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JP2926878B2 - Hollow plastic - Google Patents
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JP2926878B2 - Hollow plastic - Google Patents

Hollow plastic

Info

Publication number
JP2926878B2
JP2926878B2 JP11476790A JP11476790A JP2926878B2 JP 2926878 B2 JP2926878 B2 JP 2926878B2 JP 11476790 A JP11476790 A JP 11476790A JP 11476790 A JP11476790 A JP 11476790A JP 2926878 B2 JP2926878 B2 JP 2926878B2
Authority
JP
Japan
Prior art keywords
particles
parent
capsule
child
particle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP11476790A
Other languages
Japanese (ja)
Other versions
JPH0411641A (en
Inventor
洋祐 田中
峻徳 納谷
明 辻村
信雄 八木
隆司 日野
尚孝 山本
英孝 柴田
明 伊吹
睦男 西本
徳郎 山下
昌幸 宗村
栄一 中川
正 上村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Isuzu Motors Ltd
Original Assignee
Isuzu Motors Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Isuzu Motors Ltd filed Critical Isuzu Motors Ltd
Priority to JP11476790A priority Critical patent/JP2926878B2/en
Publication of JPH0411641A publication Critical patent/JPH0411641A/en
Application granted granted Critical
Publication of JP2926878B2 publication Critical patent/JP2926878B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

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  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、内部に多数の緻密な中空部を形成できる中
空プラスチックに関するものである。
Description: TECHNICAL FIELD The present invention relates to a hollow plastic in which a number of dense hollow portions can be formed.

[従来の技術] 従来、中空プラスチックの例として、発泡プラスチッ
クがある。この発泡プラスチックは、液体状のプラスチ
ックに、例えば水を混合させ、それを冷却して中空の状
態を作っている。また樹脂に発泡剤を混入し、これを金
型内等で、加熱して発泡剤を発泡させて成形している。
[Prior Art] Conventionally, there is a foamed plastic as an example of a hollow plastic. In this foamed plastic, for example, water is mixed with a liquid plastic and cooled to form a hollow state. In addition, a foaming agent is mixed into the resin, and the resin is heated in a mold or the like to foam the foaming agent to form the resin.

[発明が解決しようとする課題] しかしながら、発泡プラスチックは中空といっても中
空部の穴の大きさはかなり大きくしかも不均一で、かつ
剛性も低いなど、断熱材以外に材料としての利用範囲が
かなり狭く、例えば自動車のボディ,外板等には利用で
きない問題がある。
[Problems to be Solved by the Invention] However, even if foamed plastic is hollow, the size of holes in the hollow portion is considerably large and uneven, and rigidity is low. There is a problem that it is very narrow and cannot be used, for example, for a car body or an outer panel.

本発明は上記事情を考慮してなされたもので、剛性が
あり種々の用途に使用できる発泡プラスチックを提供す
ることを目的とする。
The present invention has been made in view of the above circumstances, and has as its object to provide a foamed plastic which is rigid and can be used for various applications.

[課題を解決するための手段] 本発明は、上記の目的を達成するために、融点の相違
する樹脂で親粒子と子粒子を形成し、その親粒子に子粒
子を付着接合させてカプセル粉粒体を形成し、このカプ
セル粉粒体を集合させると共に低融点樹脂のみを溶融さ
せたものである。
[Means for Solving the Problems] In order to achieve the above object, the present invention provides a method for forming capsule particles by forming parent particles and child particles with resins having different melting points, and bonding the child particles to the parent particles. Granules are formed, the capsule powders are aggregated, and only the low melting point resin is melted.

[作用] 上記の構成によれば、融点の相違する樹脂で、カプセ
ル粉粒体を形成し、このカプセル粉粒体中の低融点側樹
脂を溶融させることで、カプセル粉粒体間に緻密で均一
な中空部を形成でき、これにより軽量化ができ、中空部
がクッションとなって線膨張率の高いものに対して変形
が少なくてすみ、また防音,防圧,防熱,吸水,撥水等
の効果があり種々の用途に使用できる。
[Operation] According to the above configuration, the capsule powder is formed of resin having different melting points, and the resin having a low melting point in the capsule powder is melted. A uniform hollow portion can be formed, thereby reducing the weight. The hollow portion serves as a cushion, so that there is little deformation with respect to a material having a high linear expansion coefficient, and also soundproof, pressure-proof, heat-proof, water absorption, water repellency, etc. It can be used for various applications.

