JP3023493B2 - Casting joining method - Google Patents
Casting joining methodInfo
- Publication number
- JP3023493B2 JP3023493B2 JP4093940A JP9394092A JP3023493B2 JP 3023493 B2 JP3023493 B2 JP 3023493B2 JP 4093940 A JP4093940 A JP 4093940A JP 9394092 A JP9394092 A JP 9394092A JP 3023493 B2 JP3023493 B2 JP 3023493B2
- Authority
- JP
- Japan
- Prior art keywords
- self
- fluxing alloy
- metal member
- joining
- sintered
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims description 10
- 238000005266 casting Methods 0.000 title description 13
- 239000002184 metal Substances 0.000 claims description 28
- 229910052751 metal Inorganic materials 0.000 claims description 28
- 229910045601 alloy Inorganic materials 0.000 claims description 21
- 239000000956 alloy Substances 0.000 claims description 21
- 239000000843 powder Substances 0.000 claims description 15
- 239000011230 binding agent Substances 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 239000012298 atmosphere Substances 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000002093 peripheral effect Effects 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910001141 Ductile iron Inorganic materials 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 102200082816 rs34868397 Human genes 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Pressure Welding/Diffusion-Bonding (AREA)
- Coating By Spraying Or Casting (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は、鋳込み接合法の改良に
関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an improved casting method.
【0002】[0002]
【従来の技術】従来の鋳込み接合法として、特開昭63
−183771号公報に示すようなものがあり、このも
のは、接合しようとする金属の接合面に、自溶合金溶射
を施し、その金属を所定形状の鋳型に装着した後に金属
の溶湯を注ぎ、その際の溶湯熱を利用して溶射皮膜を溶
融、拡散させることにより、双方の金属を接合させる方
法である。2. Description of the Related Art A conventional casting method is disclosed in
There is a thing as shown in Japanese Patent No. -183771, which is subjected to self-fluxing alloy spraying on a joint surface of a metal to be joined, and after pouring the molten metal into a mold having a predetermined shape, In this method, both metals are joined by melting and diffusing the thermal spray coating using the heat of the molten metal at that time.
【0003】[0003]
【発明が解決しようとする課題】従来の鋳込み接合方法
は、金属の接合面に、自溶合金溶射を施すため隙間を有
する金属部材や複雑形状の金属部材の場合、均一な溶射
皮膜を形成させることが困難であると共に、溶射皮膜の
金属部材への密着性も不十分であり、金属部材と金属溶
湯との接合に際して高い接合強度が得られないという問
題点がある。そこで、本発明はかかる問題点を解消する
ためになされたもので、金属部材の形状に拘わらず、金
属部材と金属溶湯との接合に際して高い接合強度が得ら
れる鋳込み接合法を提供するものである。In the conventional casting method, in the case of a metal member having a gap or a metal member having a complicated shape, a uniform thermal spray coating is formed on a metal bonding surface by applying a self-fluxing alloy spray. This is difficult, and the adhesion of the thermal spray coating to the metal member is also insufficient, so that there is a problem that high joining strength cannot be obtained when joining the metal member and the molten metal. Therefore, the present invention has been made in order to solve such a problem, and it is an object of the present invention to provide a casting method in which high joining strength can be obtained when joining a metal member and a molten metal regardless of the shape of the metal member. .
【0004】[0004]
【課題を解決するための手段】本発明の鋳込み方法は、
金属部材の表面に塗布されたバインダーと該バインダー
に付着した自溶合金粉とから焼結自溶合金皮膜を形成
し、該焼結自溶合金皮膜を介して該金属部材と金属溶湯
とを接合することを特徴とする。The casting method of the present invention comprises:
A sintered self-fluxing alloy film is formed from the binder applied to the surface of the metal member and the self-fluxing alloy powder attached to the binder, and the metal member and the molten metal are joined via the sintered self-fluxing alloy film. It is characterized by doing.
