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JP2889131B2 - How to attach a metal sheet to the surface of a metal substrate - Google Patents
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JP2889131B2 - How to attach a metal sheet to the surface of a metal substrate - Google Patents

How to attach a metal sheet to the surface of a metal substrate

Info

Publication number
JP2889131B2
JP2889131B2 JP24238894A JP24238894A JP2889131B2 JP 2889131 B2 JP2889131 B2 JP 2889131B2 JP 24238894 A JP24238894 A JP 24238894A JP 24238894 A JP24238894 A JP 24238894A JP 2889131 B2 JP2889131 B2 JP 2889131B2
Authority
JP
Japan
Prior art keywords
metal sheet
metal
welding
adhesive
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP24238894A
Other languages
Japanese (ja)
Other versions
JPH0871763A (en
Inventor
政芳 赤坂
耕太郎 吉田
久 金井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP24238894A priority Critical patent/JP2889131B2/en
Publication of JPH0871763A publication Critical patent/JPH0871763A/en
Application granted granted Critical
Publication of JP2889131B2 publication Critical patent/JP2889131B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

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  • Arc Welding In General (AREA)
  • Resistance Welding (AREA)
  • Laminated Bodies (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、海洋構造物、橋梁、各
種プラント等の金属構造物の防食や海洋生物等の付着防
止のため、耐食性や防汚性の薄金属シートを金属基材の
表面に貼り付ける方法に関する。
BACKGROUND OF THE INVENTION The present invention relates to a corrosion-resistant and antifouling thin metal sheet formed of a metal substrate to prevent corrosion of metal structures such as marine structures, bridges, and various plants and to prevent adhesion of marine organisms. It relates to a method of attaching to a surface.

【0002】[0002]

【従来の技術】従来、前記金属構造物の防食や防汚は有
機・無機塗料の塗装によるものが一般的であった。この
方法では数年で塗り直しが必要となるためメンテナンス
が煩雑であり、塗り直しは危険を伴う作業であった。近
年は腐食環境等の特に厳しいところに設置される金属構
造物の防食や防汚には、耐食性や防汚性を有する金属、
例えば銅、銅合金、ステンレス、チタン、モネル等のシ
ート(以下金属シートという)を単独または普通鋼とク
ラッドしたものを金属基材の表面に貼り付け被覆する金
属シート被覆法が用いられてきている。この金属シート
被覆法は、メンテナンスが不要で長期にわたり高い防食
性や防汚性が期待できるものである。
2. Description of the Related Art Conventionally, anticorrosion and antifouling of the above-mentioned metal structure have been generally performed by applying an organic / inorganic paint. In this method, repainting is required in several years, so maintenance is complicated, and repainting is a dangerous operation. In recent years, corrosion-resistant and antifouling of metal structures installed in particularly severe places such as corrosive environments include metals with corrosion resistance and antifouling properties,
For example, a metal sheet coating method has been used in which a sheet of copper, copper alloy, stainless steel, titanium, monel, or the like (hereinafter, referred to as a metal sheet) alone or clad with ordinary steel is adhered to the surface of a metal substrate and coated. . This metal sheet coating method requires no maintenance and can be expected to have high anticorrosion properties and antifouling properties over a long period of time.

【0003】[0003]

【発明が解決しようとする課題】従来の金属シート被覆
法には各種の方法があったがそれぞれ以下の課題があっ
た。
The conventional metal sheet coating method has various methods, but has the following problems.

【0004】(1)単独の金属シートを金属基材に重ね
て隅肉溶接により金属シートの外周を金属基材に接合す
る方法。この場合、異種金属の溶接は難しく、溶接品質
の確保が困難であった。また板厚が厚い金属基材に十分
溶け込ませるためには溶接入熱を高くする必要があり、
金属シートの溶融を防ぐためには板厚をlmm以上にし
なければならなかった。このため材料コストが高価にな
るとともに、金属シートが重くなり取扱いが不便であっ
た。
(1) A method in which a single metal sheet is stacked on a metal substrate and the outer periphery of the metal sheet is joined to the metal substrate by fillet welding. In this case, welding of dissimilar metals is difficult, and it is difficult to secure welding quality. In addition, it is necessary to increase welding heat input in order to sufficiently dissolve into a thick metal substrate.
In order to prevent the metal sheet from melting, the plate thickness had to be 1 mm or more. For this reason, the material cost becomes high, and the metal sheet becomes heavy, which is inconvenient to handle.

