JP2906284B2 - Microwave absorber - Google Patents
Microwave absorberInfo
- Publication number
- JP2906284B2 JP2906284B2 JP26766790A JP26766790A JP2906284B2 JP 2906284 B2 JP2906284 B2 JP 2906284B2 JP 26766790 A JP26766790 A JP 26766790A JP 26766790 A JP26766790 A JP 26766790A JP 2906284 B2 JP2906284 B2 JP 2906284B2
- Authority
- JP
- Japan
- Prior art keywords
- dielectric constant
- microwave
- loss tangent
- high dielectric
- tangent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000006096 absorbing agent Substances 0.000 title claims description 15
- 239000000463 material Substances 0.000 claims description 66
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000010030 laminating Methods 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000006104 solid solution Substances 0.000 claims description 2
- 239000003989 dielectric material Substances 0.000 description 8
- 230000020169 heat generation Effects 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000013016 damping Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920002050 silicone resin Polymers 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000003990 capacitor Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 229910003522 Sr-Sn Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Landscapes
- Electric Ovens (AREA)
- Baking, Grill, Roasting (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
Description
【発明の詳細な説明】 産業上の利用分野 本発明は、電子レンジにおいてマイクロ波を吸収して
発熱するマイクロ波吸収体に関する。Description: TECHNICAL FIELD The present invention relates to a microwave absorber that absorbs microwaves and generates heat in a microwave oven.
従来の技術 電子レンジにおけるマイクロ波調理は、短時間に効率
良く食品を加熱することができるが、その特性上食品に
焦げ目を付けることは困難である。2. Description of the Related Art Microwave cooking in a microwave oven can heat food efficiently in a short time, but it is difficult to brown the food due to its characteristics.
そのため、マイクロ波を吸収して発熱する焦げ目付皿
なるものを設ける必要があった。焦げ目付皿は、一般に
第2図に示したように、食品10と接する側より、非粘着
表面処理された金属プレート11、マイクロ波を吸収して
発熱するマイクロ波吸収体12、および支持体15とから構
成されていた。マイクロ波吸収体12としては、フェライ
ト13をシリコンゴム14などに分散保持したものが一部商
品化されている(磁性損を利用)。For this reason, it is necessary to provide a brown plate that absorbs microwaves and generates heat. As shown in FIG. 2, the browning plate generally has a non-adhesive surface-treated metal plate 11, a microwave absorber 12 that absorbs microwaves and generates heat, and a support 15 from the side in contact with the food 10. And was composed of As the microwave absorber 12, one in which a ferrite 13 is dispersed and held in a silicon rubber 14 or the like is partially commercialized (using magnetic loss).
発明が解決しようとする課題 しかしながら、従来のマイクロ波吸収体を用いた焦げ
目付皿は、食品加熱の前に長い余熱時間が必要であった
り、発熱温度が低いという問題を有していた。なお、発
熱形態の原理の上では、たとえば、チタン酸バリウムな
どの誘電材料の誘電損の利用が考えられるが、一般に吸
収能が低く、焦げ目付皿やマイクロ波の漏洩防止に用い
る際には厚みが大きくなり実用的ではなかった。Problems to be Solved by the Invention However, the conventional browning plate using the microwave absorber has a problem that a long remaining heating time is required before heating the food or a low heat generation temperature. On the principle of the heat generation mode, for example, the use of dielectric loss of a dielectric material such as barium titanate can be considered. Was not practical.
本発明は、かかる従来の問題を解消するもので、誘電
材料であってもマイクロ波吸収能の極めて高い実用性の
あるマイクロ波吸収体を提供することを目的とする。An object of the present invention is to solve such a conventional problem, and an object of the present invention is to provide a practical microwave absorber having a very high microwave absorbing ability even with a dielectric material.
課題を解決するための手段 上記目的を達成するために、本発明のマイクロ波吸収
体は、50以上の比誘電率と0.01以下の誘電正接を有する
高誘電率材料を分散質とする収束材と、50以下の比誘電
率と0.01以上の誘電正接を有する高誘電正接材料を分散
質とする減衰材とを積層してなるものである。Means for Solving the Problems To achieve the above object, the microwave absorber of the present invention is a convergent material having a high dielectric constant material having a relative dielectric constant of 50 or more and a dielectric tangent of 0.01 or less as a dispersoid. , And a damping material having a high dielectric loss tangent material having a relative dielectric constant of 50 or less and a dielectric loss tangent of 0.01 or more as a dispersoid.