【0005】(1)バインダー バインダーとしては、水、アルコール、水溶性有機化合
物を適量混合した水溶液、或いは有機化合物を適量含有
した有機溶媒溶液が用いられる。 (2)自溶合金粉 自溶合金粉としては、Ni基粉体、Cu基粉体、Co基
粉体のいずれか1種が用いられ、その粒度は100〜3
50メッシュであり、下記に望ましい成分組成を示す。
Cu基自溶合金粉は重量%でB:0.5〜5%、Si:
0.5〜10%、Cr:30%以下、Fe:0.5〜5
%、C:0.1〜2%、Ni:5〜20%、の1種又は
2種以上を含有し、残部がCuからなる粒度100〜3
50メッシュの粉体である。Ni基自溶合金粉は重量%
でB:0.5〜5%、Si:0.5〜10%、Cr:5
〜30%、Fe:0.5〜5%、C:0.1〜2%の1
種又は2種以上を含有し、残部がNiからなる粒度10
0〜350メッシュの粒体である。Co基自溶合金粉は
重量%でB:0.5〜5%、Si:0.5〜10%、C
r:5〜30%、Fe:0.5〜5%、C:0.1〜2
%の1種又は2種以上を含有し、残部がCoからなる粒
度100〜350メッシュの粒体である。 (3)焼結自溶合金皮膜 無酸化雰囲気中で焼結した厚さ50〜300μmの多孔
質又は均質な皮膜である。 (4)焼結雰囲気 焼結雰囲気としては、N2雰囲気又はAr雰囲気等の無
酸化雰囲気が用いられる。(1) Binder As the binder, an aqueous solution obtained by mixing water, alcohol and a water-soluble organic compound in an appropriate amount, or an organic solvent solution containing an appropriate amount of an organic compound is used. (2) Self-fluxing alloy powder As the self-fluxing alloy powder, any one of Ni-based powder, Cu-based powder, and Co-based powder is used.
It is 50 mesh, and the desirable component composition is shown below.
Cu-based self-fluxing alloy powder is B: 0.5 to 5% by weight, Si:
0.5 to 10%, Cr: 30% or less, Fe: 0.5 to 5
%, C: 0.1 to 2%, Ni: 5 to 20%, and a particle size of 100 to 3 in which the balance is Cu.
It is a powder of 50 mesh. Ni-based self-fluxing alloy powder is weight%
B: 0.5 to 5%, Si: 0.5 to 10%, Cr: 5
-30%, Fe: 0.5-5%, C: 0.1-2%
Particle size of 10 or more containing Ni and the balance being Ni
It is a grain of 0 to 350 mesh. Co-based self-fluxing alloy powder is B: 0.5-5%, Si: 0.5-10%, C
r: 5 to 30%, Fe: 0.5 to 5%, C: 0.1 to 2
% Or more, and the balance is Co with a particle size of 100 to 350 mesh. (3) Sintered self-fluxing alloy film This is a porous or homogeneous film having a thickness of 50 to 300 μm sintered in a non-oxidizing atmosphere. (4) Sintering atmosphere As the sintering atmosphere, a non-oxidizing atmosphere such as an N 2 atmosphere or an Ar atmosphere is used.
【0006】[0006]
【作用】表面に焼結自溶合金皮膜を形成した金属部材と
金属溶湯とを接触せしめると、該焼結自溶合金皮膜が溶
融し、該金属部材とは拡散接合し、かつ金属溶湯とは溶
融接触して高い接合力が得られる。When a metal member having a sintered self-fluxing alloy film formed on its surface is brought into contact with a molten metal, the sintered self-fluxing alloy film is melted, diffusion-bonded to the metal member, and High bonding strength is obtained by melting contact.
【0007】[0007]
【実施例】以下、本発明の実施例について説明する。図
1に示すようなS45C鋼製リング1にスチール・ショ
ットを施し、表面の酸化物等の汚れを除去し、次いで該
リング1の内周面2にバインダーとして有機化合物を適
量含有した有機溶媒溶液を塗布した後、下記表1に示す
ような自溶合金粉を内周面2に0.1〜0.2mmの厚
さに付着させる。次いで該自溶合金粉をN2雰囲気の加
熱炉で960〜1000℃の各温度で焼結させた後、大
気中で冷却させ、該リング1の内周面2に厚さ0.05
〜0.2mmの焼結自溶合金皮膜を形成する。その後、
該リング1を砂型内に配置した後、約1380℃の球状
黒鉛鋳鉄溶湯を注湯し、図2に示すようなリング1が接
合したシャフト3を得た。Embodiments of the present invention will be described below. An S45C steel ring 1 as shown in FIG. 1 is subjected to steel shot to remove stains such as oxides on the surface, and then an organic solvent solution containing an appropriate amount of an organic compound as a binder on the inner peripheral surface 2 of the ring 1. Is applied, a self-fluxing alloy powder as shown in Table 1 below is adhered to the inner peripheral surface 2 to a thickness of 0.1 to 0.2 mm. Next, the self-fluxing alloy powder is sintered at 960 to 1000 ° C. in a heating furnace in an N 2 atmosphere, and then cooled in the air.
