JP2805632B2 - Prepack agent - Google Patents
Prepack agentInfo
- Publication number
- JP2805632B2 JP2805632B2 JP8178189A JP8178189A JP2805632B2 JP 2805632 B2 JP2805632 B2 JP 2805632B2 JP 8178189 A JP8178189 A JP 8178189A JP 8178189 A JP8178189 A JP 8178189A JP 2805632 B2 JP2805632 B2 JP 2805632B2
- Authority
- JP
- Japan
- Prior art keywords
- agent
- film
- pack
- glycol
- forming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920003169 water-soluble polymer Polymers 0.000 claims description 6
- 239000003974 emollient agent Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 description 21
- 230000000694 effects Effects 0.000 description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 16
- 238000004140 cleaning Methods 0.000 description 11
- -1 alkylene glycols Chemical class 0.000 description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 8
- 210000003491 skin Anatomy 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 238000012856 packing Methods 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 239000008213 purified water Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 235000010493 xanthan gum Nutrition 0.000 description 3
- 239000000230 xanthan gum Substances 0.000 description 3
- 229940082509 xanthan gum Drugs 0.000 description 3
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 2
- 241000416162 Astragalus gummifer Species 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 229920002385 Sodium hyaluronate Polymers 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 229920001615 Tragacanth Polymers 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 235000010407 ammonium alginate Nutrition 0.000 description 2
- 239000000728 ammonium alginate Substances 0.000 description 2
- KPGABFJTMYCRHJ-YZOKENDUSA-N ammonium alginate Chemical compound [NH4+].[NH4+].O1[C@@H](C([O-])=O)[C@@H](OC)[C@H](O)[C@H](O)[C@@H]1O[C@@H]1[C@@H](C([O-])=O)O[C@@H](O)[C@@H](O)[C@H]1O KPGABFJTMYCRHJ-YZOKENDUSA-N 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 229940051250 hexylene glycol Drugs 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 2
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 2
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 2
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 2
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 2
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 239000001814 pectin Substances 0.000 description 2
- 235000010987 pectin Nutrition 0.000 description 2
- 229920001277 pectin Polymers 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 210000002826 placenta Anatomy 0.000 description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 2
- 229940010747 sodium hyaluronate Drugs 0.000 description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 235000010487 tragacanth Nutrition 0.000 description 2
- 229940116362 tragacanth Drugs 0.000 description 2
- 150000003700 vitamin C derivatives Chemical class 0.000 description 2
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- 229940043375 1,5-pentanediol Drugs 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 1
- 229920000856 Amylose Polymers 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229920002683 Glycosaminoglycan Polymers 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229920001938 Vegetable gum Polymers 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000000305 astragalus gummifer gum Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940008396 carrot extract Drugs 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- KXKPYJOVDUMHGS-OSRGNVMNSA-N chondroitin sulfate Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](OS(O)(=O)=O)[C@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](C(O)=O)O1 KXKPYJOVDUMHGS-OSRGNVMNSA-N 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- BDWFYHUDXIDTIU-UHFFFAOYSA-N ethanol;propane-1,2,3-triol Chemical compound CCO.OCC(O)CO BDWFYHUDXIDTIU-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 210000000434 stratum corneum Anatomy 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
【発明の詳細な説明】 [産業上の利用分野] 本発明は、皮膚柔軟剤10重量%以上と水溶性高分子と
を配合したプレパック剤、更に詳細には皮膜形成型パッ
ク剤の前に使用する皮膚外用剤に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a prepack containing 10% by weight or more of an emollient and a water-soluble polymer, and more particularly to a use before a film-forming pack. And a skin external preparation.
[従来の技術] 乾燥後に皮膜を形成しないタイプのパック剤に比し
て、皮膜形成型パック剤は、皮膚面から蒸散する水分を
パックの遮蔽効果によってパック層の下にとどまらせ、
以て表面角質層を柔軟化せしめると同時に毛孔を拡げ、
パック剤の毛穴につまったよごれに対する浸透性を向上
させ、乾燥後、はがすことにより洗浄効果を発揮するも
のである。[Prior art] Compared with a pack agent which does not form a film after drying, a film-forming pack agent allows moisture evaporating from the skin surface to remain under the pack layer due to a shielding effect of the pack,
As a result, the surface stratum corneum is softened and at the same time the pores are expanded,
It improves the permeability of the pack agent to dirt clogged in pores, and exerts a cleaning effect by peeling off after drying.
