JP2803584B2 - Flexible sheath made of PVF3 and its application to flexible metal tubes - Google Patents
Flexible sheath made of PVF3 and its application to flexible metal tubesInfo
- Publication number
- JP2803584B2 JP2803584B2 JP6313351A JP31335194A JP2803584B2 JP 2803584 B2 JP2803584 B2 JP 2803584B2 JP 6313351 A JP6313351 A JP 6313351A JP 31335194 A JP31335194 A JP 31335194A JP 2803584 B2 JP2803584 B2 JP 2803584B2
- Authority
- JP
- Japan
- Prior art keywords
- sheath
- flexible
- tube
- pvf3
- application
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D23/00—Producing tubular articles
- B29D23/001—Pipes; Pipe joints
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/14—Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
- F16L9/147—Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups comprising only layers of metal and plastics with or without reinforcement
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/12—Use of polyvinylhalogenides or derivatives thereof as moulding material containing fluorine
- B29K2027/14—PVF, i.e. polyvinyl fluoride
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Laminated Bodies (AREA)
- Insulated Conductors (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Details Of Indoor Wiring (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、PVF3 製のたわみシー
ス及びたわみ金属管へのその適用に関する。The present invention relates to a flexible sheath made of PVF 3 and its application to a flexible metal tube.
【０００２】[0002]
【従来の技術】海洋油及びガスの採掘には、通常、たわ
み管が使用されている。これらのたわみ管は、内部のた
わみ鋼管と、油及びガスの漏れ防止のための機能を有す
るプラスチックシースと、金属外装とからなる。このよ
うなたわみ管は、例えば、ヨーロッパ特許EP 166,385に
記載されている。BACKGROUND OF THE INVENTION Flexible tubing is commonly used for marine oil and gas mining. These flexible pipes include an internal flexible steel pipe, a plastic sheath having a function of preventing leakage of oil and gas, and a metal sheath. Such a flexible tube is described, for example, in European Patent EP 166,385.
【０００３】流体の採掘の温度が80〜100 ℃を超えない
場合には、ポリアミドが漏れ防止の熱可塑性樹脂シース
として使用される。If the fluid mining temperature does not exceed 80 to 100 ° C., polyamide is used as a leak-proof thermoplastic sheath.
【０００４】高温、例えば、 130℃又は140 ℃までの温
度においては、ポリ（フッ化ビニリデン）が使用され
る。しかしながら、かかるポリマーは半結晶質で、高い
剛性を有するので、そのポリマーを使用すると、時々、
きわめて低温において、内部又は外部可塑化に頼ること
なしにコイル状に巻いたりコイル状のものをほどいたり
して意図する構造にすることはできない。At high temperatures, for example up to 130 ° C. or 140 ° C., poly (vinylidene fluoride) is used. However, because such polymers are semi-crystalline and have high rigidity, the use of such polymers sometimes results in
At very low temperatures, the desired structure cannot be obtained by coiling or uncoiling without resorting to internal or external plasticization.
【０００５】内部可塑化の一例が、上記の特許EP 166,3
85に挙げられている：フッ化ビニリデンを、フッ素化モ
ノマーで共重合する。したがって、そのシースのたわみ
性は増大するが、その使用温度は一般的に低くなり、し
かもそのガスの透過性が増大して突然の減圧による破裂
に対する感応性が（ホモポリマーに対して）高まるとい
うことが観察されるので、そのシースを使用すると、高
い温度及び操作圧力に対する危険が生じる。One example of internal plasticization is described in the above-mentioned patent EP 166,3.
Listed at 85: Vinylidene fluoride is copolymerized with a fluorinated monomer. Thus, while the flexibility of the sheath is increased, the operating temperature is generally lower, and the gas permeability is increased, making it more susceptible to bursting due to sudden decompression (relative to homopolymers). As a result, the use of the sheath poses a danger to high temperatures and operating pressures.
【０００６】外部可塑剤の使用については、フランスの
特許 2,560,884、2,592,655 及び 2,618,791に言及され
ている。可塑剤の中にはホモポリマーであるPVDFを柔軟
にすることによってたわみ管の取り扱い中のそのPVDFの
使用を可能にするものもある。しかしながら、操作中、
一般的にPVDFに非常に適合する可塑剤が減少することに
よって、シースがその本来の剛性をゆっくりと回復する
ということが観察される。剛性が増大するだけでなく、
可塑剤が減少し、しかもシースの収縮が妨げられる傾向
にあることにより、内部応力が発生する結果、脆化も引
き起こされる。[0006] The use of external plasticizers is mentioned in French patents 2,560,884, 2,592,655 and 2,618,791. Some plasticizers allow the use of a homopolymer PVDF during flex tube handling by softening the PVDF. However, during operation,
It is generally observed that the sheath slowly recovers its original stiffness due to the decrease in plasticizer that is very compatible with PVDF. Not only increases rigidity,
The reduction in plasticizer and the tendency to prevent shrinkage of the sheath also results in internal stress, which also causes embrittlement.
【０００７】[0007]
【発明が解決しようとする課題】本発明の目的は、上記
のようなPVDFの内部又は外部可塑化による不都合がな
い、たわみ性に優れたシース、並びに該シースで被覆さ
れた金属管及びケーブルを提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to provide a sheath having excellent flexibility and a metal tube and a cable covered with the sheath, which are free from the above-mentioned disadvantages caused by plasticization of PVDF inside or outside. To provide.
【０００８】[0008]
【課題を解決するための手段】必要とされるPVDFの内部
又は外部可塑化によるこれら全ての不都合は、トリフル
オロエチレン単位を含むポリマーの使用により克服され
ることがわかった。出願人は、トリフルオロエチレン単
位を含むポリマーを使用することによって特にたわみや
すいシース（又は管）を製造することができるというこ
とを発見した。SUMMARY OF THE INVENTION It has been found that all these disadvantages due to the required internal or external plasticization of PVDF are overcome by the use of polymers containing trifluoroethylene units. Applicants have discovered that a particularly flexible sheath (or tube) can be made by using a polymer containing trifluoroethylene units.
【０００９】したがって、PVDFから生み出される使用温
度よりもずっと高い使用温度を有するシースが得られ
る。さらに、そのシースはきわめてたわみ性に優れる。[0009] Thus, a sheath having a use temperature much higher than the use temperature produced from PVDF is obtained. Furthermore, the sheath is extremely flexible.
【００１０】また、トリフルオロエチレン（VF3）の他
に、本発明のシースのポリマーは、クロロトリフルオロ
エチレン、テトラフルオロエチレン、ヘキサフルオロプ
ロペン、フッ化ビニリデン、又はエチレン単位の残基も
含んでいてもよい。In addition to trifluoroethylene (VF 3 ), the polymer of the sheath of the present invention also contains chlorotrifluoroethylene, tetrafluoroethylene, hexafluoropropene, vinylidene fluoride, or a residue of an ethylene unit. May be.
【００１１】充填剤、顔料、又はたとえ少量のエステル
又はスルホンアミド形の可塑剤を添加しても本発明の範
囲から逸脱することはない。The addition of fillers, pigments or even small amounts of plasticizers in the ester or sulfonamide form does not depart from the scope of the invention.
【００１２】また、本発明は、本発明によるシースで被
覆されたたわみ金属管に関する。[0012] The invention also relates to a flexible metal tube covered with a sheath according to the invention.
【００１３】得られるたわみ管は、特に、液体状又は気
体状の炭化水素を高温で輸送するのに有用である。さら
に、かかるたわみ管は、ゴム、金属、編布 (textile cl
oth)のような保護層で被覆されていてもよい。The resulting flexible tubes are particularly useful for transporting liquid or gaseous hydrocarbons at elevated temperatures. In addition, such flexible tubes are made of rubber, metal, knitted fabric (textile cl
oth).
【００１４】ガスの輸送のために、シースのポリマーは
実質的にトリフルオロエチレンのホモポリマーであるの
が好ましい。For gas transport, the sheath polymer is preferably substantially a homopolymer of trifluoroethylene.
【００１５】また、本発明は、本発明のシースで被覆さ
れたケーブルに関する。[0015] The present invention also relates to a cable covered with the sheath of the present invention.
【００１６】ケーブル又はたわみ管はいずれにせよ、押
出法によってこのシースで被覆され得る。[0016] The cable or flexible tube can in any case be covered with this sheath by extrusion.
【００１７】ケーブルは、金属線、又はストランドもし
くは金属ケーブルを形成する多数のストランドであり得
る。The cable may be a metal wire, or a strand or multiple strands forming a metal cable.
【００１８】[0018]
【実施例】接合を可能にするためのくぼみ及び割れ目が
その間に存在するターンからなる直径32mmのたわみ鋼管
の周囲に、厚さ５mmの熱可塑性樹脂シースを押し出し成
形した。EXAMPLE A 5 mm thick thermoplastic sheath was extruded around a 32 mm diameter flexible steel tube consisting of turns with cavities and crevices between them to allow joining.
【００１９】巻きつけたシースを構成する種々の材料の
能力を比較するために、下記の手順が利用できる：シー
ズされた管を二つの固定した支持体の上に置く。半径75
mmの曲げ車輪を用いて、管を支持している二つの支持体
から等距離の地点に圧力をかける。シーズされた管を変
形し、管に車輪の曲率半径をもたらすのに必要な圧力を
車輪にかける。車輪のくぼみ深さは、たわみ管の変形能
力を示す。最大深さは 170mmである：この最大深さは、
シース管が車輪に沿って完全に輪状になったことに相当
する。シース管が完全に輪状になる前に破壊が生じる場
合、その深さを記録する。深さが大きい程、たわみ管の
曲げ能力は大きい。To compare the capabilities of the various materials that make up the wound sheath, the following procedure is available: The sheathed tube is placed on two fixed supports. Radius 75
Using a bending wheel of mm, pressure is applied at a point equidistant from the two supports supporting the tube. The wheel is subjected to the necessary pressure to deform the sheathed tube and provide the tube with a radius of curvature of the wheel. The depression depth of the wheel indicates the deformability of the flexible tube. The maximum depth is 170mm: this maximum depth is
This corresponds to the sheath tube being completely annular along the wheel. If the break occurs before the sheath tube is completely looped, record its depth. The greater the depth, the greater the bending capacity of the flexible tube.
【００２０】さらに、種々の温度で試験を行った。実施例１ Further, tests were performed at various temperatures. Example 1
【００２１】[0021]
【表１】 [Table 1]
【００２２】シースＩ ： VF2 ホモポリマー −Elf Atochem 社製のフォラフロン1000 (Foraflon 100
0) シースII ： VF2 ホモポリマー ＋N-ブチルベンゼンスルホンアミドを重量基準で 7.5％ シースIII ： VF2 及びヘキサフルオロプロペンのモル
比95/5の共重合体 シースIV ： VF3 ホモポリマーSheath I: VF 2 homopolymer-Foraflon 100 manufactured by Elf Atochem
0) Sheath II: VF 2 homopolymer + N-butyl benzenesulfonamide 7.5% by weight sheath III: VF 2 and copolymers sheath molar ratio 95/5 hexafluoropropene IV: VF 3 homopolymer
【００２３】実施例２ ４種のシースたわみ管に 150℃で３ヵ月間熱エージング
を実施した。次に、上記のような試験を行った。 Example 2 Four kinds of sheath flexible tubes were heat-aged at 150 ° C. for 3 months. Next, the test as described above was performed.
【００２４】[0024]
【表２】 [Table 2]
【００２５】実施例３ ４種のシースたわみ管に 180℃で３ヵ月間熱エージング
を実施した。次に、上記のような試験を行った。 Example 3 Four kinds of sheath flexible tubes were heat-aged at 180 ° C. for 3 months. Next, the test as described above was performed.
【００２６】[0026]
【表３】 [Table 3]
【００２７】[0027]
【発明の効果】本発明のシースは、たわみ性に優れてお
り、PVDF製のシースよりもかなり高い温度で使用するこ
とができる。また、かかるシースで被覆された本発明の
たわみ金属管は、例えば、海洋たわみ管として利用する
ことができる。The sheath of the present invention has excellent flexibility and can be used at a considerably higher temperature than a sheath made of PVDF. The flexible metal tube of the present invention covered with such a sheath can be used, for example, as a marine flexible tube.
フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ Ｈ０１Ｂ 7/18 Ｈ０１Ｂ 7/18 Ｈ // Ｂ２９Ｋ 27:12 (58)調査した分野(Int.Cl.6，ＤＢ名) B29D 23/00 B32B 15/08 C08F 214/18 C08J 5/00 C08L 27/12 H01B 7/18 B29K 27:12Continuation of the front page (51) Int.Cl. 6 identification symbol FI H01B 7/18 H01B 7/18 H // B29K 27:12 (58) Fields investigated (Int.Cl. 6 , DB name) B29D 23/00 B32B 15/08 C08F 214/18 C08J 5/00 C08L 27/12 H01B 7/18 B29K 27:12
Claims (5)
ーを基材とするたわみシース。1. A flexible sheath based on a polymer containing trifluoroethylene units.
ロエチレン、テトラフルオロエチレン、ヘキサフルオロ
プロペン、フッ化ビニリデン、又はエチレン単位の残基
を含むことを特徴とする、請求項１記載の製品。2. The product according to claim 1, wherein the polymer further comprises residues of chlorotrifluoroethylene, tetrafluoroethylene, hexafluoropropene, vinylidene fluoride or ethylene units.
たたわみ金属管。3. A flexible metal tube covered with the sheath according to claim 1.
たケーブル。4. A cable covered with the sheath according to claim 1.
塑剤を含む、請求項３又は４記載の製品。5. The product according to claim 3, wherein the sheath further comprises a filler, a pigment, or a plasticizer.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9315235A FR2714140B1 (en) | 1993-12-17 | 1993-12-17 | Flexible sheath in PVF3 and its application to metallic hoses. |
| FR9315235 | 1993-12-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07276523A JPH07276523A (en) | 1995-10-24 |
| JP2803584B2 true JP2803584B2 (en) | 1998-09-24 |
Family
ID=9454071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6313351A Expired - Lifetime JP2803584B2 (en) | 1993-12-17 | 1994-12-16 | Flexible sheath made of PVF3 and its application to flexible metal tubes |
Country Status (15)
| Country | Link |
|---|---|
| JP (1) | JP2803584B2 (en) |
| KR (1) | KR950018074A (en) |
| CN (1) | CN1114932A (en) |
| AU (1) | AU688413B2 (en) |
| BE (1) | BE1009248A3 (en) |
| BR (1) | BR9405112A (en) |
| CA (1) | CA2138355A1 (en) |
| DE (1) | DE4445083A1 (en) |
| DK (1) | DK143794A (en) |
| FI (1) | FI945931A7 (en) |
| FR (1) | FR2714140B1 (en) |
| GB (1) | GB2284819B (en) |
| IT (1) | IT1271733B (en) |
| NO (1) | NO944863L (en) |
| SE (1) | SE9404251L (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9611668D0 (en) * | 1996-06-05 | 1996-08-07 | Balmoral Group | Pipe coating |
| CN1100081C (en) * | 2000-08-01 | 2003-01-29 | 上海天臣新技术有限公司 | Antiforge pressure-sensitive marker of high-molecular porous compound film and its preparing process |
| JP5413454B2 (en) | 2009-03-23 | 2014-02-12 | ダイキン工業株式会社 | Fluorine resin and riser pipe |
| BR112019019919B1 (en) | 2017-05-10 | 2023-10-17 | Daikin Industries, Ltd | SHEET, LAMINATE, TUBE, RISER TUBE, AND FLOW LINE |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2739246A1 (en) * | 1977-08-31 | 1979-03-15 | Siemens Ag | Wires with balloon insulation of polyester or fluorocarbon! - giving low dielectric constant and good stability |
| JPS5951421B2 (en) * | 1978-01-24 | 1984-12-13 | 旭硝子株式会社 | Piping materials suitable for moist heat fluids |
| DE3105971A1 (en) * | 1981-02-18 | 1982-08-19 | The Kendall Co., 02101 Boston, Mass. | METHOD FOR COATING TUBES |
| JPS59177199A (en) * | 1983-03-26 | 1984-10-06 | Kurita Water Ind Ltd | Method for suppressing bacterial growth in piping |
| JPS59200202A (en) * | 1983-04-27 | 1984-11-13 | Sumitomo Chem Co Ltd | Optical transmission fiber |
| FR2560884B1 (en) * | 1984-03-06 | 1986-10-03 | Inst Francais Du Petrole | VINYLIDENE POLYFLUORIDE COMPOSITIONS WITH IMPROVED FLEXIBILITY AND THEIR USE, IN PARTICULAR IN THE MANUFACTURE OF FLEXIBLE TUBES |
| NO165612C (en) * | 1984-06-20 | 1991-03-06 | Furukawa Electric Co Ltd | FLEXIBLE COMPOSITION ROOM FOR TRANSPORTING A HIGH-TEMPERATURE FLUID. |
