JP2809565B2 - Soil conditioner composition containing sulfur and Humic Acids as active ingredients - Google Patents
Soil conditioner composition containing sulfur and Humic Acids as active ingredientsInfo
- Publication number
- JP2809565B2 JP2809565B2 JP4289533A JP28953392A JP2809565B2 JP 2809565 B2 JP2809565 B2 JP 2809565B2 JP 4289533 A JP4289533 A JP 4289533A JP 28953392 A JP28953392 A JP 28953392A JP 2809565 B2 JP2809565 B2 JP 2809565B2
- Authority
- JP
- Japan
- Prior art keywords
- sulfur
- humic acids
- soil conditioner
- humic
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Fertilizers (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は土壌改良剤に関する。よ
り詳細に言えば、硫黄とヒューミックアシズを有効成分
とする土壌改良剤に関する。The present invention relates to a soil conditioner. More specifically, the present invention relates to a soil conditioner containing sulfur and humic acid as active ingredients.
【0002】[0002]
【従来技術と発明の課題】粉末単体硫黄は土壌改良剤と
して使用されている。硫黄は植物の必須成分であり、肥
料としては通常は硫酸塩が使用される。硫黄単体は土壌
に施用されると徐々に硫酸に変化しこの際一部の微生物
に作用して窒素の無機化を促進したり土壌のpHを下降
させる。従って益もあり、害もありこの作用は土壌の種
類及び土壌の条件、硫黄の施用量で大きく異なることが
知られている。即ち、硫黄は土壌pHを下降させ、EC
を上昇させるので作物によってその施用を調整すること
が必要である。弱酸性(pH5.5〜6.0)を好む作
物(じゃがいも、にんにく、らっきょうなど)と、微酸
性を好む作物(きゅうり、トマト、なす、ねぎ、白菜な
ど)では硫黄の施用量をかなり変えることが重要で、そ
の使用には慎重を要する点があり、その対策が望れてい
た。2. Description of the Prior Art Powdered elemental sulfur is used as a soil conditioner. Sulfur is an essential component of plants, and sulfate is usually used as fertilizer. When applied to soil, sulfur alone gradually changes to sulfuric acid, which acts on some microorganisms to promote nitrogen mineralization and lower the soil pH. Therefore, it is known that there are benefits and harms, and that this effect varies greatly depending on the type of soil, soil conditions, and sulfur application rate. That is, sulfur lowers soil pH,
Therefore, it is necessary to adjust the application depending on the crop. For crops that prefer weak acidity (pH 5.5-6.0) (potatoes, garlic, radish, etc.) and those that prefer slightly acidic (cucumbers, tomatoes, eggplants, green onions, Chinese cabbage, etc.), the amount of sulfur applied should be significantly changed. Is important, and its use requires caution, and measures have been desired.
【0003】[0003]
【課題解決の手段】ヒューミックアシズは土壌中で自然
にできる腐植物質で、既に、土壌改良剤、肥料として使
用されているが、連用しても安全であり、多量使用して
も植物に障害が出ることはない。ヒューミックアシズは
レオナルダイト(亜炭になる前の堆積物)に大量に含ま
れており、これから抽出濃縮されたものは、従来日本で
使用されている腐植酸肥料(亜炭を分解し苦土、石灰、
アンモニウムなどの塩としたもの)とは製法が異なり少
量で植物に対する効果が現われる。ヒューミックアシズ
は、塩基置換容量が大きく500以上もあり養分の土壌
による固定を減少させ植物への養水分吸収を増大させ
る。更にヒューミックアシズには発根を促進したり、ま
たキレート作用により鉄、銅、マンガンなどの微量要素
の吸収を促進する効果、高濃度の窒素の害を低下させた
りするなどの効果がある。本発明者等は、硫黄にヒュー
ミックアシズを混合すると前記の硫黄の問題点が緩和さ
れ、硫黄単独、ヒューミックアシズ単独より著しい効果
が各作物で認められることを知見した。[Means for solving the problems] Humic ash is a humic substance that can be naturally formed in soil, and is already used as a soil conditioner and fertilizer. Will not come out. Humic Ashes is contained in a large amount in leonardite (sediment before it becomes lignite), and what is extracted and concentrated from this is used as humic acid fertilizers (decompose lignite to remove clay, lime,
(A salt of ammonium or the like) is different from the production method in that the effect on the plant appears in a small amount. Humic Ashes has a large base substitution capacity of 500 or more, reduces the fixation of nutrients by soil, and increases the absorption of nutrient water to plants. Further, Humic Ashes has an effect of promoting rooting, an effect of promoting absorption of trace elements such as iron, copper, and manganese by a chelating action, and an effect of reducing harm of a high concentration of nitrogen. The present inventors have found that when sulfur is mixed with Humic Acids, the above-mentioned problem of sulfur is alleviated, and a remarkable effect is observed in each crop compared with sulfur alone or Humic Acids alone.