しかしながら、皮膜形成型パック剤は、皮膜の強度の
関係で、乾燥した後皮膚から剥離するのが容易でなく、
痛みさえも伴うものであった。又、効果面においても、
毛穴につまった角栓やよごれを取る上で十分なものでは
なかった。However, film-forming packs are not easy to peel off from the skin after drying due to the strength of the film,
It was even painful. Also, in terms of effect,
It was not enough to remove horn plugs and dirt from pores.
[発明が解決しようとする課題] 本発明者は、上記した従来の皮膜形成型パック剤の欠
点である (1)皮膚より剥離する時にいたい (2)洗浄効果が十分でない を解決するために鋭意研究をした結果、皮膜形成型パッ
ク剤の前に皮膚柔軟剤と水溶性高分子とを配合した皮膚
外用剤を用いることにより、はじめて所期の目的が達成
できるとの新知見を得た。[Problems to be Solved by the Invention] The present inventor has been keen to solve the drawbacks of the above-mentioned conventional film-forming pack agents: (1) when peeling off from the skin; and (2) insufficient cleaning effect. As a result of the research, we have obtained a new finding that the intended purpose can be achieved for the first time by using an external preparation for skin containing a softening agent and a water-soluble polymer before a film-forming pack.
[課題を解決するための手段] すなわち、本発明は、皮膜柔軟剤10重量%以上と、水
溶性高分子とを配合することを特徴とするプレパック剤
である。[Means for Solving the Problems] That is, the present invention is a prepacking agent characterized by blending 10% by weight or more of a film softener and a water-soluble polymer.
以下本発明の構成について説明する。 Hereinafter, the configuration of the present invention will be described.
本発明のプレパック剤は、皮膜形成型パック剤の前に
使用するもので、使用方法としては、例えばプレパック
剤を顔面に塗布し、しばらく放置後、軽くふきとる等で
ある。その後皮膜形成型パック剤をその上に塗布し、皮
膜形成型パック剤を剥離しても痛みはなく、剥離後も肌
はしっとりしたものとなる。The prepacking agent of the present invention is used before the film-forming type packing agent, and is used, for example, by applying the prepacking agent to the face, leaving it for a while, and then gently wiping it. Thereafter, a film-forming pack is applied thereon and the film-forming pack is peeled off without pain, and the skin becomes moist even after peeling.
本発明で用いられる皮膚柔軟剤の具体例としては、例
えば、エチレングリコール、プロピレングリコール、ブ
チレングリコール、ペンチレングリコール、ヘキシレン
グリコール等のC2〜9のアルキレングリコール類、グ
リセロール等の脂肪族トリオール類、ジエチレングリコ
ール、ジプロピレングリコール、ジエチレングリコール
モノメチルエーテル等のC2〜4アルキレンを有するジ
アルキレングリコール類及びその誘導体、ポリエチレン
グリコール、ポリプロピレングリコール、エチレンオキ
サイド及びプロピレンオキサイドのブロック又はランダ
ム共重合体等のC2〜4アルキレンを有するポリアルキ
レンオキサイド類及びその誘導体、そしてエチレンオキ
サイド及びプロピレンオキサイドの共重合体のブチルモ
ノエーテル、ポリエチレンオキサイドのブチルモノエー
テル、ポリ(エチレンオキシアド−プロピレンオキサイ
ド)のグリセロールアダクト、ポリプロピレンオキサイ
ドのグリセロールアダクト等のC1〜C5エーテルを有する
ポリアルキレンオキサイド類の一種又は二種以上が用い
られる。Specific examples of the emollient used in the present invention include, for example, C2-9 alkylene glycols such as ethylene glycol, propylene glycol, butylene glycol, pentylene glycol, and hexylene glycol; and aliphatic triols such as glycerol. , diethylene glycol, dipropylene glycol, diethylene glycol alkylene glycols and derivatives thereof having a C 2 to 4 alkylene monomethyl ether, polyethylene glycol, polypropylene glycol, C. 2 to block or random copolymers of ethylene oxide and propylene oxide polyalkylene oxides and derivatives thereof having a 4 alkylene and monovinyl ether of a copolymer of ethylene oxide and propylene oxide, poly Butyl monoether Ji alkylene oxide, poly (ethyleneoxy add - propylene oxide) glycerol adduct, one polyalkylene oxides having a C 1 -C 5 ethers such as glycerol adduct of polypropylene oxide or two or more may be used.