| US4692381A (en) * | 1984-07-16 | 1987-09-08 | Pennwalt Corporation | Foamable polyvinylidene fluoride and methods |
| FR2592655B1 (en) * | 1986-01-07 | 1988-07-29 | Atochem | COMPOSITE BASED ON VINYLIDENE POLYFLUORIDE WITH IMPROVED HOLD IN CONTACT WITH HYDROCARBONS - APPLICATION TO THE MANUFACTURE OF TUBE FOR THE OIL INDUSTRY. |
| JPS6374010A (en) * | 1986-09-18 | 1988-04-04 | Toray Ind Inc | Plastic optical fiber having good heat resistance |
| JPH0640164B2 (en) * | 1987-04-22 | 1994-05-25 | セントラル硝子株式会社 | Heat resistant optical transmission fiber |
| FR2618791B1 (en) * | 1987-07-31 | 1989-12-29 | Inst Francais Du Petrole | POLYMER COMPOSITIONS COMPRISING VINYLIDENE POLYFLUORIDE AND AN ELASTOMER, THEIR PREPARATION AND THEIR USES |
| GB2223188B (en) * | 1988-08-26 | 1992-04-15 | Usui Kokusai Sangyo Kk | Coated metal pipe and method for manufacturing the same |
| BE1006615A3 (en) * | 1993-01-25 | 1994-11-03 | Solvay | Polymer compositions intended for the cables manufacturing and pipes flexible and articles made therefrom. |
-
1993
- 1993-12-17 FR FR9315235A patent/FR2714140B1/en not_active Expired - Fee Related
-
1994
- 1994-12-07 SE SE9404251A patent/SE9404251L/en not_active Application Discontinuation
- 1994-12-12 GB GB9425010A patent/GB2284819B/en not_active Expired - Fee Related
- 1994-12-13 IT ITMI942500A patent/IT1271733B/en active IP Right Grant
- 1994-12-15 BR BR9405112A patent/BR9405112A/en active Search and Examination
- 1994-12-15 NO NO944863A patent/NO944863L/en unknown
- 1994-12-16 KR KR1019940034679A patent/KR950018074A/en not_active Withdrawn
- 1994-12-16 AU AU81501/94A patent/AU688413B2/en not_active Ceased
- 1994-12-16 DE DE4445083A patent/DE4445083A1/en not_active Withdrawn
- 1994-12-16 BE BE9401137A patent/BE1009248A3/en not_active IP Right Cessation
- 1994-12-16 CA CA002138355A patent/CA2138355A1/en not_active Abandoned
- 1994-12-16 JP JP6313351A patent/JP2803584B2/en not_active Expired - Lifetime
- 1994-12-16 DK DK143794A patent/DK143794A/en not_active Application Discontinuation
- 1994-12-16 FI FI945931A patent/FI945931A7/en not_active Application Discontinuation
- 1994-12-17 CN CN94119528A patent/CN1114932A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| AU688413B2 (en) | 1998-03-12 |
| SE9404251A0 (en) | 1995-06-18 |
| JPH07276523A (en) | 1995-10-24 |
| NO944863D0 (en) | 1994-12-15 |
| FR2714140B1 (en) | 1996-01-19 |
| GB2284819B (en) | 1997-11-19 |
| DE4445083A1 (en) | 1995-06-22 |
| IT1271733B (en) | 1997-06-04 |
| BE1009248A3 (en) | 1997-01-07 |
| NO944863L (en) | 1995-06-19 |
| SE9404251D0 (en) | 1994-12-07 |
| ITMI942500A1 (en) | 1996-06-13 |
| GB9425010D0 (en) | 1995-02-08 |
| CN1114932A (en) | 1996-01-17 |
| KR950018074A (en) | 1995-07-22 |
| AU8150194A (en) | 1995-06-22 |
| FI945931L (en) | 1995-06-18 |
| SE9404251L (en) | 1995-06-18 |
| FR2714140A1 (en) | 1995-06-23 |
| FI945931A0 (en) | 1994-12-16 |
| ITMI942500A0 (en) | 1994-12-13 |
| BR9405112A (en) | 1995-08-08 |
| FI945931A7 (en) | 1995-06-18 |
| GB2284819A (en) | 1995-06-21 |
| DK143794A (en) | 1995-06-18 |
| CA2138355A1 (en) | 1995-06-18 |
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