JP2961696B2 - Stainless steel surface treated steel sheet for building materials - Google Patents
Stainless steel surface treated steel sheet for building materialsInfo
- Publication number
- JP2961696B2 JP2961696B2 JP16355590A JP16355590A JP2961696B2 JP 2961696 B2 JP2961696 B2 JP 2961696B2 JP 16355590 A JP16355590 A JP 16355590A JP 16355590 A JP16355590 A JP 16355590A JP 2961696 B2 JP2961696 B2 JP 2961696B2
- Authority
- JP
- Japan
- Prior art keywords
- stainless steel
- coating
- building materials
- steel sheet
- surface treated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001220 stainless steel Inorganic materials 0.000 title claims description 21
- 239000010935 stainless steel Substances 0.000 title claims description 21
- 239000004566 building material Substances 0.000 title claims description 10
- 229910000831 Steel Inorganic materials 0.000 title claims description 9
- 239000010959 steel Substances 0.000 title claims description 9
- 238000000576 coating method Methods 0.000 claims description 20
- 239000011248 coating agent Substances 0.000 claims description 17
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 5
- 229910052752 metalloid Inorganic materials 0.000 claims description 3
- 150000002738 metalloids Chemical class 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 description 8
- 230000007797 corrosion Effects 0.000 description 8
- 238000005524 ceramic coating Methods 0.000 description 6
- 238000007733 ion plating Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910010037 TiAlN Inorganic materials 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 208000012927 adermatoglyphia Diseases 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Physical Vapour Deposition (AREA)
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は耐食性および耐指紋性に優れる建材用ステン
レス表面処理鋼板に関する。Description: TECHNICAL FIELD The present invention relates to a stainless steel surface-treated steel sheet for building materials having excellent corrosion resistance and fingerprint resistance.
（従来の技術） ステンレス鋼板は優れた耐食性およびステンレス鋼板
独特の肌、色調を生かして、ビル内外装、エレベータ内
壁、手摺等の建材用途に幅広く使用されている。(Prior Art) Stainless steel sheets are widely used for building materials such as interior and exterior of buildings, elevator inner walls, handrails, etc., utilizing their excellent corrosion resistance and the unique skin and color tone of stainless steel sheets.
建材用ステンレス鋼板の表面処理方法として従来行わ
れている方法は鏡面仕上げ、ヘアライン仕上げ等の機械
研磨仕上げおよび化学エッチング仕上げである。Conventional methods for surface treatment of stainless steel sheets for building materials include mechanical polishing, such as mirror finishing, hairline finishing, and chemical etching.
一方、近年のファッショナブル化の動きにともない、
建材用ステンレス鋼板にも意匠性が求められるようにな
り、化学発色ステンレス鋼板あるいは塗装ステンレス鋼
板が開発され、市販されている。On the other hand, with the recent trend of fashionability,
Designability is also required for stainless steel sheets for building materials, and chemically colored stainless steel sheets or painted stainless steel sheets have been developed and marketed.
しかし、化学発色ステンレス鋼板は化学的活性度の不
均一性に起因する色ムラが発生しやすい、あるいは不働
態被膜が薄いので耐摩耗性が悪くブラシ等の摩擦で容易
に退色するといった欠点を有している。また、塗装ステ
ンレス鋼板は塗膜厚みが20μｍ程度と厚いため、鏡面仕
上げ、ヘアライン仕上げ等の表面肌が失われる欠点を有
している。However, chemically colored stainless steel sheets have the disadvantage that color unevenness is likely to occur due to non-uniformity of the chemical activity, or the passive film is thin and has poor abrasion resistance and is easily discolored by friction with a brush or the like. doing. Further, since the coated stainless steel plate has a coating film thickness as large as about 20 μm, it has a drawback that the surface skin such as mirror finish and hairline finish is lost.
これら化学発色ステンレス鋼板および塗装ステンレス
鋼板の欠点を鑑みて、最近スパッタリング、イオンプレ
ーティング、プラズマCVD等のプラズマコーティングに
よりステンレス鋼板の表面にセラミックス被膜を形成
し、意匠性を高めようとする試みが盛んに行われてい
る。In view of the drawbacks of these chemically colored stainless steel sheets and painted stainless steel sheets, recent attempts have been made to enhance the design by forming a ceramic film on the stainless steel sheet surface by plasma coating such as sputtering, ion plating, or plasma CVD. It has been done.
セラミックス膜は例えば、TiNは金色、TiAlNはブロン
ズ色といったように生成物質に基づく一定の色を呈する
ため、化学発色ステンレス鋼板のような色ムラは生じに
くく、かつ膜硬度はHv2000と非常に硬いため耐摩耗性は
良好である。また、膜厚は0.2μｍ〜５μｍと比較的薄
いため被膜後も鏡面仕上げ、ヘアライン仕上げ等の表面
肌は変化しない。Ceramic films, for example, have a constant color based on the generated material, such as gold for TiN and bronze for TiAlN. The wear resistance is good. Further, since the film thickness is relatively thin, 0.2 μm to 5 μm, the surface skin such as mirror finish or hairline finish does not change even after coating.