就中、アルキレングリコール類としては、エチレング
リコール、プロピレングリコール又はヘキシレングリコ
ール、脂肪族トリオール類としては、グリセロール、ジ
アルキレングリコール類としては、ジエチレングリコー
ル又はジプロピレングリコール、その誘導体としては、
ジエチレングリコールモノメチルエーテル又はジエチレ
ングリコールモノエチルエーテル、ポリアルキレンオキ
サイド類としては、ポリエチレングリコール−200、−3
00、−400、−600(平均分子量)、ポリプロピレングリ
コール−200〜−1200(平均分子量)、エチレンオキサ
イドとプロピレンオキサイドのブロック共重合体、その
誘導体としては、エチレンオキサイド及びプロピレンオ
キサイド共重合体のモノブチルエーテルが好ましく用い
られる。Among them, as the alkylene glycols, ethylene glycol, propylene glycol or hexylene glycol, as the aliphatic triols, glycerol, as the dialkylene glycols, diethylene glycol or dipropylene glycol, as a derivative thereof,
Diethylene glycol monomethyl ether or diethylene glycol monoethyl ether, as polyalkylene oxides, polyethylene glycol -200, -3
00, -400, -600 (average molecular weight), polypropylene glycol -200 to -1200 (average molecular weight), block copolymers of ethylene oxide and propylene oxide, and derivatives thereof include those of ethylene oxide and propylene oxide copolymer. Butyl ether is preferably used.
これら皮膚柔軟剤の配合量は、10重量%以上、好まし
くは50重量%以上、さらに好ましくは90重量%以上であ
る。10重量%未満では、効果の面で好ましくない。ま
た、90重量%以上になると、温熱効果も発揮し、皮膚の
柔軟効果が高められ、さらに毛穴につまった皮脂の固ま
りが温度上昇によりやわらかくなり、好ましい。The content of these emollients is 10% by weight or more, preferably 50% by weight or more, and more preferably 90% by weight or more. If it is less than 10% by weight, it is not preferable in terms of effect. When the content is 90% by weight or more, a heating effect is also exerted, the softening effect of the skin is enhanced, and sebum clogging of pores becomes softer due to a rise in temperature, which is preferable.
本発明で用いられる水溶性高分子の具体例としては、
ポリアクリル酸、ポリアクリル酸ナトリウム、ヒアルロ
ン酸、ヒアルロン酸ナトリウム、コンドロイチン硫酸ナ
トリウム、キチン酸のムコ多糖、カルボキシビニルポリ
マー、アルギン酸ナトリウム、アルギン酸アンモニウ
ム、カルボキシメチルセルロースナトリウム、ヒドロキ
シメチルセルロース、ヒドロキシエチルセルロース、ヒ
ドロキシプロピルセルロース、ヒドロキシプロピルエチ
ルセルロース、メチルセルロース、可溶性デンプン、カ
ルボキシメチルアミロース、デキストリン、ペクチン、
寒天末等のヘキセルロース、アラビアガム、トラガカン
トガム、キサンタンガム等の植物ガムが挙げられる。Specific examples of the water-soluble polymer used in the present invention,
Polyacrylic acid, sodium polyacrylate, hyaluronic acid, sodium hyaluronate, sodium chondroitin sulfate, mucopolysaccharide of chitinic acid, carboxyvinyl polymer, sodium alginate, ammonium alginate, sodium carboxymethylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, Hydroxypropylethylcellulose, methylcellulose, soluble starch, carboxymethylamylose, dextrin, pectin,
Hexcellulose such as agar powder, and plant gums such as gum arabic, tragacanth, and xanthan gum.