作用 上記した構成の本発明によるマイクロ波吸収体は、高
誘電率材料を分散質とする収束材が、マイクロ波を集中
させて、高誘電正接材料を分散質とする減衰材に垂直方
向よりマイクロ波を照射する。そして、このマイクロ波
を減衰材が吸収するわけであるが、吸収し切れないマイ
クロ波は収束材の方向に進むが収束材の表面で反射され
る。こうして、マイクロ波が減衰材中で吸収されるまで
多重反射させる。そのため、減衰材が効率良くマイクロ
波を吸収する作用を有すると考えられる。The microwave absorber according to the present invention having the above-described structure has a structure in which the convergent material having a high dielectric constant material as a dispersoid concentrates microwaves, and the microwave concentrator has a microscopic structure in a direction perpendicular to the attenuating material having a high dielectric tangent material as a dispersoid. Irradiate waves. Then, the microwave is absorbed by the attenuating material, and the microwave that cannot be completely absorbed proceeds in the direction of the converging material but is reflected on the surface of the converging material. In this way, multiple reflections occur until the microwaves are absorbed in the attenuating material. Therefore, it is considered that the attenuating material has a function of efficiently absorbing the microwave.
実施例 以下、本発明の一実施例について第1図を用いて説明
する。Embodiment An embodiment of the present invention will be described below with reference to FIG.
50以上の比誘電率と0.01以下の誘電正接を有する高誘
電率材料を分散質とする収束材1は、高誘電率材料2と
してたとえばチタン酸ストロンチウム粉末(比誘電率25
5、誘電正接0.001)を、たとえばシリコーン樹脂中に40
wt%混練したものを加熱成型して2mm厚みのシート状成
型物とした。50以下の比誘電率と0.01以上の誘電正接を
有する高誘電正接材料を分散質とする減衰材3は、高誘
電正接材料4としてたとえば炭化珪素−炭化チタン固溶
体1mmチョップ(商品名“チラノ繊維",宇部興産(株)
製,比誘電率10,誘電正接1)を、たとえばシリコーン
樹脂中に40wt%混練したものを加熱成型して2mm厚みの
シート状成型物とした。そして、金属プレート5にシー
ト状の減衰材3と収束材1をこの順に各各接触させて配
置させたものを実験に供した。15は支持体である。評価
はこれを電子レンジ庫内に入れマイクロ波(μ波)を4
分間照射しその直後の温度により行った。なお、比較例
Aとして、4mm厚みのシート状成型物の減衰材3、比較
例Bとして、前記高誘電率材料2と高誘電正接材料4複
合混合物(各濃度は、収束材および減衰材の50%に調整
したもの)をシリコーン樹脂に混練したものを加熱成型
して得た4mm厚みのシート状成型物を実験に供した。The convergence material 1 having a high dielectric constant material having a relative dielectric constant of 50 or more and a dielectric loss tangent of 0.01 or less as a dispersoid is a strontium titanate powder (relative dielectric constant 25
5, dielectric loss tangent 0.001), for example, 40
The mixture kneaded by wt% was heated and formed into a sheet-like molded product having a thickness of 2 mm. The attenuating material 3 containing a high dielectric loss tangent material having a relative dielectric constant of 50 or less and a dielectric loss tangent of 0.01 or more as a dispersoid is used as a high dielectric loss tangent material 4 such as a silicon carbide-titanium carbide solid solution 1 mm chop (trade name “Tyranno fiber”). , Ube Industries, Ltd.
The mixture was kneaded with, for example, 40% by weight of silicone resin in a dielectric material having a relative dielectric constant of 10 and a dielectric loss tangent of 1). Then, a sheet-shaped attenuation material 3 and a convergence material 1 were arranged in contact with each other in this order on a metal plate 5 for an experiment. 15 is a support. For evaluation, this was placed in a microwave oven and microwaves (μ waves) were
The irradiation was carried out at a temperature immediately after irradiation for one minute. As a comparative example A, a damping material 3 of a sheet-like molded product having a thickness of 4 mm, and as a comparative example B, a composite mixture of the high dielectric constant material 2 and the high dielectric loss tangent material 4 (each concentration is 50% of the convergent material and the damping material). %) Was kneaded with a silicone resin, and a 4 mm-thick sheet-like molded product obtained by heating and molding was subjected to the experiment.
なお、高誘電率材料2としては、チタン酸ストロンチ
ウム以外に、チタン酸カリウム,チタニア,Sr−Sn酸化
物,Ba−Sm−Ti酸化物などがある。また、高誘電正接材
料4としては、実施例以外にチタン酸アルカリ(金属;L
i,Na,K),合成樹脂と導電性物質(カーボンブラック,
金属粉,導電性セラミック)との複合物などがある。In addition, as the high dielectric constant material 2, besides strontium titanate, potassium titanate, titania, Sr—Sn oxide, Ba—Sm—Ti oxide, and the like are given. As the high dielectric loss tangent material 4, other than the examples, alkali titanate (metal; L
i, Na, K), synthetic resin and conductive material (carbon black,
(Metal powder, conductive ceramic).
結果を次表に示した。 The results are shown in the following table.
この結果から明らかなように本発明の実施例によれ
ば、著しい発熱特性(マイクロ波吸収能)を有する。そ
して、この特性は、収束材1と減衰材3との積層状態に
よって生ずることがわかる。 As is clear from these results, according to the embodiment of the present invention, there is a remarkable heat generation characteristic (microwave absorption ability). It can be seen that this characteristic is caused by the state of lamination of the convergence material 1 and the attenuation material 3.
誘電材料のマイクロ波吸収能に関与する物性として、
比誘電率εと誘電正接tanδがあり、両者の積とtanδを
損失係数と呼び、これがマイクロ波を吸収して発熱する
指標となっている。当然のことながら、このことより比
誘電率と誘電正接が共に大きい材料が求められるが、こ
うした材料は水以外にはない(マイクロ波による食品加
熱はこれを利用している)。すなわち、コンデンサー材
料のように、比誘電率が非常に高く誘電正接が小さいも
のか、あるいは、昨今のセラミック系の誘電材料のよう
に、比誘電率が小さく誘電正接が大きいものしかない。
そこで、こうした材料の組合せ、すなわち、比誘電率の
高い材料と誘電正接の高い材料との組合せが考えられる
が、我々は鋭意研究の結果、そうした材料の複合物の物
性は、両者の中間、もしくはそれ以下の値となることが
多い。とくに、誘電正接の低下が大きく、実用上問題が
あることを把握した。Physical properties related to the microwave absorption capacity of dielectric materials include:
There are a relative dielectric constant ε and a dielectric loss tangent tan δ, and the product of the two and tan δ are called a loss coefficient, which is an index for absorbing microwaves to generate heat. Naturally, this requires a material having a large relative dielectric constant and a large dielectric loss tangent, but such a material is the only material other than water (the food is heated by microwaves). That is, there is only a capacitor material having a very high relative dielectric constant and a small dielectric loss tangent, such as a capacitor material, or a material having a small relative dielectric constant and a large dielectric loss tangent, such as a recent ceramic dielectric material.
Therefore, a combination of such materials, that is, a combination of a material having a high relative dielectric constant and a material having a high dielectric loss tangent can be considered, but as a result of intensive studies, the physical properties of a composite of such materials are considered to be intermediate between the two, or In many cases, the value will be lower. In particular, it was found that the dielectric loss tangent was greatly reduced, and there was a problem in practical use.
また、一般に既存の材料において、比誘電率よりも誘
電正接の方が材料間格差が大きい(比誘電率が約2桁に
対して誘電正接は4桁のオーダーに及ぶ)ので、比誘電
率が小さくても誘電正接の大きい材料を用いるが、その
場合適正な厚みがないとマイクロ波を吸収しない(一般
にはマイクロ波の波長の半分の厚みが必要と言われてい
る)。In general, in existing materials, the dielectric tangent has a larger difference between materials than the relative dielectric constant (the dielectric tangent ranges from about two digits to four orders of magnitude). Although a material having a large dielectric loss tangent is used even if it is small, it does not absorb microwaves unless it has an appropriate thickness (generally, it is said that a thickness that is half the wavelength of microwaves is necessary).
こうした背景をもとに、本発明に至ったわけである
が、なおその効果の発生理由については不明な点が多
い。高誘電率材料2からなる収束材1が、マイクロ波を
集中させて高誘電正接材料4からなる減衰材3に直角方
向よりマイクロ波を照射するとともに、減衰材3がマイ
クロ波を吸収するまで収束材1と金属プレート5の間で
多重反射させる。そのため、減衰材3が効率良くマイク
ロ波を吸収すると考えている。Based on this background, the present invention has been achieved, but there are still many unknown reasons for the effects. The convergent material 1 made of the high dielectric constant material 2 concentrates the microwave and irradiates the microwave to the attenuating material 3 made of the high dielectric loss tangent material 4 from a perpendicular direction, and converges until the attenuating material 3 absorbs the microwave. Multiple reflection occurs between the material 1 and the metal plate 5. Therefore, it is considered that the attenuation member 3 efficiently absorbs the microwave.