[実施例] 以下、本発明の好適実施例を添付図面に基づいて説明
する。
Hereinafter, preferred embodiments of the present invention will be described with reference to the accompanying drawings.

第1図は、本発明の中空プラスチックを成形するカプ
セル粉粒体10の拡大断面図を示す。
FIG. 1 is an enlarged sectional view of a capsule powder 10 for molding the hollow plastic of the present invention.

先ずカプセル粉粒体10は、例えば粒径100μ以下の親
粒子11の表面に、例えば粒径10μ以下の多数の子粒子12
を付着固定して形成される。このカプセル粉粒体10の形
成は、親粒子11に子粒子12を静電付着させたままの状
態、或いはこれを特開昭62−250942号公報に開示される
ような高速気流中衝撃法や機械的衝撃法等でより確実に
固定化する。
First, the capsule powder 10 is formed, for example, on a surface of a parent particle 11 having a particle diameter of 100 μ or less, for example, a large number of child particles 12 having a particle diameter of 10 μ or less.
Is formed by adhering and fixing. The formation of the capsule particles 10 can be carried out in a state in which the child particles 12 are electrostatically attached to the parent particles 11 or by a high-speed air impact method as disclosed in Japanese Patent Application Laid-Open No. 62-250942. Fix more securely by mechanical shock method.

この親粒子11と子粒子12とは融点の相違する樹脂で形
成し、いづれか一方を低融点樹脂とし、他方を高融点樹
脂で形成する。低融点樹脂としては、例えばポリプロピ
レンPE(融点100℃),ポリプロピレンPP(150℃)など
からなり、高融点樹脂としては、ポリエーテルエーテル
ケトンPEEK(融点300℃),ナイロンPA(200℃)などか
らなる。
The parent particles 11 and the child particles 12 are formed of resins having different melting points, and one of them is formed of a low melting resin and the other is formed of a high melting resin. Examples of the low melting point resin include polypropylene PE (melting point 100 ° C) and polypropylene PP (150 ° C). Examples of the high melting point resin include polyetheretherketone PEEK (melting point 300 ° C) and nylon PA (200 ° C). Become.

今、親粒子11を低融点樹脂で形成し、子粒子12を高融
点樹脂で形成してカプセル粉粒体10を形成し、このカプ
セル粉粒体10を第2図に示すように集合した状態で、低
融点樹脂である親粒子11が溶融する温度に加熱して成形
する。親粒子11が溶融すると、その親粒子11は子粒子12
から食み出して隣接する親粒子11同士と一体化し、同時
に第3図に示すようにカプセル粉粒体10間の中空部13
が、そのまま残った緻密な中空プラスチック14が成形さ
れる。中空部13はカプセル粉粒体10より小さく、また親
粒子11と子粒子12の粒径を選ぶことで、中空部13の大き
さを調整できる。
Now, the parent particles 11 are formed of a low-melting-point resin, and the child particles 12 are formed of a high-melting-point resin to form a capsule granular material 10. The capsule granular material 10 is assembled as shown in FIG. Then, the mixture is heated to a temperature at which the parent particles 11 as the low-melting point resin are melted and molded. When the parent particle 11 melts, the parent particle 11 becomes a child particle 12
And is integrated with the adjacent parent particles 11 and, at the same time, as shown in FIG.
However, the dense hollow plastic 14 left as it is is molded. The hollow portion 13 is smaller than the capsule granule 10, and the size of the hollow portion 13 can be adjusted by selecting the particle size of the parent particle 11 and the child particle 12.

また上述の実施例では親粒子11を低融点樹脂で形成し
たが、子粒子12を低融点樹脂で形成してカプンセル粉粒
体10を形成してもよい。
In the above-described embodiment, the parent particles 11 are formed of a low-melting resin. However, the child particles 12 may be formed of a low-melting resin to form the capsule particles 10.

第4〜6図は、本発明の他の実施例を示したものであ
る。
4 to 6 show another embodiment of the present invention.