【0004】[0004]
【発明の構成】本発明は硫黄99.99〜80wt%と
ヒューミックアシズ0.01〜20wt%からなる土壌
改良剤組成物を提供する。前記土壌改良剤組成物に対し
て、ゼオライト、バーミキュライト、パーライト、椰子
殻チップ、木炭、椰子殻炭、ピートモス、バーク堆肥、
ベントナイト、ケイ藻土の少くとも1種を全組成物に対
して99重量%以下混合することができる。本発明の土
壌改良剤は好ましくは粒径5mm以下、より好ましくは
4mm以下で施用される。The present invention provides a soil conditioner composition comprising 99.99 to 80% by weight of sulfur and 0.01 to 20% by weight of Humic Acids. For the soil conditioner composition, zeolite, vermiculite, perlite, coconut shell chips, charcoal, coconut shell charcoal, peat moss, bark compost,
At least one of bentonite and diatomaceous earth can be mixed in an amount of 99% by weight or less based on the total composition. The soil conditioner of the present invention is preferably applied with a particle size of 5 mm or less, more preferably 4 mm or less.
【0005】本発明において使用されるヒューミックア
シズとは前述のようにレオナルダイトより抽出濃縮され
たもので、液体または粉体に担持されたものが今日のと
ころもっぱらアメリカ合衆国テキサス州ヒューストンの
マンモス・インターナショナル・ケミカル会社から提供
されている。従って、本発明において使用されるヒュー
ミックアシズは同社から提供されるもの及びその均等物
である。[0005] The Humic Acids used in the present invention are those extracted and concentrated from Leonardite as described above, and those supported on liquids or powders are currently exclusively used in Mammoth International, Houston, Texas, USA. Provided by a chemical company. Accordingly, the Humic Assists used in the present invention are those provided by the company and equivalents thereof.
【0006】[0006]
【作用】驚くべきことに、ヒューミックアシズは僅か
0.01wt%の添加によっても、硫黄の不利な点が著
しく克服される。ある種の触媒効果を表わすものと推定
される。硫黄とヒューミックアシズの割合を変えること
により種々の作物に効果を発現させることが出来る。ヒ
ューミックアシズ自身には肥料効果もあるが、10wt
%を超えると、硫黄との相乗効果が現れなくなり、20
wt%を超えると、今度はかえって硫黄の作用を減弱す
る。ヒューミックアシズはそれ自身肥料効果を有する
が、高価なものであり、好ましい実用的混合割合は 0.
01〜10wt%である。土壌改良剤製品としては20
〜100kg/10aの施用が望ましい。Surprisingly, the addition of only 0.01% by weight of Humic Acids significantly overcomes the disadvantages of sulfur. It is presumed to represent some catalytic effect. By changing the ratio of sulfur and Humic Acids, various crops can be effective. Humic Ashes itself has a fertilizer effect, but 10wt
%, The synergistic effect with sulfur disappears,
If the content exceeds wt%, the effect of sulfur is rather attenuated. Humic Ashes itself has a fertilizer effect, but is expensive and has a preferred practical mixing ratio of 0.1.
01 to 10 wt%. 20 as a soil conditioner product
Application of ~ 100 kg / 10a is desirable.
【0007】[0007]
【発明の具体的開示】以下本発明を実施例によって具体
的に開示する。実施例に使用したサンプルの組成を表1
に示すとおりである。DETAILED DESCRIPTION OF THE INVENTION Hereinafter, the present invention will be specifically disclosed by examples. Table 1 shows the compositions of the samples used in the examples.
As shown in FIG.