A sintered self-fluxing alloy film of about 0.2 mm is formed. afterwards,
After disposing the ring 1 in a sand mold, molten spheroidal graphite cast iron at about 1380 ° C. was poured to obtain a shaft 3 to which the ring 1 was joined as shown in FIG.
【0008】表1に接合部の剪断荷重を併記する。Table 1 also shows the shear load at the joint.
【0009】図3は該リング1とシャフト3との接合境
界を示す顕微鏡写真(3%ナイタール腐食、倍率50
倍)であり、下記表2に示すような条件により接合され
たものである。FIG. 3 is a photomicrograph (3% nital corrosion, magnification 50) showing a joint boundary between the ring 1 and the shaft 3.
Times), and were joined under the conditions shown in Table 2 below.
【0010】本発明の接合法は鉄鋳物同士、鉄鋳物と異
種材料との接合に適しているが、非鉄鋳物同士、非鉄鋳
物と異種材料との接合にも適用可能である。[0010] The joining method of the present invention is suitable for joining iron castings and between iron castings and dissimilar materials, but is also applicable to joining non-ferrous castings and joining nonferrous castings and dissimilar materials.
【0011】[0011]
【発明の効果】本発明によれば、金属部材および金属溶
湯にあまり制約されずに良好な接合部が得られ、かつ金
属部材の形状に拘わらず、高い接合強度が得られる。
又、本鋳込み接合法は自溶合金粉の歩留りが良好であ
り、バインダーの塗布により容易に自溶合金粉の付着が
可能であるので、製造工程および製造コストが低減さ
れ、しかも無酸化雰囲気中で焼結を行うので、金属部材
の高温酸化が防止させる。According to the present invention, a good joint can be obtained without much restriction by the metal member and the molten metal, and a high joint strength can be obtained regardless of the shape of the metal member.
In addition, the present casting method has a good yield of the self-fluxing alloy powder, and the self-fluxing alloy powder can be easily adhered by applying a binder. Sintering prevents high temperature oxidation of the metal member.
【図1】金属部材を示す斜視図FIG. 1 is a perspective view showing a metal member.
【図2】鋳込み接合された部材を示す斜視図FIG. 2 is a perspective view showing members joined by casting.
【図3】鋼リングと鋳鉄鋳物との接合部の金属組織を示
す顕微鏡写真FIG. 3 is a micrograph showing a metal structure of a joint between a steel ring and a cast iron casting.
1 リング 2 内周面 3 シャフト 1 ring 2 inner peripheral surface 3 shaft
【表1】 [Table 1]
【表2】 [Table 2]
───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) B22D 19/04 B22D 19/00 ──────────────────────────────────────────────────続 き Continued on front page (58) Field surveyed (Int. Cl. 7 , DB name) B22D 19/04 B22D 19/00
Claims (1)
と該バインダーに付着した自溶合金粉とから焼結自溶合
金皮膜を形成し、該焼結自溶合金皮膜を介して該金属部
材と金属溶湯とを接合することを特徴とする鋳込み接合
法。1. A sintered self-fluxing alloy film is formed from a binder applied to the surface of a metal member and a self-fluxing alloy powder adhered to the binder, and the metal member is formed through the sintered self-fluxing alloy film. A cast joining method characterized by joining a molten metal.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4093940A JP3023493B2 (en) | 1992-02-28 | 1992-02-28 | Casting joining method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4093940A JP3023493B2 (en) | 1992-02-28 | 1992-02-28 | Casting joining method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05237631A JPH05237631A (en) | 1993-09-17 |
| JP3023493B2 true JP3023493B2 (en) | 2000-03-21 |
Family
ID=14096435
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4093940A Expired - Fee Related JP3023493B2 (en) | 1992-02-28 | 1992-02-28 | Casting joining method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3023493B2 (en) |
-
1992
- 1992-02-28 JP JP4093940A patent/JP3023493B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05237631A (en) | 1993-09-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |