JP2893552B2 - Masking agent for soap and detergent - Google Patents
Masking agent for soap and detergentInfo
- Publication number
- JP2893552B2 JP2893552B2 JP19298990A JP19298990A JP2893552B2 JP 2893552 B2 JP2893552 B2 JP 2893552B2 JP 19298990 A JP19298990 A JP 19298990A JP 19298990 A JP19298990 A JP 19298990A JP 2893552 B2 JP2893552 B2 JP 2893552B2
- Authority
- JP
- Japan
- Prior art keywords
- soap
- oil
- detergent
- present
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000344 soap Substances 0.000 title claims description 31
- 239000003599 detergent Substances 0.000 title claims description 19
- 230000000873 masking effect Effects 0.000 title claims description 8
- 239000003795 chemical substances by application Substances 0.000 title claims description 5
- 235000019645 odor Nutrition 0.000 claims description 15
- 235000021243 milk fat Nutrition 0.000 claims description 6
- 230000007071 enzymatic hydrolysis Effects 0.000 claims 1
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 description 18
- 235000019198 oils Nutrition 0.000 description 18
- 235000019482 Palm oil Nutrition 0.000 description 14
- 239000003205 fragrance Substances 0.000 description 14
- 239000002540 palm oil Substances 0.000 description 14
- 235000014121 butter Nutrition 0.000 description 13
- 239000000203 mixture Substances 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000003925 fat Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 235000019197 fats Nutrition 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000002255 enzymatic effect Effects 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000014593 oils and fats Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- DNRJTBAOUJJKDY-UHFFFAOYSA-N 2-Acetyl-3,5,5,6,8,8-hexamethyl-5,6,7,8- tetrahydronaphthalene Chemical compound CC(=O)C1=C(C)C=C2C(C)(C)C(C)CC(C)(C)C2=C1 DNRJTBAOUJJKDY-UHFFFAOYSA-N 0.000 description 1
- MBZRJSQZCBXRGK-UHFFFAOYSA-N 4-tert-Butylcyclohexyl acetate Chemical compound CC(=O)OC1CCC(C(C)(C)C)CC1 MBZRJSQZCBXRGK-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 240000003133 Elaeis guineensis Species 0.000 description 1
- 235000001950 Elaeis guineensis Nutrition 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- -1 Furthermore Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 101000968491 Pseudomonas sp. (strain 109) Triacylglycerol lipase Proteins 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- GUUHFMWKWLOQMM-NTCAYCPXSA-N alpha-hexylcinnamaldehyde Chemical compound CCCCCC\C(C=O)=C/C1=CC=CC=C1 GUUHFMWKWLOQMM-NTCAYCPXSA-N 0.000 description 1
- GUUHFMWKWLOQMM-UHFFFAOYSA-N alpha-n-hexylcinnamic aldehyde Natural products CCCCCCC(C=O)=CC1=CC=CC=C1 GUUHFMWKWLOQMM-UHFFFAOYSA-N 0.000 description 1
- LFYJSSARVMHQJB-QIXNEVBVSA-N bakuchiol Chemical compound CC(C)=CCC[C@@](C)(C=C)\C=C\C1=CC=C(O)C=C1 LFYJSSARVMHQJB-QIXNEVBVSA-N 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- MWOBKFYERIDQSZ-UHFFFAOYSA-N benzene;sodium Chemical compound [Na].C1=CC=CC=C1 MWOBKFYERIDQSZ-UHFFFAOYSA-N 0.000 description 1
- 229960002903 benzyl benzoate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 235000019571 color Nutrition 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000001738 pogostemon cablin oil Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 239000001529 viverra civetta schreber and viverra zibeth a schreber absolute Substances 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
- Fats And Perfumes (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は，石鹸，洗剤用基材臭のマスキング剤に関
し，特にパーム油を主な原料とする石鹸，洗剤の基材の
有する不快臭をマスキングするために用いるマスキング
剤に関する。Description: BACKGROUND OF THE INVENTION The present invention relates to a masking agent for soap and detergent base odors, and more particularly to an unpleasant odor of soap and detergent bases made mainly from palm oil. The present invention relates to a masking agent used for masking.
