemical group CN1C(=O)N(c2ccc3n[nH]nc3c2)C2(CCN(CC2)C(=O)c2cnc(NCc3cccc(OC(F)(F)F)c3)nc2)C1=O YIWGJFPJRAEKMK-UHFFFAOYSA-N 0.000 description 1
- NOSXUFXBUISMPR-UHFFFAOYSA-N 1-tert-butylperoxyhexane Chemical compound CCCCCCOOC(C)(C)C NOSXUFXBUISMPR-UHFFFAOYSA-N 0.000 description 1
- 239000004135 Bone phosphate Substances 0.000 description 1
- ZOBLCVKESRYZRS-UHFFFAOYSA-N Cl.Cl.Cl.S(=O)(=O)(O)O Chemical compound Cl.Cl.Cl.S(=O)(=O)(O)O ZOBLCVKESRYZRS-UHFFFAOYSA-N 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical group O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- FHKPLLOSJHHKNU-INIZCTEOSA-N [(3S)-3-[8-(1-ethyl-5-methylpyrazol-4-yl)-9-methylpurin-6-yl]oxypyrrolidin-1-yl]-(oxan-4-yl)methanone Chemical group C(C)N1N=CC(=C1C)C=1N(C2=NC=NC(=C2N=1)O[C@@H]1CN(CC1)C(=O)C1CCOCC1)C FHKPLLOSJHHKNU-INIZCTEOSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は合成樹脂の変性剤、改質剤、架橋剤などとし
て広く使用されているトリアリルイソシアヌレートに代
わり得るもので、合成樹脂の物性を損なうことなくむし
ろ向上させ、低温下においても液状を保持せしめ、使用
し際して取扱を容易にしたトリアリルイソシアヌレート
系組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention is an alternative to triallyl isocyanurate, which is widely used as a modifier, modifier, cross-linking agent, etc. for synthetic resins. The present invention relates to a triallyl isocyanurate-based composition which has been improved without impairing its properties, has a liquid state even at a low temperature, and is easy to handle when used.
従来、トリアリルイソシアヌレート（以下TAICとい
う）は、塩素化ポリエチレン、EPDM、EVA、各種ゴム等
の過酸化物架橋、放射線架橋の架橋助剤、或はポリオレ
フィンの架橋助剤として広く使用されている。その他、
TAIC以外のビニール型モノマーとの共重合反応を利用し
て、ポリマーに耐熱性、耐候性、耐衝撃性、機械的強
度、接着性を付与する目的にも使用される。Conventionally, triallyl isocyanurate (hereinafter referred to as TAIC) has been widely used as a crosslinking aid for peroxide crosslinking and radiation crosslinking of chlorinated polyethylene, EPDM, EVA, and various rubbers, or as a crosslinking aid for polyolefins. . Others
It is also used for the purpose of imparting heat resistance, weather resistance, impact resistance, mechanical strength, and adhesiveness to a polymer by utilizing a copolymerization reaction with a vinyl monomer other than TAIC.
また、トリアリルシアヌレート（以下TACという）もT
AICと同様な用途を有するが、その選択は、ユーザ毎、
用途毎に行われている。Triallyl cyanurate (hereinafter referred to as TAC) is also T
It has a similar use as AIC, but its choice is per user,
It is performed for each application.
上記、TAIC,TACは、いずれもそれぞれ単独で使用され
ている。The above TAIC and TAC are each used independently.
しかしながら、上記TAIC,TACの融点は、それぞれ24
℃,27℃で、冬季には固化し、その取扱いに支障をきた
す。However, the melting points of TAIC and TAC are 24
℃, 27 ℃, solidifies in the winter and hinders its handling.
通常、外部温度が融点以下となった場合には、融点以
上の温度に保持された場所に保存するか、或は、使用す
る際に温水浴等でそのつど融解して使用している。Usually, when the external temperature becomes lower than the melting point, it is stored in a place maintained at a temperature higher than the melting point, or is melted in a hot water bath or the like at the time of use.