【0005】(2)また、金属シートにクラッド鋼を用
い、クラッド鋼の普通鋼の部分を金属基材(普通鋼)に
溶接したのち、被覆金属同士を溶接するという方法。そ
れぞれ同種金属の溶接となり溶接品質は確保できるが、
前記と同様の理由で金属シートを薄くすることはでき
ず、またクラッド鋼の製造と材料コストの高価さ及び金
属シートの取扱いの不便さを解消することはできなかっ
た。これら金属シートに単独、クラッド鋼いずれを用い
た場合も、金属基材の表面が曲線状に変化していたり、
変形している構造物に固着する場合は金属シートが厚い
ため剛性が高く、金属基材表面と金属シートの密着性が
悪くなるという課題もあった。
(2) A method in which clad steel is used as a metal sheet, and the ordinary steel portion of the clad steel is welded to a metal substrate (ordinary steel), and then the coated metals are welded to each other. Welding of the same kind of metal is possible and welding quality can be secured,
For the same reason as described above, the metal sheet could not be made thinner, and the production of clad steel, the high material cost, and the inconvenience of handling the metal sheet could not be eliminated. Even if these metal sheets are used alone or clad steel, the surface of the metal base material is changing in a curved shape,
When the metal sheet is fixed to a deformed structure, the metal sheet is thick, so that the rigidity is high, and the adhesion between the metal base material surface and the metal sheet deteriorates.

【0006】(3)最近、粘着剤、接着剤の性能向上に
ともない金属シートを粘着剤や接着剤のみで金属基材の
表面に貼りつけ被覆する方法が提案されている。この方
法は溶接による溶融の問題がないため金属シートの厚さ
を薄くできる利点があるが、金属シートの外周部の粘着
剤または接着剤が光、外気、水等に接するため、この部
分から劣化が進行し、金属シートが剥離するという課題
があった。
(3) Recently, a method has been proposed in which a metal sheet is adhered to the surface of a metal base material with only an adhesive or an adhesive to improve the performance of the adhesive or the adhesive. This method has the advantage that the thickness of the metal sheet can be reduced because there is no problem of melting by welding, but the adhesive or adhesive on the outer periphery of the metal sheet is exposed to light, outside air, water, etc. And the metal sheet peels off.

【0007】発明者らは、これらの課題を解決する手段
として特願平5−339015号および特願平6−00
2597号で金属シートを粘着剤や接着剤で金属基材の
表面に貼りつけ、外周部を爆発接合により密封シールす
る方法を提案している(図4)。これらの手段を用いる
と材料コストを低減し、かつ金属シートの外周部および
ラップ部を確実に密封シールし、メンテナンスフリーで
長期にわたって防食、防汚性能を維持することができ
る。
The inventors of the present invention have disclosed means for solving these problems as disclosed in Japanese Patent Application Nos. 5-339015 and 6-00.
No. 2597 proposes a method in which a metal sheet is attached to the surface of a metal substrate with an adhesive or an adhesive, and the outer peripheral portion is hermetically sealed by explosive bonding (FIG. 4). When these means are used, the material cost can be reduced, the outer peripheral portion and the wrap portion of the metal sheet can be securely hermetically sealed, and the maintenance-free anticorrosion and antifouling performance can be maintained for a long period of time.

【0008】本発明では、爆発接合とは異なる、取扱い
の容易な抵抗溶接法を主に用いて前述の課題を解決する
ことを目的としたものである。
An object of the present invention is to solve the above-mentioned problem mainly by using an easy-to-handle resistance welding method different from explosive joining.