（発明が解決しようとする問題点） しかし、プラズマコーティングによりセラミックスの
被膜を形成した建材用ステンレス表面処理鋼板はセラミ
ックス被膜中にピンホールの存在が避けられず、腐食環
境中にさらされると該ピンホール部からステンレス鋼板
の腐食が進行する。(Problems to be Solved by the Invention) However, in a stainless steel surface-treated steel sheet for building materials in which a ceramic coating is formed by plasma coating, the presence of pinholes in the ceramic coating is inevitable, and when exposed to a corrosive environment, the presence of the pinholes increases. Corrosion of the stainless steel plate proceeds from the hole.
このような不都合を解消すべく種々の検討がなされ、
例えば特開平１−172557にはセラミックス被膜のピンホ
ール部にクロムおよびクロム酸化物の複合物を埋設する
ことによる耐食性向上策が開示されている。Various studies have been made to resolve such inconveniences.
For example, Japanese Patent Application Laid-Open No. 1-172557 discloses a measure for improving corrosion resistance by embedding a composite of chromium and chromium oxide in a pinhole portion of a ceramic film.
しかし、上記方法は塩水噴霧試験のように試験片表面
がたえず塩水によって洗われているような環境において
は良好な耐食性を示すが金属粉等の塵埃が存在する実環
境では、塵埃からのもらい錆から腐食が進行する欠点を
有している。However, the above method shows good corrosion resistance in an environment where the surface of the test piece is constantly washed with salt water as in the salt spray test, but in an actual environment where dust such as metal powder is present, rust from the dust can be obtained. Has the disadvantage that corrosion proceeds.
また、プラズマコーティングによりセラミックス被膜
を形成した建材用ステンレス表面処理鋼板は非常に色が
鮮やかであるため、エレベータ内壁等意匠性が要求され
る部材に適しているが、色が鮮やかなだけに指紋が付着
すると、目だちやすいという欠点を有している。In addition, stainless steel surface treated steel sheets for building materials with ceramic coating formed by plasma coating are very vivid in color, so they are suitable for members requiring design properties such as elevator inner walls. There is a drawback that when adhered, it is easy to see.
（発明の構成） 上記問題点を解決するための手段として、本発明は、
ステンレス鋼板の表面上に被膜が構成されていて、第１
層がプラズマコーティングにより形成された金属、半金
属被膜であり、第２層がプラズマコーティングにより形
成された有色不透明のセラミックス被膜であり、第３層
がクリアー樹脂被膜であることを特徴とする建材用ステ
ンレス表面処理鋼板を提供する。(Constitution of the Invention) As means for solving the above problems, the present invention provides:
A coating is formed on the surface of a stainless steel plate,
A building material characterized in that the layer is a metal or metalloid film formed by plasma coating, the second layer is a colored and opaque ceramic film formed by plasma coating, and the third layer is a clear resin film. Provide stainless steel surface treated steel sheet.
プラズマコーティングとしてはスパッタリング、イオ
ンプレーティング、プラズマCVDのいずれも適用でき
る。As the plasma coating, any of sputtering, ion plating, and plasma CVD can be applied.
金属、半金属被膜としてはTi、Al、Zr、Hf、Ｖ、Nb、
Ta、Cr、Mo、Ｗ、Mn、Co、Ni、ＢおよびSiの１種もしく
は２種以上が適用でき、セラミックス被膜としては上記
金属、半金属の１種もしくは２種以上の窒化物、炭化
物、炭窒化物または酸化物が適用できる。Ti, Al, Zr, Hf, V, Nb,
One or more of Ta, Cr, Mo, W, Mn, Co, Ni, B and Si can be applied. As the ceramic coating, one or more of the above metals, metalloids, nitrides, carbides, Carbonitrides or oxides can be applied.
クリアー樹脂としては、アクリル樹脂、ポリエステル
樹脂、シリコーン樹脂、フッ素樹脂等が適用できる。塗
布方法としては刷毛法、エアスプレー法、ローラーコー
ト法等が適用できる。As the clear resin, an acrylic resin, a polyester resin, a silicone resin, a fluororesin, or the like can be used. As a coating method, a brush method, an air spray method, a roller coating method, or the like can be applied.
（発明の具体的開示） 実施例１ 板厚1mmのSUS304鋼板（ヘアライン仕上げ）をアルカ
リ系洗浄液中で１分陽極電解処理したのち、スパッタリ
ング（マグネトロンスパッタリング）によりTiNおよびT
iAlNを0.3μｍ被膜した。なお、No.5、６、８の金属被
膜の厚みは0.08μｍとした。(Specific Disclosure of the Invention) Example 1 A 1 mm thick SUS304 steel plate (hairline finish) is subjected to anodic electrolysis treatment in an alkaline cleaning solution for 1 minute, and then TiN and T are sputtered (magnetron sputtering).
iAlN was coated in a thickness of 0.3 μm. The thickness of the metal coatings of Nos. 5, 6, and 8 was 0.08 μm.