なお、本発明の一実施例においては、高誘電率材料2
および高誘電正接材料4をシリコーン樹脂中に分散し、
これだけを加熱成型したものを示したが、構造補強材
(たとえば、紙,フィルム,不織布,織布,合成樹脂シ
ート,セラミック成型体,発泡体)に被覆および含浸し
ても良いことは言うまでもない。また、各材料の充填量
(wt%)は発熱温度および使用形態により10〜80の間で
任意に調整して用いればよい。In one embodiment of the present invention, the high dielectric constant material 2
And a high dielectric loss tangent material 4 dispersed in a silicone resin,
Although only this is shown by heat molding, it goes without saying that a structural reinforcing material (for example, paper, film, nonwoven fabric, woven fabric, synthetic resin sheet, ceramic molding, foam) may be covered and impregnated. Further, the filling amount (wt%) of each material may be arbitrarily adjusted between 10 and 80 depending on the heat generation temperature and the use form.
このように本発明の実施例のマイクロ波吸収体によれ
ば、既存材料である高誘電材料と低誘電材料の組合せに
より、厚みが薄くかつ発熱温度を高くすることができ
る。As described above, according to the microwave absorber of the embodiment of the present invention, the thickness can be reduced and the heat generation temperature can be increased by the combination of the existing high dielectric material and low dielectric material.
発明の効果 以上の説明から明らかなように本発明のマイクロ波吸
収体によれば、50以上の比誘電率と0.01以下の誘電正接
を有する高誘電率材料を分散質とする収束材と、50以下
の非誘電率と0.01以上の誘電正接を有する高誘電正接材
料を分散質とする減衰材とを積層したことにより、誘電
材料であっても、かつ既存材料の組合せによりマイクロ
波吸収能の高い実用的なマイクロ波吸収体を提供でき
る。Effects of the Invention As apparent from the above description, according to the microwave absorber of the present invention, a convergent material having a high dielectric constant material having a relative dielectric constant of 50 or more and a dielectric tangent of 0.01 or less as a dispersoid, By laminating an attenuating material with a high dielectric loss tangent material having a non-dielectric constant of less than 0.01 and a dielectric loss tangent of 0.01 or more, even if it is a dielectric material, and a combination of existing materials, the microwave absorption capacity is high. A practical microwave absorber can be provided.
第1図は本発明のマイクロ波吸収体の一実施例を応用し
た焦げ目付皿の断面図、第2図は従来のマイクロ波吸収
体を応用した焦げ目付皿の断面図である。 1……収束材、2……高誘電率材料、3……減衰材、4
……高誘電正接材料。FIG. 1 is a sectional view of a browning plate to which one embodiment of the microwave absorber of the present invention is applied, and FIG. 2 is a sectional view of a browning plate to which a conventional microwave absorber is applied. 1 ... converging material, 2 ... high dielectric constant material, 3 ... attenuating material, 4
…… High dielectric loss tangent material.
Claims (2)
有する高誘電率材料を分散質とする収束材と、50以下の
比誘電率と0.01以上の誘電正接を有する高誘電正接材料
を分散質とする減衰材とを積層してなるマイクロ波吸収
体。1. A convergent material comprising a high dielectric constant material having a relative dielectric constant of 50 or more and a dielectric tangent of 0.01 or less as a dispersoid, and a high dielectric tangent material having a relative dielectric constant of 50 or less and a dielectric tangent of 0.01 or more. A microwave absorber obtained by laminating an attenuating material having a dispersoid.
高誘電正接材料が炭化珪素−炭化チタン固溶体である請
求項(1)記載のマイクロ波吸収体。2. The high dielectric constant material is strontium titanate;
The microwave absorber according to claim 1, wherein the high dielectric loss tangent material is a silicon carbide-titanium carbide solid solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26766790A JP2906284B2 (en) | 1990-10-04 | 1990-10-04 | Microwave absorber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26766790A JP2906284B2 (en) | 1990-10-04 | 1990-10-04 | Microwave absorber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04144198A JPH04144198A (en) | 1992-05-18 |
| JP2906284B2 true JP2906284B2 (en) | 1999-06-14 |
Family
ID=17447861
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26766790A Expired - Fee Related JP2906284B2 (en) | 1990-10-04 | 1990-10-04 | Microwave absorber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2906284B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6282011B2 (en) * | 2014-07-03 | 2018-02-21 | Tdk株式会社 | Dielectric antenna |
-
1990
- 1990-10-04 JP JP26766790A patent/JP2906284B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04144198A (en) | 1992-05-18 |
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