【0008】サンプルは硫黄とキャリヤーを表の割合に
混合したものにヒューミックアシズを表1通りに添加混
合して作成した。キャリヤーはゼオライトのみを使用
(数値のみ記載)したものと、木炭(木)、バーミキュ
ライト(バ)、ピートモス(ピ)を記載した数値の割合
で混合したものを使用した。サンプル16は、木炭、ピ
ートモス、ゼオライトの3種混合品である。硫黄、キャ
リヤー共4mmのふるい下を使用した。The samples were prepared by mixing and mixing Humic Acids as shown in Table 1 with a mixture of sulfur and carrier in the proportions shown in the table. The carrier used was a mixture of only zeolite (only numerical values described) and a mixture of charcoal (wood), vermiculite (ba), and peat moss (pi) at the numerical values described. Sample 16 is a mixture of three types of charcoal, peat moss, and zeolite. Both the sulfur and the carrier were used under a 4 mm sieve.
【0009】[0009]
【表1】 実施例の試験に使用したサンプルの組成 サンプル No. 硫 黄 キャリヤー ヒューミックアシズ 1 100 0 0 1′ 20 80 0 2 0 0 12%(液材) 3 0 0 90%(粉材) 4 5 95 0.05 5 5 95 0.5 6 5 95(木) 0.05 7 5 95(バ) 0.05 8 10 90 0.05 9 10 90 0.5 10 20 80 0.05 11 20 80 0.5 12 20 80(木) 0.05 13 20 80(バ) 0.05 14 50 50 0.15 15 50 50 0.5 16 5 30(木) 0.05 10(ピ) 55(ゼ) (重量部)TABLE 1 Composition of samples used in the test of Example Sample No. sulfur carrier Hugh Mick Ashizu 1 100 0 0 1 "20 80 0 2 0 0 12% (liquid material) 3 0 0 90% (powder material) 4 5 95 0.05 5 5 95 0.5 6 5 95 (Thu) 0.05 7 5 95 (B) 0.05 8 10 90 0.05 9 10 90 0.5 10 20 80 0.05 11 20 80 0.5 12 20 80 (Thu) 0.05 13 20 80 (B ) 0.05 14 50 50 0.15 15 50 50 0.5 16 5 30 (Thu) 0.05 10 (Pi) 55 (Z) (Parts by weight)
【0010】実施例1 小松菜栽培への使用 野菜育苗用市販園芸培土(N:35mg/100g,P
2O3,150mg/100g含有,pH6.5)1kg
をビニールポットに充填し、サンプル1は 10、2
0、50kg/10a相当量、サンプル 1′は 50、
100、250kg/10a相当量、サンプル 2、3
は 25、50、125、250g/10a相当量、サ
ンプル4〜16は、ヒューミックアシズとして25、5
0、125g/10a相当量になるように全層施用し
た。小松菜5粒を播種し30日間栽培した結果は表2に
示すとおりである。Example 1 Use for Komatsuna Cultivation Commercial horticultural cultivation soil for vegetable seedling raising (N: 35 mg / 100 g, P
2 O 3 , 150mg / 100g, pH 6.5) 1kg
Into a plastic pot, sample 1 is 10, 2
0, 50 kg / 10a equivalent amount, sample 1 'is 50,
100, 250kg / 10a equivalent amount, sample 2, 3
Are equivalent to 25, 50, 125, 250 g / 10a. Samples 4 to 16 are 25, 5,
0, 125 g / 10 a equivalent amount was applied to all layers. Table 2 shows the results of sowing 5 komatsuna and cultivating for 30 days.
【0011】[0011]
【表2】 実施例1の小松菜による試験 1硫黄、1′硫黄+キャリヤー (Skg/10a) サンフ゜ル No. 10 20 50 1 105 110 83 1′ 107 110 82 ヒューミックアシッズ (g/10a) サンフ゜ル No. 25 50 125 250 2 115 124 110 109 3 118 126 109 106 4 125 134 116 5 120 129 112 6 124 130 115 7 125 132 117 8 125 138 118 9 119 128 113 10 129 148 116 11 118 124 114 12 128 145 118 13 129 148 117 14 125 141 117 15 121 135 115 16 131 151 120Table 2 Test with Komatsuna in Example 1 1 Sulfur, 1 'sulfur + carrier (Skg / 10a) sample No. 10 20 50 1 105 110 83 1' 107 110 82 Humic Acids (g / 10a) sample No . 25 50 125 250 2 115 124 110 109 3 118 126 109 106 4 125 134 116 5 120 129 112 6 124 130 115 7 125 132 117 8 125 138 118 9 119 128 113 10 129 148 116 11 118 124 114 12 128 145 118 13 129 148 117 14 125 141 117 15 121 135 115 16 131 151 120
【0012】硫黄単独は弱い効果は認められるが50k
g/10aではpHの下降、ECの上昇で生育が抑制さ
れる。ヒューミックアシズ単独でも効果はかなり発現し
25〜50g/10aがかなり良好である。硫黄とヒュ
ーミックアシズの併用はキャリヤーの種類に関係なく認
められ、硫黄10〜20kg/10a、ヒューミックア
シズ25〜50g/10aで著しく効果が発現する。本
試験において、標準は無施用区とし葉菜収量 36.5g
をもって100とした。Sulfur alone has a weak effect, but 50k
At g / 10a, growth is suppressed by a decrease in pH and an increase in EC. Even if Humic Acids alone is used, the effect is considerably exhibited, and 25 to 50 g / 10a is quite good. The combined use of sulfur and Humic Acids is recognized irrespective of the type of carrier, and significant effects are exhibited when sulfur is 10 to 20 kg / 10a and Humic Acids is 25 to 50 g / 10a. In this test, the standard was untreated and the leafy vegetable yield was 36.5 g.
Was set to 100.
【0013】実施例2 ほうれんそう栽培への使用 園芸用培土(実施例1で使用)1kgをビニールポットに
充填し、サンプル1′は 25、50、100、250
kg/10a相当量、サンプル 3、4、10をヒュー
ミックアシズとして25、50、125g/10a相当
量になるよう全層施用した。ほうれんそう5粒を播種し
45日間栽培した結果は表3の通りである。Example 2 Use for Spinach Cultivation 1 kg of horticultural soil (used in Example 1) is filled in a plastic pot, and sample 1 'is 25, 50, 100, 250
Samples 3, 4, and 10 were applied in a total amount of 25, 50, and 125 g / 10a in terms of Humic Acids. Table 3 shows the results of sowing 5 spinach seeds and cultivating them for 45 days.
【0014】[0014]
【表3】 実施例2のほうれんそうによる試験 硫黄+キャリヤー (Skg/10a) サンフ゜ル No. 5 10 20 50 1′ 100 100 98 75 ヒューミックアシッズベース(g/10a) サンフ゜ル No. 25 50 125 3 108 115 114 4 125 133 121 10 115 120 103 本試験において、標準は無施用区とし収量30.5gをも
って100とした。中性に近いpHの領域を好むほうれ
んそうでは硫黄だけの効果は認められず、ヒューミック
アシッズの効果は認められるが少量の硫黄との併用はか
なり効果が顕著となる。ヒューミックアシズは硫黄によ
る生育抑制を緩和する作用がある。Table 3 Test Sulfur + Carrier (Skg / 10a) Sample No. 5 10 20 50 1 '100 100 98 75 Humic Acids Base (g / 10a) Sample No. 25 50 125 3 108 115 114 4 125 133 121 10 115 120 103 In this test, the standard was untreated and the yield was 30.5 g, which was 100. The effect of sulfur alone is not recognized in spinach which prefers a pH region close to neutrality, and the effect of Humic Acids is recognized, but the effect is remarkably remarkable when used in combination with a small amount of sulfur. Humic Ashes has the effect of alleviating the growth suppression caused by sulfur.
【0015】実施例3 じゃがいも栽培への使用 a/2000ポットに黒ぼく土壌6kgを充填し、じゃ
がいも専用配合(10−16−14)をポット当たり
N:1g相当量を全層施用した。サンプル1′は25、
50、100、250kg/10a相当量、サンプル
3、4、10はヒューミックアシズ25、50、125
g/10a相当量になるように全層施用し、じゃがいも
苗を移植し60日間栽培した結果は表4に示した通りで
ある。Example 3 Use for Potato Cultivation An a / 2000 pot was filled with 6 kg of Kuroboku soil, and a potato-specific composition (10-16-14) was applied in an amount of N: 1 g per pot in an entire layer. Sample 1 'is 25,
Samples 3, 4, and 10 are equivalent to 50, 100, and 250 kg / 10a.