本例においては、親粒子11を低融点樹脂で形成し、子
粒子12を高融点樹脂で形成すると共にその子粒子12の表
面に、第4図(a)に示すよう微小な鉄粉15を付けた状
態で第4図(b)に示すように親粒子11に子粒子12を付
着してカプセル粉粒体16とし、このカプセル粉粒体16
を、第5図に示すように形枠(図示せず)などに入れて
集合させ、高周波などにて鉄粉15の温度を上げ、鉄粉15
の周りの子粒子12を溶融させて子粒子12同士を溶着さ
せ、その後、子粒子12を溶融温度以下で親粒子11の溶融
温度以上にして、親粒子11を溶融させると共に吸引など
にて溶融親粒子11を除去することで、第6図に示すよう
に親粒子11が除去された中空部17とカプセル粉粒体16間
の中空部13からなるポーラスな中空プラスチック成形体
18とすることができる。
In this example, the parent particles 11 are formed of a low-melting-point resin, the child particles 12 are formed of a high-melting-point resin, and fine iron powder 15 is attached to the surface of the child particles 12 as shown in FIG. In this state, the child particles 12 are adhered to the parent particles 11 as shown in FIG.
Are put in a form (not shown) or the like as shown in FIG. 5 and assembled.
The child particles 12 around are melted and the child particles 12 are welded to each other.After that, the child particles 12 are melted at a temperature lower than the melting temperature and higher than the melting temperature of the parent particles 11, and the parent particles 11 are melted and melted by suction or the like. By removing the parent particles 11, as shown in FIG. 6, a porous hollow plastic molded body comprising a hollow portion 17 from which the parent particles 11 have been removed and a hollow portion 13 between the capsule powder granules 16
It can be 18.

[発明の効果] 以上説明したことから明らかなように本発明によれば
次のごとき優れた効果を発揮する。
[Effects of the Invention] As is clear from the above description, according to the present invention, the following excellent effects are exhibited.

(1)融点の相違する樹脂で、カプセル粉粒体を形成
し、このカプセル粉粒体中の低融点側樹脂を溶融させる
ことで、カプセル粉粒体間に均一な中空部を形成でき、
これにより軽量化ができ、中空部がクッションとなって
線膨張率の高いものに対して変形が少なくてすむ。
(1) Capsule particles are formed from resins having different melting points, and a low melting point resin in the capsule particles is melted to form a uniform hollow portion between the capsule particles.
As a result, the weight can be reduced, and the hollow portion serves as a cushion, so that less deformation is required for a material having a high linear expansion coefficient.

(2)防音,防圧,防熱,吸水,撥水等の効果があり種
々の用途に使用できる。
(2) It has effects such as soundproofing, pressure-proofing, heat-proofing, water absorption and water repellency, and can be used for various applications.

【図面の簡単な説明】[Brief description of the drawings]