従来，石鹸の製造に使用される原料油脂の標準的な配
合は，牛脂80〜85％，ヤシ油15〜20％とされ，その他に
パーム油，パーム核油などの植物油脂，硬化鯨油などの
動物油脂も使われるが，それほど多くは使用されていな
かった。近年，アブラヤシから得られるパーム油の生産
量は，全世界で1984年に650万トンとされ，大豆油に次
いで生産量の多い油脂となっているが，さらにその生産
量は，今後，年10％の高率で増加し,2000年には2000万
トンに及ぶと予測されている［ジャーナル オブ アメ
リカン オイル ケミスツ ソサイエティー（Journal
of American Oil Chemist's Society）第62巻，第２
号，第188〜462ページ，（1985年）］。この様な背景か
ら，従来食品向けを中心に消費されてきたパーム油は，
石鹸の原料としても重要視されつつある。Conventionally, the standard composition of raw oils and fats used for soap production is 80-85% of beef tallow and 15-20% of coconut oil. In addition, vegetable oils such as palm oil and palm kernel oil and hardened whale oil Animal fats are also used, but not so much. In recent years, the production of palm oil from oil palm was 6.5 million tons worldwide in 1984, making it the second largest oil and fat after soybean oil. And is projected to reach 20 million tonnes in 2000 [Journal of American Oil Chemistry Society (Journal)
of American Oil Chemist's Society) Vol. 62, No. 2
Issue, pp. 188-462, (1985)]. Against this background, palm oil, which has been consumed mainly for food products,
It is also gaining importance as a raw material for soap.
石鹸及び洗剤には使用中または使用後の爽快感付与す
ること，基材の持つ不快臭を変調させること，もしくは
芳香を空気中に揮散させることそのものを目的に香料が
配合されている。Perfumes are added to soaps and detergents for the purpose of imparting a refreshing sensation during or after use, modulating the unpleasant odor of the base material, or volatilizing fragrance into the air.
しかし，パーム油を原料に作られた石鹸には植物油脂
特有の不快臭があり，従来の牛脂石鹸の持つ，石鹸の香
りを想起させる好ましい軟らかなファッティー臭（fatt
y臭，脂肪臭）に欠けるなどの欠点がある上に，香料の
香り立ちが変調する，香りの持続性が十分に保たれない
などの問題がある。すなわち，香料は本来，石鹸，洗剤
の基材の持つ不快臭をマスキングすることを重要な目的
の一つとして使用されているのだが，パーム油を主原料
とする石鹸においてはその効果が十分に発揮できていな
いといえる。石鹸，洗剤に用いる香料の香り立ちを助長
し，改善する方法に関しては過去において数多くの提案
がなされているが，パーム油を主要原料とする石鹸に見
られる上述の様な問題点を解決する具体的な方策を明示
した例は，未だ見あたらない。However, soap made from palm oil has an unpleasant odor peculiar to vegetable oils and fats, which is a good soft fatty odor reminiscent of soap scent of conventional tallow soap.
In addition to the drawbacks such as lack of (y odor and fatty odor), there are problems such as the modulation of the fragrance of the fragrance and the persistence of the fragrance being not sufficiently maintained. In other words, fragrances are originally used as one of the important purposes to mask the unpleasant odor of soap and detergent base materials. However, the effect of soaps using palm oil as a main raw material is not sufficient. It can not be said that it can be demonstrated. Numerous proposals have been made in the past on methods for promoting and improving the fragrance of fragrances used in soaps and detergents. However, concrete methods for solving the above-mentioned problems found in soaps using palm oil as a main raw material have been proposed. We have not yet found an example that shows a specific strategy.
本発明の目的は，上記従来技術の問題点を解決するこ
とにあり，特にパーム油を主原料とする石鹸，洗剤の基
材の持つ不快臭をマスキングすると共に香料の香り立ち
を助長改善する石鹸，洗剤用添加剤を提供することを課
題とする。SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned problems of the prior art, and in particular, a soap using palm oil as a main raw material, a mask which masks an unpleasant odor of a base material of a detergent and promotes and improves aroma of a fragrance. It is another object of the present invention to provide a detergent additive.
本発明者らは，このような課題を解決すべく鋭意検討
を進めた結果，乳脂の酵素加水分解物を必須成分として
含む組成物をパーム油を主原料とする石鹸等の洗浄剤基
材に添加すると，基材の有する不快臭をマスキングし，
基材に好ましいファッティー臭（fatty臭）を与え，さ
らに香料の香り立ちを助長する点で優れた特性を有する
ことを発見し本発明を完成するに至った。The present inventors have conducted intensive studies in order to solve such problems, and as a result, have found that a composition containing an enzymatic hydrolyzate of milk fat as an essential component can be used as a base material for detergents such as soap using palm oil as a main raw material. When added, it masks the unpleasant odor of the base material,
The inventors have found that the base material gives a favorable fatty smell and has excellent characteristics in that it promotes the perfume scent, and has completed the present invention.
