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JP2846145B2 - Circuit board connection method - Google Patents
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JP2846145B2 - Circuit board connection method - Google Patents

Circuit board connection method

Info

Publication number
JP2846145B2
JP2846145B2 JP3141262A JP14126291A JP2846145B2 JP 2846145 B2 JP2846145 B2 JP 2846145B2 JP 3141262 A JP3141262 A JP 3141262A JP 14126291 A JP14126291 A JP 14126291A JP 2846145 B2 JP2846145 B2 JP 2846145B2
Authority
JP
Japan
Prior art keywords
connection
adhesive
circuit board
electrode
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP3141262A
Other languages
Japanese (ja)
Other versions
JPH0684558A (en
Inventor
智 小田嶋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shin Etsu Polymer Co Ltd
Original Assignee
Shin Etsu Polymer Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=15287815&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=JP2846145(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Shin Etsu Polymer Co Ltd filed Critical Shin Etsu Polymer Co Ltd
Priority to JP3141262A priority Critical patent/JP2846145B2/en
Publication of JPH0684558A publication Critical patent/JPH0684558A/en
Application granted granted Critical
Publication of JP2846145B2 publication Critical patent/JP2846145B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/30Assembling printed circuits with electric components, e.g. with resistors
    • H05K3/32Assembling printed circuits with electric components, e.g. with resistors electrically connecting electric components or wires to printed circuits
    • H05K3/321Assembling printed circuits with electric components, e.g. with resistors electrically connecting electric components or wires to printed circuits by conductive adhesives
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/36Assembling printed circuits with other printed circuits
    • H05K3/361Assembling flexible printed circuits with other printed circuits

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は回路基板の接続方法、特
には低ピッチの極細接続電極を有する液晶表示パネル
(LCD),プラズマディスプレイ(PDP)、エレク
トロルミネッセンス(EL)等の表示体と、フレキシブ
ル回路基板(FPC),硬質回路基板(PCB)等の回
路基板の接続方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for connecting circuit boards, and more particularly, to a display such as a liquid crystal display panel (LCD), a plasma display (PDP), or an electroluminescence (EL) having a fine pitch connection electrode with a low pitch. The present invention relates to a method for connecting a circuit board such as a flexible circuit board (FPC) and a rigid circuit board (PCB).

【0002】[0002]

【従来の技術】従来回路基板の接続には、絶縁性樹脂中
に導電性粒子を分散させた異方導電接着剤が用いられて
いるが、近年の回路基板の高密度化に伴う接続電極の低
ピッチ化により、電気接続が不安定化する傾向が生じ
た。このため粒径を均一にし、接触抵抗の小さいAu等
の貴金属を被覆した樹脂粒子を導電性粒子として使う等
の工夫によって、この不利の解決が試みられている。
2. Description of the Related Art Conventionally, an anisotropic conductive adhesive in which conductive particles are dispersed in an insulating resin has been used for connection of a circuit board. Due to the lower pitch, the electrical connection tends to be unstable. For this reason, attempts have been made to solve this disadvantage by making the particle size uniform and using resin particles coated with a noble metal such as Au having a small contact resistance as the conductive particles.

【0003】[0003]

【発明が解決しようとする課題】しかしながら導電性粒
子を分散させたタイプの異方導電膜による回路基板の接
続では、低ピッチになるほど導電性粒子の分散不良や、
偶然あるいは静電気等による導電粒子の連なりによる短
絡を生じる危険が増し、さらに接触抵抗を低くするため
貴金属を使ったり、粒径を極度に均一にするため導電性
粒子の歩留りが悪くなって、非常に高価なものになると
いう問題点があった。
However, in connection of a circuit board with an anisotropic conductive film of a type in which conductive particles are dispersed, the lower the pitch, the poorer the dispersion of the conductive particles,
There is an increased risk of short-circuiting due to accidental or static electricity or other series of conductive particles.In addition, precious metals are used to reduce contact resistance, and the yield of conductive particles deteriorates due to extremely uniform particle size. There was a problem that it became expensive.