【0009】[0009]

【課題を解決するための手段】上記目的を達成するため
の本発明の要旨は以下の通りである。金属基材の表面に
耐食性または防汚性を有する金属シート枠を固着し、前
記金属シート枠と同材質の薄金属シートの外周端部を金
属シート枠上に置き、重なり部分をインダイレクト抵抗
シーム溶接法により接合し密封シールすることを特徴と
する金属基材の表面に金属シートを貼り付ける方法。
The gist of the present invention to achieve the above object is as follows. A metal sheet frame having corrosion resistance or antifouling property is fixed to the surface of the metal base material, the outer peripheral edge of a thin metal sheet of the same material as the metal sheet frame is placed on the metal sheet frame, and the overlapping portion is indirect resistance seam. A method of attaching a metal sheet to a surface of a metal substrate, wherein the metal sheet is joined and hermetically sealed by a welding method.

【0010】[0010]

【作用】本発明に用いる金属シートの材質は、例えば防
食を目的とする場合は耐食性に優れた金属であるチタ
ン、モネル、ステンレス鋼等を用い、防汚を目的とする
場合は防汚性に優れた銅、銅ニッケル合金(キュプロニ
ッケル)等から選択する。これらの金属は特殊金属のた
め材料価格が高く、必要以上に厚くすると材料コストの
面で不利になる。
The material of the metal sheet used in the present invention is, for example, titanium, monel, stainless steel or the like, which is a metal having excellent corrosion resistance in the case of anticorrosion, and has antifouling property in the case of antifouling. Select from excellent copper, copper-nickel alloy (cupronickel), etc. Since these metals are special metals, their material costs are high, and if they are thicker than necessary, they are disadvantageous in terms of material costs.

【0011】従来法では、前述の通り金属シートを金属
基材に固着する際、隅肉溶接で行っていたため金属シー
トの厚さは溶接性の面から薄くすることができず、lm
m以上の板厚が必要であった。
In the conventional method, when the metal sheet is fixed to the metal substrate as described above, the thickness of the metal sheet cannot be reduced from the viewpoint of weldability because fillet welding is performed.
m or more.

【0012】本発明では枠となる金属シートについては
爆発接合または隅肉溶接により金属基材に接合するため
従来通りの板厚とするが、その枠に重ねて全体を覆う部
分には厚さlmm未満の薄金属シートを使用することで
材料コストを低減することができ、材料のハンドリング
性も向上させることができる。
In the present invention, the metal sheet serving as the frame has a conventional thickness because it is joined to the metal base material by explosive joining or fillet welding. By using a thin metal sheet less than the material, the material cost can be reduced, and the handleability of the material can be improved.

【0013】また、金属基材に固着した金属シート枠上
に薄金属シートの外周端部を溶接して固定、外周端部以
外を粘着剤または接着剤により金属基材上に固定するた
め薄金属シートの金属基材への固定部分が増加し、金属
基材からの浮き上がり、剥離等が防止でき密着性を向上
できる。
Further, the outer peripheral edge of the thin metal sheet is fixed to the metal sheet frame fixed to the metal substrate by welding, and the other than the outer peripheral edge is fixed on the metal substrate with an adhesive or an adhesive. The number of fixing portions of the sheet to the metal base increases, and the sheet can be prevented from being lifted off, separated from the metal base, and the adhesion can be improved.

【0014】さらに、金属シート枠と薄金属シートの溶
接はインダイレクト抵抗シーム溶接で行うが、金属シー
ト枠を使用することで施工が容易になり品質が確保し易
くなる。
Further, the welding of the metal sheet frame and the thin metal sheet is performed by indirect resistance seam welding. However, the use of the metal sheet frame facilitates the construction and makes it easy to ensure the quality.

【0015】[0015]

【実施例】以下、本発明の実施例を図を参照にして説明
する。図1は、本発明により金属基材の表面に金属シー
トを貼りつける手段を示す断面図、図2、図3は海中に
設置した桟橋、海洋構造物の干満帯・飛沫帯の鋼管に本
発明を適用した例で、図2は金属シート枠を鋼管に固着
した状態、図3はその上に薄金属シートを貼り付け、施
工が完了したところを示す。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to the drawings. FIG. 1 is a sectional view showing a means for attaching a metal sheet to the surface of a metal substrate according to the present invention. FIGS. 2 and 3 show a pier installed in the sea and a steel pipe in a tidal zone / splash zone of an offshore structure. FIG. 2 shows a state where a metal sheet frame is fixed to a steel pipe, and FIG. 3 shows a state where a thin metal sheet is pasted thereon to complete the construction.