また、商品として市販されているコンパウド品（珪藻
土にTAICを含浸させたもの）も冬季には固化に伴い塊状
し、使用に際しては、保温して塊状となるのを防止する
か、加温して融解するか、或は塊状のもの粉砕して使用
するなど、いずれも煩雑な操作を必要とした。In addition, the commercially available compound products (diatomaceous earth impregnated with TAIC) also solidify in the winter due to solidification. Either melting or pulverizing a lump and using it all required complicated operations.
さらに、液状態を保持させるため、長期間加温保存す
ると、着色、重合などによる劣化の原因となる不都合が
あった。Furthermore, if the liquid state is kept for a long period of time in order to maintain the liquid state, there is a disadvantage that it causes deterioration due to coloring, polymerization and the like.
本発明者らは上記の問題を解決すべく種々検討した結
果、TAIC,TACを溶融状態で混合すると、その組成物の融
点が、冬季においても固化することのない融点に降下す
ることを知見した。The present inventors have conducted various studies to solve the above problems, and found that when TAIC and TAC are mixed in a molten state, the melting point of the composition drops to a melting point that does not solidify even in winter. .
本発明は上記の知見に基づいてなされたもので、冬季
においても液状態を保持し、しかも架橋助剤やその他の
用途としてTAICに勝るとも劣らない、性能を有するTAIC
系組成物を提供することを目的とする。The present invention has been made on the basis of the above findings, and retains a liquid state even in winter, and is not inferior to TAIC as a crosslinking aid or other uses, and has a performance of TAIC.
It is intended to provide a system composition.
上記の目的を達成するため、本発明のTAIC系組成物
は、TAICI重量部に対してTAC0.05〜1.5重量部を、液状
で混合させてなる。In order to achieve the above object, the TAIC composition of the present invention is obtained by mixing 0.05 to 1.5 parts by weight of TAC with respect to part by weight of TAICI in a liquid state.
本発明に用いられるTAIC,TACは、その製造方法に拘束
されず、一般市販品のものが用いられる。The TAIC and TAC used in the present invention are not restricted by the production method, and generally available products are used.
混合割合は、TAIC1重量部に対してTACが0.05〜1.5重
量部、特に、0.1〜0.8重量部が好ましい。As for the mixing ratio, TAC is preferably 0.05 to 1.5 parts by weight, particularly preferably 0.1 to 0.8 parts by weight based on 1 part by weight of TAIC.
TAIC1重量部に対するTACの混合量が0.05重量部未満で
も、1.5重量部を越えても、TAIC系組成物の融点は15℃
以上となり、液状を保持した状態での劣化は促進され、
使用可能期間が短くなる。Even if the mixing amount of TAC with respect to 1 part by weight of TAIC is less than 0.05 part by weight or exceeds 1.5 parts by weight, the melting point of the TAIC composition is 15 ° C.
As described above, deterioration in a state where the liquid is held is promoted,
The usable period is shortened.
TAICとTACの混合方法は、混合する際、両者が液状で
あれば、添加順、添加方法等には特に制限なく、例え
ば、固体のTAICに所定量のTACを加え、混浴などで溶融
した後混合、或はいずれか一方を溶融し、これに他方の
固体を入れた後溶融し、混合してもよい。The mixing method of TAIC and TAC, when mixing, if both are liquid, the order of addition, there is no particular limitation on the method of addition, for example, after adding a predetermined amount of TAC to solid TAIC, after melting in a mixed bath etc. It is also possible to melt or mix one or the other, put the other solid in this and then melt and mix.
上記液状で混合されたTAIC系組成物は、融点が低く、
冬期においても室内に保存しておけば液状となっている
ので、合成樹脂に添加する場合の添加量が自由に調整可
能で、分散混合性に優れ、取扱いが極めて容易である。The TAIC composition mixed in the above liquid has a low melting point,
Even in the winter, if it is stored indoors, it will be in a liquid state, so the amount of addition to the synthetic resin can be adjusted freely, it will have excellent dispersibility and mixing properties, and it will be extremely easy to handle.
また、従来、TAICが珪藻土等の粉末と混合して用いら
れているように、本発明のTAIC系組成物も、珪藻土粉末
に混合して用いられるが、低温下で液状であるので、加
温することなく均一に混合され、放置しておいても含浸
したTAIC系組成物が固化して塊状となることがないの
で、粉状に保持され、使用時に粉砕する必要もない。Also, conventionally, as in the case where TAIC is used by mixing with a powder of diatomaceous earth or the like, the TAIC-based composition of the present invention is also used by being mixed with diatomaceous earth powder. Even when the TAIC composition is impregnated and left undisturbed, the impregnated TAIC composition does not solidify into a lump, so that the TAIC composition is kept in a powdery state and does not need to be ground when used.