【0004】[0004]

【課題を解決するための手段】本発明はこのような従来
技術の問題点を解決するもので、接続電極のピッチが小
さくなっても隣接電極間の短絡の危険が少なく、しかも
接触抵抗が低く、安価な回路基板の接続方法を提供する
ことを目的とするもので、これは各回路基板の接続電極
の絶縁板に対する段差の和が5μm以上である両回路基
板を、体積抵抗率が107 〜1018Ω・cmで、熟硬化
成分を含み、熱圧着時の最低溶融粘度が1×107 ポイ
ズ以下である熱接着性接着剤を用い、加熱加圧して接続
することを特徴とする回路基板の接続方法を要旨とす
る。
SUMMARY OF THE INVENTION The present invention solves the above-mentioned problems of the prior art. Even if the pitch of the connection electrodes becomes small, there is little danger of short-circuiting between adjacent electrodes, and the contact resistance is low. It is an object of the present invention to provide an inexpensive circuit board connection method, in which both circuit boards having a sum of steps of 5 μm or more with respect to an insulating plate of a connection electrode of each circuit board have a volume resistivity of 10 7. A circuit characterized in that a connection is made by applying heat and pressure to a hot-adhesive adhesive having a ripened component and a minimum melt viscosity at the time of thermocompression bonding of 1 × 10 7 poise or less at 〜1010 18 Ω · cm. The gist is a method of connecting the substrates.

【0005】本発明に用いられる接着剤は、加熱、加圧
中に固化することが望ましいので、熱硬化成分を含んだ
ものとし、熱硬化成分としては、エポキシ樹脂系、ウレ
タン系、アクリル系、シリコーン系、クロロプレン系、
ニトリル系等の合成ゴム等が例示される。信頼性向上を
目的として剥離強度、耐温度変化性、可撓性を向上させ
るためには、これらに熱可塑性樹脂をブレンドすること
が効果的である。
[0005] The adhesive used in the present invention desirably solidifies during heating and pressurizing. Therefore, the adhesive should contain a thermosetting component. As the thermosetting component, an epoxy resin type, a urethane type, an acrylic type, Silicone, chloroprene,
Examples thereof include nitrile-based synthetic rubber and the like. In order to improve peel strength, resistance to temperature change, and flexibility for the purpose of improving reliability, it is effective to blend a thermoplastic resin with them.

【0006】熱可塑性樹脂としては、ポリアミド系、ポ
リエステル系、アイオノマー系、エチレン−酢酸ビニル
共重合体(EVA),エチレン−アクリル酸共重合体
(EAA)エチレン−メタクリル酸共重合体(EM
A),エチレン−アクリル酸エチル共重合体(EEA)
等のポリオレフィン系、ニトリルゴム(NBR),スチ
レン−ブタジエンゴム(SBR)、スチレン・エチレン
−ブチレン・スチレン共重合体(SEBS)等の各種合
成ゴム系のもの、さらにはこれらの変性物、複合物があ
げられる。剥離強度、反応温度の点から最も有効なもの
は、末端または側鎖がカルボキシル化されたNBR、S
BRやSEBS等の合成ゴム100重量部に対し、一液
加熱硬化エポキシ樹脂を10〜1000重量部好ましく
は20〜200重量部ブレンドしたものである。これら
にはいずれの場合も、硬化剤、加硫剤、制御剤、劣化防
止剤、耐熱添加剤、熱伝導向上剤、粘着付与剤、軟化
剤、着色剤、各種カップリング剤、金属不活性剤等が適
宜添加されるのがよい。
Examples of the thermoplastic resin include polyamide, polyester, ionomer, ethylene-vinyl acetate copolymer (EVA), ethylene-acrylic acid copolymer (EAA), and ethylene-methacrylic acid copolymer (EM).
A), Ethylene-ethyl acrylate copolymer (EEA)
And various synthetic rubbers such as nitrile rubber (NBR), styrene-butadiene rubber (SBR), styrene-ethylene-butylene-styrene copolymer (SEBS), and modified products and composites thereof. Is raised. The most effective ones in terms of peel strength and reaction temperature are NBR and S having carboxylated terminal or side chain.
One-part heat-curable epoxy resin is blended with 10 to 1,000 parts by weight, preferably 20 to 200 parts by weight, based on 100 parts by weight of a synthetic rubber such as BR or SEBS. In any case, these include a curing agent, a vulcanizing agent, a control agent, a deterioration inhibitor, a heat-resistant additive, a heat conduction improver, a tackifier, a softener, a coloring agent, various coupling agents, and a metal deactivator. And the like are suitably added.

【0007】加熱加圧して接着する際、溶融→ゲル化→
硬化という過程を経由するが、溶融して接着剤が流れ
て、段差のある接続電極が電気的に接続される程度まで
近づかなければならないので、この場合の接着剤の溶融
粘度は1×107 ポイズ以下、好ましくは5×106
イズ以下である必要がある。また接続すべき対面する接
続電極は絶縁板に対し、すなわち電極部と非電極部間に
電極部の接着剤が流れ込む段差があることが必要で、対
面する電極の絶縁板に対する段差の和は5μm以上と
し、段差が大きすぎると接着剤が充填されず、十分な接
着強度が得られないため、100μm以下とするのがよ
い。
When bonding by heating and pressing, melting → gelation →
Although it goes through a process of curing, the adhesive must flow to the extent that it melts and the adhesive flows, and the connection electrode having a step must be electrically connected. Therefore, the melt viscosity of the adhesive in this case is 1 × 10 7. It must be less than poise, preferably less than 5 × 10 6 poise. The facing connection electrode to be connected must have a step into the insulating plate, that is, between the electrode portion and the non-electrode portion, into which the adhesive of the electrode portion flows. The sum of the steps of the facing electrode to the insulating plate is 5 μm. When the step is too large, the adhesive is not filled and sufficient adhesive strength cannot be obtained. Therefore, the thickness is preferably 100 μm or less.

【0008】またこの接続すべき電極は、接続信頼性向
上のために表面が粗面化されていたり、突起が設けられ
ていてもよいが必須要件ではない。接続すべき対面する
電極間の接着剤は加熱加圧により流れ、電極間から排除
されるが、ある部分では極く微量ではあるが電極間に残
り、またある部分では微細な凹凸により電極が直接接触
する。この際低抵抗の電気的接続を得るためには、その
回路基板の実使用状態の条件として60℃〜100℃下
で、体積抵抗率が1018Ω・cm以下でなければならな
い。しかし各回路基板の隣接する接続電極は回路基板の
駆動に支障のない程度の絶縁を保たねばならず、そのた
めには回路基板の実使用の条件下で体積抵抗率が107
Ω・cm以上であることが必要である。
The electrode to be connected may have a roughened surface or be provided with protrusions to improve connection reliability, but is not an essential requirement. The adhesive between the facing electrodes to be connected flows by heating and pressurizing and is removed from between the electrodes, but in some parts it remains between the electrodes although it is very small, and in some parts the electrodes are directly Contact. At this time, in order to obtain a low-resistance electrical connection, the circuit board must have a volume resistivity of 10 18 Ω · cm or less at 60 ° C. to 100 ° C. as a condition of actual use. However, the adjacent connection electrodes of each circuit board must maintain insulation so as not to hinder the driving of the circuit board. For this purpose, the volume resistivity is 10 7 under the conditions of actual use of the circuit board.
Ω · cm or more is required.

【0009】本発明の回路基板の接続方法は、上記のよ
うに、接続すべき電極間に上述の接着剤を膜状に形成し
たものを載置し、適当な条件で加熱、加圧することによ
って得られるが、この条件は接続に用いられる接着剤に
より決定すればよい。
According to the method of connecting circuit boards of the present invention, as described above, the above-mentioned adhesive formed in a film shape between the electrodes to be connected is placed, and heated and pressed under appropriate conditions. Although this condition can be obtained, these conditions may be determined depending on the adhesive used for connection.

【0010】[0010]

【作用】本発明の接続方法は以上のように構成され、こ
れは接続すべき電極の段差の和が5μm以上であり、こ
れを接続する接着剤の加熱時の溶融粘度が107 ポイズ
以下であるので、接着剤は電極間から流れ、極微量電極
間に残るものの、その体積抵抗率が1018Ω・cm以下
であるため、低抵抗の電気的接続が得られ、また体積抵
抗率を107 Ω・cm以上とすることで隣接する電極と
は実質的に絶縁が保たれ、また接着剤が熱硬化性を有し
ているためスプリングバックを防ぎ、電気的接続が保持
される。また導電性粒子を分散させたタイプと異なり、
短絡を生じる危険がほとんどなく、高価な導電性粒子を
使用しないので安価な接続構造が得られる。
The connection method of the present invention is constituted as described above. The sum of the steps of the electrodes to be connected is 5 μm or more, and the melt viscosity at the time of heating of the adhesive connecting the electrodes is 10 7 poise or less. Although the adhesive flows from between the electrodes and remains between the trace electrodes, the volume resistivity is 10 18 Ω · cm or less, so that a low-resistance electrical connection can be obtained and the volume resistivity can be reduced to 10 18 Ω · cm. By setting the resistance to 7 Ω · cm or more, insulation from the adjacent electrode is substantially maintained, and since the adhesive has thermosetting properties, springback is prevented and electrical connection is maintained. Also, unlike the type in which conductive particles are dispersed,
There is almost no danger of a short circuit, and an inexpensive connection structure can be obtained because expensive conductive particles are not used.