Table 4 shows the results obtained by applying the whole layer so as to obtain an amount equivalent to g / 10a, transplanting potato seedlings and cultivating them for 60 days.
【0016】[0016]
【表4】 実施例3のじゃがいもによる試験 硫黄+キャリヤー (Skg/10a) サンフ゜ル No. 5 10 20 50 1′ 103 108 113 115 ヒューミックアシッズベース(g/10a) サンフ゜ル No. 25 50 125 3 106 115 116 4 115 123 128 10 123 135 132 本試験において、標準は無施用区とし収量378gをも
って芋重指数100とした。弱酸性のpH領域を好むじ
ゃがいもは硫黄単独でも効果が認められる。ヒューミッ
クアシッズの効果も認められるが硫黄との併用は相乗的
な効果が認められて硫黄成分の多いサンプル10で効果
が著しい。Table 4 Potato Test Sulfur + Carrier (Skg / 10a) Sample No. 5 10 20 50 1 '103 108 113 115 Humic Acids Base (g / 10a) Sample No. 25 50 125 3 106 115 116 4 115 123 128 10 123 135 132 In this test, the standard was untreated and the potato weight index was 100 with a yield of 378 g. For potatoes that prefer a weakly acidic pH range, sulfur alone is effective. The effect of Humic Acids is also recognized, but the combined use with sulfur has a synergistic effect, and the effect is remarkable in Sample 10 containing a large amount of sulfur components.
【0017】実施例4 じゃがいも(圃場) 実施例3でじゃがいもに最も効果のあったサンプル10
を使用し圃場試験を行った。じゃがいも専用配合(10
−16−14)100kg/10a及びサンプル10を
50及び100kg/10aをうね施用した区を設置し
メークインを3月10日に移植した。中間調査を5月3
0日に、収穫調査を6月20日に行った結果は表5に示
した通りである。Example 4 Potato (field) Sample 10 which was most effective for potato in Example 3
Was used for field tests. Potatoes only formulation (10
-16-14) A section where 100 kg / 10a and sample 10 were applied at 50 and 100 kg / 10a was set up, and make-in was transplanted on March 10. Interim Survey May 3
The results of the harvest survey conducted on June 0 on June 0 are shown in Table 5.
【0018】[0018]
【表5】 実施例4のじゃがいも圃場試験 中間調査(5/30) 収量調査(6/20) サンフ゜ル No. いも数 いも重 いも数 いも重 無施用 58 4350g 62 7380g 指数 100 100 100 100 10(50kg/10a) 110 134 108 129 10(100kg/10a) 125 158 115 146 調査は20株について行い、表中の数値は10株当たり
で示した。50kg/10a、100kg/10aが明
らかに効果が認められ、特に100kg/10aが良好
であった。中間成績の結果から収穫期の促進の可能性が
強い。TABLE 5 EXAMPLE potato field trials intermediate survey 4 (5/30) Yield Survey (6/20) Sample No. Number of potato Imokasane Potatoes number Imokasane No application 58 4350g 62 7380g index 100 100 100 100 10 (50kg / 10a) 110 134 108 129 10 (100 kg / 10a) 125 158 115 146 The survey was conducted on 20 shares, and the values in the table are shown per 10 shares. The effects were clearly observed at 50 kg / 10a and 100 kg / 10a, and particularly good at 100 kg / 10a. The results of the interim results indicate that the harvest season is likely to be promoted.
【0019】実施例5 にんじん圃場への使用 根菜専用配合肥料(6−9−5)をN:20kg/10
a相当量及びサンプル8,10を100kg/10aに
なるように全層施用した。にんじんを7月15日に播種
し、間引き後の株間を10cmとして栽培し12月13
日に収穫した結果は表6に示した通りである。何れも効
果が認められるが、じゃがいもの場合より硫黄が少ない
サンプルの方が成績が良好である。Example 5 Use in a Carrot Field A compound fertilizer (6-9-5) dedicated to root vegetables was N: 20 kg / 10
a) and samples 8 and 10 were applied to all layers so as to obtain 100 kg / 10a. Carrots were sown on July 15 and cultivated with the interstrain after culling as 10 cm.
The results of the day harvest are shown in Table 6. Although the effects are recognized in both cases, the sample having less sulfur has better results than the case of potato.