【0016】金属基材の表面に金属シート枠1を固着す
る手段は、金属シート枠1の材質に応じて隅肉溶接と爆
発接合がある。ステンレス鋼や、クラッド鋼(普通鋼と
チタンなど)の場合には隅肉溶接により金属シートを金
属基材に直接溶接固着することができる。金属基材に直
接溶接することが困難なチタン等の場合には、爆発接合
により固着する。爆発接合の場合は金属基材と金属シー
ト枠を所定の間隔を有するように重ね、金属シート上に
アルミ板等の緩衝材を介して火薬類をセットし、雷管を
用いて点火、爆発させることによって金属基材5の表面
に金属シート枠1を固着する。
The means for fixing the metal sheet frame 1 to the surface of the metal base material includes fillet welding and explosion welding according to the material of the metal sheet frame 1. In the case of stainless steel or clad steel (such as ordinary steel and titanium), the metal sheet can be directly welded and fixed to the metal substrate by fillet welding. In the case of titanium or the like which is difficult to be directly welded to a metal substrate, it is fixed by explosive joining. In the case of explosive joining, the metal base and the metal sheet frame are stacked so as to have a predetermined interval, explosives are set on the metal sheet via a buffer material such as an aluminum plate, and ignited and exploded using a primer. Thus, the metal sheet frame 1 is fixed to the surface of the metal substrate 5.

【0017】金属基材(鋼管)へ所定の金属シート枠の
固着が済んだら次に、薄金属シート2の外周端部3が金
属シート枠1に重なるように置き、重なり部分をインダ
イレクト抵抗シーム溶接法により密封シールする。ま
た、薄金属シート2の外周端部を除く重ね合わせ範囲4
と金属基材5との間は、そのままにしておいてもよい
が、薄金属シート2の外周端部を除く重ね合わせ範囲4
にアクリル系、エポキシ系、ブチル系、ポリエチレン
系、ビニル系の合成樹脂よりなる粘着剤や接着剤6を塗
布して貼りつけた方が耐衝撃性の上から良い結果が得ら
れる。このようにすれば金属基材5と薄金属シート2を
全面にわたって接着でき、薄金属シート2の浮き上がり
等が生じることなく、さらに内部に湿気を含んだ空気を
存在させないため、防食面でより有利になるとともに、
薄金属シート2の一部に傷が発生しても粘着剤、接着剤
6で保護できる利点がある。
After the predetermined metal sheet frame has been fixed to the metal substrate (steel pipe), the outer peripheral end 3 of the thin metal sheet 2 is placed so as to overlap the metal sheet frame 1, and the overlapping portion is indirect resistance seam. Hermetically sealed by welding. The overlapping area 4 excluding the outer peripheral edge of the thin metal sheet 2
And the metal substrate 5 may be left as it is, but the overlapping area 4 excluding the outer peripheral edge of the thin metal sheet 2
Applying an adhesive or an adhesive 6 made of an acrylic, epoxy, butyl, polyethylene, or vinyl synthetic resin to the resin and attaching the adhesive resin 6 gives a better result in terms of impact resistance. In this way, the metal substrate 5 and the thin metal sheet 2 can be adhered over the entire surface, and the thin metal sheet 2 does not float up, and furthermore, there is no air containing moisture inside, so that it is more advantageous in terms of corrosion protection. Along with
There is an advantage that even if a part of the thin metal sheet 2 is scratched, it can be protected by the adhesive or the adhesive 6.