【0011】[0011]

【実施例】つぎに実施例を図面によって説明する。 (実施例1)図1に示すように、一方の回路基板はポリ
イミド(PI)厚み75μmの絶縁板1の上に電極ピッ
チ0.2mm、銅箔厚み35μm、Snメッキの接続電
極2を設け、他方の回路基板は、ガラスの絶縁板4の上
に電極ピッチ0.2mmの透明酸化錫電極(ITO)の
ガラス電極3を設けたLCDを使用した。つぎに末端カ
ルボキシル化NBR100重量部に対し、イミダゾール
変成エポキシのマイクロカプセル化したものを硬化剤と
する一液加熱硬化型エポキシ接着剤100重量部、粘着
付与剤20重量部、γ−メルカプトトリメトキシシラン
1重量部、1トリメトキシシラン1重量部を、トルエ
ン:MEK=8:2の混合溶媒に溶解させ混合した接着
剤5を、前記他方の回路基板上にコーティングし、送
風、乾燥後、厚みが30μmとなるようにした。この接
着剤5は25℃での体積抵抗率が1013Ω・cm、17
0℃での硬化前の溶融粘度が3×105 ポイズであっ
た。この接着剤5を介して前記一方の回路基板を重ね、
170℃、40kg/cm2 、30secの条件でヒー
トシール接続したところ、接続抵抗は0.5Ω以下であ
った。また150pin×10個の回路基板で試験した
ところ短絡は1点もなく、90°剥離強度は800g/
cm以上であった。
Next, an embodiment will be described with reference to the drawings. Embodiment 1 As shown in FIG. 1, one circuit board is provided with an electrode pitch of 0.2 mm, a copper foil thickness of 35 μm, and a Sn-plated connection electrode 2 on an insulating plate 1 having a polyimide (PI) thickness of 75 μm. The other circuit board used was an LCD in which a glass electrode 3 of a transparent tin oxide electrode (ITO) having an electrode pitch of 0.2 mm was provided on a glass insulating plate 4. Next, based on 100 parts by weight of terminal carboxylated NBR, 100 parts by weight of a one-part heat-curable epoxy adhesive using a microencapsulated imidazole-modified epoxy as a curing agent, 20 parts by weight of a tackifier, γ-mercaptotrimethoxysilane 1 part by weight of 1 part by weight of 1 part by weight of trimethoxysilane was dissolved in a mixed solvent of toluene: MEK = 8: 2, and the mixed adhesive 5 was coated on the other circuit board. The thickness was set to 30 μm. The adhesive 5 has a volume resistivity at 25 ° C. of 10 13 Ω · cm, 17
The melt viscosity before curing at 0 ° C. was 3 × 10 5 poise. One of the circuit boards is stacked with the adhesive 5 interposed therebetween,
When heat-sealed at 170 ° C., 40 kg / cm 2 and 30 sec, the connection resistance was 0.5Ω or less. In addition, when the test was performed on 150 pin × 10 circuit boards, there was no short circuit and the 90 ° peel strength was 800 g /
cm or more.

【0012】(実施例2)図2に示すように、実施例1
で用いた接着剤5を用い、接続電極3上に5μmの突起
6を設けた他方の回路基板と一方の回路基板の接続電極
2を重ね、170℃、40kg/cm2 、30secの
条件でヒートシール接続した。接続抵抗を測定したとこ
ろ、初期値が最大値0.5Ωであったのに対し、60
℃、95%RHに1000hrs放置後では最大値が
0.8Ωであった。
(Embodiment 2) As shown in FIG.
Using the adhesive 5 used in the above, the other circuit board provided with the projections 6 of 5 μm on the connection electrode 3 and the connection electrode 2 of one circuit board are overlapped, and heated at 170 ° C., 40 kg / cm 2 , 30 sec. Sealed connection. When the connection resistance was measured, the initial value was 0.5Ω as the maximum value,
The maximum value was 0.8Ω after being left at 95 ° C. and 95% RH for 1000 hrs.

【0013】[0013]

【発明の効果】以上のように本発明では、導電性粒子を
使わないことによって低ピッチの接続電極をもつ回路基
板の接続の際にも、隣接する接続電極間に導電粒子の連
鎖による短絡を生じる心配がなく、安価な回路基板の接
続方法を提供することができる。また接続電極の接続面
を粗面化したり、また突起を設けることによってさらに
接続の信頼性を向上することができる。
As described above, according to the present invention, a short circuit due to a chain of conductive particles between adjacent connection electrodes can be prevented even when a circuit board having a connection electrode with a low pitch is connected by using no conductive particles. It is possible to provide an inexpensive circuit board connection method without worrying about occurrence. Further, the connection reliability of the connection electrode can be further improved by roughening the connection surface of the connection electrode or providing the projection.