本発明で用いられる水溶性高分子の配合量は、0.01〜
5重量%が好ましい。0.01重量%未満では、剥離時の痛
みをなくす効果は少なく、5重量%を越えると、皮膜を
形成し、洗浄効果を発揮しにくい。The amount of the water-soluble polymer used in the present invention is 0.01 to
5% by weight is preferred. If it is less than 0.01% by weight, the effect of eliminating pain at the time of peeling is small, and if it exceeds 5% by weight, a film is formed and it is difficult to exert a cleaning effect.
本発明のプレパック剤の後に用いる皮膜形成型パック
剤は、通常のものであれば特に限定されず、例えば、皮
膜形成剤としては、ポリビニルアルコール、ポリビニル
ピロリドン、ポリアクリル酸、ポリアクリル酸ナトリウ
ム、メトキシエチレン無水マレイン酸共重合体、メタク
リル酸重合体、アクリル酸・スチレン共重合体、アクリ
ル酸・メタクリル酸アミド共重合体、アクリル酸ブチル
・メタクリル酸共重合体、スチレン・メタクリル酸共重
合体、カルボキシビニルポリマー、アルギン酸ナトリウ
ム、アルギン酸アンモニウム、カルボキシメチルセルロ
ースナトリウム、ヒドロキシメチルセルロース、ヒドロ
キシエチルセルロース、ヒドロキシプロピルセルロー
ス、ヒドロキシプロピルエチルセルロース、メチルセル
ロース、可溶性デンプン、カルボキシメチルアミロー
ス、デキストリン、ペクチン、寒天末等のヘミセルロー
ス、アラビアガム、トラガカントガム、キサンタンガム
等の植物ガムが挙げられる。The film-forming pack used after the prepack of the present invention is not particularly limited as long as it is a usual one. Examples of the film-forming agent include polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, sodium polyacrylate, and methoxy. Ethylene maleic anhydride copolymer, methacrylic acid polymer, acrylic acid / styrene copolymer, acrylic acid / methacrylamide copolymer, butyl acrylate / methacrylic acid copolymer, styrene / methacrylic acid copolymer, carboxy Vinyl polymer, sodium alginate, ammonium alginate, sodium carboxymethylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylethylcellulose, methylcellulose, soluble starch , Carboxymethyl amylose, dextrin, pectin, hemicellulose agar powder, etc., gum arabic, tragacanth, vegetable gum such as xanthan gum.
本発明のプレパック剤には、本発明の効果を損なわな
い量的、質的範囲内で、必要に応じて、動物鉱物油やエ
ステル油、トリグリセライドあるいは高級脂肪酸、高級
アルコール、直鎖、分枝、環状のシリコーン類などの油
性成分、エタノール等の低級アルコール、レシチン、ニ
ンジンエキスなどの天然抽出物、糖、糖アルコール、そ
のほかの糖誘導体、ピロリドンカルボン酸などの保湿
剤、粘土鉱物などの増粘剤、防腐防黴剤、界面活性剤、
酸化防止剤、金属イオン封鎖剤、紫外線吸収剤、無機あ
るいは有機の粉末、顔料、薬効成分、色素、香料等を配
合できる。The prepacking agent of the present invention includes, as necessary, animal mineral oil or ester oil, triglyceride or higher fatty acid, higher alcohol, straight-chain, branched, within a quantitative and qualitative range that does not impair the effects of the present invention. Oily components such as cyclic silicones, lower alcohols such as ethanol, natural extracts such as lecithin and carrot extract, sugars, sugar alcohols, other sugar derivatives, humectants such as pyrrolidone carboxylic acid, thickeners such as clay minerals , Preservatives and fungicides, surfactants,
Antioxidants, sequestering agents, ultraviolet absorbers, inorganic or organic powders, pigments, medicinal ingredients, pigments, fragrances, and the like can be added.