本発明の石鹸，洗剤用マスキング剤は，乳脂の酵素加
水分解物を必須成分として含有することを特徴とする。The masking agent for soap and detergent of the present invention is characterized by containing an enzymatic hydrolyzate of milk fat as an essential component.
本発明における乳脂とは，乳に由来する油脂を主体と
する食用とされる畜産加工品を意味し，具体的にはバタ
ー，バターオイル，発酵バター，生クリームの一種もし
くは二種以上の混合物，さらにはこれら乳脂を一種もし
くは二種以上含有する植物油脂，化学的，酵素的合成に
よって得られる油脂を示す。The milk fat in the present invention means a processed livestock product mainly composed of fat derived from milk, and specifically, butter, butter oil, fermented butter, one or a mixture of two or more kinds of fresh cream, Furthermore, vegetable oils containing one or more of these milk fats, and oils and fats obtained by chemical and enzymatic synthesis are shown.
本発明で用いる加水分解物は，加水分解反応後の水不
溶解成分の混合物として用いるのが好ましく，特に発明
の効果を十分に引き出すには，加水分解率を10〜90％に
制限して得られる混合物の使用が好ましい。The hydrolyzate used in the present invention is preferably used as a mixture of water-insoluble components after the hydrolysis reaction. In particular, in order to sufficiently bring out the effects of the present invention, the hydrolysis rate should be limited to 10 to 90%. The use of the resulting mixture is preferred.
乳脂加水分解物はさらに濃縮，乾燥，新たなる物質の
添加等の操作により，溶液状，ペースト状，粉末状，そ
の他任意の形態において使用することができる。The milk fat hydrolyzate can be used in the form of a solution, paste, powder, or any other form by operations such as concentration, drying, and addition of a new substance.
本発明における石鹸，洗剤は油脂の加水分解物塩を基
材とするものであり，特にパーム油を主原料とするも
の，より具体的には原料油脂の50％以上がパーム油であ
るものが用いられる。石鹸，洗剤なる表現は慣用的に用
いられる代表的用語を列記しただけのものであり，洗浄
用に用いる界面活性剤一般を意味し，従っていわゆる洗
浄剤なども当然に本発明にいう石鹸，洗剤に包含され
る。The soap and detergent in the present invention are based on a hydrolyzed salt of fats and oils, and in particular, those based on palm oil as a main raw material, and more specifically, those whose palm oil is 50% or more of the raw fat or oil. Used. The expressions "soap" and "detergent" are merely lists of commonly used typical terms, and refer to surfactants generally used for cleaning. Therefore, so-called detergents and the like are naturally used in the present invention. Is included.
乳脂加水分解物の石鹸，洗剤基材に占める割合は，重
量で0.001〜５％，特に0.1〜１％の範囲内であることが
好ましい。石鹸，洗剤基材との混合に用いられる方法
は，回分式，連続式を問わずいかなる装置形態を用いて
も行うことができ，また均一状態に混合するという目的
に合致したいかなる方法を用いても良い。The proportion of the milk fat hydrolyzate in the soap and detergent base is preferably in the range of 0.001 to 5%, particularly 0.1 to 1% by weight. The method used for mixing with the soap and detergent base can be any type of apparatus, whether batch or continuous, and can be performed using any method suitable for the purpose of mixing uniformly. Is also good.
次に実施例をあげて本発明をさらに具体的に説明す
る。Next, the present invention will be described more specifically with reference to examples.
なお，特性に関する評価項目は香料を添加しない場合
における基材の不快臭のマスキング程度，香料を添加し
た場合では，香り立ちの増強，基材の不快臭のマスキン
グ程度，香調の変調，および40℃,3週間後の香気の変化
の４点とし，判定は本発明品と本発明の優位性を正確に
把握するに適すると思われる比較例との差を香気評価の
専門パネラー20名により官能評価した。評価基準は次の
様に７点法を用い，各評価項目ごとに平均点で判定し
た。The evaluation items related to the characteristics were the degree of masking of the unpleasant odor of the base material when no fragrance was added, and the enhancement of the fragrance, the degree of masking of the unpleasant odor of the base material, the modulation of the odor, and The change in fragrance after 3 weeks at ℃ is 4 points, and the judgment is based on the difference between the product of the present invention and the comparative example which is considered to be suitable for accurately grasping the superiority of the present invention. evaluated. The evaluation criteria were determined by the average score for each evaluation item using the 7-point method as follows.