【図面の簡単な説明】[Brief description of the drawings]

【図1】(a)は本発明の回路基板の接続部の平面図、
(b)は(a)のX−X線に沿う縦断面図、(c)は
(a)のY−Y線に沿う縦断面図である。
FIG. 1A is a plan view of a connection portion of a circuit board according to the present invention,
(B) is a longitudinal sectional view taken along line XX of (a), and (c) is a longitudinal sectional view taken along line YY of (a).

【図2】本発明の他の例における図1の(a)のX−X
線と同じ場所の縦断面図である。
FIG. 2 is a cross-sectional view taken along line XX of FIG.
It is a longitudinal cross-sectional view of the same location as a line.

【符号の説明】[Explanation of symbols]

1、4 絶縁板 2、3 接続電極 5 接着剤 6 突起 7 上側ガラス基板 8 封止材 9 液晶 1, 4 Insulating plate 2, 3 Connection electrode 5 Adhesive 6 Projection 7 Upper glass substrate 8 Sealing material 9 Liquid crystal

フロントページの続き (56)参考文献 特開 平1−124976(JP,A) 特開 昭60−154480(JP,A) 特開 昭61−260562(JP,A) 特開 平3−95520(JP,A) 特開 昭63−250626(JP,A) 特開 平4−6771(JP,A) 特開 昭64−50307(JP,A) 実開 平2−33032(JP,U) (58)調査した分野(Int.Cl.6,DB名) H01R 11/01 G02F 1/1345 H01B 5/16Continuation of front page (56) References JP-A-1-124976 (JP, A) JP-A-60-154480 (JP, A) JP-A-61-260562 (JP, A) JP-A-3-95520 (JP) JP-A-63-250626 (JP, A) JP-A-4-6771 (JP, A) JP-A-64-50307 (JP, A) JP-A-2-33032 (JP, U) (58) Field surveyed (Int.Cl. 6 , DB name) H01R 11/01 G02F 1/1345 H01B 5/16

Claims (3)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 各回路基板の接続電極の絶縁板に対する
段差の和が5μm以上である両回路基板を、体積抵抗率
が107 〜1018Ω・cmで、熟硬化成分を含み、熱圧
着時の最低溶融粘度が1×107 ポイズ以下である熱接
着性接着剤を用い、加熱加圧して接続することを特徴と
する回路基板の接続方法。
1. A thermocompression bonding method in which both circuit boards each having a sum of steps of 5 μm or more with respect to an insulating plate of a connection electrode of each circuit board have a volume resistivity of 10 7 to 10 18 Ω · cm, contain a hardened component, A method for connecting circuit boards, wherein the connection is performed by applying heat and pressure using a heat-adhesive adhesive having a minimum melt viscosity of 1 × 10 7 poise or less.
【請求項2】 熱接着性接着剤が、熱可塑性樹脂100
重量部に対し、少なくとも熱硬化成分としてエポキシ樹
脂を10〜1000重量部含む請求項1に記載の接続方
法。
2. The method according to claim 1, wherein the heat-adhesive adhesive is a thermoplastic resin.
The connection method according to claim 1, wherein the thermosetting component contains at least 10 to 1000 parts by weight of an epoxy resin based on parts by weight.
【請求項3】 接続電極の段差の和が5〜100μmで
ある請求項1または2に記載の接続方法。
3. The connection method according to claim 1, wherein the sum of the steps of the connection electrode is 5 to 100 μm.
JP3141262A 1991-05-17 1991-05-17 Circuit board connection method Expired - Fee Related JP2846145B2 (en)

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Application Number Priority Date Filing Date Title
JP3141262A JP2846145B2 (en) 1991-05-17 1991-05-17 Circuit board connection method

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Publication Number Publication Date
JPH0684558A JPH0684558A (en) 1994-03-25
JP2846145B2 true JP2846145B2 (en) 1999-01-13

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JP2010177698A (en) * 2010-04-12 2010-08-12 Fujitsu Semiconductor Ltd Method for manufacturing electrostatic chuck
JP2010166086A (en) * 2010-04-12 2010-07-29 Fujitsu Semiconductor Ltd Semiconductor manufacturing apparatus using electrostatic chuck

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