[発明の効果] 本発明のプレパック剤を用いることにより、皮膜形成
型パック剤の欠点である (1)皮膚より剥離する時にいたい (2)洗浄効果が十分でない を解決することができる。すなわち、皮膜形成型パック
剤の前に、本発明のプレパック剤を用いると、皮膜形成
型パック剤の剥離時の痛みはなく、十分な洗浄効果が得
られる。[Effects of the Invention] By using the prepack agent of the present invention, it is possible to solve the drawbacks of the film-forming pack agent: (1) when peeling from the skin, and (2) insufficient cleaning effect. That is, when the pre-packing agent of the present invention is used before the film-forming type pack, there is no pain when the film-forming type pack is peeled off, and a sufficient cleaning effect can be obtained.
[実施例] 次に本発明の一層の理解のために、実施例をあげて更
に詳細に説明する。本発明はこれによって限定されるも
のではない。なお、配合量は重量%である。実施例に先
立ち、本発明の効果試験方法及び評価方法を以下に示
す。[Examples] Next, in order to further understand the present invention, examples will be described in more detail. The present invention is not limited by this. In addition, the compounding amount is weight%. Prior to the examples, the effect test method and the evaluation method of the present invention will be described below.
18〜35歳の女性パネル68名にプレパック剤を顔面に塗
布し、しばらく放置後、軽くふきとり続いて皮膜形成型
パック剤をその上に塗布してもらった。この時の剥離時
の痛み、使用後のしっとり感、角栓(毛穴に詰まった皮
脂)やよごれのとれ方について以下の基準で判定した。The pre-pack was applied to the face of 68 female panels aged 18 to 35 years, left to stand for a while, then gently wiped, and then the film-forming pack was applied thereon. Pain at the time of peeling, moist feeling after use, keratin plugs (sebum clogged in pores) and how to remove dirt were determined according to the following criteria.
剥離時の痛み ◎…45名以上が痛みを感じない ○…35名以上が痛みを感じない △…15名以上が痛みを感じない ×…痛みを感じない人が15名未満 剥離後のしっとりさ ◎…45名以上がしっとりさを感じる ○…35名以上がしっとりさを感じる △…15名以上がしっとりさを感じる ×…しっとりさを感じない人が15名未満 洗浄効果 ◎…45名以上が洗浄効果があると答えた ○…35名以上が洗浄効果があると答えた △…15名以上が洗浄効果があると答えた ×…洗浄効果があると答えた人人が15名未満 実施例1、比較例1、2 表−1に示すプレパック剤を塗布後、皮膜形成型パッ
ク剤を塗布し、剥離時の痛み、洗浄効果について評価し
た。結果を表−2に示す。Pain during peeling ◎… More than 45 people do not feel pain ○… More than 35 people do not feel pain △… More than 15 people do not feel pain ×… less than 15 people do not feel pain Moist after peeling ◎… More than 45 people feel moisturized ○… More than 35 people feel moisturized △… More than 15 people feel moisturized ×… No more than 15 people do not feel moisturizing Cleaning effect ◎… More than 45 people Respondents who have a cleaning effect ○… More than 35 people answered that they have a cleaning effect △… More than 15 people answered that they have a cleaning effect ×… Less than 15 people who answered that they have a cleaning effect 1. Comparative Examples 1 and 2 After applying the prepacks shown in Table 1, a film-forming pack was applied, and the pain at the time of peeling and the cleaning effect were evaluated. Table 2 shows the results.
皮膜形成型パック剤 ポリビニルアルコール 15 グリセリン 2 エタノール 5 防腐剤 適量 ビタミンC誘導体 適量 香料 適量 精製水 残余 表−2から明らかなように本発明のプレパック剤を使
用することにより、使用後しっとりし、剥離時の痛みが
なく、角栓やよごれをとる効果に優れていた。 Film-forming pack agent Polyvinyl alcohol 15 Glycerin 2 Ethanol 5 Preservatives proper amount Vitamin C derivative proper amount Perfume proper amount Purified water residue As is evident from Table 2, the use of the prepack agent of the present invention gave excellent moistening after use, no pain at the time of peeling, and an excellent effect of removing plugs and dirt.