次に実施例、比較例を示して本発明を具体的に説明す
る。Next, the present invention will be specifically described with reference to Examples and Comparative Examples.
実施例１ 固体のTAIC9重量部およびTAC1重量部を容器に入れ、3
0〜35℃の湯浴にを用いて溶融し、撹拌、混合して、液
状のTAIC系組成物とした。Example 1 9 parts by weight of solid TAIC and 1 part by weight of TAC were placed in a container,
The mixture was melted in a hot water bath at 0 to 35 ° C., stirred and mixed to obtain a liquid TAIC composition.
この組成物の固化温度は８℃であった。 The solidification temperature of this composition was 8 ° C.
次いで、10インチのロール混練機に塩素化ポリエチレ
ン（昭和電工株式会社製造，エラスレンTR）を100重量
部巻付け、これに、予め珪酸マグネシウム80重量部、顔
料カーボンブラック３重量部、三塩基性硫酸鉛10重量
部、酸化アンチモン10重量部を調整混合した混合物およ
び可塑剤であるジイソデシルフタレート20重量部を添加
して混練した。この混練したものに、更に2,5−ジメチ
ル−2,5−ジ（ｔ−ブチルパーオキシ）−ヘキサン（化
薬アクゾ社製，カヤヘキサAD−40）6.3重量部と、上記T
AIC系組成物３重量部を加えて混練した。Then, 100 parts by weight of chlorinated polyethylene (manufactured by Showa Denko KK, Eraslen TR) is wound around a 10-inch roll kneader, and then 80 parts by weight of magnesium silicate, 3 parts by weight of pigment carbon black, tribasic sulfuric acid A mixture obtained by adjusting and mixing 10 parts by weight of lead and 10 parts by weight of antimony oxide and 20 parts by weight of diisodecyl phthalate as a plasticizer were added and kneaded. The kneaded mixture was further mixed with 6.3 parts by weight of 2,5-dimethyl-2,5-di (t-butylperoxy) -hexane (Kayahexa AD-40, manufactured by Kayaku Akzo Co., Ltd.)
3 parts by weight of the AIC composition was added and kneaded.
この最終混練したものをシート出しし、100℃におけ
るムーニー粘度を測定した。また別にシート出しした物
をプレス機にかけ、184℃で10分間架橋した後、ダンベ
ルに打抜き試験片を作製した。The final kneaded product was taken out of a sheet, and the Mooney viscosity at 100 ° C. was measured. Separately, the sheet was put on a press machine, crosslinked at 184 ° C. for 10 minutes, and punched into a dumbbell to prepare a test piece.
この試験片を用いて、引張特性、耐熱性、電気特性等
を測定した。Using this test piece, tensile properties, heat resistance, electrical properties and the like were measured.
実施例２ TAIC8重量部を容器に入れ、30℃の湯浴で溶融し、こ
れにTACの粉末２重量部を添加溶融して混合し、TAIC系
組成物をつくった。この組成物の固化温度は−3.5℃で
あった。Example 2 8 parts by weight of TAIC was put in a container, melted in a water bath at 30 ° C., and 2 parts by weight of TAC powder was added and melted and mixed to prepare a TAIC composition. The solidification temperature of this composition was -3.5 ° C.
この組成物を、実施例１の組成物に代えて用いた以外
は、実施例１と同じにした。This example was the same as Example 1 except that this composition was used in place of the composition of Example 1.
実施例３ 30〜35℃の液状のTAIC7重量部および液状のTAC3重量
部を合体混合しTAIC系組成物をつくった。Example 3 7 parts by weight of liquid TAIC at 30 to 35 ° C and 3 parts by weight of liquid TAC were combined and mixed to prepare a TAIC composition.
この組成物の固化温度は−７℃であった。 The solidification temperature of this composition was -7 ° C.