【0020】[0020]
【表6】 実施例5のにんじん圃場試験 サンプル 葉重 根長 根径 根重 No. (g) (cm) (cm) (g) 無施用 (62) (17.9) (4.5) (214) 指数 100 100 100 100 8(100kg/10a) 146 108 110 127 10(100kg/10a) 138 104 104 117 調査は50本について行い、表中の数値は1本当たりで
示した。[Table 6] Carrot field test of Example 5 Leaf weight Root length Root diameter Root weight No. (g) (cm) (cm) (g) No application (62) (17.9) (4.5) (214) Index 100 100 100 100 8 (100kg / 10a) 146 108 110 127 10 (100kg / 10a) 138 104 104 117 The survey was conducted on 50 pieces, and the values in the table are shown per piece.
フロントページの続き (58)調査した分野(Int.Cl.6,DB名) C09K 17/42 C05F 11/00 C05G 1/00 C09K 17/50Continuation of front page (58) Field surveyed (Int.Cl. 6 , DB name) C09K 17/42 C05F 11/00 C05G 1/00 C09K 17/50
Claims (3)
ックアシズ0.01〜20wt%とからなる土壌改良剤
組成物。1. A soil conditioner composition comprising 99.99 to 80% by weight of sulfur and 0.01 to 20% by weight of Humic Acids.
ックアシズ0.01〜10wt%とからなる請求項1に
記載の土壌改良剤組成物。2. The soil conditioner composition according to claim 1, comprising 99.99 to 90% by weight of sulfur and 0.01 to 10% by weight of Humic Acids.
くとも1wt%を含み、残部ゼオライト、バーミキュラ
イト、パーライト、椰子殻チップ、木炭、椰子殻炭、ピ
ートモス、バーク堆肥、ベントナイト、ケイ藻土から選
ばれるキャリヤーからなる土壌改良剤組成物。3. A composition comprising at least 1% by weight of the composition according to claim 1 or 2 and the balance being zeolite, vermiculite, perlite, coconut shell chips, charcoal, coconut shell charcoal, peat moss, bark compost, bentonite, diatomaceous earth. A soil conditioner composition comprising a selected carrier.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4289533A JP2809565B2 (en) | 1992-10-02 | 1992-10-02 | Soil conditioner composition containing sulfur and Humic Acids as active ingredients |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4289533A JP2809565B2 (en) | 1992-10-02 | 1992-10-02 | Soil conditioner composition containing sulfur and Humic Acids as active ingredients |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06116558A JPH06116558A (en) | 1994-04-26 |
| JP2809565B2 true JP2809565B2 (en) | 1998-10-08 |
Family
ID=17744487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4289533A Expired - Lifetime JP2809565B2 (en) | 1992-10-02 | 1992-10-02 | Soil conditioner composition containing sulfur and Humic Acids as active ingredients |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2809565B2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000303068A (en) * | 1999-04-22 | 2000-10-31 | Mitsui Touatsu Hiryo Kk | Sulfur coated soil conditioner |
| JP2001348573A (en) * | 2000-06-06 | 2001-12-18 | Saitama Prefecture | Soil conditioner |
| JP5013558B2 (en) * | 2010-07-22 | 2012-08-29 | 岩手県 | Bark fiber culture method and bark fiber culture |
| CN103333696A (en) * | 2013-07-10 | 2013-10-02 | 丹阳市淸云农业发展有限公司 | Modifier used for alkaline soil |
| MX379138B (en) * | 2015-02-06 | 2025-03-10 | Tiger Sul Products Canada Co | Sulphur-based fertilizer composition with humic acid content |
| CN108329098A (en) * | 2018-03-22 | 2018-07-27 | 山东农业大学 | A kind of efficiently ultra tiny phosphorus potassium-activator fertilizer and preparation method thereof |
| CN110184070A (en) * | 2019-03-22 | 2019-08-30 | 江苏长三角环境科学技术研究院有限公司 | A kind of curing and stabilizing agent and application method for heavy metal pollution site remediation |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3417133A1 (en) * | 1984-05-07 | 1985-11-07 | Schering AG, 1000 Berlin und 4709 Bergkamen | LEAF FERTILIZER FOR TARGETED LONG-TERM APPLICATION |
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1992
- 1992-10-02 JP JP4289533A patent/JP2809565B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06116558A (en) | 1994-04-26 |
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