一部のサンプルはアクリル、ポリエステル、シリコー
ンおよびフッ素樹脂をバーコーターで20μｍ塗布した。Some of the samples were coated with acrylic, polyester, silicone and fluororesin at 20 μm using a bar coater.
その後、海岸に近い工業地帯に１年暴露を行い耐食性
を調査した。After that, they were exposed to the industrial zone near the coast for one year to investigate the corrosion resistance.
結果を表１に示す。セラミックス被覆のままのサンプ
ルには、点錆の発生が認められるが本発明例では発錆は
認められない。Table 1 shows the results. In the sample with the ceramic coating as it is, spot rust is observed, but no rust is observed in the present invention.
実施例２ 板厚0.7mmのSUS304鋼板（鏡面仕上げ）をアルカリ系
洗浄液中で５分超音波洗浄したのち、イオンプレーティ
ング（RFイオンプレーティング）により、TiN、AlNおよ
びSiO2を１μｍ被覆した。なおNo.2、４、５、７の金
属、半金属被覆厚みは0.5μｍとした。 After washing 5 minutes ultrasound SUS304 steel plate (mirror finish) in alkaline in the wash liquor of Example 2 thickness of 0.7 mm, by ion plating (coating RF ion plating), TiN, the AlN and SiO 2 were 1μm coated. The thicknesses of the metal and semimetal coatings of Nos. 2, 4, 5, and 7 were 0.5 μm.
一部のサンプルはアクリル、ポリエステル、シリコー
ンおよびフッ素樹脂をエアースプレーで30μｍ塗布し
た。Some samples were coated with acrylic, polyester, silicone and fluororesin by air spray at 30 μm.
その後、人工指紋液をゴム栓に付着させ、1kg/m2の圧
力で押し付けたときの指紋の付着の有無を調査した。Thereafter, an artificial fingerprint solution was attached to a rubber stopper, and the presence or absence of fingerprint attachment when pressed at a pressure of 1 kg / m 2 was investigated.
結果を表２に示す。セラミックス被覆ままのサンプル
では指紋の50％以上が付着しているが、本発明例では、
指紋の付着は認められない。Table 2 shows the results. More than 50% of the fingerprints are attached to the sample without ceramic coating, but in the present invention,
No fingerprints are observed.
（効 果） 以上のごとく、本発明によると耐食性および耐指紋性
に優れる建材用ステンレス表面処理鋼板の提供が可能と
なる。 (Effects) As described above, according to the present invention, it is possible to provide a stainless steel surface-treated steel sheet for building materials having excellent corrosion resistance and fingerprint resistance.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平２−50997（ＪＰ，Ａ) 特開 平２−133565（ＪＰ，Ａ) 特開 平２−38558（ＪＰ，Ａ) (58)調査した分野(Int.Cl.6，ＤＢ名) C23C 14/00 - 14/58 B32B 1/00 - 35/00 E04C 2/00 - 2/54 ────────────────────────────────────────────────── ─── Continuation of the front page (56) References JP-A-2-50997 (JP, A) JP-A-2-133565 (JP, A) JP-A-2-38558 (JP, A) (58) Field (Int.Cl. 6 , DB name) C23C 14/00-14/58 B32B 1/00-35/00 E04C 2/00-2/54
Claims (1)
ていて、第１層がプラズマコーティングにより形成され
た金属、半金属被膜であり、第２層がプラズマコーティ
ングにより形成された有色不透明のセラミックス被膜で
あり、第３層がクリアー樹脂被膜であることを特徴とす
る建材用ステンレス表面処理鋼板。1. A colored opaque ceramic, wherein a coating is formed on a surface of a stainless steel plate, a first layer is a metal or metalloid coating formed by plasma coating, and a second layer is formed by plasma coating. A stainless steel surface-treated steel sheet for building materials, wherein the coating is a coating and the third layer is a clear resin coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16355590A JP2961696B2 (en) | 1990-06-21 | 1990-06-21 | Stainless steel surface treated steel sheet for building materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16355590A JP2961696B2 (en) | 1990-06-21 | 1990-06-21 | Stainless steel surface treated steel sheet for building materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0452268A JPH0452268A (en) | 1992-02-20 |
| JP2961696B2 true JP2961696B2 (en) | 1999-10-12 |
Family
ID=15776127
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16355590A Expired - Lifetime JP2961696B2 (en) | 1990-06-21 | 1990-06-21 | Stainless steel surface treated steel sheet for building materials |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2961696B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8268067B2 (en) | 2009-10-06 | 2012-09-18 | 3M Innovative Properties Company | Perfluoropolyether coating composition for hard surfaces |
-
1990
- 1990-06-21 JP JP16355590A patent/JP2961696B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0452268A (en) | 1992-02-20 |
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