この組成物を実施例１のTAIC系組成物の代わりに用い
た以外は、実施例１と同じにした。Example 1 was repeated except that this composition was used in place of the TAIC-based composition of Example 1.
比較例１ 実施例１の組成物の代わりに、TAIC単体を用いた以外
は、実施例１と同じにした。Comparative Example 1 The procedure of Example 1 was repeated except that TAIC alone was used instead of the composition of Example 1.
実施例１〜３、比較例１の各種測定結果を一括して、
第１表に示す。Various measurement results of Examples 1 to 3 and Comparative Example 1 are collectively
It is shown in Table 1.
但し、測定方法は、 引張特性:JIS K−6301準拠 ３号ダンベル,500mm/m
in.23℃,60％ 耐熱性:JIS K−6301準拠 120℃×120hrs.熱処理 体積固有抵抗:JIS K−6911準拠 500V,23℃,60％ 酸素指数:JIS K−7201準拠 による。 However, the measurement method is as follows: Tensile properties: JIS K-6301 compliant No. 3 dumbbell, 500mm / m
in. 23 ° C, 60% Heat resistance: JIS K-6301 compliant 120 ° C x 120hrs. Heat treatment Volume specific resistance: JIS K-6911 compliant 500V, 23 ° C, 60% Oxygen index: JIS K-7201 compliant.
第１表より明らかなように本発明の組成物を用いた場
合は、TAIC単体を用いた場合と比較して、伸びが大幅に
改良され、他の物性は損色のないことがわかる。As is clear from Table 1, when the composition of the present invention was used, the elongation was greatly improved and other physical properties were free from discoloration as compared with the case of using TAIC alone.
実施例４ 10インチのロール混練機に塩素化ポリエチレン（昭和
電工株式会社製，エラスレンTR）を100重量部巻付け、
これに予め珪酸マグネシウム90重量部、顔料カーボンブ
ラック３重量部、三塩化硫酸鉛10重量部、酸化アンチモ
ン10重量部および可塑剤であるジイソブチルフタレート
35重量部を添加混練した。この混練したものに更に2,5
−ジメチル−2,5−ジ（ｔ−ブチルパーオキシ）−ヘキ
サン（化薬アクゾ社製，カヤヘキサAD−40）6.3重量部
と塩素化パラフィン３重量部と、実施例１において用い
たTAIC系組成物３重量部を加えて混練した。Example 4 100 parts by weight of chlorinated polyethylene (Eraslen TR, manufactured by Showa Denko KK) was wound around a 10-inch roll kneader.
90 parts by weight of magnesium silicate, 3 parts by weight of carbon black pigment, 10 parts by weight of lead trichloride sulfate, 10 parts by weight of antimony oxide and diisobutyl phthalate as a plasticizer
35 parts by weight were added and kneaded. Add a further 2,5
6.3 parts by weight of -dimethyl-2,5-di (t-butylperoxy) -hexane (Kayahexa AD-40 manufactured by Kayaku Akzo Co., Ltd.), 3 parts by weight of chlorinated paraffin, and the TAIC composition used in Example 1 3 parts by weight of the mixture were added and kneaded.
この最終混練したものをシート出しし、100℃におけ
るムーニー粘度を測定した。また別にシート出しした物
をプレス機にかけ、184℃で10分間架橋した後、ダンベ
ンルに打抜き、試験片を作製した。この試験片を用いて
各種特性を測定した。The final kneaded product was taken out of a sheet, and the Mooney viscosity at 100 ° C. was measured. Separately, a sheet was put on a press, crosslinked at 184 ° C. for 10 minutes, and then punched out into dumbbell to prepare a test piece. Various characteristics were measured using this test piece.
実施例５ TAIC系組成物として、実施例２の組成物を用いた以外
は、実施例４と同じようにした。Example 5 The procedure of Example 4 was repeated except that the composition of Example 2 was used as the TAIC composition.
実施例６ TAIC系組成物として実施例３の組成物を用いた以外
は、実施例４と同じにした。Example 6 The procedure of Example 4 was repeated except that the composition of Example 3 was used as the TAIC composition.
比較例１ 実施例１で用いたTAIC系組成物の代わりにTAIC単体を
用いた以外は、実施例４と同じにした。Comparative Example 1 The procedure of Example 4 was repeated except that the TAIC alone was used instead of the TAIC composition used in Example 1.