実施例2 プレパック剤 グリセリン 50.0 1,3−ブチレングリコール 48.0 キサンタンガム 0.5 L−アスコルビン酸−2−硫酸ナトリウム 0.2 精製水 残余 皮膜形成型パック剤 ポリビニルアルコール 12 酢酸ビニルエマルジョン 12 カルボキシメチルセルロース 10 ナイロンパウダー 5 防腐剤 適量 プラセンタ−エキス 適量 精製水 残余 実施例3 プレパック剤 高分子量シリコーン(分子量6,000) 10.0 有機シリコーン樹脂 5.0 ジメチルポリシロキサン(5cs) 22.5 スクワラン 5.0 ビタミンEアセテート 0.1 グリセリン 25.0 1,3−ブチレングリコール 25.0 ヒアルロン酸ナトリウム 0.05 ポリオキシエチレン(100モル付加) 硬化ヒマシ油 2.5 ビタミンC誘導体 適量 精製水 残余 皮膜形成型パック剤 ポリビニルアルコール 12 酢酸ビニルエマルジョン 10 ポリエチレングリコール1000 5 エタノール 5 防腐剤 適量 プラセンタ−エキス 適量 精製水 残余 実施例2及び3のプレパック剤を塗布した後、皮膜形
成型パック剤を使用することにより、使用後しっとり
し、剥離時のいたみがなく、角栓やよごれをとる効果に
優れていた。Example 2 Prepacking agent Glycerin 50.0 1,3-butylene glycol 48.0 Xanthan gum 0.5 L-Ascorbic acid-2-sodium sulfate 0.2 Purified water Residue Film-forming packing agent Polyvinyl alcohol 12 Vinyl acetate emulsion 12 Carboxymethylcellulose 10 Nylon powder 5 Preservative Appropriate amount Placenta extract qs purified water residue Example 3 Prepack agent high molecular weight silicone (molecular weight 6,000) 10.0 organic silicone resin 5.0 dimethyl polysiloxane (5cs) 22.5 squalane 5.0 vitamin E acetate 0.1 glycerin 25.0 1,3-butylene glycol 25.0 sodium hyaluronate 0.05 Polyoxyethylene (100 mol addition) Hardened castor oil 2.5 Vitamin C derivative Appropriate amount Purified water Residue Film forming pack agent Polyvinyl alcohol 12 Vinyl acetate emulsion 10 Polyethylene glycol Coal 1000 5 Ethanol 5 Preservatives Appropriate amount Placenta extract Appropriate amount Purified water Residue After applying the pre-packing agents of Examples 2 and 3, use a film-forming type packing agent to make it moist after use and no damage at the time of peeling. It was excellent in removing horns and dirt.
Claims (1)
とを配合することを特徴とするプレパック剤。(1) A pre-pack preparation comprising 10% by weight or more of an emollient and a water-soluble polymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8178189A JP2805632B2 (en) | 1989-03-31 | 1989-03-31 | Prepack agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8178189A JP2805632B2 (en) | 1989-03-31 | 1989-03-31 | Prepack agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02258713A JPH02258713A (en) | 1990-10-19 |
| JP2805632B2 true JP2805632B2 (en) | 1998-09-30 |
Family
ID=13756024
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8178189A Expired - Fee Related JP2805632B2 (en) | 1989-03-31 | 1989-03-31 | Prepack agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2805632B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5512277A (en) | 1991-05-15 | 1996-04-30 | Kao Corporation | Keratotic plug remover |
| JP3245403B2 (en) * | 1999-04-02 | 2002-01-15 | 花王株式会社 | Gomage cosmetics |
| DE10084591T1 (en) | 1999-05-12 | 2002-03-28 | Kao Corp | Keratotic plug removal means |
| JP5306099B2 (en) * | 2009-07-30 | 2013-10-02 | 株式会社マンダム | PREPACK COMPOSITION AND PACKING METHOD, AND PACKING COSMETIC SET |
-
1989
- 1989-03-31 JP JP8178189A patent/JP2805632B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02258713A (en) | 1990-10-19 |
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