【0018】金属シート枠1上に薄金属シート2の外周
端部3をインダイレクト抵抗シーム溶接するには図1に
示すように、2ヶのローラー電極を有する抵抗溶接機の
一方のローラー電極7を金属シート枠1と薄金属シート
2の重なり部上に配置し、他方のローラー電極7を金属
シート枠1上に接触させて通電しながら溶接方向に移動
させる。溶接条件は金属シートの材質、板厚に応じて、
適当な値を選ぶ必要がある。
For indirect resistance seam welding of the outer peripheral end 3 of the thin metal sheet 2 onto the metal sheet frame 1, as shown in FIG. 1, one roller electrode 7 of a resistance welding machine having two roller electrodes is used. Is disposed on the overlapped portion of the metal sheet frame 1 and the thin metal sheet 2, and the other roller electrode 7 is moved in the welding direction while being in contact with the metal sheet frame 1 and energized. The welding conditions depend on the material and thickness of the metal sheet.
You need to choose an appropriate value.

【0019】金属シート枠1の間隔は規定寸法の薄金属
シート一枚分の幅とするか、または、複数枚の薄金属シ
ート2どうしをラップさせて広くすることもできる。そ
の場合、薄金属シート2を金属基材5に貼りつける前に
薄金属シート2のラップ部を対向するローラー電極7を
使用した抵抗溶接によりあらかじめ接合しておく。また
は複数枚の薄金属シート2を金属基材5に貼りつけた後
薄金属シート2のラップ部を平行するローラー電極7を
用いたインダイレクトシーム溶接により接合してもよ
い。
The interval between the metal sheet frames 1 can be made equal to the width of one thin metal sheet of a prescribed size, or can be made wider by wrapping a plurality of thin metal sheets 2 together. In that case, before the thin metal sheet 2 is attached to the metal base material 5, the lap portion of the thin metal sheet 2 is joined in advance by resistance welding using the roller electrode 7 facing the thin metal sheet 2. Alternatively, a plurality of thin metal sheets 2 may be attached to the metal substrate 5 and then the lap portions of the thin metal sheets 2 may be joined by indirect seam welding using parallel roller electrodes 7.

【0020】以上のような手順で金属基材5上に金属シ
ート枠1を利用して薄金属シート2を貼り付けることが
できる。
The thin metal sheet 2 can be stuck on the metal substrate 5 using the metal sheet frame 1 in the above-described procedure.

【0021】[0021]

【発明の効果】本発明は、金属基材表面に枠となる金属
シートを爆発接合または隅肉溶接により接合し、その上
に薄金属シートを操作が容易で品質が確保できる抵抗シ
ーム溶接で密封シールする金属シート被覆法である。従
って、従来の金属シート被覆法のように金属基材の被覆
範囲全面にわたり金属シートを隅肉溶接するものと比較
して、薄い金属シートを使用することができるため、金
属シートの材料コストを低減し、材料のハンドリング性
を向上することができる。また金属基材に固着した金属
シート枠を介して薄金属シートを貼り付けるため金属基
材への密着性が向上し、施工が容易になる。
According to the present invention, a metal sheet serving as a frame is joined to the surface of a metal substrate by explosive joining or fillet welding, and a thin metal sheet is sealed thereon by resistance seam welding, which is easy to operate and ensures quality. This is a metal sheet coating method for sealing. Therefore, compared with the conventional metal sheet coating method in which the metal sheet is fillet welded over the entire area covered with the metal base material, a thin metal sheet can be used, thereby reducing the material cost of the metal sheet. In addition, the material handling properties can be improved. In addition, since the thin metal sheet is attached via the metal sheet frame fixed to the metal substrate, the adhesion to the metal substrate is improved, and the construction is facilitated.

【0022】また、金属シートの外周端部を抵抗シーム
溶接して密封シールするため、金属基材は光、外気、水
等から完全に遮断され、完全な防食が期待できる。さら
にラップ部および端部以外の重ね合わせ部に粘着剤、接
着剤を用いた場合には端部を光、外気、水等から完全に
遮断できるため粘着剤、接着剤に劣化が生じることがな
く、長期にわたりメンテナンスフリーで防食や防汚性能
を維持できる効果がある。
In addition, since the outer peripheral edge of the metal sheet is hermetically sealed by resistance seam welding, the metal substrate is completely shielded from light, outside air, water and the like, and complete corrosion protection can be expected. Furthermore, when an adhesive or an adhesive is used for the overlapping portion other than the wrap portion and the end portion, the end portion can be completely shielded from light, outside air, water, etc., so that the adhesive and the adhesive do not deteriorate. It has the effect of maintaining corrosion- and antifouling performance without maintenance for a long time.

【0023】さらに、チタンのように一般炭素鋼との溶
接では金属間化合物の生成等により割れ発生等溶接その
ものが不可能な金属についても使用することができる。
Further, it is also possible to use a metal such as titanium which cannot be welded due to generation of an intermetallic compound or the like in welding with general carbon steel.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明による金属シートの貼り付け実施例を示
す端部断面図である。
FIG. 1 is an end sectional view showing an embodiment of attaching a metal sheet according to the present invention.

【図2】本発明に係わる鋼管への金属シート枠の固着状
況を示す図である。
FIG. 2 is a view showing a state of fixing a metal sheet frame to a steel pipe according to the present invention.

【図3】本発明に係わる鋼管への薄金属シートの貼り付
け完成状況を示す図である。
FIG. 3 is a view showing a completed state of attaching a thin metal sheet to a steel pipe according to the present invention.

【図4】従来例(爆発接合による薄金属シートの貼り付
け)を示す図である。
FIG. 4 is a view showing a conventional example (pasting of a thin metal sheet by explosive joining).

【符号の説明】[Explanation of symbols]

1 金属シート枠 2 薄金属シート 3 外周端部 4 外周端部を除く重ね部分 5 金属基材 6 粘着剤または接着剤 7 ローラー電極 8 隅肉溶接 9 抵抗溶接 10 爆発接合 11 金属シート A 緩衝材 B 火薬類 REFERENCE SIGNS LIST 1 metal sheet frame 2 thin metal sheet 3 outer peripheral end 4 overlapping portion excluding outer peripheral end 5 metal base material 6 adhesive or adhesive 7 roller electrode 8 fillet welding 9 resistance welding 10 explosive joining 11 metal sheet A buffer material B Explosives

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 金属基材の表面に耐食性または防汚性を
有する金属シート枠を固着し、前記金属シート枠と同材
質の薄金属シートの外周端部を金属シート枠上に置き、
重なり部分をインダイレクト抵抗シーム溶接法により接
合し密封シールすることを特徴とする金属基材の表面に
金属シートを貼り付ける方法。
1. A metal sheet frame having corrosion resistance or antifouling property is fixed to a surface of a metal substrate, and an outer peripheral end of a thin metal sheet of the same material as the metal sheet frame is placed on the metal sheet frame.
A method of attaching a metal sheet to a surface of a metal substrate, wherein overlapping portions are joined and sealed by indirect resistance seam welding.
JP24238894A 1994-09-12 1994-09-12 How to attach a metal sheet to the surface of a metal substrate Expired - Fee Related JP2889131B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24238894A JP2889131B2 (en) 1994-09-12 1994-09-12 How to attach a metal sheet to the surface of a metal substrate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24238894A JP2889131B2 (en) 1994-09-12 1994-09-12 How to attach a metal sheet to the surface of a metal substrate

Publications (2)

Publication Number Publication Date
JPH0871763A JPH0871763A (en) 1996-03-19
JP2889131B2 true JP2889131B2 (en) 1999-05-10

Family

ID=17088420

Family Applications (1)

Application Number Title Priority Date Filing Date
JP24238894A Expired - Fee Related JP2889131B2 (en) 1994-09-12 1994-09-12 How to attach a metal sheet to the surface of a metal substrate

Country Status (1)

Country Link
JP (1) JP2889131B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000273973A (en) * 1999-03-24 2000-10-03 Nippon Steel Corp Corrosion resistant metal sheet coating method to prevent deterioration of concrete structures
JP5271785B2 (en) * 2009-04-21 2013-08-21 新日鐵住金株式会社 Steel sheet pile anticorrosion structure and anticorrosion method

Also Published As

Publication number Publication date
JPH0871763A (en) 1996-03-19

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