７点法評価基準 ＋３点 比較品に比べ非常によい ＋２点 比較品に比べよい ＋１点 比較品に比べややよい ０点 比較品と同等である −１点 比較品に比べやや劣る −２点 比較品に比べ劣る −３点 比較品に比べかなり劣る また，油脂の加水分解率は，下記に示す計算式より算
出した。7-point method evaluation criteria +3 points Very good compared to the comparison product +2 points Good compared to the comparison product +1 point Slightly better than the comparison product 0 point Same as the comparison product -1 point Slightly inferior to the comparison product -2 comparison Inferior to product -3 points Substantially inferior to comparative product In addition, the hydrolysis rate of fats and oils was calculated by the following formula.
実施例 １ 市販の業務用バターオイル（ケン化価228,酸価0.12,
含水率0.2％）を原料として，以下の方法にてバターオ
イル加水分解物を調製した。バターオイル100gにイオン
交換水100gを加え,37℃にて撹拌下，リパーゼＰ（天野
製薬製）を2g添加し,37℃,12時間反応させた後，昇温
し,20分間,90℃の温度を保ち酵素を失活させた。加水分
解率は64％であった。分液操作によって得られた油層を
無水硫酸ナトリウムにて乾燥させ，濾過を経て，バター
オイル加水分解物81.7gを得た。 Example 1 Commercially available commercial butter oil (saponification value 228, acid value 0.12,
Using a water content of 0.2% as a raw material, a butter oil hydrolyzate was prepared by the following method. Add 100 g of ion-exchanged water to 100 g of butter oil, add 2 g of lipase P (manufactured by Amano Pharmaceutical) at 37 ° C. with stirring, react at 37 ° C. for 12 hours, raise the temperature, and heat at 90 ° C. for 20 minutes. The temperature was maintained to inactivate the enzyme. The hydrolysis rate was 64%. The oil layer obtained by the liquid separation operation was dried over anhydrous sodium sulfate, and filtered to obtain 81.7 g of a butter oil hydrolyzate.
得られたバターオイル加水分解物をパーム油ケン化物
を主要成分とする石鹸素地に0.5重量％添加し，石鹸練
り上げ機を用いて十分に混合した後，成型し，石鹸を調
製した。The obtained butter oil hydrolyzate was added to a soap base containing saponified palm oil as a main component at 0.5% by weight, mixed thoroughly using a soap kneader, and then molded to prepare a soap.
比較例 １ 実施例１のバターオイル加水分解物を除いた他は全く
同様な方法で石鹸を調製した。Comparative Example 1 A soap was prepared in exactly the same manner as in Example 1, except that the butter oil hydrolyzate was removed.
比較例１を基準に，実施例１の調製品が基材臭をどの
程度マスキングしているか官能評価で比較した。結果は
＋2.95の点数で実施例１の本発明品が優位であると判定
された。On the basis of Comparative Example 1, the sensory evaluation was performed to determine how much the preparation of Example 1 masked the odor of the base material. As a result, the product of Example 1 of the present invention was judged to be superior with a score of +2.95.
実施例 ２ 実施例１で調製したバターオイル加水分解物をパーム
油ケン化物を主要成分とする石鹸の素地に0.5％添加
し，十分に混合し後，次に示すシプレー調の香気を有す
る香料組成物を1.0％添加し，石鹸練り上げ機を用いて
混合後，成型し，石鹸を調製した。Example 2 0.5% of the butter oil hydrolyzate prepared in Example 1 was added to a soap base containing saponified palm oil as a main component, and after thoroughly mixing, a perfume composition having the following spray-like aroma was obtained. The product was added 1.0%, mixed using a soap kneader, and then molded to prepare a soap.
成 分 重量比 リナロール 10.0 リナリルアセテート 15.0 Ｐ−tert−ブチルシクロヘキシルアセテート 20.0 α−ヘキシルシンナミックアルデヒド 20.0 ジャスミン Ｓ−156† 5.0 ローズ アルディア MS/37† 7.0 アンバーグリス シンス† 1.0 アルデヒド Ｃ−11 0.5 シベットアブソリュート10％エタノール溶液 0.5 トナリッド 5.0 ベンジルベンゾエート 10.0 オークモスアブソリュートカラレス 3.0パチュリーオイル 3.0 計 100.0 †：曽田香料（株）商品名 比較例 ２ 実施例２においてバターオイル加水分解物を除き，他
は全く同様な方法にて実施例２に示した香料組成物を添
加した石鹸を調製した。Ingredients Weight ratio Linalool 10.0 Linalyl acetate 15.0 P-tert-butylcyclohexyl acetate 20.0 α-hexylcinnamic aldehyde 20.0 Jasmine S-156 † 5.0 Rose Aldia MS / 37 † 7.0 Ambergris Sins † 1.0 Aldehyde C-11 0.5 Civet absolute 10 % Ethanol solution 0.5 Tonalid 5.0 Benzyl benzoate 10.0 Oak Moss Absolute Colores 3.0 Patchouli Oil 3.0 Total 100.0 †: Trade name of Koda Soda Co., Ltd. A soap to which the fragrance composition shown in Example 2 was added was prepared.