第1図は本発明の一実施例を示す拡大断面図、第2図は
第1図のカプセル粉粒体を用いて成形する際の状態を示
す拡大断面図、第3図はその成形後の成形体の拡大断面
図、第4図は本発明の他の実施例を示す拡大断面図、第
5図は第4図のカプセル粉粒体を用いて成形する際の状
態を示す拡大断面図、第6図はその成形後の成形体の拡
大断面図である。 図中、10はカプセル粉粒体、11は親粒子、12は子粒子、
13は中空部である。
FIG. 1 is an enlarged sectional view showing one embodiment of the present invention, FIG. 2 is an enlarged sectional view showing a state of molding using the capsule powder of FIG. 1, and FIG. FIG. 4 is an enlarged cross-sectional view of a molded body, FIG. 4 is an enlarged cross-sectional view showing another embodiment of the present invention, FIG. 5 is an enlarged cross-sectional view showing a state at the time of molding using the capsule granular material of FIG. FIG. 6 is an enlarged sectional view of the molded body after the molding. In the figure, 10 is a capsule powder, 11 is a parent particle, 12 is a child particle,
13 is a hollow part.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 八木 信雄 神奈川県藤沢市土棚8番地 株式会社い すゞ中央研究所内 (72)発明者 日野 隆司 神奈川県藤沢市土棚8番地 いすゞ自動 車株式会社藤沢工場内 (72)発明者 山本 尚孝 神奈川県藤沢市土棚8番地 株式会社い すゞ中央研究所内 (72)発明者 柴田 英孝 神奈川県藤沢市土棚8番地 株式会社い すゞ中央研究所内 (72)発明者 伊吹 明 神奈川県川崎市川崎区殿町3丁目25番1 号 いすゞ自動車株式会社川崎工場内 (72)発明者 西本 睦男 神奈川県藤沢市土棚8番地 いすゞ自動 車株式会社藤沢工場内 (72)発明者 山下 徳郎 神奈川県藤沢市土棚8番地 株式会社い すゞ中央研究所内 (72)発明者 宗村 昌幸 神奈川県藤沢市土棚8番地 株式会社い すゞ中央研究所内 (72)発明者 中川 栄一 神奈川県藤沢市土棚8番地 株式会社い すゞ中央研究所内 (72)発明者 上村 正 神奈川県藤沢市土棚8番地 株式会社い すゞ中央研究所内 (56)参考文献 特開 昭60−8332(JP,A) 特開 昭50−98973(JP,A) 特開 昭48−25064(JP,A) (58)調査した分野(Int.Cl.6,DB名) C08J 9/24 - 9/26 C08J 3/12 B29C 67/20 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Nobuo Yagi, No. 8 clay bowl, Fujisawa, Kanagawa Prefecture Isuzu Central Research Institute Co., Ltd. (72) Takashi Hino, No. 8 clay bowl, Fujisawa City, Kanagawa Prefecture Isuzu Motors Limited Fujisawa In the factory (72) Inventor Naotaka Yamamoto 8 Dosana, Fujisawa-shi, Kanagawa Pref.Isuzu Central Research Institute Co., Ltd. (72) Inventor Hidetaka Shibata 8 Dosana, Fujisawa-shi, Kanagawa Pref. Isuzu Central Research Co., Ltd. (72) Invention Person Akira Ibuki 3-25-1, Tonomachi, Kawasaki-ku, Kawasaki-shi, Kanagawa Prefecture Isuzu Motor Co., Ltd. Kawasaki Plant (72) Inventor Mutsumi Nishimoto 8 Tsuzuna, Fujisawa City, Kanagawa Prefecture Isuzu Motors Fujisawa Plant (72) Invention Tokuo Yamashita 8 Tsuchin, Fujisawa-shi, Kanagawa Prefecture Isuzu Central Research Institute Co., Ltd. (72) Inventor Masayuki Munemura God 8 Isuzu Central Research Institute, Fujisawa-shi, Kawasaki, Japan (72) Inventor Eiichi Nakagawa 8 Edoshana Fujisawa-shi, Kanagawa Prefecture, Japan Inside Isuzu Central Research Institute, Inc. (72) Inventor Tadashi Uemura, Tsuchiya, Fujisawa-shi, Kanagawa No. 8 Inside Isuzu Central Research Laboratory Co., Ltd. (56) References JP-A-60-8332 (JP, A) JP-A-50-98973 (JP, A) JP-A-48-25064 (JP, A) (58) Field surveyed (Int.Cl. 6 , DB name) C08J 9/24-9/26 C08J 3/12 B29C 67/20

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】融点の相違する樹脂で親粒子と子粒子を形
成し、その親粒子に子粒子を付着接合させてカプセル粉
粒体を形成し、このカプセル粉粒体を集合させると共に
低融点側樹脂を溶融させて成形したことを特徴とする中
空プラスチック。
A parent particle and a child particle are formed of resins having different melting points, and the child particle is adhered and bonded to the parent particle to form a capsule powder. A hollow plastic obtained by melting and molding a side resin.
JP11476790A 1990-04-27 1990-04-27 Hollow plastic Expired - Fee Related JP2926878B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11476790A JP2926878B2 (en) 1990-04-27 1990-04-27 Hollow plastic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11476790A JP2926878B2 (en) 1990-04-27 1990-04-27 Hollow plastic

Publications (2)

Publication Number Publication Date
JPH0411641A JPH0411641A (en) 1992-01-16
JP2926878B2 true JP2926878B2 (en) 1999-07-28

Family

ID=14646180

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11476790A Expired - Fee Related JP2926878B2 (en) 1990-04-27 1990-04-27 Hollow plastic

Country Status (1)

Country Link
JP (1) JP2926878B2 (en)

Also Published As

Publication number Publication date
JPH0411641A (en) 1992-01-16

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