実施例４〜６、比較例３の各種測定結果を一括して第
２表に示す。Table 2 shows various measurement results of Examples 4 to 6 and Comparative Example 3.
但し、測定方法は、 引張特性:JIS K−6301準拠 ３号ダンベル,500mm/m
in.23℃,60％ 耐熱性:JIS K−6301準拠 120℃×120hrs.熱処理 耐油性:JIS K−6301準拠 ASTM No.2油120℃×18hr
s.処理 圧縮永久歪み:JIS K−6301準拠 70℃×22hrs.処理 体積固有抵抗:JIS K−6911準拠 500V,23℃,60％ 酸素指数:JIS K−7201準拠 による。 However, the measurement method is as follows: Tensile properties: JIS K-6301 compliant No. 3 dumbbell, 500mm / m
in.23 ℃, 60% Heat resistance: JIS K-6301 compliant 120 ℃ × 120hrs.Heat treatment Oil resistance: JIS K-6301 compliant ASTM No.2 oil 120 ℃ × 18hr
s. Treatment Compression set: JIS K-6301 compliant 70 ° C x 22hrs. Treatment Volume resistivity: JIS K-6911 compliant 500V, 23 ° C, 60% Oxygen index: JIS K-7201 compliant.
以上説明したように、本発明のTAIC系組成物は、それ
ぞれの単体に比べて固化温度が大幅に低下するので固化
しなくなり、従来低温期間中には、使用するたびに加温
溶解して使用しなければならなかった煩雑さから解放さ
れる。また珪藻土類粉末等に含浸させたコパウンド品
も、溶融液化する必要がなく、混合均一化し、しかもブ
ロッキングしないので、取扱いが容易となる。しかも、
重合体に用いてもTAIC単体を用いた場合と損色なく、対
象物によっては、伸びが増大する等、多くの利点を有す
る。As described above, the TAIC-based composition of the present invention does not solidify because the solidification temperature is significantly reduced as compared with each of the individual components. Freed from the hassle that had to be done. Also, a compound product impregnated with diatomaceous earth powder or the like does not need to be melted and liquefied, is uniformly mixed, and does not block, so that it is easy to handle. Moreover,
Even if it is used for a polymer, it has many advantages, such as an increase in elongation depending on the object, without color loss as compared with the case of using TAIC alone.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 中村 輝雄 神奈川県川崎市川崎区千鳥町３―２ 昭 和電工株式会社川崎樹脂研究所内 (58)調査した分野(Int.Cl.6，ＤＢ名) C08F 251/00 - 292/00 C08F 226/06 C08K 5/3492──────────────────────────────────────────────────続 き Continuation of front page (72) Inventor Teruo Nakamura 3-2 Chidoricho, Kawasaki-ku, Kawasaki-shi, Kanagawa Prefecture Showa Denko KK Kawasaki Resin Research Institute (58) Field surveyed (Int.Cl. 6 , DB name) C08F 251/00-292/00 C08F 226/06 C08K 5/3492
Claims (1)
し、トリアリルシアヌレートを0.05〜1.5重量部を、液
状で混合させてなるトリアリルイソシアヌレート系組成
物。1. A triallyl isocyanurate-based composition obtained by mixing 0.05 to 1.5 parts by weight of triallyl cyanurate with 1 part by weight of triallyl isocyanurate in a liquid state.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5585590A JP2801726B2 (en) | 1990-03-07 | 1990-03-07 | Triallyl isocyanurate composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5585590A JP2801726B2 (en) | 1990-03-07 | 1990-03-07 | Triallyl isocyanurate composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03258818A JPH03258818A (en) | 1991-11-19 |
| JP2801726B2 true JP2801726B2 (en) | 1998-09-21 |
Family
ID=13010669
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5585590A Expired - Fee Related JP2801726B2 (en) | 1990-03-07 | 1990-03-07 | Triallyl isocyanurate composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2801726B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006299147A (en) * | 2005-04-22 | 2006-11-02 | Asahi Kasei Chemicals Corp | Cross-linking agent |
-
1990
- 1990-03-07 JP JP5585590A patent/JP2801726B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH03258818A (en) | 1991-11-19 |
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