比較例２で調製した石鹸を基準として実施例２より得
られた本発明品の官能評価を行った。結果は表１に示す
ごとく評価項目の全ての点で実施例２の本発明品が優位
であると判定された。Based on the soap prepared in Comparative Example 2, the sensory evaluation of the product of the present invention obtained in Example 2 was performed. As shown in Table 1, the product of Example 2 of the present invention was determined to be superior in all of the evaluation items as shown in Table 1.
実施例 ３ さらに実施例１で得られたバターオイル加水分解物と
実施例２に示した香料組成物とを以下に示した様に粒状
洗剤に配合した。 Example 3 Further, the butter oil hydrolyzate obtained in Example 1 and the fragrance composition shown in Example 2 were blended in a granular detergent as shown below.
成 分 重量比 Ａ型ゼオライト 15 直鎖アルキル（C12〜C13）ベンゼン スルホン酸ナトリウム 10 α−オレフィン（C14〜C18） スルホン酸ナトリウム 10 パーム油石鹸 2 ケイ酸ナトリウム 10 炭酸ナトリウム 10 カルボキシメチルセルロース 0.60 バターオイル加水分解物 （実施例４例示品） 0.10 香料組成物（実施例５例示品） 0.15 水 10 比較例 ３ 実施例３からバターオイル加水分解物を除いた組成を
有する粒状洗剤を調製した。Component Weight ratio Type A zeolite 15 Linear alkyl (C12-C13) benzene sodium sulfonate 10 α-olefin (C14-C18) Sodium sulfonate 10 Palm oil soap 2 Sodium silicate 10 Sodium carbonate 10 Carboxymethylcellulose 0.60 Butter oil water Decomposed product (exemplified product of Example 4) 0.10 Fragrance composition (exemplified product of Example 5) 0.15 Water 10 Comparative Example 3 A granular detergent having a composition obtained by removing butter oil hydrolyzate from Example 3 was prepared.
比較例３を基準として実施例３より得られた粒状洗剤
について官能評価を行ったところ表２に示すごとく評価
項目の全ての点で実施例３によって示された本発明品が
優位であると判定された。The granular detergent obtained from Example 3 was subjected to a sensory evaluation based on Comparative Example 3, and as shown in Table 2, it was determined that the product of the present invention shown in Example 3 was superior in all of the evaluation items as shown in Table 2. Was done.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ Ａ６１Ｋ 7/46 ３３１ Ａ６１Ｋ 7/46 ３３１ 7/50 7/50 (72)発明者 江藤 武顯 千葉県野田市船形1573―４ 曽田香料株 式会社野田支社内 (56)参考文献 特開 平４−45198（ＪＰ，Ａ) 特開 昭47−26841（ＪＰ，Ａ) (58)調査した分野(Int.Cl.6，ＤＢ名) C11D 3/50 C11D 9/44 C11D 3/384 C11D 3/46 C11D 9/48 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 6 Identification code FI A61K 7/46 331 A61K 7/46 331 7/50 7/50 (72) Inventor Takeaki Eto 1573-4 Funagata Noda City, Chiba Prefecture (56) References JP-A-4-45198 (JP, A) JP-A-47-26841 (JP, A) (58) Fields investigated (Int. Cl. 6 , DB name) ) C11D 3/50 C11D 9/44 C11D 3/384 C11D 3/46 C11D 9/48
Claims (1)
て含有することを特徴とする石鹸、洗剤用基材臭のマス
キング剤。1. A masking agent for base odors for soaps and detergents, comprising an enzymatic hydrolysis product of milk fat as an essential component.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19298990A JP2893552B2 (en) | 1990-07-23 | 1990-07-23 | Masking agent for soap and detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19298990A JP2893552B2 (en) | 1990-07-23 | 1990-07-23 | Masking agent for soap and detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0480299A JPH0480299A (en) | 1992-03-13 |
| JP2893552B2 true JP2893552B2 (en) | 1999-05-24 |
Family
ID=16300380
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19298990A Expired - Fee Related JP2893552B2 (en) | 1990-07-23 | 1990-07-23 | Masking agent for soap and detergent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2893552B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4961062B2 (en) * | 2006-12-22 | 2012-06-27 | 株式会社エー・アンド・デイ | Pressure band for blood pressure measurement |
-
1990
- 1990-07-23 JP JP19298990A patent/JP2893552B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0480299A (en) | 1992-03-13 |
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